Phuong Phap Lam BTTN Hoa 11 Nguyen Hien Hoang

TRCH TI LIU NGUYN HIN HONG- NGUYN CU PHC- L NGC T- khi 11
CHNG 1: S IN LI
Bi 1: S IN LI
I. Ph !" #$%
Cu 1: Vit pt in li ca cc cht sau y trong nc:
a. H
2
!
"
# HCl!
"
# $a!H# %a&!H'
2
# ()
2
&!
"
'
*
# +l&$!
*
'
*
.
,. HCl!# -Cl!
*
# &$H
"
'
2
!
"
# $aHC!
*
# -
2
!
*
# $a
*
.!
"
# Ca%r
2
# $a
2
C!
*
.
c. H
*
.!
"
# H
2
# H
2
C!
*
# H
2
!
*
.
Cu 2: /0nh n1ng 2 3ol4l ca cc ion trong 55 sau:
a. 166 3l 55 ch7a "#28g +l&$!
*
'
*
.
,. 6#2 l0t 55 ch7a 11#9g $aCl.
Cu *: /0nh n1ng 2 cc ion trong 55 thu :c ;hi:
a. /r2n 2663l 55 $aCl 2< =i 2663l 55 CaCl
2
6#><.
,. /r2n "66 3l 55 ()
2
&!
"
'
*
6#2< =i 1663l 55 ()Cl
*
6#*<.
c. /r2n 2663l 55 ch7a 12g <g!
"
=? *66 3l 55 ch7a *"#2g +l
2
&!
"
'
*
.
Cu ":
a. /0nh th@ t0ch 55 -!H 1"A &BC1#12Dg43l' cE ch7a sF 3ol !H
G
,Hng sF 3ol !H
G
cE trong 6#> l0t
55 $a!H 6#><.
,. /0nh th@ t0ch 55 HCl 6#>< cE ch7a sF 3ol H
I
,Hng sF 3ol H
I
cE trong 6#* l0t 55 H$!
*
6#2<.
Cu >:
a. HJa tan ho?n to?n 12#>g tinh th@ Cu!
"
.>H
2
! trong nc th?nh 266 3l 55. /0nh n1ng 2 3ol4l
cc ion trong 55 thu :c.
,. HJa tan D#6Dg ()&$!
*
'
*
.KH
2
! trong nc th?nh >66 3l 55. /0nh n1ng 2 3ol4l cc ion trong
55 thu :c.
Cu 8: /0nh n1ng 2 3ol cc ion trong 55 CH
*
C!!H 1#2<. %it chL cE 1#"A phn tM CH
*
C!!H N in
li th?nh ion. Cho ,it CH
*
C!!H l? cht in li 3Onh hay yuP
Cu 9: CQn ,ao nhiRu l0t 55 HCl 2< tr2n =i 1D63l 55 H
2
!
"
*< @ :c 1 55 cE n1ng 2 3ol4l ca H
I
l? "#><. Cho ,it

H
2
!
"
in li ho?n to?n.
II. Ph !&'( )hi*+
Cu 1: B5 in li 5Sn in :c l? 5o sT 5i chuy@n ca:
a. cc Cation ,. cc anion c. cc phn tM hJa tan 5. cc cation =? anion.
Cu 2: Cht n?o sau y kh,) 5Sn in :cP
a. -Cl rUn# ;han ,. CaCl
2
nEng chVy c. $a!H nEng chVy 5. H%r hJa tan trong nc
Cu *: ChWn cu -.i : cht in li
a. X? nhYng cht ;hi tan trong nc tOo th?nh 55 5Sn in
,. .hn li th?nh ion 5Zng =? 3 [ trOng thi nEng chVy ho\c 55.
c. ]:c chia th?nh 2 loOi: in li 3Onh =? in li yu
5. %ao g13 tt cV cc aît# ,a_Z# 3uFi# oît.
Cu ": /rong ù tranh in li ca cc cht# =ai trJ ca nc l?
a. Bung 3bi ;hbng phn cTc# chi phFi sT in li
,. Bung 3bi phn cTc# tOo icu ;in cho sT in li.
c. <bi trdng hJa tan cho cc cht in li.
5. XiRn ;t cc cation =? anion.
Cu >: .hZng tranh in li n?o 5i y =it ;hbng eng P
a. HCl H
I
I Cl
G
,. CH
*
C!!H

CH
*
C!!
G
I H
I
.
c. H
*
.!
"
*H
I
I.!
"
*G
. 5. $a
*
.!
" *$a
I
I .!
"
*G
.
Cu 8: .hZng tranh in li n?o 5i y :c =it eng P
a. H
2
!
"

H
I
I H!
"
G
,. H
2
C!
*

2H
I
I C!
*
2G

c. H
2
!
*
2H
I
I !
*
2G
5. $a
2

2$a
I
I
2G
.
Cu 9: ChWn nhE3 cht cu ;hbng in li trong nc:
a. H$!
2
# CH
*
C!!H ,. HC!!H# HC!!CH
*
c. -<n!
"
# C
8
H
8
5. C
8
H
12
!
8
# C
2
H
>
!H
Cu D: ChWn cu sai:
+. Cht in li cE th@ phn li th?nh ion 5Zng =? 3 trong nc.
G/0 L1 Ch2 N)$3* - 1 - T&45) THPT N)$36 7.i
%. B5 cht in li cE th@ 5Sn in :c.
C. F in t0ch 5Zng =? 3 ,Hng nhau trong 55 in li.
B. B5 cht in li 3Onh =? yu cfng 5Sn in nh nhau.
Cu K: B5 n?o sau y 5Sn in P
a. saccaro_o =? 3anto_o ,. aît clohi5ric =? ;aliclorua
c. gluco_o =? hructo_o 5. iot trong 5ung 3bi hYu cZ.
Cu 16: 2 in li phi thu2c
a. %Vn cht cc ion tOo th?nh cht in li ,. Bung 3bi# nhit 2# n1ng 2# ,Vn cht cht tan.
c. ]2 tan ca cht in li trong nc 5. /0nh ,No hJa ca 55 cht in li.
Cu 11: ]2 in li l? tL sF giYa sF phn tM cht tan N in li =? j.
a. cha in li ,. sF phn tM 5ung 3bi c. sF 3ol cation =? anion 5. tkng sF phn tM cht tan.
Cu 12: -hi pha llang 55 CH
*
C!!H tha 2 in li sm:
a. giV3 ,. tnng c. ;hbng ki 5. cE th@ tnng ho\c giV3.
Cu 1*: $u thR3 55 CH
*
C!!$a =?o 55 CH
*
C!!H tha n1ng 2 H
I
sm:
a. giV3 ,. tnng c. ;hbng ki 5. cE th@ tnng ho\c giV3.
Cu 1": <2t 55 cE ch7a cc ion: Cu
2I
&6#62 3ol'# -
I
&6#6* 3ol'# $!
*
G
&6#6> 3ol' =a2 !
"
2G
&^ 3ol'.
gi tro ^ l?:
a. 6#6> ,. 6#6"> c. 6#6* 5. 6#6*>
Cu 1>: pu tranh in li ca cht in li yu:
a. cE t0nh thuqn nghoch ,. ;hbng cE t0nh thuqn nghoch
c. ;hi giV3 nhit 2 tnng. 5. tnng ;hi nhit 2 giV3.
Cu 18: B5 cE ch7a <g
2I
&6#62 3ol'# -
I
&6#16 3ol'# Cl
G
&6#6" 3ol' =? chL cJn 1 ion nYa l?
a. $!
*
G
&6#6* 3ol' ,. C!
*
2G
&6#61> 3ol' c. !
"
2G
&6#61 3ol' 5. $H
"
I
&6#61 3ol'.
Cu 19: B5 CH
*
C!!H 6#1< =i 2 in li
C1.*2A cE n1ng 2 H
I
l?
a. 6#661*2< ,.1#*2< c. 6#1< 5. 6#61*2<
Cu 1D: B5 CH
*
C!!H 6#662>< cE rH
I
s C16
G"
<. 2 in li
ca CH
*
C!!H l?
a. 6#6"A ,. 1#66A c. *#"6A 5. "#66A.
Cu 1K: B5 t g13: 6#6K 3ol Cl
G
# 6#6" 3ol $a
I
# a 3ol ()
*I
# =? , 3ol !
"
2G
. -hi cb cOn t thu :c
9#91>g 3uFi ;han. gi tro a#, th)o th7 tT:
a. 6#62 =? 6#66> ,. 6#6* =? 6#62 c. 6#6" =? 6#6*> 5. 6#6> =? 6#6>
Cu 26: B5 u ch7a 2 cation l? ()
2I
&^ 3ol' =a2 +l
*I
&y 3ol' =? 2 anion l? Cl
G
&6#2 3ol' =? !
"
2G
&6#* 3ol'. -hi cb cOn 55 thu :c "8#Kg 3uFi ;han. gi tro ^# y th)o th7 tT:
a. 6#2> =? 6#1 ,. 6#19> =? 6#1> c. 6#18 =? 6#18 5. 6#1 =? 6#2
BI 2: AXIT, BAZ V MUI
I. Ph !" #$%
Cu 1: th)o %ronGst)t# cc phn tM & ho\c ion' sau y: H$!
*
# H
2
!# $H
*
# $H
"
I
# H!
*
G
# vn&!H'
2
# H!
"
G
#
C!
*
2G
# $a
I
# CH
*
C!!
G
# Cl
G
l? aît# ,a_Z# lwng t0nh hay trung t0nhP giVi th0ch.
Cu 2: =it phZng tranh phVn 7ng ch7ng tx C!
*
2G
#
2G
l? 32t ,a_o =? HC!
*
G
=? H
G
l? cht lwng t0nh.
Cu *: 16 3l 55 + &ch7a $aHC!
*
=? $a
2
C!
*
' tc 5ing =7a =i 16 3l 55 $a!H 1<. $hng > 3l 55 +
tc 5ing =ya ht =i 16 3l 55 HCl 1<. /0nh n1ng 2 3ol cc ion trong 55 sau phVn 7ng.
Cu ":
a. /0nh th@ t0ch 55 $a!H 6#>< cQn cho =?o 1>6 3l 55 vn!
"
1< @ l?3 ;t ta ht ion vn
2I
.
,. $u tip tic thR3 >6 3l 55 $a!H 1<. Cho ,it hin t:ng ^Vy ra =? =it phZng tranh phVn
7ng. /0nh n1ng 2 3ol cc ion trong 55 sau phVn 7ng.
Cu >: Chia 1>#8g +l&!H'
*
th?nh 2 phQn ,Hng nhau:
I phQn 1: tc 5ing =i 1>6 3l 55 H
2
!
"
1<.
I phQn 2: tc 5ing =i 1>6 3l 55 $a!H 1<.
HNy t0nh ;hFi l:ng 3uFi tOo th?nh trong 3zi trdng h:p.
Cu 8: @ hJa tan ht 8#"g ()
2
!
*
cQn 5fng >6g 55 HCl. /0nh n1ng 2 CA =? C
<
ca 55 HCl. %it rHng 55
HCl trRn cE ;hFi l:ng riRng BC1#69 g43l.
Cu 9:
a. /0nh n1ng 2 3ol ca ion H
I
trong 55 HC!!H 6#1< &cho hHng sF phn li aît -
a
C1#9D.16
G"
'.
,. /0nh n1ng 2 3ol ca ion !H
G
trong 55 $H
*
6#1< &cho hHng sF phn li ,a_o -
,
C1#D6.16
G>
'.
Cu D:
G/0 L1 Ch2 N)$3* - 8 - T&45) THPT N)$36 7.i
a. t0nh n1ng 2 cc ion =? phn tM cha phn li trong 55 CH
*
C!!H 6#1< &-
a
C1#9>.16
G>
'
,. 55 H$!
2
6#16< cE rH
I
s C8#1*.16
G*
<. t0nh hHng sF phn li -
a
cua* H$!
2
.
II. Ph !&'( )hi*+
Cu 1: /h)o thuyt in li:
a. %a_Z l? h:p cht trong phn tM cE nhE3 !H.
,. +ît l? h:p cht cE ;hV nnng phn li H
I
trong nc.
c. <uFi aît =Sn cJn hi5ro trong phn tM
5. <uFi trung hJa cu ;hbng cJn hi5ro trong phn tM.
Cu 2: /h)o thuyt %ronGst)t &thuyt .roton':
a. ,a_Z l? h:p cht trong phn tM cE nhE3 !H.
,.+ît l? h:p cht cE ;hV nnng phn li H
I
trong nc.
c. %a_o l? cht nhdng proton H
I
.
5. Cht lwng t0nh cE th@ cho proton# ho\c nhqn proton.
Cu *: B5 aît:
a. ch7a ion H
I
# cE =o chua. ,. hJa tan :c cc ;i3 loOi
c. hJa tan :c cc oît ,a_Z 5. ch7a ion H
I
# cE =o chua =? hJa tan :c cc oît ,a_Z.
Cu ": BNy g13 chL cc 3uFi trung hJa l?
a. $aCl#-$!
*
# &$H
"
'
2
!
"
# Ca!
"
# Ca
*
&.!
"
'
2
.
,. $a
2
!
"
# -{# $aH# %aC!
*
.
c. $aH!
"
# -cl!
*
# CH
*
C!!$H
"
# ().
5. $a
2
!
*
# Ca
*
&.!
"
'
2
# +lCl
*
# -HC!
*
.
Cu >: ChWn 3uFi trung hJa
a. $aHC!
*
,. -H!
"
c. Ca&H
2
.!
"
'
2
5. $a
2
H.!
*
.
Cu 8: /h)o thuyt in li# cht n?o sau ;hi tan trong nc =ya cE th@ phn li H
I
=ya cE th@ phn li !H
G
P
a. $a!H ,. H
2
!
"
c. -
2
C!
*
5. vn&!H'
2
Cu 9: /h)o %ronGst)t# 5Ny chL g13 ,a_Z l?
a. $a!H# $H
*
# C!
*
2G
# Cl
G
,. Ca&!H'
2
# CH
*
C!!$a#
2G
# HC!
*
G
.
c. -!H# %a&!H'
2
# .!
"
*G
# !
*
2G
5. Xi!H# +l&!H'
*
# HC!!-# $!
*
G
.
Cu D: ChWn h:p cht lwng t0nh:
a. vn&!H'
2
# H!
"
G
# H
2
! ,. +l&!H'
*
# .,&!H'
2
c. Cr&!H'
*
# C!
*
2G
5. +l&!H'
*
# .!
"
*G
.
Cu K: ChWn pht ,i@u eng nht =c +l&!H'
*
:
a. ,a_Z lwng t0nh ,. hi5roît lwng t0nh c. hi5roît ;i3 loOi 5. ,a_Z yu ;hbng tan.
Cu 16: $c Eng =ai trJ aît trong phVn 7ng:
a. HCl I H
2
! | H
*
!
I
I Cl
G
,. HC!
*
G
I H
2
!

H
*
!
I
I C!
*
2G
.
c. CH
*
C!!
G
I H
2
!

CH
*
C!!H I !H
G
5. Cu!
"
I >H
2
!| Cu!
"
.>H
2
!.
Cu 11: t}t cc phVn 7ng sau# chWn phVn 7ng aît ,a_o
1. vn I 2HCl | vnCl
2
I H
2
.
2. H
2
!
"
I vn&!H'
2
| vn!
"
I 2H
2
!.
*. *()! I 16H$!
*
| *()&$!
*
'
*
I $! I >H
2
!.
". 2H
*
!
I
I Cu! | Cu
2I
I *H
2
!.
a. 1#2 ,. 1#* c. 2#" 5. 2#*.
Cu 12: .hVn 7ng giYa 3uFi Ca&HC!
*
'
2
=? 55 HCl l?
a. phVn 7ng oî hEa ;hM ,. phVn 7ng th c. phVn 7ng aît ~ ,a_Z 5. phVn 7ng trao ki.
Cu 1*: HJa tan *2 g Cu! ,Hng 32t l:ng =ya 55 H
2
!
"
26A. $1ng 2 A cht tan trong 55 sau phVn
7ng:
a. 2"#8A ,. 2D#69A c. 21#DA 5. 2>#>A
Cu 1": B5 aît ho3ic HC!!H 6#6>< cE:
a. rH
I
sC6#6>< ,. rH
I
srHC!!
G
s c. rH
I
srHC!!
G
s 5. rH
I
s6#6><.
Cu 1>: Cho 55 %a&!H'
2
6#1<. ChWn nh gi eng:
a. r!H
G
sC6#16< ,. r!H
G
sCr%a
2I
s c. r!H
G
sC6#26< 5. 6#16<r!H
G
s6#26<.
Cu 18: Cho cc 55 cE cfng n1ng 2 3ol: H( &1' H
2
!
"
&2' H%r &*' . tp n1ng 2 ion H
I
tnng 5Qn:
a. 12* ,. 1*2 c. *12 5. 2*1.
Cu 19: HHng sF phn li ,a_o -
,
ca 32t Zn ,a_o yu:
G/0 L1 Ch2 N)$3* - 9 - T&45) THPT N)$36 7.i
a. phi thu2c =?o n1ng 2 ,. ;hbng phi thu2c =?o nhit 2.
c. hQu nh ;hbng phi thu2c =?o p sut 5. c?ng ln tha lTc ,a_o c?ng nhx.
Cu 1D: Cho hai aît H+ =? H% =i hHng sF phn li aît lQn l:t l? -
1
=? -
2
&cho ,it -
1
-
2
'. /a cE th@
5T on:
a. 2 3Onh aît H+H% ,. 2 3Onh aît: H+H% c. rH
I
s
H+
rH
I
s
H%
5. rH
I
s
H+
rH
I
s
H%.
Cu 1K: ]@ trung hJa 6#K"*g H
*
.!
*
&aît photphoro' cQn 5fng 16 3l 55 $a!H 2#*<. F nc ca H
*
.!
*
l?:
a. 1 ,.2 c. * 5. *.
Cu 26: Cho cn ,Hng in li sau: % I H
2
!

H%
I
I !H
G
. %i@u th7c hHng sF phn li ,a_o ca % l?:
a.
r s
r sr s
b
B
K
HB OH
+
=
,.
2
r sr s
r sr s
b
B H O
K
HB OH
+
=
c.
r sr s
r s
b
HB OH
K
B
+
= 5.
2
r sr s
r sr s
b
HB OH
K
B H O
+
=
BI 3: S IN LI CA NC! "H!CH# TH$ AXIT!BAZ.
I. Ph !" #$%
Cu 1: /0nh pH ca 3zi 55 sau:
a. H$!
*
6#6"< ,. H
2
!
"
6#61< I HCl 6#6>< c. $a!H 16
G*
< 5. -!H 6#1< I %a&!H'
2
6#2<
Cu 2:
a. B5 H
2
!
"
cE pHC2. /0nh n1ng 2 3ol4l ca H
I
=? H
2
!
"
. Chp nhqn H
2
!
"
in li ho?n to?n.
,. Cho 6#2"g <g =?o 6#8 l0t 55 H
2
!
"
trRn. /0nh th@ t0ch ;h0 H
2
thot ra &;tc'.
Cu *: + l? 55 %a&!H'
2
cE pHC1*
a. /0nh n1ng 2 3ol4l ca %a&!H'
2
.
,. $u pha loNng 55 + > lQn tha pH ca 55 3i l? ,ao nhiRu.
Cu ":
a. /r2n *663l 55 H$!
*
6#*< =i 2663l 55 $a!H 1#><. /0nh pH ca 55 thu :cP
,. /r2n 1663l 55 %a&!H'
2
6#68< =i "663l HCl 6#62 <. /0nh pH ca 55 tOo th?nh.
Cu >: CQn pha loang",ao nhiRu lQn 3zi 55 sau
a. H
2
!
"
cE pHC2 @ :c 55 3i cE pHC*.
,. $a!H cE pHC1* @ :c 55 3i cE pHC12.
Cu 8: /a3 tL l th@ t0ch pha tr2n 2 55 sau:
a. HCl &pHC*' =i HCl &pHC>' @ :c 55 3i cE pHC".
,. $a!H &pHC1*' =i $a!H &pHC11' @ :c 55 3i cE pHC12.
Cu 9: /0nh pH =? 2 in li
ca H$!
2
trong 55 H$!
2
6#12<. Cho hHng sF in li - ca H$!
2
l? >.16
G
"
.
Cu D: o snh pH ca cc 55 cE cfng n1ng 2 3ol4l
a. $H
*
# $a!H# %a&!H'
2
.
,. HCl# H
2
!
"
# CH
*
C!!H.
Cu K: /0nh V l0t 55 $a!H cE pHC1* cQn thR3 =?o 55 ch7a 6#6* 3ol +lCl
*
@ thu :c:
a. X:ng +l&!H'
*
cTc Oi.
,. 6#62 3ol +l&!H'
*
;t ta.
Cu 16:
a. /r2n V l0t 55 HCl 6#>< =i 2 l0t 55 %a&!H'
2
6#6>< thu :c 55 t cE pHC2#*. /0nh V.
,. /r2n 2>63l 55 ch7a HCl 6#6D< =? H
2
!
"
6#61 < =i 2>63l 55 $a!H a 3ol4l :c >663l 55
cE pHC12. /0nh a.
II. Ph !&'( )hi*+
Cu 1: <2t 55 + cE rH
I
s C2.16
G*
< sm cE 3bi trdng:
a. aît ,. ,a_o c. trung t0nh 5. lwng t0nh
Cu 2: B5 =i r!H
G
s C 2.16
G*
<# sm cE:
a. pH9 ,. pH9 c.rH
I
s 16
G9
5. rH
I
s
16
G9
.
Cu *: Cho ù t03 =?o 55 cE pHCD#"# chL tho sm cE 3?u:
a. ânh ,. x c. trung t0nh 5. h1ng
Cu ": /r2n 2663l 55 HCl 6#1>< =i *663l 55 $a!H 6#12<# sau E thR3 ph)nolphtal)in =?o tha 55 sm
cE 3?u:
a. h1ng ,. t03 c. ;hbng 3?u 5. t03 ânh
G/0 L1 Ch2 N)$3* - : - T&45) THPT N)$36 7.i
Cu >: /hR3 V 3l 55 $a!H 6#2>< =?o 1663l 55 HCl 6#1< &cE 3\t chL tho ph)nolphtal)in'. -hi 55 ût
hin 3?u h1ng tha gi tro V l?
a. 1663l ,. >63l c. "63l 5. 863l
Cu 8: /0ch sF ion ca nc trong 55 -CrH
I
s r!H
G
s .
a. tnng ;hi tnng nhit 2 ,. giV3 ;hi nhit 2 tnng
c. tnng ;hi nhit 2 giV3 5. ;hbng ki th)o nhit 2.
Cu 9: B5 H
2
!
"
cE pHC2# n1ng 2 3ol ca H
2
!
"
l?
a. 16
G2
< ,. 2.16
G2
< c. >.16
G2
< 5. >.16
G*
<
Cu D: B5 hzn h:p %a&!H'
2
6#6>< I -!H 6#6>< cE pH l?:
a. 1*#19 ,. 12#1* c. 12#> 5.1*#>
Cu K: /r2n *663l hzn h:p H
2
!
"
pHC1 =i 2663l 55 %a&!H'
2
6#682><# 55 thu :c cE pH ,Hng
a. 2#> ,. 12 c. 2 5. 11#>
Cu 16: B5 CH
*
C!!H 6#1< cE 2 in li
C1#*2A# cE pH l?
a. 2#8 ,.2#9 c. 2#DD 5. 2#D
Cu 11: 32t nhit 2 ^c onh# 55 Hcl! 6#1< cE pHC"#1> cE 2 in li l?
a. 6#69A ,. 6#6"*A c. 6#6"A 5. 6#6>>A
Cu 12: B5 $H
*
1< =i 2 in li ".16
G*
cE pH l?
a. 16#8 ,. 11#8 c. D#>D 5. 11#D
Cu 1*: B5 aît H$!
2
cE pHC2#18. -hi thR3 tinh th@ 3uFi $a$!
2
=?o 55 aît trRn tha pH ca 55 sm
a. tnng ,. giV3 c. ;hbng ki 5. tnng r1i giV3
Cu 1": CE " 55 H
*
.!
"#
HCl# H
2
!
"
# $H
"
Cl cE cfng n1ng 2. Bung 5och cE pH nhx nht l?
a. H
*
.!
"
,.

