.

5

2 (
60) 2
( )
www.krookook.com
.. 2554


.......................................................................................... 1
.................................................................................. 8
...................................................................................... 20
..................................................................................... 44

 | 1

(Rate of Chemical Reaction)

3
1. ..
2. ..
3. ..
(Ea)
1
1.1)

H2O + CO CO2 + H2

1.2)

NO2 + CO CO2 + NO

3 ...
..

[]

Ea

Ea

Ea

2 | 6

.
2
2.1) 2KMnO4(s) + 16HCl(aq) 2KCl(aq) + MnCl2(aq) + 8H2O(l) + 5Cl2(g)

2.2) 2NO(g) + O2(g) 2NO2(g)

2.3) 2Al(s) + 2NaOH(aq) + 6H2O(l) 2NaAl(OH)4(aq) + 3H2(g)

2.4) Cu(s) + S(s) CuS(s)

..

( )
-
()

3
3.1) 2KMnO4(s) K2MnO4(s) + MnO2(s) + O2(g)

3.2) H2O2(l) +2H+(aq) + 3I-(aq) I3-(aq) + 2H2O(l)

3.3) 2NO2(g) 2NO(g) + O2(g)

3.4) 2Al(s) + 2NaOH(aq) + 6H2O(l) 2NaAl(OH)4(aq) + 3H2(g)

3.5) 2HCl(aq) + Na2S2O3(aq) 2NaCl(aq) + H2O(l) + SO2(g) + S(s)

 | 3

........................................................ ..
H2O2(l) +2H+(aq) + 3I-(aq) I3-(aq) + 2H2O(l)
-

..

..

..
4
4.1) 2Al(s) + 2NaOH(aq) + 6H2O(l) 2NaAl(OH)4(aq) + 3H2(g)
..
..
4.2) 2KMnO4(s) + 16HCl(aq) 2KCl(aq) + MnCl2(aq) + 8H2O(l) + 5Cl2(g)
..
..
5 2A + B 3C A [A] = 5.0 0.6
t1/2
5.1) A
.
5.2) B

5.3) C

5.4)

4 | 6

...............

...................................

.......................................

6 2O3(g) 3O2(g)
O3
y ............................................
x

y ............................................
x

7 NO2(g) + CO(g) NO(g) + CO2(g)

NO2
y ............................................
x

y ............................................
x

 | 5

8

y ............................................
x

y ............................................
x

9 D + E F D E

1
2
3
4

[D]
(mol/dm3)
1.0
2.0
3.0
1.0

[E]
(mol/dm3)
1.0
1.0
1.0
2.0

(mol/dm3min)
0.15
0.30
0.45
0.15

9.1 ..........................................
9.2 ........
9.3
...................................................
9.4

9.5 ........................

6 | 6

10 2A + B C A B

1
2
3
4

[A]
mol/dm3
0.20
0.20
0.10
0.30

[B]
mol/dm3
0.10
0.20
0.10
0.10

C 0.5 mol (s)
20
10
80
....

10.1 ..........................................
10.2 ........
10.3
...................................................
10.4

10.5 ........................
11
11.1) X + Y 2Z

R = k[X]

[X] [Y] [Y] [X] Rx, RY

11.2 2P + Q S

R = k[P]2[Q]

[P] [Q] [Q] [P] Rx, RY

 | 7

.................................................................................................................................


..................................................................................................................................

.....................................................................................................................

