Professional Documents
Culture Documents
equilibriaandLeChateliersPrinciple PDF
equilibriaandLeChateliersPrinciple PDF
equilibriaandLeChateliersPrinciple PDF
DYNAMIC
EQUILIBRIA
DYNAMIC
Thereactionstakeplaceatthe
samespeed.
Allreactantsandproductsare
present.
EQUILIBRIUM
Theforwardandreversereactions
arebothtakingplace.
Theconcentrationofallreactants
andproductsremainconstant.
DYNAMICEQUILIBRIUM
2HI(g)34H
2
Imagineyoustartwith0.100MHI.Itbreaksdown
toformH
2andI
2
.However,H
2
andI
2
reacttoformHI.
Afteratime,equilibriumisreachedwiththerateat
whichHIdecomposesequalstherateatwhichit
isformed.
(g)+I
2
(g)
(mqre
lieft
iesi
whenequilibriumliestothe
left:
therearemorereactants
thanproducts(i.e.moreH
2
andN
2
thanNH
3
)
3H
2
(g)+N
2
(g)342NH
3
(g)
hriumlies
EqUilitotheright
whenequilibriumliestothe
right:
therearemoreproducts
thanreactants(i.e.moreNH
3
thanH
2
andN
2
)
3H
2
(g)+N
2
(g)342NH
3
(g)
Makeithotterequilibriummovesto
coolit.Makeitcolderequilibrium
movestoheatit.Raisethepressure
equilibriummovestolowerit.Lowerthe
pressureequilibriummovestoraise
it.Addachemicalequilibriummoves
togetridofit.Removeachemical
equilibriummovestomakemore.
Iftheconditionsofanequilibrium
arechanged,thepositionofthe
equilibriummovestoopposethe
change.
LECHATELIERSPRINCIPLE
[Co(H
2
addCl
addH
2
addCl
THEEFFECTOF
CONCENTRATION
O)
6
O
pinkblue
O
]2++4Cl34[CoCl
4
]2+6H
2