HCl c. H
2
!
"
# 5. $H
"
Cl
Cu 1>: CE " 55 $a!H# %a&!H'
2
# $H
"
!H# $a
2
C!
*
cE cfng n1ng 2. Bung 5och cE pH ln nht l?
a. $a!H# ,. c. $H
"
!H# 5. $a
2
C!
*
.
Cu 18: B5 H
2
!
"
cE pHC2. .ha loNng 55 n lQn :c 55 cE pHC" . gi tro n l?
a. 16 ,. 166 c. 26 5. 266
Cu 19: B5 + ch7a %a&!H'
2
cE pHC2# ;hi pha loNng 55 + 26 lQn tha pH ca 55 3i l?
a. 11#D ,. 12#9 c. 16#> 5. 16#9
Cu 1D: /r2n *663l 55 HCl cE pHC2 =i 2663l HCl pHC*# thu :c 55 3i cE pH l?
a. 2#1K ,. 2#"K c. 2#*6 5. 2#9K
Cu 1K: /r2n V
1
3l 55 $a!H cE pHC12 =i V
2
3l 55 $a!H cE pHC1* th)o tL l V
1
:V
2
C 1:" thu :c 55
cE pH
a. 12#D ,.12#K1 c. 12#> 5. 12#8
Cu 26. pH ca 55 CH
*
C!!H 6#6>< l?
a. 1#* ,. 1#*pH9 c. C9 5. 9.
BI %: &H'N (NG T)A* +I I*N T)*NG ,UNG ,$CH CH-T IN LI
I. Ph !" #$%
Cu 1: Vit pt ion thu gWn ca cc phVn 7ng sau &nu cE' ^Vy ra trong 55 c\p cht sau:
a. ()Cl
*
I $a!H
,. vn&!H'
2
I H$!
*
c. -$!
*
I $aCl
5. Cu&!H'
2 &r'
I %a&!H'
2
). <g&!H'
2 &r'
I H
2
!
"
.
h. vn &r' I HCl
g. $aH
2
.!
"
I HCl
h. $aHC!
*
I $a!H
Cu 2: Vit pt phn tM# ion thu gWn cc phVn 7ng sau
a. %aCl
2
I +g$!
*
,. -HC!
*
I %a&!H'
2
c. -!H I ()Cl
2
5. Ca&HC!
*
'
2
I Ca&!H'
2
). -
2
!
*
I HCl
h. Ca&HC!
*
'
2
I HCl
Cu *: Vit pt phn tM =? ion thu gWn cc phVn 7ng ^Vy ra trong 55 th)o cc sZ 1 sau
G/0 L1 Ch2 N)$3* - ; - T&45) THPT N)$36 7.i
a. %a!
*
Ij.| %aCl
2
Ij.
,. () I j.| ()Cl
2
I j
c. -
*
.!
"
I j| +g
*
.!
"
I j
5. $a
2
i!
*
I j| H
2
i!
*
I j
). +l%r
*
I j| +l&!H'
*
I j
Cu ": Vit pt phn tM cc phVn 7ng cE pt ion ret gWn nh sau# 3zi trdng h:p chWn 2 th0 5i ;hc nhau
a. ()
*I
I *!H
G
| ()&!H'
*
,. 2H
I
I C!
*
2G
| H
2
! I C!
2
c. *Ca
2I
I 2.!
"
*G
| Ca
*
&.!
"
'
2
.
5. H
I
I CH
*
C!!
G
|CH
*
C!!H
Cu >: HNy icu ch Cu ,Hng * phVn 7ng trao ki ion ;hc nhau ^Vy ra trong 55. /y E ret ra ,Vn cht
ca phVn 7ng trong cc 55 n?y
Cu 8. Vit pt phVn 7ng hEa hWc 5i 5Ong phn tM =? ion thu gWn ca cc phVn 7ng trao ki ion trong 55
tOo th?nh cc ;t ta sau: Cu# C5# <n# vn# ().
Cu 9: CE th@ pha ch 55 ch7a 1ng thdi cc ion sau hay ;hbngP
a. $a
I
# ()
*I
# Cl
G
# !H
G
,. -
I
# Cu
2I
# Cl
G
# !
"
2G
c. $a
I
#Cl
G
# !
"
2G
# %a
2I
5. $a
I
# H
I
# $!
*
G
# C!
*
2G
.
Cu D: HNy giVi th0ch
a. Va sao cc 55 $a
2
C!
*
=? 55 -
2
cE pH9 P
,. Va sao cc 55 vnCl
2
=? 55 +l
2
&!
"
'
*
cE pH9 P
Cu K: Cho ,it ;hoVng gi tro pH ca 3zi 55 : $H
"
Cl# $a
2
!
"
# -HC!
*
# $aH!
"
# ()&$!
*
'
*
# $a
2
C!
*
#
CH
*
C!!$a# C
8
H
>
!$a# $a
2
. giVi th0ch P
Cu 16: ChL 5fng thR3 ù t03# hNy phn ,it > 55: $a!H# +lCl
*
# ()
2
&!
"
'
*
# $H
"
Cl# HCl ch7a trong cc
lW riRng ,it.
Cu 11: <2t 55 u cE ch7a cc ion Cl
G
# !
"
2G
# $H
"
I
. -hi cho 1663l 55 u phVn 7ng ht =i 2663l 55
%a&!H'
2
thu :c 8#KKg ;t ta =? thot ra 2#2" l0t ;h0 &;c'.
a. /0nh n1ng 2 3ol4l cc ion trong 55 u.
,. /0nh n1ng 2 3ol4l ca 55 %a&!H'
2
N 5fng.
Cu 12: <2t 55 + cE ch7a cc ion $a
I
#!
"
2G
# C!
*
2G
# $H
"
I
. Chia 55 + l?3 2 phQn ,Hng nhau
Ph 1: .hVn 7ng =i 55 %a&!H'
2
5# un nEng thu :c "#88g ;t ta =? "96#" 3l ;h0 u
&1*#>
6
C#1at3'
Ph 80 /c 5ing =i 55 HCl 5 thu :c 2*>#2 3l ;h0 &1*#>
6
C#1at3'
/0nh tkng ;hFi l:ng 3uFi trong 55 +.
Cu 1*: CE 1 l0t 55 hzn h:p $a
2
C!
*
6#1< =? &$H
"
'
2
!
"
6#2><. Cho "*g hzn h:p %aCl
2
=? CaCl
2
=?o 55
E. au ;hi ;t thec phVn 7ng thu :c *K#9g ;t ta + =? 55 %. t0nh th?nh phQn A ;hFi l:ng cc cht
trong +
Cu 1": /0nh n1ng 2 ion H
I

a. CH
*
C!!$a 6#1< & ,it -
,
ca CH
*
C!!
G
l? >#91.16
G16
'.
,. $H
"
Cl 6#1< &-
a
C>#>8.16
G16
'
II. Ph !&'( )hi*+
Cu 1: .hVn 7ng trao ki ion trong 55
a. CE sT thay ki sF oî hEa cc nguyRn tF
,. -hbng cE sT thay ki sF oî hEa ca cc nguyRn tF
c. CE th@ cE ho\c ;hbng thay ki sF oî hEa cc nguyRn tF
5. ChL ^Vy ra cht in li 3Onh
Cu 2: .hZng tranh ion thu gWn ca phVn 7ng cho ,it:
a. Cc ion tT 5o trong 55
,. Cc ion cJn lOi trong 55 sau phVn 7ng.
c. /rung hJa in giYa cc ion tha3 gia phVn 7ng
5. %Vn cht phVn 7ng ^Vy ra giYa cc cht in li.
Cu *: ]icu ;in @ phVn 7ng trao ki ion trong 55 ^Vy ra :c
a. Cc cht phVn 7ng phVi l? cht 5 tan
,. Cc cht phVn 7ng phVi l? cht in li yu
c. Cc cht phVn 7ng phVi l? cht in li 3Onh
5. Vn ph3 tOo th?nh cE cht ;t ta# ,ay hZi ho\c in li yu.
G/0 L1 Ch2 N)$3* - < - T&45) THPT N)$36 7.i
Cu ": C\p hEa cht n?o sau y cE th@ ^Vy ra phVn 7ng P
a. Cu I HCl ,. $a$!
*
I HCl c. $a
2
!
"
I H
2
!
"
&\c' 5. -Cl I H
2
C!
*
.
Cu >: &$hYng' 55 n?o 5i y cE pH9 P
a. $a
2
,. $H
"
Cl c. -
2
C!
*
5. $a
2
# H
2
C!
*

Cu 8: ChWn c\p 55 5i y cE pH9 P
a. $aCl# $a$!
2
,. CH
*
C!!$a c. $a
*
.!
"
# -$!
*
5. $H
"
$!
*
# ()%r
2
.
Cu 9: ChWn c\p cht sau y ;hbng ,o thy phn
a. nCl
2
# $aCl ,. -Cl# $a$!
*
c. Cu&$!
*
'
2
# &CH
*
C!!'
2
Cu 5. -%r# -
2
.
Cu D: Cc ion trong 5Ny n?o cE th@ t1n tOi trong cfng 32t 55 P
a. $a
I
# Cu
2I
# Cl
G
# !H
G
,. -
I
# %a
2I
# Cl
G
# !
"
2G
.
c. -
I
# ()
2I
# !H
G
# C!
*
2G
5. -
I
# ()
*I
# Cl
G
# !
"
2G
.
Cu K: .hZng tranh $H
"
I
I !H
G
| $H
*
I H
2
! l? phZng tranh ion thu gWn ca phVn 7ng
a. &$H
"
'
2
!
"
I 2$a!H |
,. &$H
"
'
2
!
"
I %a&!H'
2
|
c. 2&$H
"
'
*
.!
"
I *Ca&!H'
2
|
5. $H
"
Cl I $H
"
!H |
Cu 16: ChWn phZng tranh phVn 7ng eng
a. C!
2
I H
2
! I CaCl
2
| CaC!
*
I 2HCl
,. () I $a
2
!
"
| ()!
"
I $a
2
c. $a
2
!
"
I Cu&!H'
2
| Cu!
"
I 2$a!H
5. ()&$!
*
'
*
I *$a!H | ()&!H'
*
I *$a$!
*
.
Cu 11: Vi 8 ion %a
2I
# <g
2I
# $a
I
# !
"
2G
# C!
*
2G
# $!
*
G
. $gdi ta cE th@ :c * 55 cE th?nh phQn ion ;hbng
trfng l\p l?
a. <g!
"
# $a$!
*
# %a&$!
*
'
2
.
,. <g&$!
*
'
2
# $a
2
!
"
# %a&$!
*
'
2
.
c. <g&$!
*
'
2
# %a!
"
# $a
2
C!
*
.
5. %a&$!
*
'
2
# <g!
"
# $a
2
C!
*
.
Cu 12: Vi D ion: %a
2I
# <g
2I
# .,
2I
# $a
I
# !
"
2G
# C!
*
2G
# $!
*
G
# Cl
G
$gdi ta cE th@ :c " 55 &3zi 55 ch7a 1
cation =? 1 anion' cE th?nh phQn ion ;hbng trfng l\p l?
a. .,&$!
*
'
2
# %aCl
2
# <g!
"
# $a
2
C!
*
.
,. .,&$!
*
'
2
# <g!
"
# %a&$!
*
'
2
# $a
2
C!
*
.
c. .,Cl
2
# %a&$!
*
'
2
# <g!
"
# $a
2
C!
*
.
5. .,&$!
*
'
2
# %aCl
2
# <gC!
*
# $a
2
!
"
.
Cu 1*: ChWn nhqn ^}t eng
"H./ "H0/ "H1/
+ $a
2
C!
*
. $aCl CH
*
C!!$a
% +lCl
*
$a
2
!
"
CH
*
C!!$a
C $H
"
Cl $a
2
C!
*
. $a
2
!
"
B +lCl
*
$a
2
C!
*
. CH
*
C!!$a
Cu 1": B5 1 3uFi trung hJa t tc 5ing =i %a&$!
*
'
2
thu :c ;t ta trUng &;hbng tan trong aît'. <\t
;hc# 55 t tc 5ing =i $a!H un nEng thu :c ;h0 cE 3fi ;hai. Vqy t l?
a. ()!
"
,. &$H
"
'
2
C!
*
c. Cu!
"
5. &$H
"
'
2
!
"
.
Cu 1>: B5 1 3uFi trung hJa =i %a&$!
*
'
2
thu :c ;t ta trUng &;hbng tan trong aît'.<\t ;hc# 55 t
tc 5ing =i $a!H 5 cE ;t ta ;)o trUng r1i tan. t l?
a. &$H
"
'
2
!
"
. ,. ()!
"
c. <g!
"
5. +l
2
&!
"
'
*
.
Cu 18: ChWn 1 hEa cht @ phn ,it cc 3Su 55 sau: $a
2
!
"
# $H
"
Cl# ()Cl
*
# -Cl:
a. $a!H ,. +g$!
*
c. %a&!H'
2
5. %aCl
2
.
Cu 19: .hZng tranh phVn 7ng n?o sau y ;hbng eng P
a. HC!
*
G
I H
*
!
I

C!
2
I 2H
2
!.
,. HC!
*
G
I !H
G

C!
*
2G

I H
2
!.
c. vn&H
2
!'
"
2I
I H
2
!

vn&H
2
!'
*
&!H'

I
I
H
*
!
I

5. vn&H
2
!'
"
2I
I H
2
!

vn&H
2
!'
*
&!H'

2I
I
H
*
!
I
.
G/0 L1 Ch2 N)$3* - = - T&45) THPT N)$36 7.i
Cu 1D: B5 + ch7a +l
*I
# <g
2I
# Cl
G
. ]@ ;t ta ht ion Cl
G
trong 166 3l 55 + cQn 2663l 55 +g$!
*
6#*<.
/hR3 $a!H 5 =?o 1663l 55 + :c 6#D9g ;t ta. F 3ol +l
*I
trong 1663l 55 + l?
a. 6#61 3ol ,. 6#61> 3ol c. 6#66> 3ol 5. 6#612 3ol
CHNG 2: NIT ! &H*T&H*
BI 2: NIT 3 AM*NIAC 3 MUI AM*NI
I. Ph !" #$%
Cu 1: Vit cc phZng tranh phVn 7ng ,i@u 5in cc chuy@n hEa sau
a. $H
"
$!
2
$
2
$! H$!
*
$a$!
*
.
,. $H
"
$!
*
$
2
$H
*
&$H
"
'
2
!
"
$H
*
c. +
2
H O
55 +
2 "
H SO
%
KOH
+
*
HNO
B
o
t C
I H
2
!.
5. $ito nito oît nito p)oît nito a3oniac a3oni nitrat
a3oniac 1ng &{{' hi5roît 1ng&{{' t)tr)a3in hi5roît 1ng&{{' t)tr)a3in
sunhat.
Cu 2:
a. .hn ,it cc 55 sau ,Hng pp hEa hWc
1. &$H
"
'
2
!
"
# $a$!
*
# $H
"
$!
*
# $a
2
C!
*
.
2. -
2
C!
*
# &$H
"
'
2
!
"
# -
2
!
"
# -Cl.
*. $H
"
$!
*
# $H
"
Cl# &$H
"
'
2
!
"
# &$H
"
'
2
C!
*
.
,. X?3 th n?o @ tch riRng cc cht ra ;hxi hzn h:p g13 $aCl# <gCl
2
# $H
"
Cl.
Cu *: /r2n * l0t $! =i 16 l0t ;hbng ;h0. /0nh th@ t0ch $!
2
tOo th?nh =? th@ t0ch ;h0 hzn h:p ;h0 sau phVn
7ng. &%it !
2
chi3 14> th@ t0ch ;go8ng ;h0# phVn 7ng ^Vy ra ho?n to?n# cc ;h0 o [ cfng icu ;in'.
Cu ": CQn ,ao nhiRu l0t ;h0 $
2
=? H
2
&;tc' @ icu ch >1g $H
*
,it hiu sut phna* 7ng l? 2>A.
Cu >: Hzn h:p $
2
# H
2
cE tL l th@ t0ch l? 1:*. $ung hzn h:p [ nhit 2 cao @ ^Vy ra phVn 7ng tkng h:p
$H
*
. Hzn h:p ;h0 thu :c hJa tan trong nc tOo th?nh >66g 55 $H
*
19A. /0nh ;hFi l:ng $
2
,an Qu
,it hiu sut phVn 7ng l? 2>A.
Cu 8:
a. /y 112 l0t ;h0 $
2
=? *K2 l0t ;h0 H
2
tOo :c *"g $H
*
. /0nh hiu sut phVn 7ng . /h@ t0ch cc ;h0
o [ ;tc.
,. CQn ly ,ao nhiRu l0t ;h0 $
2
=? H
2
@ tOo ra :c 261#8 l0t $H
*
. ,it hiu sut phVn 7ng l?
1DA . /h@ t0ch cc ;h0 o [ ;tc.
Cu 9: /hTc hin phVn 7ng giYa 16 l0t H
2
=? "6 l0t $
2
=i ,2t () l?3 êc tc nung nEng. Hzn h:p sau phVn
7ng :c 5Sn ùa 55 H
2
!
"
loNng 5 &hp thi ;h0 $H
*
' cJn lOi "6 l0t ;h0. /a3 hiu sut phVn 7ng tkng
h:p $H
*
. Cc th@ t0ch cu o [ cfng nhiRt 2 =? p sut.
Cu D: Vit cc phZng tranh phVn 7ng icu ch $H
*
a. /y CaC!
*
# &$H
"
'
2
!
"
=? H
2
!
,. /y <g# $
2
# =? H
2
!.
Cu K: BSn 1#*"" l0t ;h0 $H
*
=?o ,anh cE ch7a 6#892 l0t Cl
2
&cc ;h0 o [ ;tc'.
a. /0nh A th)o th@ t0ch ca hzn h:p sau phVn 7ng.
,. /0nh ;hFi l:ng 3uFi a3oni clorua thu :c.
Cu 16: Cho 1#> l0t ;h0 $H
*
&;c' ùa Fng Tng 12g Cu! nung nEng thu :c cht rUn t
a. /0nh ;hFi l:ng Cu! ,o ;hM.
,. /0nh th@ t0ch 55 HCl cE pHC1 tFi thi@u @ tc 5ing ht l:ng Cu! cE tirng t.
Cu 11: Xy hzn h:p $H
"
$!
*
# $H
"
Cl cho tc 5ing =i 55 $a!H 5 un nh thu :c 2#12> g ;h0 . Cfng
l:ng hzn h:p trRn tc 5ing =i 55 +g$!
*
5 thu :c 1"#*>g ;t ta.
a. Vit phZng tirnh21 hEa hWc [ 5Ong phn tM =? 5Ong ion thu gWn
,. /0nh th?nh phQn A 3zi nuFi trong hzn h:p ,an Qu
Cu 12: B5 $H
*
2>A cE ;hFi l:ng riRng BC6#K1g43l.
a. /rong 1663l 55 cE hJa tan ,ao nhiRu l0t $H
*
o [ ;c..
,. /0nh th@ t0ch 55 $H
*
trRn l?3 ;t ta ht cation +l
*I
cE trong 1663l 55 +l
2
&!
"
'
*
1#11><.
II. Ph !&'( )hi*+
Cu 1: -h0 $
2
rt ,cn# [ nhit 2 thdng ;hbng tha3 gia phVn 7ng hEa hWc l? 5o
a. $itZ cE ,n ;0nh nguyRn tM nhx
,. $itZ cE 2 3 in ln nht trong phn nhE3 ch0nh.
G/0 L1 Ch2 N)$3* - > - T&45) THPT N)$36 7.i
c. ]2 3 in ca $ ln nhng chL thua ! =? (.
5. /rong phn tM nito cE liRn ;t ,a rt ,cn.
Cu 2: {on $
*G
cE cu hanh ) giFng cu hanh ) ca
a. +r ,. +l
*I
c. Cl 5. $a
Cu *: !ît n?o sau y :c icu ch trTc tip ty ;h0 nitZ =? oî P
a. $! ,. $!
2
c. $
2
! 5. $
2
!
>
.
Cu ": H:p cht ca $ l?
a. $! ,. $!
2
c. $
2
! 5. $
2
!
>
.
Cu >: -h0 n?o :c iu ch ty phVn 7ng nhit phn 3uFi nitrat ca ;i3 loOi P
a. $! ,. $!
2
c. $
2
! 5. $
2
.
Cu 8: /rong phJng th0 nghi3 ngdi ta icu ch 1 l:ng nhx ;h0 nitZ# ,Hng cch
a. $hit phn $H
"
$!
*
n ;hFi l:ng ;hbng ki
,. Chng ct phn oOn ;hbng ;h0 loNng.
c. ]un 55 $a$!
2
=? 55 $H
"
Cl ,No hJa.
5. ]un nEng <g ;i3 loOi =i 55 H$!
*
loNng
Cu 9: .ht ,i@u n?o sau sai =c nitZ
a. Bo liRn ;t ,a rt ,cn nRn [ nhit thdng $
2
;}3 hoOt 2ng.
,. <2t l:ng nhx nitZ 5fng @ sVn ût $H
*
# phn O3# H$!
*
# thuFc nk.
c. Bo [ phn nhE3 ch0nh nhE3 V nRn $itZ cE hEa tro V
5. $
2
cE trong cc h:p cht hYu cZ ph7c tOp nh protit# aît a3in.
Cu D: [ icu ;in thdng ;hbng t1n tOi hzn h:p ;h0
a. $
2
# !
2
,. $!# !
2
c. $H
*
# !
2
5. $
2
# H
2
.
Cu K: $
2
th@ hin t0nh ;hM trong phVn 7ng =i
a. H
2
,. !
2
c. Xi 5. <g
Cu 16: /rong phJng th0 nghi3 cE th@ icu ch $
2
,Hng cch:
a. $hit phn $a$!
2
,. ]un hzn h:p $H
"
Cl =? $a$!
2
c. /hy phn <g
*
$
2
5. .hn hy ;h0 $H
*
.
Cu 11: ChWn &cc' 3uFi )3 nhit phn tOo th?nh ;h0 $
2