8 | 6

1. 2Na + 2C3H7OH 2C3H7ONa + H2 Na 11.5 g C3H7OH 40.0 g
10 C3H7OH g/min (Na = 23 C3H7 = 60)
1. 1.15

2. 3.00

3. 4.00

4. 6.00

2. T1 T2

x

T1

1. T1 T2

T2

2. T1 T2
3. T1 T2
4. T1
y

T2

3. (C2H4N2) C2H6N2 C2H6 + N2

(min) C2H6N2 (mol)

0
0.36
15
0.30
30
0.25
48
0.19
75
0.13

1. C2H6N2 0.11 mol 30

2. C2H6N2 50
3. C2H6N2 15 0.004 mol/min
4. C2H6N2 75 0.0017 mol/min

 | 9

4. A B

A
mol/dm3
1
0.1
2
0.2
3
0.1
4
X
X mol/dm3

B
mol/dm3
0.1
0.1
0.2
0.1

1. 0.011

2. 0.2

3. 0.033

4. 3.0

mol/dm3.s
8.40 10-5
16.80 10-5
33.60 10-5
2.80 10-5

KMnO4 H2C2O4 H2SO4

2 KMnO4 + 5H2C2O4 + 3H2SO4 K2SO4 + 2 MnSO4 + 8 H2O + 10CO2

(mol/dm3)
(cm3)

KMnO4
0.005
2

H2C2O4
0.2
1

H2SO4
0.02
2

5. 2
1.
2. pH
3. H2C2O4 0.0001 mol/dm3.min
4. CO2 0.56 mol/min
6.
1.
2.

3.

4. KMnO1

10 | 6

7. 2X2O5(g) 4XO2(g) + O2(g) X2O5

A
0-1500 mol/dm3s
1. 8.0 , 3.010-3
2. 8.0 , 1.510-3
3. 6.5 , 3.010-3
4. 6.5 , 1.510-3

[X2O5] (mol/dm3)
A
6.3
4.8
3.5
2.4
1.5

(s)
0
500
1000
1500
2000
2500

. M + A C + X

Ea = 52 kJ

. X + B

C+Y

Ea = 25 kJ

. Y + B

Ea = 12 kJ

8.
1. A

2. B

3. M

4.

9.
1. M + 2B 2C

2. M

3. Y

4. C

10.
-

2ClO2 (aq) + 2OH (aq) Cl (aq) + Cl (aq) + H2O (I)

[ClO2] (M)
1
0.01
2
0.02
3
0.01
4
0.02
5
0.02
a m

[OH] (M)
0.01
0.01
0.02
0.02
A

1. 0.04 , 28.0 104

2. 0.04 , 14.0 104

3. 0.08 , 28.0 104

4. 0.02 , 14.0 104

(M/s)
3.5 104
14.5 104
7.0 104
m
56.0 104

 | 11

11. Mg + 2 HCl MgCl2 + H2 Mg

()
(g)
0
3.00
50
2.00
100
1.20
150
0.60
200
0.10
250
0.75
50-100
g.s-1
1. 0.016 : 0.009

2. 0.016 : 0.003

3. 0.018 : 0.009

4. 0.024 : 0.015
-

12. 2 Mn + 16 H+ + 5C2
C2

2 Ma2+ + 8 H2O + 10 CO2

17.6 g/s ( 1 g/cm3)

1. Mn

9.52 g/s

2. 5.76 cm3/s
3. Mn2+ 0.008 mol/s
4. CO2 STP 8.96 dm3/s
13. I + ClO IO + Cl

[I] mol/dm3
[ClO] mol/dm3
1
0.01
0.02
2
0.02
0.01
3
0.01
0.01

IO mol/s
12.2 102
12.2 102
6.1 102

I. IO I CIO
II. [I] = 0.01 mol/dm3 [CIO] = 0.005 mol/dm3 IO 3.05 102 mol/s
III.
1.

2. 1

3. 2

4. 3

12 | 6

14. 2A + B + C 3D + E
[A] (mol/dm3) [B] (mol/dm3)
1
0.1
0.2
2
0.2
0.2
3
0.1
0.2
4
0.1
0.1
5
0.3
0.2
R (mol/dm3.s)
1. 4.0 102
3. 7.5 103

2.
4.

