M T Cr

Pf M.,alb-arg, lucios, greu,se top. La 1900 C

Pc f. resist. La ag. corozivi obisnuiti, stabil fata d apa si aer
R. nm -rc la t mari cu X2=> CrX3, O2=> Cr2O3, S2=>Cr2 S3
R. H2O Cr+H2O=>Cr(OH)3+ H2
R. ac Rc cu ac. Neox si ox cu degajare de H2.Pasiv fata de HNO3 dil si conc si apa regala la rece
R. baz Rc cu hiroxizii alc in topitura
Compusii
NO -2;-1;0;+1 (numai in CC)
+4;+5 (comp. putini stabili sau intermediari in rc)
+2;+3;+6 comp stabili

Combinatii Cr
II
Cr
III
Cr
VI

Prop. A-b, si redox Sol. Ap. [Cr(H2O)6]
2+
Red. Puternic (mai put. Decat Fe
2+
)
Sol.Ap. [Cr(H2O)6]
3+
, ac. Br.s
-amf. Rdox(o,r slab)
Ox:CrCl3+Zn->CrCl2+ZnCl2

Rd:CrCl3+KNO3+Na2CO3->Na2CrO4+KNO2+NaCl+CO2

Na[Cr(OH)4]+NaClO+NaOh->Na2CrO4+NaCl+H2O

Halogenuri -solide:-anh-albe
-hidr.-col,s.in H2O
CrCl26 H2O
-solide anhr-rosii,g.s. in H2O
-hidr-col,u.s in H2O
CrCl36 H2O
Cr+F2 -putin sol
Dioxodialogenurile:
CrO2F2;
K2Cr2O7+KCl+H2SO4->CrO3Cl2+K2SO4+H2O
Hidr. Usor: CrO2Cl2+H2O->H2CrO4+HCl
Rc. Cu b.alc: CrO2Cl2+NaOH->Na2CrO4+NaCl+H2O


Oxidul -CaO-solid, g.in H2O Obt: Cr+O2->Cr2O3
K2Cr2O7+C->Cr2O3+K2CO3+CO2-
g.s.in H2O
K2Cr2O7+H2SO4->CrO3+K2SO4+H3O,ox.putr,toxic
Anhidrida ac. Cromici H2CrnO3n+1
n=1 ac.cromic; n=2 dicromic; n=3 tricromic

Hidroxid. - caract.bazic. prop. Red.
sare de Cr
II
+ hidr. alc
-pp. Cr(OH)3-carct. Amfoter,HO alc/CO3 alc/NH3 +
sare de Cr
+HCl->CrCl3+ H2O
+NaOH->Na[Cr(OH)4]

Sulfura Cr+S->Cr2S3-s.in H2O, in sol nu se poate obt. Din
cauza rc. De hidr
CrCl3+(NH4)2S+H2O->Cr(OH)3+H2S+NH4Cl

Oxoacizi CrO3+H2O->H2CrO4
Sar.ac.cromici:
CROMATi-solide,sol:Na2CrO4,K2CrO4
g.sol:
DICROMATI-se ob prin ac sol ap de cromati
Sol:Na2Cr2O7,K2Cr2O7,(NH4)2Cr2O7
g.sol:Ag2Cr2O7
c.ox.puternic:ox:I
-
la I2, Fe
2+
la Fe
3+
,HNO2 la HNO3
NaNO2+K2Cr2O7+H2SO4->NaNO3+Cr2(SO4)3+K2SO4+H2O
FeSO4+K2Cr2O7+H2SO4->

Sarurile oxoac. CrSO47 H2O sol.in H2O Cr2(SO4)318 H2O s.in H2O / 6 H2O
Cr(NO3)3 9H2O -s.in H2O

Comb. Comp. Geom.octa- NC=6 [Cr(CN)6]
4-

Geom.tetra.-NC=4 Cr(acac)2
paramg. Col.In a / v
NC=6 :-cationice [Cr(H2O)6]
3+
,[Cr(NH3)6]
3+
-anionice
-neutre Cr(pic)3