a. $H
"
$!
2
,. $H
"
$!
*
c. $H
"
HC!
*
5. $H
"
$!
2
=? $H
"
$!
*
.
Cu 12: BNy cc cht cu phVn 7ng =i a3oniac trong icu ;in th0ch h:p l?
a. HCl# !
2
# Cl
2
# ()Cl
*
,. H
2
!
"
# %a&!H'
2
# ()!# $a!H
c. HCl# H$!
*
# +lCl
*
# Ca! 5. -!H# H$!
*
# Cu!# CuCl
2
.
Cu 1*: $hx ty tf 55 $H
*
n 5 =?o 55 Cu!
"
=? lUc cu 55. puan st thy:
a. CE ;t ta ;)o ânh la3 nhicn 5Qn ;hbng tan
,. CE ;t ta ;)o ânh la3#tan 5Qn tOo 55 ânh thS3
c. CE ;t ta ;)o ânh la3 nhicu 5Qn r1i tan 5Qn n ht.
5. /Oo 55 ânh thS3.
Cu 1": $hx ty ty 55 $H
*
n 5 =?o 55 vnCl
2
=? lUc cu 55. puan st thy
a. CE ;t ta ;)o trUng nhicu 5Qn ;hbng tan.
,. CE ;t ta ;)o trUng nhicu 5Qn r1i tan tOo 55 ic.
c. CE ;t ta ;)o trUng tnng 5Qn r1i tan tOo 55 trong suFt.
5. -hbng cE hin t:ng ga ^Vy ra.
Cu 1>: %Oc clorua cE th@ tan :c trong
a. 55 $H
*
\c ,. 55 H$!
*
\c c. 55 $a!H \c 5. nc cdng toan.
Cu 18: -h0 $H
*
l? cht ;h0 ùan trWng trong cbng nghip sVn ût H$!
*
. /0nh cht hEa hWc \c trng
cho $H
*
l?
a. Vya cE t0nh ;hM =ya cE t0nh oî hEa
,. ChL cE t0nh oî hEa
c. Vya cE t0nh oî hEa =ya cE t0nh ,a_Z
5. Vya cE t0nh ;hM =? =ya cE t0nh ,a_Z
Cu 19: ]@ icu ch :c >1g $H
*
=i hiu sut phVn 7ng Ot 2>A# th@ t0ch ;h0 $
2
&;c' cQn l?
a. **#8 l0t ,. 89#2 l0t c. 1*"#" l0t 5. 28D#D l0t
G/0 L1 Ch2 N)$3* - ? - T&45) THPT N)$36 7.i
Cu 1D: /0nh ,a_Z ca $H
*
5o:
a. /rRn $ cJn c\p ) tT 5o
,. .hn tM cE * liRn ;t c2n ghEa tro phn cTc
c. $H
*
tan :c nhicu trong nc
5. $H
*
tc 5ing =i nc tOo $H
"
!H.
Cu 1K: $H
*
th@ hin t0nh ,a_Z trong phVn 7ng
a. 2$H
*
I H2!" | &$H
"
'
2
!
"
,. 2$H
*
I *Cu! | *Cu I $
2
I *H
2
!.
c. "$H
*
I >!
2
| "$! I 8H
2
!
5. 2$H
*
I *Cl
2
| $
2
I 8HCl.
Cu 26: [ nhit 2 26
6
C 32t l0t nc hJa tan :c a l0t $H
*
. gi tro a l?
a. >66 ,. *66 c. "66 5. D66
Cu 21: /rong phJng th0 nhi3 cc lo ch7a 55 $H
*
# n1ng 2 tFi a cng chL Ot :c:
a. >6A ,. 9>A c. *6A 5. 2>A
Cu 22: ]icu ch $H
*
ty hzn h:p g13 $
2
=? H
2
&tL l 3ol 1:*'. /L ;hFi hzn h:p trc so =i hzn h:p sau
phVn 7ng l? 6#8. Hiu sut phVn 7ng l?
a. 9>A ,. 86A c. 96A 5. D6A
Cu 2*: /hTc hin phVn 7ng giYa $
2
=? H
2
&tL l 3ol 1:"'# trong ,anh ;0n cE êc tc# thu :c hzn h:p cE
p sut giV3 16A so ,an Qu &cfng icu ;in'. Hiu sut phVn 7ng l?
a. 2>A ,. >6A c. 9>A 5. 86A
Cu 2": B5 $H
*
cE th@ tc 5ing :c =i cc 55:
a. $aCl# CaCl
2
,. -$!
*
# -
2
!
"
c. CuCl
2
# +lCl
*
5. %a&$!
*
'
2
# +g$!
*
.
Cu 2>: C\p 3uFi n?o tc 5ing =i 55 $H
*
5 cu thu :c ;t ta P
a. $a
2
!
"
# <gCl
2
,. +lCl
*
# ()Cl
*
c. Cu!
"
# ()!
"
5. +g$!
*
# vn&$!
*
'
2
.
Cu 28: Cht n?o sau y cE th@ l?3 ;hb ;h0 $H
*
P
a. .
2
!
>
,. H
2
!
"
\c c. Cu! ,2t 5. $a!H &rUn'
Cu 29: Hin t:ng th0 nghi3 n?o sau y l? h:p l0 nht P
,456 789: N:; N<*H =>5 7? N:; 5?@9 NH
3
=>5 7?
+ +lCl
*
CE ;t ta rFi tan CE ;t ta rFi tan
% +g$!
*
C ()Cl
*
B vnCl
2
Cu 2D: <2t hzn h:p hai cht g13 $
2
! =? 32t oît ca nitZ &$
^
!
y
' cE tL ;hFi hz h:p so =i hi5ro l? 1D#>.
/a3 ^#y
a. ^CyC1 ,. ^C1 yC2 c. ^C2 yC" 5. ^C2 yC*.
Cu 2K: -hi nhit phn "6g a3oni nitrit tha th@ t0ch ;h0 $itZ thu :c &;tc' ,Hng:
a. "#"D l0t ,. D#K8 l0t c. 1" l0t 5. 22#" l0t
Cu *6: <2t hz h:p t g13 2 ;h0 C!
2
=? 32t oît ca 32t $itZ. /a3 cbng th7c =? t0nh A th@ t0ch oît ca
$itZ# ,it tL ;hFi hZi ca hzn h:p t so =i hi5ro ,Hng 1D#>.
a. Cbng th7c $
2
!# th?nh phQn >6A
,. Cbng th7c $!# th?nh phQn >6A
c. Cbng th7c $!
2
# th?nh phQn >6A
5. Cbng th7c $
2
!
"
# th?nh phQn >6A
Cu *1: $ung hzn h:p g13 2 3ol a3oniac =? > 3ol oî @ phVn 7ng ho?n to?n trong 1 ,anh ;0n r1i a =c
nhit 2 ,an Qu & ,it nc [ th@ hZi' . /L l p sut ,anh sau phVn 7ng so =i ,an Qu l?
a. 1>41" ,. 164D c. 1649 5. 849
Cu *2: <uFi :c 7ng 5ing l?3 ,2t n[i trong thTc ph3 l?
a. &$H
"
'
2
C!
*
,. $a
2
C!
*
c. $H
"
HC!
*
5. $H
"
Cl
Cu **: $u chL 5fng 55 $a!H ;hbng th@ tch $
2
ra ;hxi hzn h:p =i :
a. !
2
,. !
2
c. Cl
2
5. HCl
Cu *": -hi nung a3oni clorua# @ trnh sT tc 5ing tr[ lOi giYa ;h0 $H
*
=? HCl cQn phVi
a. Cho hzn h:p ;h0 ang nEng ùa 55 $a!H
,. $ung nEng a3oni clorua trong icu ;in ;hbng cE ;hbng ;h0
c. /r2n a3oni clorua =i i!
2
trc ;hi nung
G/0 L1 Ch2 N)$3* - 1@ - T&45) THPT N)$36 7.i
5. /r2n a3oni clorua =i caîhi5roît trc ;hi nung
Cu *>: ]@ phn ,iRt " 55: &$H
"
'
2
!
"
# $H
"
Cl# $a
2
!
"
# $a!H ta cE th@ chL 5fng:
a. 55 %aCl
2
,. 55 +g$!
*
c. 55 %a&!H'
2
5. 55 $a!H
Cu *8: B5 ch7a " 3uFi: CuCl
2
# ()Cl
*
# vnCl
2
# +lCl
*
. $u thR3 =?o 55 trRn $a!H 5 r1i thR3 tip $H
*

5 sm thu :c ;t ta ch7a:
a. 1 cht ,. 2 cht c. * cht 5. " cht
Cu *9: ChWn pht ,i@u eng P
a. Cc 3uFi a3oni cu ,o nhit phn cho ;h0 a3oniac
,. <uFi a3oni l? cht tinh th@ ion# phn tM g13 anion a3oni =? cation ;i3 loOi
c. /inh th@ 3uFi a3oni cu 5 tan trong nc =? l? cht in li 3Onh
5. <uFi a3oni tc 5ing =i 55 ;ic3 \c# nEng cE thot ;h0 l?3 giy ù hEa ânh.
BI A: AXIT NIT)IC V MUI NIT)AT
I. Ph !" #$%
Cu 1: %k tec =? cn ,Hng phZng tranh phVn 7ng th)o phZng php cn ,Hng ) =? =it phZng tranh ion
ret gWn:
1. vn I
*
HNO
&loNng' |j I $! Ij
2. <g I
*
HNO
&loNng' | $
2
IjIj
*. ()
*
!
"
I
*
HNO
&loNng' | $! IjIj
". ()
2
I
*
HNO
&#t
6
' |
2 "
H SO
IjIj
>. +s
2
*
I
*
HNO
I H
2
! | $! I jIj
8. ()
2
!
*
I
*
HNO
&loNng' | jIj
Cu 2: Vit phZng tranh hEa hWc cho cc 5Ny chuy@n hEa sau:
1.
*
HNO
| +g$!
*
|$!
2
| $!| $a$!
*
| $a$!
2
| $
2

2. $H
*
| $!|$!
2
|$a$!
*
|
*
HNO
| Cu&$!
*
'
2
| Cu!| CuCl
2
|Cu&!H'
2
| rCu&$H
*
'
"
s
&!H'
2
| $H
*
.
*. $H
*
|$!|$!
2
|
*
HNO
|Cu&$!
*
'
2
|$!
2
|
*
HNO
| $H
"
$!
*
|$a$!
*
|$H
*
". %Oc nitrat| $itZ| aît nitric| nhb3 nitrat| a3oni nitrat| ;ali nitrat| aît nitric| ,Oc
nitrat.
>.
%
2
C H O + +

Mg +
$
2
!
+ C
6
2
4 *666 N C
(
C +
%
B
HCl
g
NaOH
Cu&!H'
2
.
Cu *:
a. ChL 5fng 1 3uFi# nRu phZng php phn ,it " 55: %a&!H'
2
# $a!h#
*
HNO
# $a$!
*
.
,. ChL 5fng nhit phn =? H
2
!# nRu cch phn ,it cc 3Su hEa cht th@ rUn: ()&$!
*
'
*
# -!H#
$H
"
Cl# Hg&$!
*
'
2
# +l&$!
*
'
*
.
Cu ": Cho ,a 3ing +l ;i3 loOi =?o ,a Fng nghi3 ch7a 55 H$!
*
n1ng 2 ;hc nhau# hin t:ng ùan
st :c :
I ng 1: cE ;h0 ;hbng 3?u ,ay ra hEa nu trong ;hbng ;h0.
I ng 2: cE ;h0 ;hbng 3?u# ;hbng chy# hZi nh hZn ;hbng ;h0.
I ng *: ;hbng cE ;h0 thot ra# nhng 55 tOo th?nh cho tc 5ing =i 55 $a!H 5# cE ;h0 3fi ;hai
thot ra.
Cu >: Cho 3 ga3 hzn h:p t g13 vn =? Cu tc 5ing =ya =i 8"3l 55
*
HNO
1>< &\c' un nEng ta
thu :c 32t 55 + =? ;h0 $!
2
. Cb cOn 55 + :c ">#21g hzn h:p 2 3uFi.
a. /0nh 3
,. Cho 2 3uFi trong 55 + tc 5ing =ya =i 2663l 55 $a!H @ thu :c ;hFi l:ng ;t ta
ln nht =? nhx nht. t0nh n1ng 2 3ol4l ca 55 trong 3zi trdng h:p.
Cu 8: Hzn h:p g13 +l# () =? Cu# ;hFi l:ng *"#Dg# :c chia th?nh 2 phQn ,Hng nhau:
G phQn 1: cho =?o 55
*
HNO
q3 \c# ngu2i tha cE "#"D l0t &;tc' 32t cht ;h0 3?u x nu ,ay ra
G phQn 2: cho =?o 55 HCl tha cE D#K8 l0t &;tc' 32t cht ;h0 ,ay ra.
G/0 L1 Ch2 N)$3* - 11 - T&45) THPT N)$36 7.i
/0nh ;hFi l:ng 3zi ;i3 loOi trong hzn h:p.
Cu 9: HJa tan "#D8g 32t ;i3 loOi < &hEa tro ;hbng ki' =?o l:ng =ya 55
*
HNO
22A thu :c 1#*""
l0t &;tc' hzn h:p ;h0 $
2
=? $
2
! cE tL ;hFi hZi so =i H
2
l? 1#12> &;hbng tOo th?nh $H
"
$!
*
'
a. tc onh <
,. /0nh n1ng 2 A ca 3uFi trong 55 thu :c.
Cu D: <2t oît ;i3 loOi <
^
!
y
# trong E < chi3 92#"1A ;hFi l:ng. -hM ho?n to?n oît n?y ,Hng ;h0
C! thu :c 18#Dg ;i3 loOi <. HJa tan ho?n to?n l:ng < ,Hng
*
HNO
\c nEng thu :c 3uFi ca < =?
6#K 3ol ;h0 $!
2
. Vit phZng tranh phVn 7ng =? ^c onh cbng th7c oît.
Cu K: $ung 1>#6" ga3 Cu&$!
*
'
2
32t thdi gian thy cJn lOi D#>8 ga3 cht rUn.
a. /0nh hiu sut ca phVn 7ng nhit phn
,. tc onh th?nh phQn A cht rUn cJn lOi
c. Cho ;h0 sinh ra hp thi ho?n to?n =?o 1K*#>2 ga3 55 $a!H *#1A :c 55 t. /0nh CA cht
tan trong 55 t.
Cu 16: -hi nung D*#8g hzn h:p Cu&$!
*
'
2
=? Hg&$!
*
'
2
n ;hi ;hFi l:ng ;hbng ki tha thu :c 1K#6"
l0t hzn h:p ;h0 &;tc'
a. /0nh ;hFi l:ng 3zi 3uFi ,an Qu. Cho HgC266
,. Cho hzn h:p ;h0 thu :c hp thi =?o *89#8g H
2
!. t0nh n1ng 2 A cht tan trong 55 thu :c.
II. Ph !&'( )hi*+
Cu 1: $ trong phn tM
*
HNO
cE hEa tro:
a. * ,. " c. > 5. I>
Cu 2: +ît nitric ;hi tc 5ing =i ;i3 loOi ;hbng tOo ra ;h0 H
2
=a:
a.
*
HNO
cE t0nh oî hEa 3Onh ,.
*
HNO
l? cht in li 3Onh
c. tc nhn oî hEa l? gFc $!
*
G
5. ion H
I
N chuy@n hEa th?nh H
2
!.
Cu *: gFc nitrat $!
*
G
th@ hin t0nh oî hEa trong 3bi trdng
a. aît ,. ,a_o c. trung t0nh 5. aît ho\c ,a_o
Cu ": .hZng tranh phVn 7ng: vn I
*
HNO
| vn&$!
*
'
2
I $H
"
$!
*
I H
2
!. CE tkng h sF cc cht tha3
gia l?
a. 16 ,. 12 c. 1" 5. 18
Cu >: B5
*
HNO
\c ;hbng 3?u# nhng 5i tc 5ing ca nh sng# 55 cE 3?u hZi =?ng l? 5o:
a.
*
HNO
,o ;hM ,[i tOp cht cE trong ;hbng ;h0
,.
*
HNO
,o phn t0ch th?nh $!
2
# r1i tan lOi trong 55
c. 55 hp thi cc ;h0 cE 3?u lSn trong ;hbng ;h0
5. 55 lSn 1 0t ;h0 $! N ,o oî hEa tip th?nh $!
2
.
Cu 8: HJa tan D"g hzn h:p Cu =? vn! ,Hng 55
*
HNO
loNng 5# thu :c "#"D l0t ;h0 &;tc' tha tL l sF
3ol Cu =? vn! tZng 7ng l?:
a. 6#9> ,. 1 c. 1#> 5. 6#*9>
Cu 9: t}t phVn 7ng sau: ()! I
*
HNO
| t I $! I H
2
!. t =? tkng h sF cn ,Hng ca sVn ph3 l?
a. ()&$!
*
'
2
=? 1D ,. ()&$!
*
'
*
=? K c. ()&$!
*
'
*
=? 8 5. ()&$!
*
'
*
=? 22
Cu D: HJa tan 12#Dg ;i3 loOi hEa tro {{ trong 1 l:ng =ya 55
*
HNO
8DA &BC1#"6g43l'# thu :c D#K8
l0t &;tc' 32t l:ng ;h0 5uy nht 3?u nu x. /Rn ca ;i3 loOi =? th@ t0ch 55
*
HNO
N phVn 7ng l?
a. 1ng# >2#K"3l ,. 1ng# 16>#DD3l c. thy ngn# 8>#13l 5. canî# 162#D3l
Cu K: -hi un nEng# phVn 7ng giYa c\p cht n?o sau y tOo ra ,a oît P
a. aît nitric \c =? cac,on ,. aît nitric \c =? 1ng
c. aît nitric \c =? lu hunh 5. aît nitric \c =? ,Oc
Cu 16: -hi hJa tan ">g hzn h:p Cu =? vn! trong 55
*
HNO
1< ly 5# thy thot ra 8#92 l0t ;h0 $!
&;c'. -hFi l:ng vn! trong hzn h:p ,an Qu l?
a. 2>#Dg ,. 18#2g c. 2D#Dg 5. 2>#2g
Cu 11: +ît nitric \c# ngu2i# phVn 7ng :c =i tt cV cc cht trong nhE3 n?o sau y P
a. H
2
# Cu# $H
*
# +g ,. <g&!H'
2
# $H
*
# C!
2
#+u
c. <g&!H'
2
# $H
*
# Cu!# .t 5. Ca!# $H
*
# +l# ()Cl
2
G/0 L1 Ch2 N)$3* - 18 - T&45) THPT N)$36 7.i
Cu 12: Cho 6#6K 3ol Cu =?o "663l 55 ch7a
*
HNO
6#*< =? H
2
!
"
6#1<. ]n ;hi phVn 7ng ;t thec# th@
t0ch ;h0 $! 5uy nht thot ra &;tc' l?
a. 6#892 lit ,. 6#DK8 l0t c.1#*"" l0t 5. 1#12 l0t
Cu 1*: Cho *6#8g hzn h:p Cu# vn# () tc 5ing 55
*
HNO
loNng 5 thu :c 55 ch7a K2#8g 3uFi ;han.
$ung hzn h:p trRn n ;hFi l:ng ;hbng ki thu :c cht rUn cE ;hFi l:ng l?
a. "8#8g ,. *D#8g c. 82#8g 5. "K#2g
Cu 1": Cho *#>Dg +l# ()# Cu ,Hng 55
*
HNO
thu :c 6#6" 3ol $! =? 6#68 3ol $!
2
;hFi l:ng hzn h:p
3uFi ;han thu :c:
a. 18#>Dg ,. 1>#*2g c. 1"#9"g 5. 1D#22g
Cu 1>: Cho 1"#1g +l =? <g hJa tan ht trong 55
*
HNO
thu :c 6#2 3ol ;h0 $! =? 6#1 3ol ;h0 $
2
!.
/kng sF hai 3ol ;i3 loOi l?
a. 6#>> ,. 6#86 c. 6#8> 5. 6#">
Cu 18: Cho 1* ga3 vn =?o 55
*
HNO
&=ya ' thu :c 8#92 l0t hzn h:p $! =? $!
2
&o [ ;tc'. F 3ol
*
HNO
tFi thi@u trong 55 l?:
a. 6#9 ,. 6#> c. 1#2 5. 1#6
Cu 19: ]@ phn ,it * 55 loNng
*
HNO
# HCl# H
2
!
"
ta chL 5fng ;i3 loOi
a. +l. <g ,. Cu#+g c. vn#() 5. Cu#%a
Cu 1D: ]un nEng 88#2g .,&$!
*
'
2
# sau phVn 7ng thu :c >>#"g cht rUn# Hiu sut phVn 7ng l?
a. D6A ,. 96A c.>6A 5.*6A
Cu 1K: 5Ny 3uFi nitrat ;hi nhit phn cu cho ra ;i3 loOi P
a. vn&$!
*
'
2
# -$!
*
# .,&$!
*
'
2
,. Cu&$!
*
'
2
# Xi$!
*
# -$!
*
c. Ca&$!
*
'
2
# Xi$!
*
# -$!
*
5. Hg&$!
*
'
2
# +g$!
*
.
Cu 26: Cho phVn 7ng 2<&$!
*
'
n

6
t
<
2
!
3
I j$!
2
I j!
2
. ChWn ;i3 loOi < trong sF cc ;i3 loOi
sau: & ,it 3n'
a. -# na ,. ()# Cr c. Cu# <g 5. +g# Hg
Cu 21: /rong phJng th0 nghi3# icu ch
*
HNO
,Hng phVn 7ng
a. $a$!
*
I H
2
!
"
&# t
6
' |
*
HNO
I $aH!
"
.
,. "$!
2
I 2H
2
! I !
2
| "
*
HNO
c. $
2
!
>
I H
2
! | 2
*
HNO
5. %a&$!
*
'
2
I H
2
!
"
| %a!
"
I 2
*
HNO
Cu 22: $hit phn ho?n to?n 3uFi $!
*
&: cation hEa tro 1' thu :c ;h0 nu thot ra =? phQn rUn thu
:c ;hbng tan trong 55 H
2
!
"
loNng. ChWn 3uFi th0ch h:p:
a. $a$!
*
,. $H
"
$!
*
c. Cu&$!
*
'
2
5. +g$!
*
Cu 2*: $ung 8#>Dg Cu&$!
*
'
2
32t thdi gian :c "#K8g rUn =? hzn h:p ;h0 t. Cho t =?o nc :c
*663l 55 u cE pH l?
a. 1#66 ,. 1#1D c. 1#>2 5.1#96
Cu 2": ChWn phZng tranh phVn 7ng nhit phn =it ;hbng eng:
a. 2-$!
*

6
t
2-$!
2
I !
2
.
,. Hg&$!
*
'
2

6
t
Hg I 2$!
2
I !
2
.
c. 2()&$!
*
'
2

6
t
2()o I "$!
2
I !
2
.
5. "+l&$!
*
'
*

6
t
2+l
2
!
*
I 12$!
2
I *!
2
.
Cu 2>: $hit phn ho?n to?n *#>Dg hzn h:p $a$!
*
=? Cu&$!
*
'
2
. /o?n ,2 sVn ph3 ;h0 thu :c 5Sn
ùa H
2
! tha cE 6#22" l0t &;tc' ;h0 ;hbng ,o hp thi. .hQn trn3 ;hFi l:ng $a$!
*
trong hzn h:p ,an Qu
a. *8#>DA ,. >2#>2A c. ">#8DA 5. "9#"DA
Cu 28: ChL 5fng cch nhit phn# cE th@ phn ,it c\p hEa cht &th@ rUn' sau:
a. &$H
"
'
2
C!
*
# $H
"
Cl ,. +g$!
*
# %a&!H'
2
c. CaC!
*
# $H
"
HC!
*
5. % ho\c C
Cu 29: B5 t &loNng' ch7a cc ion H
I
# Cu
2I
# $!
*
G
# !
"
2G
. ]@ nhqn ,it sT cE 3\t cc anion trong t ta 5fng
a. ,2t Cu# 55 %aCl
2
. ,. +g$!
*
# %a&!H'
2
. c. $a!H# 55 %aCl
2
. 5. HCl# %a&!H'
2
.
G/0 L1 Ch2 N)$3* - 19 - T&45) THPT N)$36 7.i
Cu 2D: ChWn cu sai: 3uFi nitrat
a. /h@ hin t0nh oî hEa trong 3bi trdng aît
,. HQu ht cu ,o nhit phn
c. CE th@ :c 5fng l?3 phn O3
5. t 5 tan trong 3Wi 5ung 3bi
Cu 2K: <2t 55 ch7a 6#6K 3ol -$!
*
# thR3 "663l 55 H
2
!
"
6#6D<. Bung 5och tOo th?nh hJa tan :c tFi
a 3 ga3 ,2t Cu. gi tro ca 3 l?
a. D#8"g ,. 6#98Dg c. 1#>*8g 5. "#>*2g
Cu *6: ChWn 3uFi ;hi nhit phn ho?n to?n ;hbng cE cht rUn tOo th?nh
a. $a$!
*
,. CaC!
*
c. $H
"
$!
*
5. Cu&$!
*
'
2
.
BI /: &H*T&H* 3 AXIT &H*T&H*)IC V MUI &H*T&HAT
I. Ph !" #$%
Cu 1: ]Ft chy ht K#*g photpho trong oî. Vn ph3 tOo th?nh tc 5ing =i 1963l 55 $a!H 2< thu
:c 3uFi:
a. $a
2 "
H .!
=? $a
2 "
H.!
,. $a
2 "
H .!
=?
* "
$a .!
c.
2 "
$a H.!
=?
* "
$a .!
5.
* "
$a .!