[C] (mol/dm3) (mol/dm3.s)

0.1
2.5 103
0.1
5.0 103
0.2
1.0 102
0.2
1.0 102
0.1
R

1.0 102
5.0 103

15.
1

P(aq) + A(aq) + X(s) Y(aq) + C(aq)

()

C(aq) + D(aq) 2 Z(g) + E(aq)

( )

Z(g) + Y(aq)

E(aq) + X(s)

( )

. A(aq)

. D(aq)

. A(aq)

. X(s)

. P(aq)
1. . . . . .

2.

. . . .

3. . . .

4.

. .
-

16. 4Mn2+ (aq) + 6H2O(l) + 5O2(g) 12H+ (aq) + 4Mn (aq) MnSO4
1 mol/dm3 100 cm3 O2 Mn2- = 0.02 mol/dm3.s
O2
1. 0.05 mol/dm3.s

2. 0.0025 mol/s

3. 0.64 g/s

4. 0.56 dm3/s STP

 | 13

17. (H2C2O4) KMnO4

H2SO4 KMnO4 KMnO4
2 KMnO4 + 5 H2C2O4 + 3 H2SO4 K2SO4 + 2 MnSO4 + 8 H2O + 10CO2

(cm3)

KMnO4
K2C2O4
H2SO4
MnSO4
(0.005 mol/dm3) (0.05 mol/dm3) (1 mol/dm3) (0.1 mol/dm3)
1
2
2
1

2
2
2
1

3
2
2
1
3
4
4
4
2

(oC)
15
25
25
15

1. 3 2 3 2
2
2. 2 1 2 1

3. 4 1 4

4. 4 2 4

18. 2A(s) + 3B(aq) C (aq) + 3 D(g) A 21.6 g B

3 mol/dm3 500 cm3 A, B, C, D
( A = 27)
1.

2.

3.

4.

14 | 6

19.

A) 2 Mn (aq) + 16 H+ (aq) + 5S2 2 Mn2+ (aq) + gH2O(1) + 5S(s)

B) 2 Al(s) + 2 NaOH (aq) + 6H2O 2 NaAI(OH)2 (aq) + 5 H2(g)
-

C) 2 S2 (aq) + Br2 (aq)) 2 S4 (aq) + 2 Br2 (aq)

D) N2 (g) + 3 H2(g) 2 NH3 (g)

H2

H2

Al

H2

S2

S2

20. X 2 A

B 4 C (
)
1.

2.

3.

4.

 | 15

21. 2 X(s) + 3 Y(aq) 2 Z(aq) + Q(aq)

2
I II

kJ

1. 100 kJ
2. I A C II F H
3. I II
4. I II
22. 2
( )
1

A + B C
1. 1 2
2. 1 Ea 2
3. 1 2
4. 3 1 1 2

16 | 6

23. Tx Ty
AB + XB2 XB + AB2

Tx Ty

Tx

. Tx
. Tx

Ty

. Tx
. Tx

1. 1

2. 2

3. 3

4. 4

24. NaOH

1.
2.
3.
4.
25.
1.

2. E

3.

4. E

 | 17

26. B X A

1. 10,100 kJ
2. 3
3. A B X
4. 3900 kJ
27. A P

1

A + X AX

AX PX

PX P + X

(kJ)
1. X A P
2. AX PX
3. A P 1000 kJ
4. A + X 3500 kJ P

18 | 6

28. 3 1)

Cl2 2 Cl

2)

N2O + Cl N2 + ClO

3)

ClO + ClO Cl2 + O2

1. Cl2
2. Cl2
3. Cl2
4. Cl2
29.
I

II
III
IV

1. I II III IV

2. II III

3. III IV

4. III

30. CaCO3(s) + 2HCl(aq) CaCl2(aq) + H2O(l) + CO2(g)

2 CaCO3
1

CaCO3 10 g HCl 2 mol/dm3 500 cm3 40oC

CaCO3 10 g HCl 1.5 mol/dm3 800 cm3 60oC

2 1
1. 2
2. 2
3. 2 = Ea
4. 2 1

 | 19

31. A (s) + B (aq) X (aq) + Y (g) +

. A . B
.

1.

