TIU CHUN NH NC Nhm I

TCVN
3795-83

NATRI HIDROXIT K THUT
Phng php xc nh hm lng natri hidroxit tng lng
baz v natri cacbonat
Sodium hidroxide technical
Method of test for sodium hidroxide, total of alkaline and
sodium carbonate contents
C hiu lc t 1-7-1984
Tiu chun ny quy nh phng php chun xc nh natri hidroxit vi hm lng ln
hn 10 %, tng lng baz trn 10 % v natri cacbonat trong khong t 0,1 % n 3 %.
1 . QUY NH CHUNG
1.1.Khi tin hnh th nu khng c ch dn no khc, phi dng thuc th loi tinh khit
phn tch ( TKPT) v nc ct theo TCVN 2117-77.
1.2 Ly mu theo TCVN 3794-83
1.3. tin hnh th, phi chun b dung dch theo quy nh di y:
Cn 60 g mu trong cc cn c nt kn vi chnh xc 0,01 g, chuyn ht mu cn sang
bnh nh mc dung tch 1 lit. thm nc ct n vch mc, lc u.
Cha dung dch vo chai polyetylen kh, sch, c nt kn khi mu lu
2. PHNG PHP XC NH HM LNG NATRI HIDROXIT
2.1. Nguyn tc
Dng dung dch axit clohidric chun tng lng baz trong dung dch vi ch th
metyl da cam. Hm lng natri hidroxit l hiu ca tng lng baz v hm lng natri
cacbonat c xc nh theo 3.4.2.
2.2. Thuc th v dung dch
Axit clohidric, dung dch 1 N
Metyl da cam, dung dch 0,1 % trong nc.
2.3. Tin hnh th
Dng pipet ht 50 ml dung dch chun b theo iu 1.3 cho vo bnh nn dung tch 250
ml, thm 2 git metyla da cam ri chun vi dung dch axit clohidric n khi dung dch
chuyn t mu vng sang mu da cam.
2.4. Tnh ton kt qu
2.4.1 Hm lng natri hidroxit ( X) tnh bng phn trm theo cng thc:

V. 0,04 . 100 . 1000
X =
M. 50
- 0,7547 . X
2



V. 80
X =
M
- 0,7547 . X
2


trong :
V-lng dung dch axit clohidric 1 N tiu tn khi chun , tnh bng ml;
M-khi lng mu th, tnh bng g;
X
2
- hm lng natri cacbonat xc nh c theo iu 3.4.2;
0,04-lng natri hidroxit tng ng vi 1 ml dung dch axit clohidric ng 1
N, tnh bng g;
0,7547- h s tnh chuyn natri cacbonat ra natri hdroxit.
2.4.2 Kt qu cui cng l trung bnh cng ca t nht hai kt qu xc nh song song khi
chnh lch gi cc kt qu khng vt qu 0,5 % so vi kt qu nh nht.
3. PHNG PHP XC NH TNG HM LNG BAZ V NATRI
CACBONAT
3.1. Nguyn tc
Dng axit clohidric chun mu th vi ch th fenolftalein, sau vi ch th metyla da
cam. Ln chuyn mu theo ch th fenolftalein tng ng vi lng natri hydroxit v mt na
lng natri cacbonat.
3.2. Thuc th v dung dch
Axit clohidric, dung dch 0,1 N v 1N,
Fenolftalein, dung dch 0,1 % trong ru etylic;
Metyl da cam. dungdch 0,1 % trong nc;
Nc ct khng cha cacbon dioxit chun b theo TCVN 1055-71.
3.3. Tin hnh th
Dng pipet ht 50 ml chun b theo iu 1.3, cho vo bnh nn dung tch 500 ml, thm
vo khong 50 ml nc ct khng cha cacbon dioxit. Sau thm 3 git dung dch
fenolftalein. Dng axit clohidric 1 N chun n mt mu. Xc nh gn ng lng axit
clohidric 1 N tiu tn.
Dng pipet ht 50 ml dung dch chun b theo iu 1.3. cho vo bnh nn dung tch 500
ml, thm 50 ml nc ct khng cha cacbon dioxit. Dng dung dch axit clohidric 1 N
chun vi fenolftalein n khi kt thc ( lng axit clohidric 1 N chun nh hn 0,5 ml
n 1 ml so vi ln chun d trc) th dng li. Dng axit clohidric 0,1 N chun tip cho
n khi kt thc. Lng axit clohidric tiu tn V
2
( K c lng axit clohidric 0,1 N sau khi
quy v 1 N). Thm 2 git dung dch ch th metyla dacam ri tip tc chun cho n lc mu
chuyn t vng sang vng da cam ( V
1
).
3.4. Tnh ton kt qu
3.4.1. Tng lng baz ( X
1
) chuyn ra natri hydroxit, tnh bng phn trm theo cng thc:

V
1
. 0,04. 1000. 100 V
1
. 80
X
1
= =
M .50 M
3.4.2. Hm lng natri cacbonat ( X
2
) tnh bng phn trm theo cng thc:

( V
1
- V
2
) . 0,053. 1000. 100 ( V
1
V
2
) .212
X
2
= =
M.50 M
trong :
V
1
- lng dung dch axit clohydric tiu tn trong qu trnh chun dung dch th vi ch
th fenolftalein v metyla da cam tnh bng ml;
V
2
- lng dung dch axit clohydric tiu tn trong qu trnh chun dung dch th vi ch
th fenolftalein tnh bng ml;
M- khi lng mu th, tnh bng g;
0,04- lng natri hydroxit tng ng vi 1 ml dung dch axit clohydric ng 1N, tnh bng
g.
3.4.3 Kt qu cui cng l trung bnh cng ca t nht hai kt qu xc nh song song khi
chnh lch gi cc kt qu khng vt quy nh:
i vi natri hydroxit 0,5 %
i vi natri cacbonat 5 %
so vi kt qu nh nht