Cu 2: /rong icu ;in thdng# photpho hoOt 2ng hEa hWc 3Onh hZn $itZ =a
a. $guyRn tM photpho cE 2 3 in ln hZn nguyRn tM $itZ
,. $guyRn tM photpho cE ,n ;0nh nguyRn tM ln hZn nguyRn tM $itZ
c. XiRn ;t giYa cc nguyRn tM trong phn tM photpho ;}3 ,cn hZn
5. .hotpho cE nguyRn tM ;hFi ln hZn nguyRn tM $itZ
Cu *: .hotpho trUng =? photpho x l? 2 5Ong thf hanh nRn
a. cu cE t0nh cht =a8tli1 =? t0nh cht hEa hWc nh nhau
,. cu cE cu tOo phn tM nh nhau
c. cu 5 nEng chVy =? 5 ,ay hZi
5. cu tc 5ing =i oî tOo th?nh oît
Cu ": .hotpho trUng =? photpho x cE cu trec th)o th7 tT l?:
a. poli3)# phn tM. ,. nguyRn tM# phn tM c. phn tM# poli3) 5. phn tM# nguyRn tM
Cu >: ]un nEng hzn h:p canî =? photpho &;hbng cE ;hbng ;h0' phVn 7ng ho?n to?n tOo th?nh hzn h:p
t
1
. Cho t
1
tc 5ing ht =i 55 HCl 1< tOo th?nh hzn h:p ;h0 t
2
g13:
a.
2
H
=? HCl ,.
2
H
c. .H
*
=?
2
H
5.
*
.H
Cu 8: B5 aît phtphoric cE ch7a cc ion &,x ùa sT in li ca nc':
a.
H
+
#
*
"
.!

,.
H
+
#
2
"
H.!

#
*
"
.!

c.
H
+
#
2 "
H .!

#
*
"
.!

5.
H
+
#
2 "
H .!

#
2
"
H.!

#
*
"
.!

.
Cu 9: C\p cht n?o cE th@ ^Vy ra phVn 7ng
a.
* "
H .!
=? ,. $a =?
* "
H .!
c.
* "
H .!
=? !
2
5.
* "
H .!
=?
*
H$!
Cu D: Cho "Dg 55 $a!H 16A tc 5ing =i 16g 55 aît photphoric *K#2A. -hFi l:ng 3uFi ;han thu
:c sau phVn 7ng l?:
a. 8#>8g ,. "#""g c. "#Dg 5. K#2"g
Cu K: ]Ft chy ho?n to?n 8#Dg hzn h:p cht + ca photpho tOo th?nh 1"#2g .
2
!
>
=? H
2
! . Cbng th7c
phn tM ca + l?:
a.
* "
H .!
,. H
"
.
2
!
9
c.
*
.H
5. H
*
.!
*
.
Cu 16: ChWn 5Y ;in eng liRn ùan n aît photphoric:
1. th@ lxng 2. 5 tan *. cE t0nh oî hEa ". 5 nEng chVy
>. rt ,cn nhit 8. in li trung ,anh
a. 1#"#8 ,. 2#"#8 c. 2#*#> 5. 1#2#8
Cu 11: /r2n ">6 3l 55 $a!H 1< =i 1>63l 55
* "
H .!
2<# 55 thu :c ch7a
a.
* "
$a .!
=? $a!H ,.
2 "
$a H.!
=?
* "
$a .!

c.
2 "
$aH .!
=?
* "
H .!
5.
2 "
$aH .!
=?
2 "
$a H.!
.
Cu 12: HJa tan 1"2g .
2
!
>
3l =?o >66g 55
* "
H .!
2"#>A. $1ng 2 A ca
* "
H .!
trong 55 thu :c
a. "K#81A ,. >8#*2A c. "D#D8A 5. 8D#9>A
G/0 L1 Ch2 N)$3* - 1: - T&45) THPT N)$36 7.i
Cu 1*: /r2n 55 ch7a a 3ol Ca&!H'
2
=i 55 ch7a , 3ol
* "
H .!
. ChWn tL l hCa4, @ sao phVn 7ng# th?nh
phQn 3uFi thu :c g13 Ca&
2 "
H .!
'
2
=? CaH.!
"

a. 1h2 ,. 6#>h1 c. 2h* 5. 1h1#>
Cu 1": .ht ,i@u n?o sau y ;hbng ch0nh ^c
a. Cc 3uFi ihi5rophotphat cu 5 tan
,. Cc 3uFi photphat# hi5rophotphat ca ;ali# natri# a3oni 5 tan
c. Cc 3uFi photphat tan ,o thy phn tOo 3bi trdng ,a_Z
5. Cc 3uFi photphat tan ,o thy phn tOo 3bi trdng aît
Cu 1>: ]@ nhqn ,it " lW ch7a cc 55 $a
2
# $aCl#
* "
$a .!
# $a$!
*
chL cQn 5fng
a. %aCl
2
,. +g$!
*
c. ù t03 5. HCl
Cu 18: ChWn 3uFi 5 tan trong nc nht
a. Ca
*
&.!
"
'
2
,. CaH.!
"
c. Ca&
2 "
H .!
'
2
5. CaH.!
"
.
2
H !

Cu 19: t}t chuy@n hEa:
* "
H .!

* " 2
Ca &.! '
Ca&
2 "
H .!
'
2
=i hiu sut D6A. ]@ icu ch :c *6 3ol
Ca&
2 "
H .!
'
2
;hFi l:ng
* "
H .!
cQn
a. >#DD tn ,. "#K tn c. D#K tn 5. K#D tn
Cu 1D: -hFi l:ng ù\ng photphorit &ch7a 82A Ca
*
&.!
"
'
2
' cQn thit @ icu ch 1 tn
* "
H .!
"KA &hiu
sut D6A' l?
a. 1#>82> tn ,. 1#2*6" tn c. 1#8>2> tn 5. 1#>28> tn.
BI B: &HCN BDN HDA HEC
I. Ph !" #$%
Cu 1: ChWn pht ,i@u ;hbng ch0nh ^c. .hn ,En hEa hWc
a. Ch7a cc nguyRn tF 5inh 5wng nng cao nnng sut cy tr1ng
,. t}t =c ngu1n gFc g13 2 loOi: phn ,En hYu cZ =? =b cZ
c. ]:c gWi l? phn O3 nu ch7a cc 3uFi a3oni
5. ]:c gWi l? phn ln nu ch7a cc 3uFi a3oni photphat
Cu 2: .hn O3 l? loOi phn cE ch7a nguyRn tF
a. ()# ,. - c. $ 5. .
Cu *: ]2 5inh 5wng ca phn O3 :c nh gi ,Hng h?3 l:ng
Cu ": .hn ln l? loOi phn cE ch7a nguyRn tF
a. ()# ,. - c. $ 5. .
Cu >: ]2 5inh 5wng ca phn ln :c nh gi ,Hng h?3 l:ng
a. A$# A.# A- ,. A-
2
! c. A$ 5. A.
2
!
>
Cu 8: .hn urR thu2c loOi phn
a. ;ali ,. ]O3 c. Xn 5. Vi l:ng
Cu 9: up)photphat thu2c loOi
a. phn ;ali ,. phn O3 c. phn ln 5. phn =i l:ng
Cu D: Cbng th7c ca up)photphat ;}p
a. Ca&
2 "
H .!
'
2
I
"
Ca!
,. Ca
"
H.!
c. Ca&
2 "
H .!
'
2
5. Ca
"
H.!
.
2
H !

Cu K: .hn ;ali l? loOi phn cung cp cho cy tr1ng 5i 5Ong
a. - ,. ion -
I
c. $ 5. .
Cu 16: ]2 5inh 5wng ca phn ;ali :c nh gi ,Hng h?3 l:ng
a. A$# A.# A- ,. A-
2
! c. A$ 5. A.
2
!
>
Cu 11: H?3 l:ng &A' -Cl trong 32t loOi phn ,En cE A-
2
! C >6 l?
a. 9K#2>A ,. 92#8DA c. D6#8*A 5. 9"#9>A
Cu 12: .hn a3ophot l?
a.
" * "
&$H ' .!
,.
"
$H
2 "
H .!
c.
" 2
&$H '
"
H.!
5.
" 2
&$H '
"
H.!
I
"
$H
2 "
H .!

Cu 1*: ]@ icu ch 2"#9 ;g a3ophot &tL l sF 3ol cc 3uoi81trong a3ophot l? 1:1' tha ;hFi l:ng
* "
H .!

nguyRn cht cQn
a. K#D;g ,. 1K#8 ;g c. 1"#9;g 5. 18#D;g
CHNG 3: CACB*N 3 SILIC
BI F: CACB*N V HG& CH-T CA CACB*N
G/0 L1 Ch2 N)$3* - 1; - T&45) THPT N)$36 7.i
I. Ph !" #$%
Cu 1: .hn ,it ,a cht ;h0 C!
2
#
2
!
# $
2
ch7a trong ,a ,anh riRng ,it ,Hng phZng php hEa. Vit cc
phZng tranh phVn 7ng ch7ng 3inh.
Cu 2: %k tec =? =it cc phZng tranh phVn 7ng ^Vy ra:
a. C I
2 "
H !
&\c'
o
t
P ,. CIC!
2

o
t
P
c. Ca&HC!
*
'
2

o
t
CaC!
*
I P 5. CaC!
*
o
t
P
). C!
2
I Ca&!H'
2

o
t
P h. CaC!
*
I HCl | P
g. Ca&HC!
*
'
2
I HCl | P h. Ca&HC!
*
'
2
I Ca&!H'
2
| P
Cu *: Vit cc phZng tranh phVn 7ng th)o sZ 1 chuy@n hEa sau:
C | C!
2
| $a
2
C!
*
| $aHC!
*
| $a
2
C!
*
| <gC!
*
| <g&HC!
*
'
2
| CaC!
*
| C!
2
| C! |().
Cu ": Cho "#" ga3 C!
2
hp thi ho?n to?n =?o 1>63l 5ung 5och $a!H 1<. /0nh ;hFi lZng nhYng cht
cE trong 5ung 5och.
Cu >: Hp thi ho?n to?n 2#8DD l0t ;h0 C!
2
&;tc' =?o 2#> l0t 5ung 5och %a&!H'
2
n1ng 2 a 3ol4l0t# thu
:c 1>#98 ga3 ;t ta. /0nh gi tro ca a.
Cu 8: /rung hJa *> ga3 hzn h:p =? -
2
C!
*
,Hng 5ung 5och HCl =ya # thu :c 5ung 5och + =? 8#92 l0t
;h0 C!
2
&;tc'.
a. /0nh th?nh A ;hFi l:ng 3zi 3uFi trong hzn h:p ,an Qu.
,. Cb cOn 5ung 5och + :c hzn h:p rUn %. /0nh ;hFi l:ng hzn h:p %.
Cu 9: HJa tan 11#8 ga3 3uFi cac,onat ca ;i3 loOi < cE hE tro {{ ,Hng 5ung 5och
2 "
H !
&loNng' =ya
thu :c 32t cht ;h0 =? 5ung 5och +. cb cOn +# :c 1>#2 ga3 3uFi sunhat trung hJa# ;han. tc onh
cbng th7c ca 3uFi cac,onat.
Cu D: Bung 5och t ch7a a 3ol $a
2
C!
*
5ung 5och u ch7a , 3ol HCl &,2a'. Cho ty ty 5ung 5och t =?o
5ung 5och u thu :c V
1
l0t ;h0 C!
2
&;tc' cJn nu cho ty ty 5ung 5och u =?o 5ung 5och t thu :c V
2
l0t
;h0 C!
2
&;tc'. Cho ,it hin t:ng ^Ny ra =? t0nh V
1
=? V
2
th)o a#,.
Cu K: Cho V l0t ;h0 C!
2
&;tc' hp thi ho?n to?n =?o 2663l 5ung 5och hzn h:p -!H =? %a&!H'
2
6#9><
thu :c 2*#8" ga3 ;t ta. /a3 V.
Cu 16: Cho ;h0 C! ùa 3 ga3 hzn h:p + g13 Cu! =? +l
2
!
*
nung non5s# thu :c n ga3 hzn h:p rUn
%. /o?n ,2 ;h0 thot ra 5Sn ùa 5ung 5och Ca&!H'
2
5 thu :c p ga3 ;t ta. /a3 h th7c liRn h giYa
3#n#p.
II.Ph !&'( )hi*+0
Cu 1: Cu hanh )l)ctron cVu nguyRn tM cac,on l?
a. 1
2
2
2
2.
1
,. 1
2
2
2
2.
2
c. 1
2
2
2
2.
*
5. 1
2
2
2
2.
"
Cu 2: F )l)ctron hEa tro ca cac,on:
a. *. ,. ". c. >. 5. 8.
Cu *: -i3 cZng =? than cha l? hai 5Ong thf hanh ca nhau ,[i =a cheng
a. cE cu tOo 3Ong tinh th@ giFng nhau. ,. cu 5o nguyRn tF ca,on tOo nRn.
c. cE t0nh cht =qt l0 tZng tT nhau. 5. cE t0nh cht hEa hWc tZng tT nhau.
Cu ": $hqn ^}t n?o sau y eng =c t0nh oî hEa ca cac,onP
a. Cac,on ;hbng cE t0nh ;hM =? t0nh oî hEa. ,.Cac,on chL cE t0nh ;hM .
c. Cac,on chL cE t0nh oî hEa. 5. Cac,on cE cV t0nh ;hM =? t0nh oî hEa.
Cu >: Cac,on th@ hin t0nh oî hEa trong phVn 7ng:
a. CI !
2
| C!
2
,. CI C!
2
| 2C!
c. CI 2H
2
| CH
"
5. C I "H$!
*
| " $!
2
I C!
2
I 2H
2
!
Cu 8: Cac,on th@ hin t0nh ;hM trong phVn 7ng:
a. 2C I Ca | CaC
2
,. C I 2
2 "
H !
| 2
2
!

I C!
2
I 2
2
H !
.
c. CI 2H
2
| CH
"
5. *C

I "+l

| +l
"
C
*
.
Cu 9: !ît cac,on C! th@ hin t0nh ;hM trong phVn 7ng:
&1' C! I !
2
| C!
2
&2' C! I Cu! | C!
2
I Cu
&*' *C! I ()
2
!
*
| *C!
2
I 2() &"' C! I Cl
2
| C!Cl
2 .
a. &1' =? &2' ,. &1' =? &*' c. &1'# &2' =? &*' 5. &1'# &2'# &*' =? &"'.
G/0 L1 Ch2 N)$3* - 1< - T&45) THPT N)$36 7.i
Cu D: /huFc thM 5fng @ phn ,it C!
2
=?
2
!
l?
a. 5ung 5och Ca&!H'
2
. ,. 5ung 5och %a&!H'
2
.
c. 5ung 5och %r
2
loNng. 5. 5ung 5och $a!H.
Cu K: Cho 6#1 3ol C!
2
hp thi ho?n to?n =?o 5ung 5och ch7a 6#* $a!H. Cht tan trong 5ung 5och thu
:c l?
a. $aHC!
*
,. $a
2
C!
*
c. $aHC!
*
=? $a
2
C!
*
5. $a
2
C!
*
=? $a!H 5
Cu 16: ic 2#22" l0t ;h0 C!
2
&;tc' =?o "6 ga3 5ung 5och $a!H 16A. Cht tan trong 5ung 5och thu :c
l?
a. $aHC!
*
,. $a
2
C!
*
c. $aHC!
*
=? $a
2
C!
*
5. $a
2
C!
*
=? $a!H 5
Cu 11: Cho "#"g
2
C!
hp thi ho?n to?n =?o 1>63l 55 -!H 1<. Bung 5och thu :c ch7a
a.
*
-HC!
,.
2 *
- C!
c.
*
-HC!
=?
2 *
- C!
5.
2 *
- C!
=? -!H
Cu 12: -hi Ft 16 ga3 32t 3Su th}p t trong
2
!
5 r1i 5Sn to?n ,2 sVn ph3 ;h0
2
C!
ùa nc =bi
trong 5 tha thu :c 6#>g ;t ta. H?3 l:ng cac,on trong 3Su th}p t l?
a. 6#>A ,. 6#8A c. 2#2A 5. >#6A
Cu 1*: BSn 1#12 l0t
2
C!
i ùa 2 l0t 55
2
Ca&!H'
6#62<. -hFi l:ng ;t ta tOo th?nh l?
a. 2 ga3 ,. * ga3 c. " ga3 5. > ga3
Cu 1": Cho 5ung 5och Ca&!H'
2
=aoh 5ung 5och Ca&HC!
*
'
2
thy cE:
a. ;t ta trUng sau E tan 5Qn. ,. ,Wt ;h0 =? ;t ta trUng.
c. ;t ta trUng ût hin 5. ,Wt ;h0 ,ay ra.
Cu 1>: CE th@ 5fng $a!H &th@ rUn' @ l?3 ;hb cht ;h0:
a. $H
*
#
2
!
# C!# Cl
2
. ,. $
2
# $!
2
#
2
C!
#
2
H
.
c. $H
*
#
2
!
# $
2
#
2
H
. B. $
2
# Cl
2
#
2
!
#
C!.
Cu 18: Cho ty ty 55 ch7a a 3ol HCl =?o 55 ch7a , 3ol
2 *
$a C!
1ng thdi ;huy cu# thu :c V l0t ;h0
&;tc' =? 55 t. -hi cho 5 nc =bi trong =?o 55 t thy cE ;t ta ût hin. %i@u th7c liRn h giYa V =i
a#, l?:
a. VC22#"&aG,' ,. VC11#2&aG,' c. VC11#2&aG,' 5. VC22#"&aI,'
Cu 19: Hp thi ho?n to?n "#"D l0t ;h0
2
C!
&;tc' =?o 55 ch7a 18 ga3 $a!H thu :c 55 t. -hFi l:ng
3uFi tan trong 55 t l?
a. 16#8g ,. 1>#Kg c. 18#Dg 5.21#2g
Cu 1D: <2t loOi ch7a D6A
*
CaC!
# 16#2A
2 *
+l !
=? K#DA
2 *
() !
=c ;hFi l:ng. $ung [ nhit 2
1666
6
C 32t thdi gian thu :c cht rUn cE ;hFi l:ng ,Hng 9DA ;hFi l:ng trc ;hi nung. Hiu sut
phVn 7ng phn hy
*
CaC!
l?
a. 82#>A ,. >6#6A c. 9DA 5. K9#>A
Cu 1K: BSn lu1ng ;h0
2
C!
ty ty n 5 =?o Fng nghi3 ch7a nc =bi trong. Hin t:ng ùan st :c:
a. -hbng cE ;t ta ût hin
,. CE ;t ta trUng # ;hbng tan
c. CE ;t ta trUng# sau E ;t ta tan.
5. CE ;t ta ânh# sau E ;t ta tan
Cu 26: Cho >#8 l0t hzn h:p t g13
2
$
=?
2
C!
&;tc' i chq3 ùa > l0t 55
2
Ca&!H'
6#62< @ phVn 7ng
^Vy ra ho?n to?n# thu :c > ga3 ;t ta. /h@ t0ch
2
C!
&;c' l?
a. *#*8 l0t ho\c1#12 l0t ,. 2#2" l0t ho\c *#*8 l0t c. "#"D l0t ho\c 2#2" lit 5. 1#12 l0t ho\c *#*8 l0t
Cu 21: Cho ;h0 C! ùa Fng s7 ch7a 1>#2 ga3 hzn h:p cht rUn Cu! =? ()! nung nEng. au 32t thdi
gian thu :c hzn h:p ;h0 % =? 1*#8g cht rUn C. Cho hzn h:p ;h0 % hp thi ho?n to?n =?o 55
2
Ca&!H'

5 thy cJ ;t ta. au ;hi phVn 7ng ;t thec lWc ly ;t ta =? sy ;hb. -hFi l:ng ;t ta thu :c l?
a. 16g ,. 1>g c. 26g 5. 2>g
Cu 22: ChWn 5Ny cc cht cu ,o nhit phn [ nhit 2 cao
a.
2 *
+l !
#
*
CaC!
#
*
$aHC!
,. Cu&$!
*
'
2
# Ca&HC!
*
'
2
#
*
$aHC!

c. <g&!H'
2
#
2 *
$a C!
# $a!H 5.
2 *
$a C!
# <g&HC!
*
'
2
# Ca!
G/0 L1 Ch2 N)$3* - 1= - T&45) THPT N)$36 7.i
BI 1H: SILIC 3 HG& CH-T CA SILIC 3 CING NGH SILICAT
I. Ph !" #$%
Cu 1: $ghicn thy tinh thbng thdng th?nh ,2t# r1i cho =?o nc. $heng giy ù t03 =?o nc tha giy
ù sm chuy@n sang 3?u ânh. giVi th0ch =? =it phZng tranh hEa hWc
Cu 2: <2t loOi thy tinh ch7a 1*#6A
2
$a !
# 11#9A Ca! =? 9>#*A i!
2
=c ;hFi l:ng. HNy ^c onh
th?nh phQn ca loOi thy tinh n?y ,i@u 5in 5i 5Ong cc oît.
Cu *: ]Ft 3 ga3 + &ch7a silic =? hi5ro'# trong AHC12#>A =c ;hFi l:ng. Cht % sinh ra tc 5ing =i
$a!H tOo 3uFi C. Cho aît clohi5ric 5 tc 5ing =i 3uFi C tha cE ;t ta ;)o tOo th?nh. $ung ;t ta tha
thu :c *6g cht %. tc 5onh cbng th7c =? t0nh ;hFi l:ng + N 5fng. %it 1g ;h0 + chi3 th@ tich1la2
6#9 l0t &;c'.
Cu ": Cho 2>g hzn h:p silic =? than tc 5ing =i 55 $a!H \c# 5# un nEng# thu :c 11#2 lit ;h0
2
H

&;c'. tc onh A ;hFi l:ng ca silic trong hzn h:p ,an Qu# ,it phVn 7ng cE hiu sut 166A.
II. Ph !&'( )hi*+
Cu 1: $guyRn tM cac,on =? silic giFng nhau =c
a. Cu hanh ) ,. sF ) [ lp ngo?i cfng c. sF lp ) 5. sF in t0ch hOt nhn
Cu 2 : trong cc phVn 7ng sau & th)o th7 tT'. i l? cht oî hEa hay cht ;hM P
i I 2-!H I
2
H !
|
2 *
- i!
I 2
2
H
&1' i I
2
(
|
"
i(
&2'
Cu *: ilic ioît phVn 7ng :c =i cc cht trong 5Ny n?o sau y P
a. $a!H# <g!# HCl ,. -!H#
*
<gC!
#H( c. $a!H# <g# H( 5. -!H#<g# HCl.
Cu ": .hZng tranh ion thu gWn: 2
H
+
I i!
*
2G
|
2 *
H {!
ca phVn 7ng hEa hWc ^Vy ra giYa:
a.
2 *
H C!
=?
2 *
$a i!
,.
2 *
H C!
=?
2 *
- i!
c. HCl =?
*
Cai!
5. HCl =?
2 *
$a i!