2.

3.

4.

32. 4Mn2+(aq) + 6H2O(l) + 5O2(g) 12H+(aq) + 4MnO4-(aq) MnSO4 1

mol/dm3 100 cm3 O2 Mn2+ = 0.02 mol/dm3s
O2
1.

0.05 mol/dm3s

2.

0.0025 mol/s

3.

0.64 g/s

4.

0.56 dm3/s STP

20 | 6

1
1.
1)
2)
3)
4)
2. 1 cm3 0.1 / 20 cm3

1) Zn

2) Zn

3) HCl

4) HCl

3.
1)
2)
3)
4)
4.

1)

2)

3)

4)

5.

1)

2)

3)

4) 1, 2 3

 | 21

6.
1) 1 1 HCI 0.1 mol/dm3
2) 2 0.5 HCI 0.2 mol/dm3
3) 1 HCI 0.1 mol/dm3
4) 1 HCI 0.2 mol/dm3
7.
1)
2)
3)
4)
8. 1 4 A D
1.

Cl2 (g) + 2 Br- (aq) Br2(1) + 2 Cl- (aq)

2.

I2 (s) + 2S2O2-3 (aq) 2I- (aq) + S4O2-6 (aq)

3.

3H2(g) + N2(g) 2NH 3(g)

4.

CO2(g) + H2O(I) HCO-3 (aq) + H+(aq)

B PH

1 4
1) D, C, A, B

2) D, A, C, B

3) D, C, B, A

4) D, B, A, C

9.
1)
2)
3)
4)

22 | 6

10. N2O5 N2O5

2N2O5(g) 4NO2(g) + O2(g)
NO2 O2

1) O2
2) O2
3)
4)
11.
1)
2)
3)
4)
12.
1.

2.

3.

4.

1) 1, 2 3

2) 1 3

3) 2 4

4) 4

13. V3+ V4+ 2

V3+ + Cu2+ V4+ + Cu+
Cu+ + Fe3+ Cu2+ + Fe2+

1) V4+

2) Cu2+

3) Fe3+

4) Fe2+

 | 23

14. 1 M HCI 25 cm3

1) 1 M HCI 100 cm3

2) 2 M HCI 25 cm3

3) 2 M HCI 5o cm3

4)

15. Mg(s) + 2HCl(aq) MgCl2(aq) + H2(g)

1)
2)
3)
4)
16.

1)
2)
3)
4)
17.
1)
2)
3)
4)
18.

1)
2)
3)
4)

24 | 6

19.
1)
2)
3)
4)
20.

1)
2) g
3)
4)
21. X ( ) Y ( )

. X
5
. X

. X

. X

. X
5

1) X
2)
3) X
4) X

 | 25

22. X(s) + Y(aq) Z(g)

1.

2.

3.

4.

X Y

1) 1 2

2) 2 3

3) 3 4

4) 1 4

23. A+B P
A B

1) A
2) P
3) A B
4) A P
24.
2A(g) + B(s) C(g) + D(g)
1.

2.

B C D B

3.

30 kJ/mol 30 kJ/mol

4.

A
A

1) 1 2

2) 3 4

3) 1 4

4) 2 3

26 | 6

25. 1)
( 2)

1.

2.

3.

4.

1) 1 2

2) 1 3

4) 3 4

4) 2 4

 | 27

2
1. A(s) + B(aq) C(aq) + D(g)
1) A B
2) D B
3) A
4) A
2. A(aq) + B(aq) C(aq) + D(aq)
1)
2)
3) A
4) C
3. 10C
90% 20 20C

1) 2.5

2) 5

3) 10

4) 15

4.
1 cm3
50, 100,
150, 200 300
1) 50

2) 150

3) 200

4) 300

28 | 6

A B 5-8

A
B
()
()
-5
1
1.2 x 10
4.2 x 10-5
2
2.4 x 10-5
8.4 x 10-5
3
4.8 x 10-5
8.4 x 10-5
4
4.8 x 10-5
4.2 x 10-5
5.