Cu >: ChWn hEa cht cE th@ hJa tan +l =? i
a. -!H ,. HCl c.
2 "
H !
loNng 5. 55
*
$H

Cu 8: ChWn pht ,i@u eng =c =qt liu silicat:
a. /hy tinh cE cu trec =b onh hanh nRn nhit 2 nhit 2 nEng chVy ^c onh
,. ti 3nng :c 5fng trong ^y 5Tng# l? loOi =qt liu ;hbng ;t 50nh
c. /hy tinh# s?nh ^7# î 3nng cu cE ch7a 32t sF 3uFi silicat trong th?nh phQn
5. 7 l? loOi gF3 5n 5ing# gF3 ; thuqt =? gF3 ^y 5Tng
Cu 9: ]@ ;hUc chY hanh lRn thy tinh# ta 5fng aît
a. HC; \c ,. H%r c.
2 "
H !
\c 5. H(
Cu D: <2t loOi thy tinh 5fng @ ch tOo 5ing ci nh? ,p ch7a 18#6A
2
$a !
K#6A Ca! =? 9>#6A
2
i!
=c ;hFi l:ng. /rong loOi thy tinh n?y# 1 3ol Ca! ;t h:p =i
a. 1#812> 3ol
2
$a !
=? 9#812> 3ol
2
i!

,. 1#8 3ol
2
$a !
=? 9#99 3ol
2
i!

c. 2 3ol
2
$a !
=? 8 3ol
2
i!

5. 1 3ol
2
$a !
=? 8 3ol
2
i!

Cu K: /hy tinh ;hbng cE cu trec tinh th@ 3? l? cht =b onh hanh# nRn thy tinh:
a. cE h sF n[ nhit rt nhx ,. cE nhicu 3?u sUc ;hc nhau
c. trong suFt 5. ;hbng cE nhit 2 nEng chVy ^c onh
Cu 16: -hFi l:ng
2 *
$a C!
cQn 5fng @ sVn ût :c 12o ;g thy tinh &
2
$a !
.Ca!.8
2
i!
' =i hiu
sut K6A l?:
a. 2>#*D;g ,. 2K#>8;g c.*6#>2;g 5.*2#8";g
ChZng ": ]{ C$g V H+ HC H C.
%?i 11: < ] V H+ HC H C
{{{. %{ /. . B$g:
G/0 L1 Ch2 N)$3* - 1> - T&45) THPT N)$36 7.i
Cu 1: Cah)in# 32t cht cE nhicu trong cah)# tr?# nc cola# cE cbng th7c phn tM l?
8 10 2 4
C H O N
. /0nh A
;hFi l:ng 3zi nguyRn tF trong phn tM cah)in.
Cu 2: ]Ft chy ho?n to?n 9#9> ga3 =ita3in C &chL ch7a C# H# !' thu :c 11#82 g
2
C!
=? *#19 g
2
H !
.
tc onh A ;hFi l:ng 3zi nguyRn tF trong phn tM =ita3in C.
Cu *: !î hEa ho?n to?n 6#1*> g h:p cht +# r1i cho sVn ph3 lQn l:t ùa ,anh 1 ch7a
2 "
H !
q3 \c
=? ,anh 2 cha -!H# tha thy ;hFi l:ng ,anh 1 tnng thR3 6#119 g# ,anh 2 tnng thR3 6#*K8 g. th0 nghi3
;hc# ;hi nung 1#*> g h:p cht + =i Cu! tha thu :c 112 3l &;tc' ;h0
2
$
. tc onh A ;hFi l:ng 3zi
nguyRn tF trong h:p cht +.
Cu ": ]onh l:ng
2
$
trong 2 ga3 h:p cht hYu cZ ,Hng pp ;)l5ahl &nitZ trong h:p cht hYu cZ chuy@n
hEa th?nh
*
$H
'# to?n ,2 ;h0
*
$H
:c hp thi =?o >6 3l 55
2 "
H !
6#><# phQn aît thya :c trung
hJa =ya ,[i *6 3l 55 $a!H 1<. /a3 A ;hFi l:ng $P
{V. C H{ /C $gH{<
Cu 1: ChWn 5Ny h:p cht cu l? cht hYu cZ:
+.
2 8
C H
# C!#
2 6
C H O
%.
4
CH
#
2 "
C H
#
*
CaC!
C.
2 2
C H
#
8 12 8
C H !
#
4 11
C H N
B.
4 10
C H
#
2 4 2
C H O
#
3
NaHCO
.
Cu 2: ]Ft chy ho?n to?n 6#8 ga3 h:p cht hYu cZ t thu :c 6#""D lit
2
C!
&;tc'. .hQn trn3 ;hFi
l:ng cac,on trong t l?:
+. *6A %. "6A C. ""#D A B. 86A
Cu *: ]Ft chy ho?n to?n 8#2 g cht hYu cZ + thu :c 2#2" l0t
2
$
&;tc'. .hQn trn3 ;hFi l:ng ca
2
$

trong + l?:
+. 22#" A %. 22#8A C. ">#2A B. 82#6A
Cu ": .hn t0ch 2#* ga3 cht hYu cZ u thu :c 2#9 g
2
H !
. .hQn trn3 ;hFi l:ng ca hiro trong u l?:
+. 8#>A %. 1*A C. 2*A B. 29A
Cu >: ]Ft chy ho?n to?n 6#K2 ga3 cht hYu cZ thu :c 1#98 g
2
C!
=? 1#6D g
2
H !
. .hQn trn3 ;hFi
l:ng cac,on =? hiro trong cht hYu cZ l?:
+. >2#19A =? "9#D*A %. "9#D*A =? >2#19A C. >2#19A =? 1*#6"A B. >2#19A =?
8#>2A
Cu 8: !î hEa ho?n to?n 6#"8 g cht +# 5Sn ^Vn ph3 lQn l:t ùa ,anh 1 &
2 "
H !
\c' =? ,anh 2 &-!H
5'# thy ;hFi l:ng ,anh 1 tnng 6#>" g# ,anh 2 tnng 6#DD g. .hQn trn3 ;hFi l:ng oî trong + l?
+. "1#*A %. "*#9 A C. *6#>"A B. *"#9DA
Cu 9: .hn t0ch cht hYu cZ + &C# H# !' tha :c: 3
C
I 3
H
C *#> 3
!
. .hQn trn3 ;hFi l:ng ca oî l?:
+. 2D#>9A %. 28#89A C. 22#22A B. 1>#*DA
Cu D: .hn t0ch 3 ga3 cht hYu cZ t ta chL thu :c a ga3
2
C!
=? , ga3
2
H !
. %it *a C 11, =? 93 C
*&aI,'. .hQn trn3 ;hFi l:ng ca oî l?:
+. 88#89A %. ""#""A C. "D#>2A B. >8.*DA
Cu K: ]Ft chy ho?n to?n *#81 ga3 cht hYu cZ t thu :c hzn h:p ;h0 g13
2
C!
#
2
H !
=? HCl. BSn
hzn h:p n?y ùa ,anh ch7a 55
*
+g$!
4
*
$H
thy cE 2#D9 g ;t ta. .hQn trn3 ;hFi l:ng Cl trJng t l?:
+. 1>#*8A %. *K#*2A C. 2D#>KA B. 1K#88A
Cu 16: ]Ft chy ho?n to?n cht hYu cZ &C# H# !' tha sF 3ol
2
C!
=?
2
H !
,Hng nhau. %it sF 3ol oî cQn
5fng ,Hng sF 3ol
2
C!
. Cht hYu cZ ch7a nguyRn tF C =i A ;hFi l:ng:
+. *9#K*A %. "K#22A C. "6A B. >6#*DA
%?i 12: C$g /HC .H$ / H. CH/ H C
{{{. %{ /. . B$g:
Cu 1: $ilon ~ 8 loOi tZ nilon phk ,in nht# cE 8*#8DA cac,on K#D6A hiro 1"#1"A oî =? 12#*DA nitZ.
tc onh cbng th7c Zn giVn nht ca nlon ~ 8.
Cu 2: cfng icu ;in =c nhit 2# p sut# 1 lit hZi hirocac,on t cE ;hFi l:ng ,Hng 32t nMa ;hFi
l:ng ca " lit ;hbng ;h0. tc onh ;hFi l:ng 3ol phn tM &phn tM ;hFi' ca t.
Cu *: -t ùV phn t0ch cc nguyRn tF trong nicotin nh sau: C:9"A H:D#8>A $:19#*>A. tc onh cbng
th7c Zn giVn nht# cbng th7c phn tM ca nicotin# ,it nicotin cE ;hFi l:ng 3ol phn tM l? 182.
G/0 L1 Ch2 N)$3* - 1? - T&45) THPT N)$36 7.i
Cu ": ]Ft chy ho?n to?n >#8 ga3 h:p cht hYu cZ + thu :c 1*#2 g
2
C!
=? *#8 g
2
H !
. /L ;hFi hZi
ca + so =i
2
H
l? 2D. tc onh cbng th7c phn tM ca +.
Cu >: /r2n 166 c3
*
cht hYu cZ
x y z
C H O
=i ">6 c3
*
oî 5 r1i )3 Ft chy. /h@ t0ch ;h0 thu :c sau
phVn 7ng l? 8>6 c3
*
. BSn ùa
2 "
H !
\c tha cJn *>6 c3
*
. /ip tic 5Sn ùa ,anh Tng 55 -!H 5 tha chL
cJn >6 c3
*
. /a3 cbng th7c phn tM ca cht hYu cZ# cc th@ t0ch cu o [ cfng nhit 2 p sut.
Cu 8: +ît a ch7c +# 3Och h[# cbng th7c Zn giVn nht l?
3 4 3
C H O
. tc onh cbng th7c phn tM +.
{V. C H{ /C $gH{<
Cu 1: + cE tL ;hFi hZi so =i
2
O
l? *#12>. -hFi l:ng 3ol phn tM &phn tM ;hFi' ca + l?
+. *2 g43ol %. 8" g43ol C. 166 g43ol B. >6 g43ol
Cu 2: Cfng icu ;in =c nhit 2 p sut# 9 l0t hZi hirocac,on t cE ;hFi l:ng gp 2 lQn ;hFi l:ng ca
9 l0t
2
$
. -hFi l:ng 3ol phn tM ca t l?
+. >D g43ol %. 96 g43ol C. 2D g43ol B. >8 g43ol
Cu *: icu ;in 1*8#>
6
C# p sut 2at3# "" ga3 )st) u cE th@ t0ch D#" lit. -hFi l:ng 3ol phn tM ca u
l?
+. 22 g43ol %. "" g43ol C. DD g43ol B. 88 g43ol
Cu ": ChWn cbng th7c Zn giVn ;hbng eng:
Cbng th7c cu tOo Cbng th7c Zn giVn
+.
3 2 2 3
CH CH CH CH
2 5
C H
%.
3 2
CH CH COOH CH
*
!
C.
3 3
CH CO CO CH
2 3
C H O
B.
3 2 2 2
CH O CH CH CH OH
2 5
C H O
Cu >: /rong cc cht sau: &1' r:u )tylic &
2 >
C H !H
' &2' an)hit ho3ic &HCH!' &*' aît a^)tic &
*
CH C!!H
' &"' )tyl a^)tat &
* 2 >
CH C!!C H
' &>' gluco_Z &
8 12 8
C H !
'. Cht n?o cE cbng th7c Zn giVn
nht l? CH
2
!P
+. &1'# &2'# &*' %. &2'# &*'# &"' C. &2'# &*'# &>'. B. &*'# &"'# &>'
Cu 8: +li_arin &32t lWa ph3 nh23'# cE 28#9A oî =c ;hFi l:ng. -hFi l:ng 3ol phn tM ca ali_arin
,Hng 2"6 g43ol. F nguyRn tM oî trong 32t phn tM ali_arin l?:
+. 1 %. 2 C. * B. "
Cu 9: Hirocac,on t ch7a D>#9 A cac,on =c ;hFi l:ng. cbng th7c phn tM ca t l?: &1'
4
CH
&2'
2 "
C H
&*'
3 6
C H
.
+. &1' %. &*' C. &1' =? &2' B. &2' =? &*'
Cu D: ]Ft chy ho?n to?n 2 3ol h:p cht hYu cZ + cQn 1 3ol
2
O
# thu :c " 3ol
2
C!
=? 2 3ol
2
H !
.
F nguyRn tM oî trong phn tM + l?:
+. 1 %. 2 C. * B. "
Cu K: .hn t0ch 32t hEa cht :c ;t ùV: >1#>DA C D#8"A H *K#>1A =c ;hFi l:ng. Cbng th7c Zn
giVn nht ca h:p cht n?y l?:
+.
2 4
C H S
%.
4 7
C H S
C.
7 14 2
C H S
B.
15 29 2
C H S
Cu 16: ]Ft chy ho?n to?n 2 l0t ;h0 32t hirocac,on t N cQn D l0t
2
O
# thu :c 8 l0t
2
C!
. Cc th@ t0ch
o [ cfng nhit 2 =? p sut# cbng th7c phn tM ca t l?:
+.
3 4
C H
%.
3 6
C H
C.
3 8
C H
B.
4 10
C H
Cu 11: H:p cht % cE cbng th7c Zn giVn nht l?
4
CH N
. Cbng th7c phn tM ca % l?:
+.
4
CH N
%.
2 8 2
C H N
C.
3 12 3
C H N
B.
4 16 4
C H N
Cu 12: H:p cht t cE cbng th7c Zn giVn nht l?
2 4
C H Cl
. Cbng th7c phn tM ca t l?:
+.
2 4
C H Cl
%.
2 4 2
C H Cl
C.
4 8 2
C H Cl
B.
6 12 2
C H Cl
Cu 1*: +3ph)ta3in# 32t loOi cht gy nghin# ch7a A ;hFi l:ng cac,on l? D6A. %it ;hFi l:ng 3ol
phn tM 2>6 g43ol. Cbng th7c phn tM a3ph)ta3in l?:
+.
8 12
C H N
%.
9 13
C H N
C.
8 12 2
C H N
B.
18 26 2
C H N
G/0 L1 Ch2 N)$3* - 8@ - T&45) THPT N)$36 7.i
Cu 1": Hzn h:p g13 hirocac,on t =? oî cE tL l 3ol tZng 7ng l? 1:16. %qt tia lMa in Ft chy hzn
h:p trRn# 5Sn hZi chy ùa 55
2 "
H !
\c# cJn lOi hzn h:p ;h0 u cE tL ;hFi so =i
2
H
,Hng 1K. Cbng th7c
phn tM t l?:
+.
3 8
C H
%.
3 6
C H
C.
4 8
C H
B.
3 4
C H
Cu 1>: ]Ft chy ho?n to?n cht hYu cZ t &
x y z
C H O
' thu :c sF 3ol
2
C!
,Hng sF 3ol
2
H !
. /h@ t0ch
2
O
cQn ,Hng 1#2> lQn th@ t0ch
2
C!
cfng nhit 2 =? p sut. Cbng th7c phn tM t l?:
+.
2 4 2
C H O
%.
2
CH O
C.
4 8 2
C H O
B.
3 6 2
C H O
Cu 18: ]Ft chy ho?n to?n cht hYu cZ + &C# H# !' tha tL sF 3ol cc cht tha3 gia =? sVn ph3:
n
+
: 2
O
n
:
2
CO
n
:
2
H O
n
C 1:":*:". Cbng th7c phn tM + l?:
+.
3 6
C H O
%.
3 8 2
C H O
C.
3 8
C H O
B.
3 6 2
C H O
Cu 19: ]Ft chy ho?n to?n 3 ga3 t &
x y z
C H N
' thu :c 19#8 g
2
C!
# 12#8 g
2
H !
=? 2#2" lit
2
$
&;tc'.
Cbng th7c phn tM t l?:
+.
3 9
C H N
%.
2 8 2
C H N
C.
4 7
C H N
B.
2 7
C H N
Cu 1D: ]Ft chy ho?n to?n hirocac,on + &;h0' tha trong hzn h:p sVn ph3#
2
C!
chi3 98#>2A ;hFi
l:ng. Cbng th7c phn tM + l?:
+.
4 8
C H
%.
5 10
C H
C.
4 6
C H
B.
3 8
C H
Cu 1K: ]Ft cht hYu cZ t &;hbng cE C C ' chL thu :c sVn ph3 l?
2
C!
=?
2
H !
. -hFi l:ng 3ol
phn tM t l? 9" g43ol. F cbng th7c phn tM cE th@ cE:
+. 1 %. 2 C. * B. "
Cu 26: ]Ft chy ho?n to?n cht + cQn 8#92 l0t
2
O
&;tc'. BSn sVn ph3 &
2
C!
=?
2
H !
' =?o nc =bi
trong cE 5 :c *6ga3 ;t ta# =? ,anh =bi tnng 1D#8 ga3. %it >6<
+
166# cbng th7c phn tM + l?:
+.
3 6
C H O
%.
2 4 2
C H O
C.
4 10
C H O
B.
3 6 2
C H O
.
Bi 13: C-U T)JC &HCN TK HG& CH-T HLU C
IIIM BI TN& O& ,PNG:
Cu 1: $hYng cht n?o sau 5y l? 1ng ng ho\c 1ng phnP
a.
3 2 2 2 3
CH CH CH CH CH
g.
3 3
CH C CH
,.
3 3 2 3
CH CH(CH ) CH CH
h.
2 3
CH CH CH CH CH = =
c.
3 3 3
CH CH(CH ) CH
i.
3 3
CH COCH
5.
3 2 2
CH CH CH CH =
.
2 2
CH CH CH OH =
).
2 2
CH CH CH CH = =
;.
3 2
CH CH OH
h.
3 3
CH C C CH
l.
3 2
CH CH CH O =
.
Cu 2: Vit cbng th7c cu tOo cc 1ng phn cE cbng th7c phn tM:
a4
5 12
C H
,4
3 8
C H O
c4
3 7
C H Cl
54
3 9
C H N
)4
3 6
C H
.
Cu *: tc onh sF liRn ;t Zn# liRn ;t bi# liRn ;t ,a# liRn ;t # liRn ;t trong phn tM 3zi cht sau:
a4
3 2 3
H N CH CH
,4
2 2
H C CH CH CH = =
c4
2
HC C CH CH =
54
3
H C C(OH) O =
.
Cu ": tc onh cc cht cE 1ng phn hanh hWc. Vit cbng th7c cc 1ng phn cisG # transG cho cc trdng
h:p cE 1ng phn hanh hWc.
a4
3 2
CH CH CH =
,4
3 2 5
CH CH CH C H =
c4
3 2 2 5
(CH ) C CH C H =
54
2 5
C H CH CH Cl =
)4 Cl CH CH Cl = h4
3
Br CH CBr CH =
{V. C H{ /C $gH{<:
Cu 1: Cc cht cE cbng th7c phn tM hZn ;}3 nhau 32t hay nhicu nhE3
2
CH
=? t0nh cht hEa hWc tZng
tT l? cc cht
+. 1ng phn %. 1ng ng C. 1ng =o B. 1ng ;hFi.
G/0 L1 Ch2 N)$3* - 81 - T&45) THPT N)$36 7.i
Cu 2: Cc cht cE cbng th7c phn tM hZn ;}3 nhau 32t ho\c nhicu nhE3
2
CH
:
+. thu2c cfng 32t 5Ny 1ng ng %. cE th@ cfng ho\c ;hc 5Ny 1ng ng.
C. cE t0nh cht hEa hWc tZng tT nhau B. cE cu tOo hEa hWc tZng tT nhau.
Cu *: Cho cc cht sau: &1'
3 2 3
CH CH CH
&2'
2 3
CH CH CH =
&*'
3 2 2 3
CH CH CH CH
&"'
2 2
CH CH =
. Cc cht 1ng Vng =i nhau l?:
+. &1' =? &2' %. &1' =? &*' C. &2' =? &"' B. %#C cu eng.
Cu ": ChWn pht ,i@u eng nht: ]1ng phn l? nhYng cht ;hc nhau cEj
+. cfng cbng th7c chung &ca 5Ny 1ng ng' %. phn tM ;hFi ,Hng nhau.
C. cfng cbng th7c phn tM. B. cfng t0nh cht hEa hWc.
Cu >: t}t cc cht sau: &1'
3 2 2 3
CH CH CH CH
&2'
3 2 2 2 3
CH CH CH CH CH
&*'
3 3 2 3
CH CH(CH ) CH CH
&"'
3 2 3 2 3
CH CH CH(CH ) CH CH
&>'
3 2 2
CH CH CH CHO

&8'
3 2 3
CH CO CH CH
. $hYng cht 1ng phn =i nhau l?:
+. &1'# &2'# &*'# &"' %. &2'# &*'# &>' =? &8' C. &>' =? &8' B. &*' =? &"'.
Cu 8: XiRn ;t hEa hWc ch yu =? phk ,in nht h:p cht hYu cZ l?:
+. XiRn ;t c2ng hEa tro %. liRn ;t ion C. liRn ;t hiro B. liRn ;t
=an5)raals.
Cu 9: /rong phn tM a^)til)n H C C H # cc nguyRn tM liRn ;t =i nhau ,Hng:
+. 1 liRn ;t =? " liRn ;t %. > liRn ;t .
C. 2 liRn ;t =? * liRn ;t B. * liRn ;t =? 2 liRn ;t .
Cu D: -t luqn n?o sau y engP
&1' $hYng cht 1ng phn cE cfng ;hFi l:ng 3ol phn tM.
&2' $hYng cht cE cfng ;hFi l:ng 3ol phn tM l? 1ng phn.
&*' $hYng cht 1ng phn cE cbng th7c cu tWa giFng ho\c ;hc nhau.
+. &1' =? &2' %. &1' =? &*' C. &2' =? &*' B. &1'# &2' =? &*'.
Cu K: F 1ng phn cE cbng th7c phn tM
3 6 2
C H Cl
:
+. 2 %. * C. " B. >
Cu 16: F 1ng phn ca
3 8
C H O
=?
3 9
C H N
lQn l:t l?:
+. " =? * %. 2 =? " C. * =? * B. * =? "
Cu 11: ChWn cbng th7c phn tM cE sF 1ng phn nhicu nht: &1'
4 10
C H
&2'
3 9
C H N
&*'
3 8
C H O
&"'
3 7
C H Cl
+. &1' %. &2' C. &*' B. &"'
Cu 12: ChWn c\p 1ng phn =o tr0:
+.
3 3
CH CH CH CH
#
2 2 3
H C CH CH CH =
%.
3 3 3
CH CH(CH ) CH
#
3 2 2 3
CH CH CH CH
C.
3 2 2
CH CH CH CHO
#
3 2 3
CH CO CH CH

B.
3 2 3
CH CH(OH) CH CH
#
3 2 2 3
CH CH O CH CH
Cu 1*: /0nh cht hEa hWc cc cht phi thu2c:
+. th?nh phQn nguyRn tF %. sF nguyRn tM 3zi nguyRn tF.
C. cu tOo hEa hWc B. cV +# %# C
Cu 1": Cc cht cE A ;hFi l:ng cc nguyRn tF giFng nhau sm cE cfng:
+. cbng th7c phn tM %. 5Ny 1ng ng
C. cbng th7c Zn giVn nht B. cbng th7c cu tOo.
Cu 1>: o =i cbng th7c phn tM# cbng th7c cu tOo cJn cho ,it:
+. cu trec hEa hWc ca phn tM.
%. trqt tT liRn ;t giYa cc nguyRn tM trong ;hbng gian.
C. HEa tro cc nguyRn tF tha3 gia liRn ;t.
B. /rqt tT =? loOi liRn ;t giYa cc nguyRn tM trong 3\t phng.
%?i 1": .H$ $g H C
{{{. %{ /. . B$g
Cu 1: .hn loOi cc phVn 7ng sau &phVn 7ng th# phVn 7ng c2ng# phVn 7ng tch'.
G/0 L1 Ch2 N)$3* - 88 - T&45) THPT N)$36 7.i
a4
8 8
C H
I
2
%r

o
Fe/ t

6 5
C H Br
I H%r
,4
2 >
C H !H

o
2 4
H SO !t
2 "
C H
I
2
H !
c4
3 6
C H
I
2
%r

3 6 2
C H Br
54
3 6
C H
I
2
H !

H
+
* 9
C H !H
)4
2 5
C H Cl

0
"OH/ r#$%&/ t

2 "
C H
I HCl
h4
*
CH C!!H
I
2
Cl

'

2
Cl CH COOH
Cu 2: Cho cc phVn 7ng:
a4 tan tha3 gia phVn 7ng th =i
2
Cl
3 3
CH CH
I Cl

3 2
CH CH

I HCl
3 2
CH CH

I
2
Cl

3 2
CH CH Cl
I Cl
,4 til)n than gia phVn 7ng c2ng =i HCl:

2 2
CH CH =
I
H
+

3 2
CH CH
+
3 2
CH CH
+
I Cl

3 2
CH CH Cl
c4 /hy phn )tyl clorua trong 3bi trdng ;ic3:
3 2
CH CH Cl

3 2
CH CH
+
I Cl
3 2
CH CH
+
I OH

3 2
CH CH OH
.
HNy cho ,it# ti@u phn n?o l? gFc tT 5o# gFc cac,o tT 5o# cation# cac,ocation.
{V. C H{ /C $gH{<
Cu 1: .hVn 7ng n?o sau y thu2c loOi phVn 7ng thP
+.
2 "
C H
I
2
H

0
Ni!t

2 8
C H
%.
2 8
C H
I
2
Cl

a()t

2 5
C H Cl
I HCl
C.
2 "
C H
I
2
H !

H
+

2 >
C H !H
B.
* 9
C H !H

2 4
0
H SO a*+
140 C

3 6
C H
I
2
H !
Cu 2: trong cc phVn 7ng sau# phVn 7ng n?o ;hbng thu2c cfng 32t loOi =i cc phVn 7ng cJn lOiP
+.
3 6
C H
I HCl

3 7
C H Cl
%.
2 "
C H
I
2
H !

H
+
2 >
C H !H
C.
3 8
C H
I
2
Cl

a()t

3 7
C H Cl
I HCl B.
2 "
C H
I
2
%r

2 4 2
C H Br
Cu *: ChWn phVn 7ng hYu cZ cE sT oî hEa ;hM:
+.
3
CH C CH
I
*
+g$!
I
*
$H

3
CH C C,-
I
4 3
NH NO
%.
*
CH C!!H
I
2 >
C H !H

* 2 >
CH C!!C H
I
2
H !
C.
*
CH C!!H
I $a!H

3
CH COONa
I
2
H !
B. 2
2 >
C H !H
I 2 $a
2
2 5
C H ONa
I
2
H
Cu ": ChWn phVn 7ng th ;hbng oî hEa ;hM:
+.
3 3
CH CH
I
2
Cl

a(

3 2
CH CH Cl
I HCl
%.
8 8
C H
I
2
%r

Fe

6 5
C H Br
I H%r
C.
3 2
CH CH Cl
I $a!H

3 2
CH CH OH
I $aCl
B.
*
CH C!!H
I $a

3
CH COONa
I
1
2

2
H
Cu >: .hVn 7ng n?o sau y ùa ti@u phn trung gian gFc tT 5oP
+.
4
CH
I
2
Cl

a(

3
CH Cl
I HCl
%. HCl I
2
H !

3
H O
+
I Cl
C.
2 2
CH CH =
I HCl

3 2
CH CH Cl
B.
3 2
CH CH Cl
I $a!H

3 2
CH CH OH
I $aCl.
Cu 8: $hE3 chL g13 cac,ocation:
+.
3 2
(CH ) CH
+

3 3
(CH ) C
+
%.
2
Ca
+

3 2
CH CH
+
C.
3
CH
+

3 3
(CH ) C
B.
H
+

3 3
(CH ) C
+
.
G/0 L1 Ch2 N)$3* - 89 - T&45) THPT N)$36 7.i
ChZng >: H{]!C+C%!$ $!
%{ 1>: +$-+$ V t{CX!+$-+$.
{{{. %{ /. . B$g
Cu 1: /a3 cbng th7c phn tM ca an;an trong 3zi trdng h:p sau:
a. ;hFi l:ng ri))ngan;an [ *6
6
C =? 9>6 33Hg l? 2#*6D g4l
,. tL ;hFi hZi so =i
2
O
l? 2#2>.
c. AH C 18#2D
5. ]Ft chy *#* ga3 an;an thu :c >#" g
2
H !
.
Cu 2: tc onh cbng th7c phn tM an;an trong 3zi trdng h:p sau:
a4 ]Ft chy ho?n to?n an;an =i 32t l:ng
2
O
=ya # tkng th@ t0ch cc sVn ph3 ,Hng 948 tkng th@ t0ch
cc cht tha3 gia phVn 7ng &cfng icu ;in nhit 2 =? p sut'.
,4 -hi clo hEa an;an thu :c 32t 5Sn ût 3onoclo 5uy nht cE **#**A clo =c ;hFi l:ng.
c4 ]Ft chy an;an =i l:ng
2
O
=ya # tOo th?nh 32t hzn h:p sVn ph3 cE tL ;hFi hZi so =i
2
$
l?
1K41D.
54 ]Ft chy ho?n to?n *#>2 ga3 32t an;an# sVn ph3 chy ùa 11#> l0t 55
2
Ca&!H'
6#62< :c 22 ga3
;t ta.
Cu *: a4 ]Ft 3 ga3 an;an# 5Sn to?n ,2 hZi chy ùa ,anh ch7a 55
2
Ca&!H'
# ,anh tnng lRn *2#D g =? cE
*6 ga3 ;t ta ût hin. ]un nEng phQn nc lWc ût hin thR3 16 ga3 ;t ta nYa. /0nh 3 =? cbng
th7c phn tM ca an;an.
,4 ]Ft chy a ga3 an;an# to?n ,2 sVn ph3 chy 5Sn ùa nc =bi trong cE 5 tha :c *6 ga3 ;t ta.
X:ng nc =bi trong cJn lOi &sau ;hi tch ;t ta' nh hZn l:ng nc =bi ,an Qu l? D#9 ga3. /a3 cbng
th7c phn tM.
Cu ": a4 <2t hirocac,on cE cbng th7c thTc nghi3
x 2x 1 n
(C H )
+
. Hxi nE thu2c 5Ny 1ng ng n?oP
,4 .hQn trn3 ;hFi l:ng H trong an;an sm ,in ki nh th n?o ;hi ;hFi l:ng 3ol phn tM tnng 5Qn trong
5Ny 1ng ngP
Cu >: <2t hzn h:p t th@ ;h0 g13 2 hirocac,on liRn tip nhau trong 5Ny 1ng ng. ]Ft chy 1 3ol hzn
h:p t cQn >#K 3ol
2
O
=? thu :c *#8 3ol
2
C!
. Xqp cbng th7c phn tM ca 2 hirocac,on trRn.
Cu 8: a4 + =? % l? an;an. %it tL ;hFi hZi ca + so =i % l? 2#9>. Xy >#2D ga3 + =? 2#" ga3 % cho =?o
,anh 5ung t0ch 2 lit tha p sut trong ,anh Ot "#>*8 at3 o [ 1*8#>
6
C. /a3 cbng th7c phn tM ca + =? %.
,4 <2t hzn h:p g13 2 an;an liRn tip# cE tL ;hFi hZi so =i
2
H
l? 18#9>. /a3 cbng th7c phn tM =? A th@
t0ch 3zi an;an.
Cu 9: ]Ft chy ho?n to?n "#12 ga3 hzn h:p 2 an;an cQn >2#8" lit ;hbng ;h0 &;tc' &;hbng ;h0 g13 D6A
2
$
=? 26A
2
O
=c th@ t0ch'.
a4 /0nh ;hFi l:ng
2
C!
=?
2
H !
sinh ra.
,4 /a3 cbng th7c phn tM =? A th@ t0ch 3zi an;an# ,it cheng cE sF cac,on gp bi nhau.
c4 $u cho to?n ,2
2
C!
=?
2
H !
ùa 166 ga3 55 $a!H 1"#"A tha n1ng 2 A =? cc cht trong 55 thu
:c l? ,ao nhiRuP
Cu D: ]Ft chy hzn h:p g13 6#"D ga3 an;an + =? 1#18 ga3 an;an % r1i 5Sn hZi chy ùa 55 nc =bi
trong cE 5 thu :c 11 ga3 ;t ta.
a4 /a3 tkng sF 3ol hzn h:p 2 an;an =? ;hFi l:ng
2
H !
tOo th?nh 5o phVn 7ng Ft chy.
,4 /a3 cbng th7c phn tM + =? %# ,it tL ;hFi hZi ca % so =i + l? *#82>
c4 /0nh A sF 3ol ca + =? % trong hzn h:p Qu.
Cu K: ]Ft chy 6#892 lit hzn h:p 2 an;an &;tc'# hZi chy cho =?o ,anh ch7a 55
2
Ca&!H'
cE 5 tha ;hFi
l:ng 55 thu :c giV3 i so =i l:ng 55 nc =bi ,an 5Qu l? 6#KD g.
a4 /0nh th@ t0ch
2
O
cQn &;tc' =? tL ;hFi hzn h:p 2 an;an so =i
2
H
.
,4 /a3 cbng th7c phn tM 2 an;an# ,it an;an cE ;hFi l:ng phn tM nhx chi3 th@ t0ch gp 2 lQn
an;an cJn lOi.
G/0 L1 Ch2 N)$3* - 8: - T&45) THPT N)$36 7.i
Cu 16: <2t hzn h:p g13 )tan =? propan. Xy *6 c3
*
hzn h:p n?y tr2n =i
2
O
5 r1i )3 Ft chy. au
;hi l?3 lOnh tha :c 16D c3
*
hzn h:p ;h0 g13
2
C!
=?
2
O
cE tL ;hFi hZi so =i
2
H
l? 26. Cc th@ t0ch
;h0 o [ cfng icu ;in nhit 2 =? p sut. /a3 A th@ t0ch )tan =? propan trong hzn h:p ,an Qu.
Cu 11: a4 .hn t0ch 19 ga3 5Sn ût iclo ca 32t an;an + thu :c 1"#2 ga3 clo. tc onh cbng th7c
phn tM ca +P
,4 CE th@ icu ch + ,Hng cch nung 3uFi $a ca aît hYu cZ =i =bi tr2n $a!H &hiu sut phVn 7ng
D6A'. /a3 ;hFi l:ng 3uFi ;han cQn 5fng nu nh cQn icu ch 6#>8 lit + &;tc'.
{V. C H{ /C $gH{<
Cu 1: hirocac,on no l? h:p cht hYu cZ
+. chL g13 liRn ;t Zn# 3Och h[ hay =Jng. %. ch7a C# H =? cu tOo chL g13 liRn ;t Zn.
C. ;hbng ch7a liRn ;t bi ho\c ,a. B. =i 3Och cac,on chL g13 liRn ;t Zn.
Cu 2: Cbng th7c phn tM n?o sau y cE th@ p 5ing cho hirocac,on noP
+.
n 2n 2
C H
+
%.
n 2n
C H
C.
n 2n 2
C H

B. + =? %
Cu *: F l:ng 1ng phn cE cbng th7c phn tM
6 14
C H
l?:
+. * %. " C. > B. 8
Cu ": F l:ng 1ng phn 3Och =Jng cE cbng th7c phn tM
5 10
C H
l?:
+. * %. " C. > B. 8
Cu >: gFc hirocac,on n?o cE tRn gWi s)c ~ ,utyl:
+.
3 2 2 2
CH CH CH CH
%.
3 2 3
CH CH CH(CH )
C.
3 3
C(CH )
B.
3 3 2
CH CH(CH ) CH
Cu 8: <2t 5Sn ût ca clo ca hirocac,on + cE cbng th7c Zn giVn nht CH
2
Cl. Cbng th7c phn tM +
l?:
+.
4
CH
%.
2 8
C H
C.
2 "
C H
B.
3 8
C H
Cu 9: .hVn 7ng \c trng ca hirocac,on no:
+. th %. nhit phn C. oî hEa B. chy
Cu D: /Rn gWi n?o ;hbng eng =i cu tOoP
+.
3 4
C(CH )
&n)op)ntan' %.
3 3 2 3
CH CH(CH ) CH CH
&isop)ntan'
C.
3 2 5 2 3
CH CH(C H ) CH CH
&2G)tyl ,utan' B.
3 2 3
CH CH(Cl) CH CH
&2 ~ clo ,utan'.
Cu K: ]Ft chy ho?n to?n V l0t &;tc' hzn h:p cc an;an thu :c "#" ga3
2
C!
=? 2#*" ga3
2
H !
. gi
tro V l?:
+. 6#**8 %. 6#892 C. 6#D9" B. 6#""D
Cu 16: ]Ft chy ho?n to?n 8#92 l0t hzn h:p g13 32t an;an =? 32t îcloan;an thu :c 6#D 3ol
2
C!
=?
6#K 3ol
2
H !
. .hQn trn3 =c th@ t0ch ca an;an l?:
+. 88#89A %. "6A C. **#**A B. 2>A
Cu 11: ]@ Ft chy ho?n to?n 32t parahin &an;an' + cQn oî th)o tL l 3ol l?
2
O
n
: n
+
C >:1. Cbng th7c
phn tM ca +:
+.
2 8
C H
%.
3 8
C H
C.
4 10
C H
B.
5 12
C H
Cu 12: ChWn c\p an;an ;hi phVn 7ng th =i
2
Cl
&tL l 3ol 1:1' cu chL tOo 32t sVn ph3 th 3onoclo
5uy nht:
+. )tan# iso,utan %. n)op)ntan C. propan# n)op)ntan B. propan# isopropan.
Cu 1*: <)tylîclop)ntan ;hi thTc hin phVn 7ng th =i
2
Cl
&tL l sF 3ol 1:1' tOo :c sVn ph3 3onoclo
tFi a l?:
+. 2 %. * C. " B. >
Cu 1": BQn hzn h:p g13 propan =? îclopropan ùa 55
2
%r
tha:
+. 55 ,ro3 ;hbng phai 3?u# cE ;h0 thot ra %. 55 ,ro3 ,o phai 3?u# cE ;h0 thot ra.
C. 55 ,ro3 ;hbng phai 3?u# ;hbng cE ;h0 thot ra. B. 55 ,ro3 ,o phai 3?u# ;hbng cE ;h0 thot ra.
Cu 1>: ]Ft chy ho?n to?n *#*8 l0t &;tc' hzn h:p 2 an;an liRn tip thu :c "#"D l0t
2
C!
&;tc'. Cbng
th7c phn tM ca 2 an;an l?:
G/0 L1 Ch2 N)$3* - 8; - T&45) THPT N)$36 7.i
+.
4
CH
=?
2 8
C H
%.
3 8
C H
=?
4 10
C H
C.
2 8
C H
=?
3 8
C H
B.
4 10
C H
=?
5 12
C H
.
Cu 18: ]bt chy ho?n to?n 1#12 l0t &;tc' hzn h:p 2 an;an liRn tip thu :c "#1" g
2
H !
. BSn sVn ph3
chy ùa 55 nc =bi trong 5# ;hFi l:ng ;t ta thu :c l?:
+. 2Dg %. 1>g C. 1Dg B. 18g
Cu 19: ]Ft chy a 3ol hzn h:p 2 hirocac,on liRn tip trong 5Ny 1ng ng cQn 1#1D 3ol
2
O
# thu :c
6#92 3ol
2
C!
. Cbng th7c phn tM 2 hirocac,on l?:
+.
3 8
C H
=?
4 10
C H
%.
4
CH
=?
2 8
C H
C.
2 8
C H
=?
3 8
C H
B.
4 10
C H
=?
5 12
C H
Cu 1D: ]Ft chy ho?n to?n cc an;an tha tL l
2
2
CO
H O
n
.
n
=
cE gi tro trong ;hoVng
+. 1h1#> %. 1h2 C. 6#>h1 B. 6#2>h1
Cu 1K: ChWn pht ,i@u ;hbng ch0nh ^c:
+. îclo,utan ;hbng tha3 gia phVn 7ng c2ng. %. îcloan;an cng thu2c loOi hirocac,on no.
C. ticlopropan cE th@ l?3 phai 3?u 55
2
%r
. B. îclopropan ;hbng l?3 phai 3?u 55
"
-<n!
Cau 26: Cra+)in/ nG p)ntan thu 5:c sF l:ng hirocac,on tFi a l?:
+. * %. " C. > B. 8
Cu 21: /rong phJng th0 nghi3# 3)tan :c icu ch ty:
+.
3 2 3
CH CH CH
%.
3
CH COONa
C.
4 3
,l C
B.
3
CH COONa
=?
4 3
,l C
.
Cu 22: -hi Ft chy ho?n to?n hirocac,on# tL l sF 3ol
2
C!
=?
2
H !
l? 6#D. cbng thc phn tM ca
hirocac,on l?:
+.
4
CH
%.
3 8
C H
C.
4 10
C H
B.
3 6
C H
Cu 2*: ]Ft chy 3 ga3 hzn h:p t g13 cc an;an =? îcloan;an# thu :c 11#2 l0t
2
C!
&;tc' =? K#K
ga3
2
H !
. gi tro 3 l?:
+. 9#1 %. D#8 C. 8#> B. 9#D
Cu 2": XoOi ;h0 n?o ch7a nhicu 3)tan nhtP
+. ;h0 5Qu 3x %. ;h0 thiRn nhiRn C. ;h0 ,fn ao B. ;h0 crUc;inh.
Cu 2>: ])3 nhit phn 3)tan [ 1>66
6
C# r1i l?3 lOnh nhanh# sVn ph3 ch0nh thu :c:
+.
2 "
C H
%.
2 8
C H
C.
2 2
C H
B.
3 4
C H
%?i 18: +$-$
{{{. %{ /. . B$g:
G/0 L1 Ch2 N)$3* - 8< - T&45) THPT N)$36 7.i
Cu 1: Hzn h:p t g13 1 an;an =? 1 an;)n. ]Ft chy ho?n to?n t# 5Sn hZi chy ùa 55
2
Ca&!H'
5# ,anh
tnng 9#KD ga3 =? cE 12 ga3 ;t ta. /a3 ;hFi l:ng hzn h:p t =? cbng th7c phn tM 3zi hirocac,on.
%it an;an chi3 86A th@ t0ch hzn h:p.
Cu 2: Hzn h:p ;h0 + g13
2
H
=? 1 ol)hin
n 2n
C H
cE tL l sF 3ol l? *:2. ]un nEng hzn h:p + =i ,2t $i
êc tc# :c hzn h:p %# cE tL ;hFi hZi so =i
2
H
l? 11#2>. Hiu sut phVn 7ng l? HA
14 lqp ,i@u th7c t0nh hiu sut H th)o n
24 %it H"6A. tc onh cbng th7c phn tM =? t0nh HP
Cu *: Hzn h:p ;h0 + gz3
2
H
=? 32t an;)n t. ]Ft chy 8 ga3 + tha :c 19#8 ga3
2
C!
. <\t ;hc cho
8 ga3 + ùa 55
2
%r
5 tha cE *2 ga3
2
%r
tha3 gia phVn 7ng. /a3 cbng th7c phn tM t =? A th@ t0ch 3zi
cht trong +.
Cu ": Hzn h:p t g13 1 an;an =? 1 an;)n. Cho 1#8D l0t hzn h:p t ùa 55
2
%r
5# ,anh tnng 3 ga3# ;h0
thot ra cE th@ t0ch 1#12 l0t. $u Ft chy 1#8D l0t t r1i 5Sn sVn ph3 ùa 55 =bi trong 5 tha cE 12#> ga3
;t ta. Cc th@ t0ch o [ ;tc. tc onh cbng th7c phn tM cc hirocac,on =? t0nh 3P
Cu >: /rong ,anh ;0n 5ung t0ch ;hbng ki >#8 l0t ch7a 6#> 3ol
2
H
=? 6#1 3ol
2 "
C H
cfng =i 32t 0t ,2t
$i. $ung nEng ,anh 32t thdi gian r1i l?3 lOnh ,anh n 6
6
C# p sut trong ,anh lec E l? p. Hzn h:p sau
phVn 7ng tc 5ing =ya =i 6#D ga3
2
%r
trong 55. /a3 A th@ t0ch
2
H
N tha3 gia phVn 7ng. /0nh hiu
sut phVn 7ng hi5ro hEa =? p sut p.
Cu 8: Hzn h:p ;h0 + g13
2
H
=? 2 ol)hin 1ng ng liRn tip. Cho 1K#6" l0t ;h0 + &;tc' ùa ,2t
0
Ni!t
hzn h:p ;h0 % &hiu sut 166A =? =qn tFc phVn 7ng ca 2 ol)hin l? nh nhau'. Cho % ùa 55
2
%r