(
)
6.2 x 10-4
2.48 x 10-3
4.96 x 10-3
2.48 x 10-3

1) 1, 2 A B
A B
2) 2, 3 B A
3) 1, 3 A B
A B
4) 3, 4 A B

6. V = , k =
(A) = A , (B) = B

1) 1, 2 V = k(A)(B)
2) 1, 3 V = k(A)(B)
3) 2, 3 V = k(A)
4) 3, 4 V = k(A)
7. V = k(A)(B)
1) 1
2) 2 3
3) 3 4
4)
8. k
1) 1.23 x 106

2) 1.03 x 102

3) 0.96 x 10-3

4) 0.71 x 10-7

 | 29

9-10
A + B C


( )

( )
A
B
1
0.010
0.010
2.0
2
0.010
0.020
4.0
3
0.030
0.020
12.0
9. r =
K =
(A) = A (B) = B

1) r = k(A)

2) r = k(B)

3) r = k(A)(B)2

4) r = k(A)(B)

10. k ( )
1) 2.0 x 106

2) 2.0 x 104

3) 2.0 x 102

4) 20

11.

(C)
()
16
400
40
50
56
12.5
2
1) 8 C

2) 10 C

3) 12 C

4) 16 C

30 | 6

12. (Hb) (CO) 20 C , pH 7.3

4Hb + 3CO Hb4 (CO)3

Hb
(mol / dm3)
(mol / dm3 sec)
(Hb)
(CO)
3.00
1.00
0.90
6.00
1.00
1.80
6.00
2.00
3.60
Hb 3.0 mol/dm3 CO 2.00 mol/dm3 Hb
mol/dm3
1) 0.90

2) 1.80

3) 2.70

4) 3.60

13. X
5 cm3 20C
(C)

()

30

100

40

50

50

25

1) 150

2) 200

3) 250

4) 300

14. A P
A P A
, s
0
50
100
150
100
1) 0.0048 mol/dm3

(A) , mol / dm3

1.00
0.61
0.37
0.22
2) 0.0030 mol/dm3

3) 0.0030 0.0048 mol/dm3

4) 0.0078 mol / dm3

 | 31

15.
A + B 25 C

Mol/l.s
0.001
0.001
1.000
0.002
0.001
2.000
0.003
0.001
3.000
0.004
0.001
4.000

A
Mol/l

B
Mol/l

1) A
2) B
3)
B A
B
4) B 100
16. A + B C
(A)
(mol / dm3)
1
1.0
2
2.0
3
3.0
4
1.0
5
1.0

(B)
(mol / dm3)
1.0
1.0
1.0
2.0
3.0

(mol / dm3.min)
0.15
0.30
0.45
0.15
?

1) 5 = 0.15 mol / dm3.min

2) (B)
3) (A)
4) = k(A) k = 0.15 min-1

32 | 6

17. A P A
(s)

(A) (mol/dm3)

2.0

100

1.0

200

0.5

300

0.25

A 3.0 mol / dm3 1.5 mol / dm3

1) 50

2) 100

3) 150

4) 200

18.
A + 2B C

A
B
Cm3
3
3
0.1 mol/dm
0.2 mol/dm
1
10.00
10.00
10.00
2
15.00
10.00
5.00
3
15.00
5.00
10.00

(s)
16
16
8

1) A B
2) A
3) B
4) B A
19. A B C
0, 2 0 A, B C

1) = k (A)(B)2

2) = k (B)2

3) = k (A)(B)

4) = k (A)(B)2(C)

 | 33

20. X Y 100 kJ/mol

75 kJ/mol X Y
1) 25 kJ / mol

2) 175 kJ / mol

3) 25 kJ / mol

4) 175 kJ / mol

21.
1)
2)
3)
4)
22.

.
.
.
.

1)

2)

3)

4)

23.
.