thy 55 ,o nhOt 3?u. <\t ;hc ;hi Ft chy
1
2
hzn h:p %# thu Zc "*#>8 ga3
2
C!
=? 26#"* ga3
2
H !
.
1. tc onh cbng th7c cu tOo =? gWi tRn cc ol)hin
2. /0nh A th@ t0ch cc ;h0 trong hzn h:p +
Cu 9: /rong ,anh ;0n 5ung t0ch 1*#"" l0t ch7a hzn h:p + g13
2
H
#
2 "
C H
=?
3 6
C H
&;tc' =? sF 3ol cc
an;)n ,Hng nhau. $ung nEng ,anh 32t thdi gian &cE $i'# sau E a =c 6
6
C# p sut trong ,anh lec E l? p.
/L ;hFi so =i
2
H
ca hzn h:p ;h0 trong ,anh trc phVn 7ng l? 8#> =? sau phVn 7ng l? 9#D.
1. /0nh A th@ t0ch hzn h:p + =? p sut p
2. /0nh hiu sut c2ng
2
H
Fi =i 3zi ol)hin# ,it rHng nu cho ;h0 trong ,anh sau phVn 7ng ùa
55
2
%r
5# ,anh ch7a 55
2
%r
tnng *#> ga3.
{V. C H{ /C $gH{<:
Cu 1: gWi tRn an;)n cE cbng th7c cu tOo sau:
2 3
3 3
2 5 3
CH CH
H C CH C C CH
C H CH
|
=
| |
+. *#" ~ i)tyl ~ 2 ~ 3)tylp)nt ~ 2 ~ )n %. 2 ~ 3)tyl ~ *#" ~ i)tylp)nt ~ 2 ~ )n.
C. * ~ )tyl ~ 2#" ~ i3)tylh)^ ~ 2 ~ )n B. 2#" ~ i)tyl ~ * ~ )tylh)^ ~ 2 ~ )n.
Cu 2: ]Ft chy 32t hirocac,on t thu :c 2#8DD l0t &;tc'
2
C!
=? 2#18 g
2
H !
. t thu2c 5Ny 1ng ng
+. an;an %. an;)n C. îcloan;an B. an;)n ho\c îcloan;)n.
Cu *: ]Ft chy 1 3ol an;)n + cQn 8 3ol
2
O
. %it + ;hbng cE 1ng phn hanh hWc# tRn ca + l?:
+. p)n ~ 1 ~ )n %. 2 ~ 3)tylprop)n C. ,ut ~ 1 ~ )n B. ,ut ~ 2 ~ )n
Cu ": F 1ng phn cu tOo ca
4 8
C H
:
+. * %. " C. > B. 8
Cu >: +n;)n cE cbng th7c phn tM
6 12
C H
cE ,ao nhiRu c\p 1ng phn hanh hWc cis ~ transP
+. * %. " C. > B. 8
Cu 8: /rong cc phVn 7ng sau# cht t l?:
G/0 L1 Ch2 N)$3* - 8= - T&45) THPT N)$36 7.i
+. t
0
600 C
u I v u I
2
H !

H
+
/ u I
2
H

0
Ni!t
v
+.
2 2
C H
%.
3 8
C H
C.
4 10
C H
B.
5 12
C H
Cu 9: Hiro hEa an;)n ta :c:
+. an;)n ;hc cE nhicu nguyRn tM H hZn %. an;)n cE cfng sF nguyRn tM C =i an;)n
trRn.
C. an;)n cE =o tr0 nFi bi thay ki B. an;an tun th)o ùy tUc <ac ~ cbp ~ nhi ~
cbp.
Cu D: Hiro hEa t &
5 10
C H
' cE
0
Ni!t
thu :c isop)ntan. -hi c2ng HCl =?o t# sVn ph3 ch0nh cE Cl

lRn ;t =i C ,qc 2. Cu tOo ca t:
+.
3 3 3
CH C(CH ) CH CH =
%.
3 3 2
CH CH(CH ) CH CH =
C.
3 3 2 3
CH C(CH ) CH CH
B.
2 3
CH CH >
Cu K: puy tUc <ac ~ cbp ~ nhi ~ cbp :c p 5ing =i phVn 7ng c2ng tc nhn
+. Fi ^7ng =?o an;)n Fi ^7ng %. Fi ^7ng =?o an;)n ,t Fi ^7ng
C. ;hbng Fi ^7ng =?o an;)n Fi ^7ng B. ;hbng Fi ^7ng =?o an;)n ,t Fi ^7ng
Cu 16: Hirocac,on + &
6 12
C H
' ;hi tc 5ing =i H%r tOo th?nh 32t sVn ph3 5uy nht# + l?:
+. îcloh)ân %. h)^ ~ 2 ~ )n C. 2#* ~ i3)tyl ,ut ~ 2 ~ )n B. 2 ~ 3)tylp)nt ~ 2 ~
)n.
Cu 11: -hi c2ng nc &êc tc aît' =?o 2 ~ 3)tyl,ut ~ 2 ~ )n thu :c sVn ph3 ch0nh l?:
+.
2 3 2 3
HO CH CH(CH ) CH CH
%.
3 3 2 3
H C C(CH )(OH) CH CH
.
C.
3 3 2 2
H C CH(CH ) CH CH OH
B.
3 3 3
H C CH(CH ) CH(OH) CH
.
Cu 12: H:p cht n?o sau y chL cho 32t sVn ph3 ;hi c2ng =i
2
H !
+.
3 3 3
H C C(CH ) CH CH =
%.
3 3 3 3
H C C(CH ) C(CH ) CH =
C.
3 2 3
H C CH CH CH CH =
B.
3 3 3 3
H C C(CH ) CH CH(CH ) CH =
.
Cu 1*: nhit 2 thp# 5ung 5och
"
-<n!
loNng oî hEa )til)n tOo th?nh:
+. r:u )tylic %. )tyl)n glicol C. aît ho3ic B. ;h0
2
C!
=?
2
H !
Cu 1": .hVn 7ng oî hEa prop)n ,Hng 55
"
-<n!
loNng cho sVn ph3 l?:
+.
*
CH CH!
%.
*
CH C!!H
C.
3 2
H C CH(OH) CH (OH)
B.
2 2 2
H C(OH) CH CH (OH)
.
Cu 1>: ]@ phn ,it ;h0
2
!
=?
2 "
C H
cE th@ 5fng
+. 55
"
-<n!
%. 55
2
%r
C. 55 $aCl B. 55
2
%a&!H'
Cu 18: ]@ phn ,it giYa ;h0
2 "
C H
=i ;h0
2 8
C H
cE th@ 5fng:
+. 55
"
-<n!
%. nc
2
%r
C. 55 $a!H B. 55
"
-<n!
hay
55
2
%r
Cu 19: ]Ft chy ho?n to?n hirocac,on t ,Hng 32t l:ng oî =ya . Vn ph3 5Sn ùa ,anh Tng
2 "
H !
\c tha th@ t0ch giV3 hZn 32t nMa. t thu2c 5Ny 1ng ng
+. an;an %. an;)n C. îcloan;an B. an;in
Cu 1D: Cho sZ 1 phVn 7ng: t
0
"OH/ t
" ~ 3)tylp)nt ~ 1 ~ )n I H%r. Cbng th7c cu tOo ca t l?:

+.
3 3 2 2 2
CH CH(CH ) CH CH CH Br
%.
3 3 2 2 3
CH C(Br)(CH ) CH CH CH
C.
2 3 2 3
Br CH CH(CH ) CH CH
B.
3 3 3
CH CH(CH ) CH(Br) CH
Cu 1K: Hirat hEa an;)n n?o sau @ thu :c:
3 2 2 5 2 3
CH CH C(C H )(OH) CH CH
+. * ~ )tylp)nt ~ 1 ~ )n %. * ~ )tylp)nt ~ 2 ~ )n
C. * ~ )tylp)nt ~ * ~ )n B. *#* ~ i3)tylp)nt ~ 2 ~ )n.
Cu 26: /ch H%r ty 2 ~ ,ro3 ~ 2 ~ 3)tyl,utan cho sVn ph3 ch0nh l?:
+.
2 3 2 3
H C C(CH ) CH CH =
%.
3 3 3
H C C(CH ) CH CH =
G/0 L1 Ch2 N)$3* - 8> - T&45) THPT N)$36 7.i
C.
3 3 2
H C CH(CH ) CH CH =
B.
3 3 2
H C C(CH ) C CH = =
Cu 21: -hM nc 3 ga3 )tanol =i
2 "
H !
\c [ 196
6
C thu :c 8#92 l0t )til)n &;tc'. Hiu sut phVn
7ng Ot 9>A# gi tro 3 l?:
+. "8 g %. 2* g C. 1D#" g B. *"#> g
Cu 22: /rong phJng th0 nghi3# )t)n cE th@ icu ch trTc tip ty:
+.
2 >
C H !H
%.
3 3
CH CH
C.
2 2
CH Cl CH Cl
B.
3 2 3
CH CH CH
Cu 2*: /rong cbng nghip# )til)n cE th@ icu ch trTc tip ty:
+. ;h0 crac;inh 5Qu 3x %. c hiro hEa )tan C. ;hM nc r:u )tylic B. cV + =? %.
Cu 2": -hi icu ch
2 "
C H
ty
2 >
C H !H
=?
2 "
H !
\c [ 196
6
C tha ;h0 sinh ra cE lSn
2
C!
=?
2
!
. ]@
loOi ,x :c tOp cht cE th@ 5fng
+. 55
2
%r
%. 55 thuFc t03 C. 55 $a!H B. 55
2 3
" CO
Cu 2>: ]Ft chy ho?n to?n hzn h:p 2 an;)n thu :c 9#2 ga3
2
H !
. Cho to?n ,2 ;h0
2
C!
=ya thu :c
=?o 55
2
Ca&!H'
5 tha thu :c 3 ga3 ;t ta. gi tro 3 l?:
+. "6 %. 26 C. 166 B. 266
Cu 28: ]Ft chy ho?n to?n hzn h:p 2 an;)n :c &3 I *2' ga3
2
C!
=? &3 ~ "8' ga3
2
H !
. gi tro 3 l?:
+. 166 %. 162 C. D" B. K2
Cu 29: ]Ft chy ho?n to?n hzn h:p g13 an;an + =? an;)n %. Cho sVn ph3 chy lQn l:t ùa ,anh 1
ch7a &
2 5
1 O
5' =? ,anh 2 &-!H rUn 5'# thy ,anh 1 tnng "#1" ga3# ,anh 2 tnng 8#18 ga3. F 3ol an;an
+ trong hzn h:p l?:
+. 6#68 %. 6#6K C. 6#6* B. 6#6">
Cu 2D: Cho "#"D l0t &;tc' hzn h:p 2 ol)hin ; tip nhau i ùa ,anh ch7a nc ,ro3 5 thy ;hFi l:ng
,anh tnng thR3 9 ga3. Cbng th7c phn tM ca 2 ol)hin l?:
+.
2 "
C H
#
3 6
C H
%.
4 8
C H
,
5 10
C H
C.
3 6
C H
#
4 8
C H
B.
2 "
C H
#
4 8
C H
.
Cu 2K: ]Ft chy ho?n to?n 6#1 3ol hzn h:p g13
4
CH
#
2 "
C H
=?
4 10
C H
thu :c 6#1" 3ol
2
C!
=? 6#2*
3ol
2
H !
. F 3ol ca an;an =? an;)n trong hzn h:p l?:
+. 6#6K =? 6#61 %. 6#61 =? 6#6K C. 6#6D =? 6#62 B. 6#6" =? 6#68
Cu *6: /r2n 6#62 3ol an;)n =? 6#6* 3ol r1i Ft chy# hZi chy hp thi ho?n to?n =?o ,anh ch7a 55 =bi
trong 5 thu :c 12 ga3 ;t ta. Cbng th7c phn tM ca cheng l?:
+.
3 6
C H
=?
3 8
C H
%.
4 8
C H
=?
3 8
C H
C.
3 6
C H
=?
2 8
C H
B.
2 "
C H
=?
2 8
C H
%?i 19: +$-+]{$
{{{. %{ /. . B$g:
Cu 1: BTa =?o \c i@3 cu tOo ca an;ai)n =? ;hi ni3 =c hEa tro# hNy ch7ng 3inh cbng th7c phn tM
chung ca an;a5i)n l?
n 2n 2
C H

. $hYng cht cE cbng th7c phn tM
n 2n 2
C H

cu l? an;ai)n phVi ;hbngP
Cu 2: Hzn h:p + g13 1 an;ai)n =? 32t an;)n cE th@ t0ch 8#92 l0t &;tc' :c chia th?nh 2 phQn ,Hng
nhau:
G phQn 1: ]Ft chy ho?n to?n :c D#K8 l0t
2
C!
&;tc' =? 8#* ga3
2
H !
.
G .hQn 2: BSn ùa 55
2
%r
5# ,anh tnng 3 ga3.
a4 /0nh 3 =? > th@ t0ch 3zi ;h0 trong hzn h:p.
,4 tc onh cbng th7c phn tM ca an;)n =? an;ai)n.
Cu *: ]Ft chy 2#1D ga3 hzn h:p + 32t an;)n t =? 32t an;ai)n liRn h:p u# ta thu :c 2#*" ga3
2
H !
. %it rHng sF nguyRn tM H trong t ,Hng sF nguyRn tM C trong u.
Cu ": Cho "*#2 ga3 ,uta ~ 1#* ~ i)n phVn 7ng =i 55
2
%r
:c >*#> ga3 h:p cht + =? *2#1 ga3 h:p
cht %. .hn tM + hay % cu cE 9"#99A %r =c ;hFi l:ng. Vit cbng th7c cu tOo ca +# % =? t0nh hiu
sut chung ca phVn 7ng c2ng. %it % cE 1ng phn hanh hWc.
{V. C H{ /C $gH<
Cu 1: +n;ai)n l?
G/0 L1 Ch2 N)$3* - 8? - T&45) THPT N)$36 7.i
+. h:p cht hYu cZ cE 2 liRn ;t bi trong phn tM %. hirocac,on 3Och h[ cE 2 liRn ;t bi liRn
tip
C. hirocac,on 3Och h[ cE 2 liRn ;t bi trong phn tM B. hirocac,on cE cbng th7c chung
n 2n 2
C H

Cu 2: ChWn pht ,i@u ;hbng ch0nh ^c:
+. poli)n l? nhYng hirocac,on ch7a 2 liRn ;t bi trong phn tM.
%. ]i)n l? nhYng hirocac,on trong phn tM cE 2 liRn ;t bi.
C. +n;ai)n liRn h:p cE 2 liRn ;t bi ;c nhau trong phn tM.
B. +n;ai)n cng thu2c loOi poli)n.
Cu *: <2t h:p cht hYu cZ 3Och h[# cbng th7c
n 2n 2
C H

thu2c 5Ny 1ng ng:
+. an;ai)n %. îcloan;)n C. iîcloan;an B. an;ai)n liRn
h:p.
Cu ": {sopr)n cE th@ c2ng H%r th)o tL l sF 3ol 1:1 tOo ra sF sVn ph3 tFi a l?:
+. 8 %. * C. " B. >
Cu >: HCl c2ng =?o isopr)n th)o tL l sF 3ol 1:1# ch yu tOo th?nh:
+.
2 3 3
CH C(CH ) CH(Cl) CH =
%.
3 3 2
CH C(CH ) CH CH Cl =
C.
3 3 2
CH C(CH )(Cl) CH CH =
B. cV % =? C
Cu 8: .hVn 7ng c2ng ca ,utai)n =i HCl th)o tL l sF 3ol 1:1# [ nhit 2 cao# ch yu tOo th?nh sVn
ph3:
+.
3 2
CH CHCl CH CH =
%.
3 2
CH CH CH CH Cl =
C.
2 2 2
Cl CH CH CH CH =
B.
3 2 3
CH CHCl CH CH
Cu 9: F sVn ph3 &;hbng ;@ 1ng phn hanh hWc' ;hi isopr)n c2ng
2
%r
th)o tL l 3ol 1:1 l?
+. 2 %. * C. " B. >
Cu D: /rfng h:p ,uta ~ 1#* ~ i)n# cE th@ thu :c tFi a 3y loOi poli3)P
+. 1 %. 2 C. * B. "
Cu K: Hzn h:p g13 1 an;an &^ 3ol' =? 1 an;ai)n &^ 3ol'# )3 Ft chy ho?n to?n sm thu :c:
+.
2
CO
n

2
H O
n
%.
2
CO
n

2
H O
n
C.
2
CO
n
C
2
H O
n
B.
2
CO
n

2
H O
n
Cu 16: ]Ft chy ho?n to?n 1 3ol an;ai)n + cQn 9 3ol oî. Cbng th7c phn tM + l?:
+.
4 6
C H
%.
5 8
C H
C.
3 4
C H
B.
6 10
C H
Cu 11: F 1ng phn cu tOo &3Och h[' cE cbng th7c phn tM
5 8
C H
l?:
+. 8 %. 9 C. D B. K
Cu 12: Cht n?o sau y cE 1ng phn hanh hWcP
14 ,ut ~ 2 ~ )n 24 p)nta ~ 1#* ~ i)n *4 isopr)n "4 poli,utai)n >4 ,uta ~
1#* ~ i)n
84 iso,util)n
+. 1#2#8 %. 1#2#" C. "#>#8 B. *#"#8
Cu 1*: ]Ft chy 16#2 ga3 an;ai)n lin h:p thu :c 16#D ga3
2
H !
. Cbng th7c cu tOo eng ca
an;ai)n:
+.
2 2 2
CH CH CH CH CH = =
%.
2 2
CH CH CH CH = =
C.
2 3
CH CH CH CH CH = =
B.
2 2 3
CH C CH CH CH = =
.
Cu 1": ]Ft chy ho?n to?n a 3ol an;)n + =? , 3ol i)n %# thu :c 8#292 l0t
2
C!
&;tc' =? >#K" ga3
2
H !
. F 3ol ca % l?
+. 6#62 3ol %. 6#6* 3ol C. 6#6"> 3ol B. 6#6> 3ol
Cu 1>: Vn ph3 Ft chy hzn h:p t &g13 1 an;an =? 1 an;ai)n' 5Sn ùa 55 =bi trong 5# ,anh tnng 1"
ga3 =? cE 22 ga3 ;t ta. /h@ t0ch oî cQn &;tc' l?:
+. >#*D" l0t %. 9#>D" l0t C. 9#818 l0t B. 8#292 l0t
Cu 18: Hzn h:p 2 an;ai)n liRn h:p &sF C liRn tip'# Ft chy ho?n to?n :c tL l sF 3ol
2
C!
=?
2
H !

l? 1#2D. Cbng th7c ca 2 i)n l?:
+.
3 4
C H
=?
4 6
C H
%.
4 6
C H
=?
5 8
C H
C.
5 8
C H
=?
6 10
C H
B.
6 10
C H
=?
7 12
C H
G/0 L1 Ch2 N)$3* - 9@ - T&45) THPT N)$36 7.i
Cu 19: Bfng 55
"
-<n!
;hbng phn ,it :c:
+. ,utan =? ,uta ~ 1#* ~ i)n %. )til)n =? ,uta ~ 1#* ~ i)n
C. îclo,utan =? ,ut ~ 2 ~ )n B. ,utan =? ,ut ~ 2 ~ )n
Cu 1D: Hzn h:p + g13
2 8
C H
=? 32t i)n liRn h:p
4 6
C H
# tL ;hFi ca + so =i
2
H
l? 21. Cho 6#2 3ol +
ùa 55 ch7a *2 ga3
2
%r
tha:
+. 55
2
%r
,o phai 3?u 32t phQn %. 55
2
%r
,o 3t 3?u ho?n to?n.
C. 3?u ca 55
2
%r
;hbng thay ki B. ;hbng cE ;h0 thot ;hxi ,anh ch7a
2
%r
.
Cu 1K: ng 5ing ùan trWng ca ,uta ~ 1#* ~ i)n l?:
+. ]icu ch ,utan %. ]icu ch ,ut)n C. sVn ût cht 5o B. sVn ût cao
su.
Cu 26: ]@ sVn ût 8#"D ;g poli,utai)n phVi tch
2
H
ty V 3
*
,utan &29#*
6
C# 1 at3' r1i )3 trfng h:p#
,it hiu sut chung ca ù tranh l? D6A. gi tro V l?:
+. *#818 3
*
%. "#>*2 3
*
C. "#892 3
*
B. *#8K8 3
*
%?i 1D: +$-{$
{{{. %{ /. . B$g:
Cu 1: BTa =?o ;hi ni3 1ng ng# ch7ng 3inh cbng th7c phn tM chung cc 1ng ng ca a^)til)n &
2 2
C H
' l?
n 2n 2
C H

.
Cu 2: a4 <2t hzn h:p ;h0 + g13 a^)til)n# propin =? ,ut ~ 2 ~ )n. ]Ft chy ho?n to?n *#*8 l0t &;tc' +.
/a3 ;hFi l:ng
2
C!
=?
2
H !
. %it tL ;hFi hZi ca + so =i
2
H
l? 21#".
,4 $u cho 2#2" l0t hzn h:p + tc 5ing =i
*
+g$!
4
*
$H
5 :c 1K#8D ga3 ;t ta. /a3 A th@
t0ch cc ;h0 trong hzn h:p +.
Cu *: <2t ,anh ;0n ch7a 6#6* 3ol
2 2
C H
6#61> 3ol
2 "
C H
6#6" 3ol
2
H
. $ung nEng ,anh &cE $i' n
phVn 7ng ^Vy ra ho?n to?n# thu :c hzn h:p ;h0 +. Cho + tc 5ing =i
*
+g$!
4
*
$H
5 thu :c *#8
ga3 ;t ta. /0nh sF 3ol 3zi cht trong +
Cu ": Cho 32t an;in lxng =?o 32t ,anh ch7a
*
+g$!
4
*
$H
5. au phVn 7ng ;hFi l:ng ,anh tnng 2#6>
ga3 =? ût hin "#92> ga3 ;t ta.
a4 tc onh cbng th7c phn tM ca an;in
,4 Hiro an;in n?y thu :c isoan;an. Vit cbng th7c cu tOo eng =? gWi tRn an;in.
Cu >: ]Ft chy * c3
*
hzn h:p 2 an;in +# % ; tip nhau tOo th?nh 11 c3
*

2
C!
&th@ t0ch cc ;h0 o [
cfng icu ;in nhit 2# p sut'.
a4 /a3 cbng th7c phn tM =? A th@ t0ch ca + =? % &<
+
<
%
'.
,4 Xy *#*8 l0t hzn h:p trRn &;tc' 5Sn ùa 55
*
+g$!
4
*
$H
5 thu :c 9#*> ga3 ;t ta. tc
onh cbng th7c cu tOo ca +# %.
{V. C H{ /C $gH{<:
Cu 1: ChWn onh ngha Qy : +n;in l?:
+. h:p cht hYu cZ 3Och h[ cE liRn ;t bi C C C %. hirocac,on 3Och h[ chL cE 32t liRn ;t bi
C C C
C. hirocac,on 3Och h[ ch7a liRn ;t bi C C C B. hirocac,on 3Och h[ 1ng phn ca i)n.
Cu 2: ]Ft chy 2 an;in &liRn tip trong 5Ny 1ng ng' :c tL l sF 3ol
2
C!
=?
2
H !
l? 94>. Cbng th7c
phn tM ca 2 an;in l?:
+.
2 2
C H
=?
3 4
C H
%.
3 4
C H
=?
4 6
C H
C.
4 6
C H
=?
5 8
C H
B.
5 8
C H
=?
6 10
C H
Cu *: ]Ft chy 6#> 3ol hzn h:p 2 an;in thu :c 1#2 3ol
2
C!
. /h@ t0ch
2
O
cQn &;tc' l?:
+. 22#" l0t %. **#8 l0t C. *"#92 lit B. ""#D l0t
Cu ": ]Ft chy 1 3ol hirocac,on t &3Och h[' ta :c K#8 3ol
2
C!
=? 6#"> 3ol
2
H !
. ChWn cbng th7c
phn tM t:
+.
4 6
C H
%.
3 4
C H
C.
5 8
C H
B.
4 4
C H
G/0 L1 Ch2 N)$3* - 91 - T&45) THPT N)$36 7.i
Cu >: /Rn an;in :c gWi ;hbng eng l? 2 ~ 3)tyl ~ > ~ )tylh)^ ~ * ~ in. HNy chWn cch gWi tRn lOi cho
eng:
+. > ~ )tyl ~ 2 ~ 3)tylh)^ ~ * ~ in %. *#8 ~ i3)tylh)pt ~ " ~ in
C. 2#> ~ i3)tylh)pt ~ * ~ in B. *#8 ~ i3)tylh)pt ~ *~ in.
Cu 8: Cht n?o cE 1ng phn hanh hWcP
+.
3 3
CH C C CH
%.
3 2
CH CH CH =
C.
2 3 2
CH CH CH(CH ) =
B.
3
HC C CH CH CH =
.
Cu 9: o =i an;)n tha an;in cE:
+. liRn ;t C
C 5?i hZn liRn ;t C C C %. liRn ;t C
C ngUn hZn liRn ;t C C C.