1)

2)

3)

4)

24.
10

C
B

( y x )
1) A
3) C

2) B
4) D

34 | 6

3
1. Zn(s) HCl(aq)
Zn(s) + 2HCl(aq) ZnCl2(aq) + H2(g)
(s)

20

30

50

70

H2(cm3)

1)
2)
3)
4)
2.
1)
2)
3)
4)
3. CaCO3(s) + 2HCl(aq) CaCl2(aq) + H2O(l) + CO2(g)

1)
2)
3)
4)

4.

1)
2)
3)
4)

 | 35

5. X Y Z
X Y Z

1. X Y Z Z > Y > Z
2. X, Y Z
3. Z > Y > X

1) 1 2
3) 1 3

2) 2 3
4) 1 2 3

6. T1 T2 T3
(T1 < T2 < T3)
1)
2)
3)
4)

T1
T2
T3
T1
T2

7.
5C2O42-(aq) + 2MnO4-(aq) + 16H+(aq) 10CO2(g) + 2Mn2+(aq) + 8H2O(l)

1) CO2 2)
3) C2O42- 4) MnO4-

36 | 6

8. 2A 3B A 0.568 m 0.552 m 2.50

B
1) 1.60 x 10-4M/

2) 1.07 x 10-4M/

3) 7.11 X 10-5M/

4) 3.55 x 10-5M/

9. X Y Z 1/3
X 2 Y
Z
1) 3x + 2Y Z

2) 6X + Y 4Z

3) 3X + 2Y 3Z

4) 1/3 X + 2Y Z

10. 2A + 3B

1) C > A >
B
2) x1 = 15, x2 = 13, x3 = 12
3) A 0 2
3 C 2 4
4) y1 = 3, y2 = 5, y3 = 6
11. N2O5 2N2O5 4NO2 + O2 N2O5 1.8x10-5
5
1)
2)
3)
4)

NO2 = 9.0x10-5 mol

NO2 = 4.5x10-5 mol
O2 = 18x10-5 mol
O2 = 4.5x10-5 mol

12. A B 90 40 10OC
2 A 90 10

1) 10
3) 30

2) 20
4) 40

 | 37

13. Mg(s) +
2HCl(aq) MgCl2 (aq) + H2 (g)
H2 (cm3)

(s)

12

13

40

60

89

1)
2)
3)
4)

40 H2 = 3/40 cm3/s
H2 = = 5/89 cm3/s
H2 1 cm3
H2

14. (NO) Cl2

(NOCl) 0.030 mol/dm3.s

1) 0.015

2) 0.030

3) 0.060

4) 0.010

15. 2N2O5(g) 4NO2(g) + O2(g) 2

1
2

(s)

O2 (mol/l)

600

0.0021

1,200

0.0036

4,200

0.0072

4,800

0.0075

1)
2)
3)
4)

5
2

38 | 6

16. A 2C

1)
2)
3)
4)

(min)

[A] (10-2mol/dm3)

10

1.94

50

1.71

120

1.38

170

1.18

200

1.08

A 224
A 0.02 mol/dm3
A 4.53 x 10-5 mol/dm3.min
A

17.
1)
2)
3)
4)

Ea (kJ)

E (kJ)

70

+30

90

-40

110

+20

50

-15

B = 40 kJ
A Ea = 100 kJ
C = 20 kJ
D Ea 65 kJ

18. A P A P (E) 48 kJ/mol

(Ea) = 120 kJ/mol
1) Ea > 120 kJ/mol
2) A P Ea
3) Ea = 120 kJ/mol > Ea
4) A
19. A + 2B 3C+5D A B C
D 250 kJ 510 kJ

1) 260 kJ

2) 260 kJ

3) 760 kJ

4) 760 kJ

 | 39

20. A + B C + D

1) a + b + c
2) b + c + d
3) a + b
4) b
21. 20
1) d
2) c
3) d
4) a + b + c
22.

R(s) P(s) 2 ( A B)
R

1) A B
2) A B
3) B
4) R B
23. A B 0.5 mol/dm3 2 cm3
1.0 mol/dm3 1 cm3 0.05 mol/dm3
2 cm3 A 40C B 60C 1,800
A B
A 1,200 B
A
1) 3.0

2) 2.5

3) 1.5

4) 0.33

40 | 6

24. 10C
30
20C
1) 2.5

2) 5

3) 7.5

4) 10

25.
2 A(aq) B(aq) A (t)
[A] = 4 - t 4
1) 0.125

2)

0.250

3) 0.375

4)

0.500

26. X Y X (g) + 3Y (g) XY3 (g)

(X)
(Y)

mol/dm3
mol/dm3
1
0.10
0.10
2
0.10
0.20
3
0.10
0.30
4
0.30
0.10
1) Y

XY3
mol/(dm3,s)
0.10
0.04
0.09
0.03

2) X Y
3) X Y
4) Y X
27. P + Q R
P (M)

Q (M)

R (M/s)

1.5

1.0

0.08

1.5

1.5

0.18

3.0

1.5

0.36

3.0

1.0

4 mol/L.s
1) 0.0027

2) 0.0016

3) 0.160

4) 0.240

 | 41

28.

A ( ) B ( ) ( )

1.2 x 10-5

4.2 x 10-5

6.2 x 10-6

2.4 x 10-5

8.4 x 10-5

2.48 x 10-5

4.8 x 10-5

8.4 x 10-5

4.96 x 10-5

4.8 x 10-5

4.2 x 10-5

2.48 x 10-5

1) 1 4 A
2) 2 3 A
3) 3 4 B
4) [A] [B]
29. A B C D
A + 4B + 2C

3D A B

(mol/dm3)

1)
2)
3)
4)

[A]

[B]

[C]

(mol/s)

0.1

0.1

0.1

0.2

0.2

0.1

0.1

0.4

0.2

0.2

0.1

1.6

0.2

0.2

0.2

1.6

[ A ] = 0.2 [ B ] = 0.1 [ C ] = 0.3 0.4 mol/s

A, B C A
C
D

42 | 6

30. A2 + B2 2AB
10 kJ
1) A2 + B2 2AB = 70 kJ

(kJ)

2) 2AB A2 + B2 = 45 kJ
3) A2 + B2 2AB = 25 kJ

4) 2AB A2 + B2 = 15 kJ
31. A + B C

[A] (mol/dm3)

[B] (mol/dm3)

Rate (mol/dm3.min)

1.0

1.0

0.15

2.0

1.0

0.30

3.0

1.0

0.45

1.0

2.0

0.15

1.0

3.0

1) 5 = 0.15 mol / dm3.min
2) [B]
3) [A]
4) = k[A] k = 0.15 min-1
32. A + B + 2C D + 2E
[A] mol/dm3 [B] mol/dm3 [C] mol/dm3
1
0.01
0.01
0.01
2
0.02
0.01
0.01
3
0.01
0.01
0.02
4
0.01
0.02
0.02
5
0.03
0.01
0.03

1) A B

2) B C

3) A C

4) A B C

R mol/dm3 s1
0.24
0.48
0.24
0.48
0.72

 | 43

33. 2
1 A + B 2C
2 A + 2B D
A B 10
5
. A B 2 2
B 1
. A 1 2 A 2
. C D
. C D

1) .

2)

3)

4)

44 | 6

1
1-5

6-10

11-15

16-20

21-25

3
1
4
3
4

4
1
1
3
3

3
2
2
1
2

2
3
3
3
3

3
4
4
3
1

1-5

6-10

11-15

16-20

21-24

4
4
2
1
4

4
3
1
4
2

1
2
2
3
2

2
2
4
2
3

1
2
4
4

1-5

6-10

11-15

16-20

21-25

26-30

31-33

1
4
2
3
2

3
4
1
2
3

4
2
1
1
3

4
4
2
4
2

1
1
1
3
1

4
1
4
1
3

2
1
3