C. cE 2 liRn ;t ;hbng ,cn# an;)n chL cE 1 liRn ;t B. CV % =? C.
Cu D: Hai cht 3Och h[ cE cbng th7c phn tM
4 6
C H
=?
3 4
C H
# chfng l?:
+. 1ng phn %. 1ng ng C. 1ng ng liRn tip B. 1ng ng ho\c
;hbng.
Cu K: Cho "#D ga3 an;in tc 5ing =ya =i 55
2
%r
tOo th?nh "*#2 ga3 sVn ph3 c2ng. Cbng th7c ca
an;in la:
+.
3 4
C H
%.
4 6
C H
C.
5 8
C H
B.
2 2
C H
Cu 16: ng 5ing ca a^)til)n:
+. H?n cUt ;i3 loOi %. thUp sng C. tkng h:p hYu cZ B. cV +# %# C
Cu 11: F l:ng 1ng phn cE cbng th7c phn tM
6 10
C H
ch7a C C :
+. > %. 8 C. 9 B. D
Cu 12: F l:ng 1ng phn cbng th7c phn tM
6 10
C H
cE th@ tc 5ing =i 55
*
+g$!
4
*
$H
:
+. 2 %. * C. " B. >
Cu 1*: ]Ft chy ho?n to?n V l0t &;tc' an;in t thu :c 16#D ga3
2
H !
. $u cho to?n ,2 sVn ph3 chy
hp thi ht =?o nc =bi trong tha ;hFi l:ng ,anh tnng >6#" ga3. gi tro V l?:
+. *#*8 %. 2#2" C. 8#92 B. "#"D
Cu 1": Cho D#1 ga3 an;in tc 5ing =i
*
+g$!
4
*
$H
5# thu :c 2"#1> ga3 ;t ta. Cu tOo ca an;in:
+.
3
CH C CH
%.
3 3
CH C C CH
C.
3 2
CH CH C CH
B.
3 2 2
CH CH CH C CH
Cu 1>: Cho 6#1 3ol
2 2
C H
tc 5ing =i 55 ch7a 6#1" 3ol
2
%r
tha ;t thec phVn 7ng# 55 ,ro3 sm:
+. ,o 3t 3?u ho?n to?n %. ,o phai 3?u 32t phQn
C. cE 3?u ;hbng ki B. cE 3?u q3 hZn ,an Qu
Cu 18: ]Ft chy 32t an;in 3Och cac,on phn nhnh# thu :c tL l sF 3ol
2
C!
=?
2
H !
l? >:". Cbng
th7c cu tOo ca an;in:
+.
3 3 3
CH CH(CH ) C C CH
%.
3 3 2
CH C(CH ) C CH
C.
3 3
CH CH(CH ) C CH
B.
3 3 2
CH CH(CH ) CH C CH
Cu 19: Cho a^)til)n phVn 7ng =i clo# sVn ph3 thu :c cE 2 1ng phn# cbng th7c cu tOo ca sVn
ph3 l?:
+.
2 2
CH CCl =
%. Cl CH CH Cl = C.
2 2
CHCl CHCl
B. CH CCl
Cu 1D: +^)til)n c2ng nc :c sVn ph3 l?:
+.
2
CH CH OH =
%.
3 2
CH CH OH
C.
*
CH CH!
B.
*
CH C!!H
Cu 1K: .ropin )3 hirat hEa :c:
+.
3 2
CH CH CH O =
%.
3 3
CH COCH
C.
3 2
H C C(OH) CH =
B.
3
H C CH CH OH =
Cu 26: +^)til)n tc 5ing =i 55
"
-<n!
4
0
t tOo th?nh:
+. a^t oâlic %. ;h0 cac,onic C. ;ali oâlat B. aît a^)tic
Cu 21: /a3 h:p a^)til)n &cE êc tc C [ 866
6
C' thu :c:
+. =inyl a^)til)n %. i=inyl C. ,)n_)n B. cupr)n
Cu 22: $ho h:p a^)tl)n thu :c sVn ph3 cE t0nh cht:
G/0 L1 Ch2 N)$3* - 98 - T&45) THPT N)$36 7.i
+. tc 5ing :c =i 55
*
+g$!
4
*
$H
tOo ;t ta.
%. ;hi Ft chy :c sF 3ol
2
C!
=?
2
H !
,Hng nhau.
C. -hi hiro hEa =i êc tc .54
0
t :c ,utan.
B. -hbng l?3 phai 3?u 55
2
%r
.
Cu 2*: /rong * cht
2 2
C H
#
2 "
C H
#
2 8
C H
tha cht n?o chy cho ngWn lMa sng nht:
+.
2 2
C H
%.
2 "
C H
C.
2 8
C H
B. cu chy sng nh
nhau.
Cu 2": Cho 3 ga3
2 2
C H
ùa Fng Tng than hoOt t0nh [ 866
6
C thu :c 9#D ga3 ,)n_)n. %it hiu sut
phVn 7ng 86A. gi tro 3 l?:
+. 2" %. 1* C. 9#2 B. 22
Cu 2>: ]cu ch
2 2
C H
trong phJng th0 nghi3
+.
2
CaC
I
2
H !
%. nhit phn
4
CH
C.
2 2
Br CH CH Br
B.
,-C C,-
I
HCl
Cu 28: Cht + &3Och h[' cE cbng th7c phn tM
7 8
C H
. Cho + tc 5ing =i
*
+g$!
4
*
$H
:c ;t ta %.
%it ;hFi l:ng 3ol phn tM % ln hZn + l? 21" =C. F 1ng phn thxa icu ;in trRn:
+. 2 %. * C. " B. >
Cu 29: Cho >#2 ga3 hirocac,on + &3Och thng'# th@ ;h0# tc 5ing ho?n to?n =i 55
*
+g$!
4
*
$H
:c
1>#K ga3 ;t ta. Cbng th7c cu tOo ca +:
+.
3
HC C CH
%.
2
HC C CH CH =
C. HC C CH CH B.
2 2
HC C CH CH
Cu 2D: /y + cE cbng th7c
n
(CH)
cE th@ sVn ût cao su ,una ,Hng * phVn 7ng liRn tip# cbng th7c + l?:
+.
2 2
C H
%.
4 4
C H
C.
8 8
C H
B.
8 8
C H
Cu 2K: Cho 6#1 3ol hirocac,on + 3Och h[ tc 5ing =ya =i 55 ch7a *2 ga3
2
%r
. + thu2c 5?y 1ng
ng:
+. an;)n %. an;in C. îcloan;an B. an;in ho\c
an;ai)n.
Cu *6: C\p cht n?o sau y ;hbng phn ,it :c ,Hng 55
2
%r
P
+. )til)n# ,ut ~ 1 ~ )n %. îlcopropan# prop)n C. ,uta ~ 1#* ~ i)n# ,ut ~ 1 ~ in B. cV +#
%# C
Cu *1: ]Ft chy ho?n to?n ^ 3ol hzn h:p * an;in thu :c 16#6D l0t
2
C!
&;tc' =? >#" ga3
2
H !
. gi tro
ca ^ l?:
+. 6#1> %. 6#2> C. 6#6D B. 6#6>
Cu *2: Hzn h:p g13 6#2 3ol an;)n + =? 6#6* 3ol an;in % :c Ft chy ho?n to?n# sVn ph3 ùa nc
=bi trong :c 1" ga3 ;t ta. Cbng th7c phn tM +# % l?:
+.
2 "
C H
=?
4 6
C H
%.
4 8
C H
=?
2 2
C H
C.
3 6
C H
=?
3 4
C H
B.
3 6
C H
=?
2 2
C H
Cu **: ]Ft chy hzn h:p ;h0 t g13 1 an;an + =? 1 an;in %# :c 18#D l0t
2
C!
&;tc' =? 1*#> ga3 nc.
.hQn trn3 =c th@ t0ch ca + =? % trong t lQn l:t l?:
+. cu >6A %. "6A =? 86A C. 86A =? "6A B. *6A =? 96A
Cu *": ]Ft chy ho?n to?n 2 l0t hzn h:p
2 2
C H
=? 32t hirocac,on +# thu :c " l0t
2
C!
=? " l0t
2
H !

&cc th@ t0ch o [ cfng
0
t #p'. Cbng th7c phn tM + l?:
+.
3 6
C H
%.
2 8
C H
C.
4 6
C H
B.
3 8
C H

Cu *>: ]Ft chy ho?n to?n 6#1 3ol hzn h:p 2 hirocac,on cE ;hFi l:ng 3ol phn tM ;hFi hZn ;}3 nhau
1" =C# thu :c 9#D" l0t
2
C!
&;tc' =? "#> ga3 hZi nc. Cbng th7c phn tM ca 2 hirocac,on l?:
+.
3 8
C H
=?
4 10
C H
%.
3 4
C H
=?
4 6
C H
C.
2 "
C H
=?
3 6
C H
B.
4 8
C H
=?
5 10
C H
G/0 L1 Ch2 N)$3* - 99 - T&45) THPT N)$36 7.i
Cu *8: Hzn h:p t g13 an;ai)n + =? an;in %. ]Ft chy ho?n to?n 6#" 3ol t# tOo th?nh >"#D ga3
2
C!

=?
2
H !
. Cbng th7c phn tM ca +# % l?:
+.
3 4
C H
=?
4 6
C H
%.
4 6
C H
=?
5 8
C H
C.
4 6
C H
=?
2 2
C H
B.
5 8
C H
=?
3 4
C H
CH$g 9: H{]!C+C%!$ /H<. $g-$ H{]!C+C%!$ /H{$ $H{$. H /H$g H+
V H{]!C+C%!$.
%{ 1K: %$v$ V ]-$g ]$g
{{{. %{ /. . B$g
Cu 1: Vit cbng th7c cu tWa =? gWi tRn cc 1ng phn cE cbng th7c phn tM:
a4
8 10
C H
,4
7 7
C H Br
c4
9 12
C H
Cu 2: Vit phZng tranh hEa hWc ca cc phVn 7ng th)o sZ 1 chuy@n hEa sau:
3 2 4 3 2 4
0
2
HNO / H SO HNO / H SO
1 2 121 121
Br !t
3
tol&en 34N43(t/&o5+no6trinitrotol&en)
Benzen 7 7
etyl8enzen 7
Z
]
Cu *: Hirocac,on thZ3 t cE cbng th7c phn tM l?
8 10
C H
. %it t ;hbng l?3 3t 3?u 55 ,ro3. -hi ,o
hiro hEa# t chuy@n th?nh u cE cbng th7c phn tM
8 16
C H
. t tc 5ing =i ,ro3 th)o tL l 3ol 1:1 cE êc
tc ,2t () chL cho 32t sVn ph3. tc onh cbng th7c cu tOo ca t.
Cu ": Vit phZng tranh hEa hWc ca cc phVn 7ng tkng h:p stir)n =? cao su ,una ~ ty ;h0 3)tan.
Cu >: /ranh ,?y phZng php hEa hWc nhqn ,it cc cht lxng sau: ,)n_)n# tolu)n# stir)n# ph)nyla^)til)n
Cu 8: t l? 32t hirocac,on thu2c 5Ny 1ng ng ca ,)n_)n. ]Ft chy ho?n to?n 32t l:ng u r1 cho sVn
ph3 lQn l:t ùa ,anh 1 ch7a
2 "
H !
q3 \c =? ,anh 2 ch7a -!H# tha thy ;hFi l:ng ,anh 1 tnng thR3
6#K ga3# ,anh 2 tnng thR3 *#>2 ga3. tc onh cbng th7c phn tM ca t.
Cu 9: u l? 32t hirocac,on cE AC C K*#*1A =? AH C 9#8KA.
a4 tc onh cbng th7c Zn giVn nht ca u
,4 tc onh cbng th7c cu tOo ca u# ,it 1 3ol u phVn 7ng =ya =i " 3ol
2
H
ho\c 1 3ol
2
%r

trong 5ung 5och.
{V. C H{ /C $gH{<:
Cu 1: H:p cht thZ3 ;hbng thu2c 5Ny 1ng ng ,)n_)n l?:

CH*
%.
C H
*
CHCCH2
C.
C H* CH*
B.
6 5 2 3
C H CH CH
Cu 2: Cht n?o ;hbng th@ cE 1ng phn l? h:p cht thZ3P
+.
8 8
C H
%.
8 10
C H
C.
8 16
C H
B.
9 12
C H
Cu *: F 1ng phn ar)n &thZ3' cE cfng cbng th7c
9 12
C H
l?:
+. > %. 8 C. 9 B. D
Cu ": CE ,ao nhiRu 1ng phn thZ3 cE cbng th7c phn tM
7 7
C H Cl
P
+. 1 %. 2 C. * B. "
Cu >: gWi tRn h:p cht thZ3 cE cu tOo sau:
3 6 3 2 5
CH C H (Cl)(C H )
G/0 L1 Ch2 N)$3* - 9: - T&45) THPT N)$36 7.i
+,,,
ggg,
+. 1 ~ )tyl ~ 2 ~ clo ~ " ~ 3)tyl,)n_)n. %. 2 ~ clo ~ 1 ~ )tyl ~ " ~ 3)tyl,)n_)n.
C. 1 ~ 3)tyl ~ * ~ clo ~ " ~ )tyl,)n_)n. B. 1 ~ )tyl ~ " ~ 3)tyl ~ 2 ~ clo,)n_)n.
Cu 8: gFc hirocac,on n?o :c gWi l? gFc ph)nylP
+.
6 5 2
C H CH
%.
3 6 4
H C C H
C.
6 5
C H
B.
6 5 2 2
C H CH CH
Cu 9: gWi tRn th)o 5anh php gFc ~ ch7c h:p cht sau:
3 6 4 2
CH C H CH Cl
+. 1 ~ clo3)tyl ~ " ~ 3)tyl,)n_)n. %. ,)n_)n3)tyl clorua.
C. " ~ 3)tyl,)n_)n clorua. B. " ~ clo3)tyl ~ 1 ~ 3)tyl,)n_)n.
Cu D: o ~ îl)n l? tRn thbng 5ing ca:
+. 1#* ~ i3)tyl,)n_)n. %. )tyl,)n_)n C. 1#2 ~ i3)tyl,)n_)n B.
isopropyl,)n_)n.
Cu K: .hVn 7ng \c trng cho cc hirocac,on thZ3 l?:
+. phVn 7ng c2ng %. phVn 7ng th C. phVn 7ng oî hEa B. phVn 7ng nhit
phn .
Cu 16: u thu2c 5Ny 1ng ng ,)n_)n. ]Ft chy ho?n to?n u thu :c tL sF ;hFi l:ng
2
C!
=?
2
H !
l?
114*. Cbng th7c phn tM u l?:
+.
8 10
C H
%.
9 12
C H
C.
7 8
C H
B.
8 8
C H
Cu 11: /a3 h:p a^)til)n &icu ;in ' thu :c:
+. =inyla^)til)n %. i=inyl C. ,)n_)n B. cupr)n.
Cu 12: -hi =Jng ,)n_)n N cE sn 32t nhE3 an;yl tha nhE3 th ; tip sm u tiRn =?o =o tr0:
+. 3)ta %. ortho =? para C. 3)ta =? para B. ortho =? 3)ta.
Cu 1*: Vn ph3 ch0nh ;hi cho nitro,)n_)n tc 5ing =i
*
H$!
,Fc ;hEi &cE
2 "
H !
\c#
0
t ':
+. p ~initro,)n_)n %. 3 ~initro,)n_)n
C. o ~initro,)n_)n B. initro,)n_)n &oG ho\c pG'
Cu 1": tir)n cE cbng th7c cu tOo:
+.
3 6 4 2
H C C H CH CH =
%.
6 5 2
C H CH CH =
C.
6 5
C H C CH
B.
6 5 2 3
C H CH CH
Cu 1>: .hn ,it ,)n_)n =? tolu)n ta cE th@ 5fng
+. 55
"
-<n!
4
0
t %. 55
2
%r
C. 55
*
+g$!
4
*
$H
B. ù t03.
Cu 18: $hE3 cht ;hbng tha3 gia phVn 7ng trfng h:p l?:
+. a^)til)n# stir)n %. )til)n# propil)n C. isopr)n# iso,util)n B. îcloh)ân# ,)n_)n
Cu 19: <2t hirocac,on + cbng th7c Zn giVn nht l? CH. %it 1 3ol + phVn 7ng tFi a =i " 3ol
2
H
#
ho\c 1 3ol
2
%r
trong 55
2
%r
5. Cbng th7c cu tOo ca + l?:
+.
8 8
C H
%.
6 5 2 3
C H CH CH
C.
2 6 4 2
H C CH C H CH CH = =
B.
2
CH C CH CH =
Cu 1D: Cho tolu)n tc 5ing =i
2
Cl
trong icu ;in cE nh sng &tL l 3ol 1:1'# sVn ph3 hYu cZ thu :c
l?:
+. o ~ clotolu)n. %. 3 ~ clotolu)n. C. p ~ clotolu)n. B. ,)n_yl clorua.
Cu 1K: .hVn 7ng n?o sau y ca h:p cht thZ3 N =it ;hbng engP
+.
8 8
C H
I
2
Cl
o
Fe/ t

6 5
C H Cl
I HCl
%.
6 5 3
C H CH
I
2
Cl

o
Fe/ t

6 4 3
o Cl C H CH
I HCl
C.
6 5 3
C H CH
I
2
Cl

a()t
6 4 3
' Cl C H CH
I HCl
B.
6 5 3
C H CH
I
2
Cl

a()t
6 5 2
C H CH Cl
I HCl.
Cu 26: .hVn 7ng giYa )tyl ,)n_)n =i
2
Cl
&cE nh sng =? tL l 3ol 1:1' tOo ra sVn ph3 ch0nh:
+.
6 5 2 2
C H CH CH Cl
%.
6 5 3
C H CH(Cl) CH
C.
6 4 2 3
Cl C H CH CH
B.
6 4 2 5
C H (Cl)(C H )
Cu 21: HCl c2ng =?o stir)n tOo sVn ph3 ch0nh:
+.
Cu 22:
G/0 L1 Ch2 N)$3* - 9; - T&45) THPT N)$36 7.i
Cu 2*: ]Ft chy ho?n to?n a 3ol hirocac,on % :c hiu sF 3ol giYa
2
C!
=?
2
H !
l? *a. Cbng th7c
ca % cE 5Ong:
+.
n 2n 2
C H

%.
n 2n 4
C H

C.
n 2n 6
C H

B.
n 2n 8
C H

Cu 2": ChWn pht ,i@u eng:
&1' Cc nguyRn tM trong phn tM ,)n_)n cu trRn 32t 3\t phng.
&2' %)n_)n thu2c loOi hirocac,on no =a 5 tha3 gia phVn 7ng th.
&*' %)n_)n tha3 gia phVn 7ng c2ng 5 hZn phVn 7ng th.
&"' %)n_)n tha3 gia phVn 7ng th 5 hZn phVn 7ng c2ng.
&>' Cc an;yl,)n_)n l?3 3t 3?u thuFc t03 ;hi un nEng.
+. &1'# &"'# &>' %. &2'# &"'# &>' C. &1'# &*'# &"' B. &1'# &*'# &>'
Cu 2>: ]Ft chy 6#1 3ol tolu)n cQn th@ t0ch ;hbng ;h0 &;tc' l?:
+. 26#18 l0t %. D6#8" l0t C. 166#D6 l0t B. 112#66 l0t
Cu 28: -hbng th@ phn ,it c\p cht n?o ,Hng 55 ,ro3P
+. îcloh)ân# =nyl,)n_)n %. ph)nyla^)til)n# stir)n
C. ph)nyla^)til)n# ,)n_)n B. )tyl,)n_)n# ph)nyl)til)n.
Cu 29: Hirocac,on t cbng th7c phn tM
8 10
C H
# ;hbng l?3 phai 3?u 55 ,ro3. Hiro hEa & $i#
0
t ' tOo
th?nh 1#* ~ i3)tylîcloan;an. Cbng th7c cu tOo ca t l?:
Cu 2D: ChWn pht ,i@u sai: tir)nj.
+. ;hbng phVn 7ng =i 55
"
-<n!
%. cE th@ tha3 gia phVn 7ng trfng h:p =? 1ng trfng h:p.
C. =ya cE t0nh cht tZng tT an;)n =ya cE t0nh giFng ,)n_)n.
B. cJn :c gWi l? =inyl ,)n_)n hay ph)nyl)til)n.
%?i 26: $g-$ H{]!C+C%!$ /H{$ $H{$
{{{. %{ /. . B$g:
Cu 1: /hTc hin phVn 7ng crac;inh ho?n to?n 8#8 ga3 propan thu :c hzn h:p + g13 2 hirocac,on.
Cho + ùa ,anh ch7a 12> 3l 55
2
%r
cE n1ng 2 a 3ol4l# 55 ,ro3 ,o 3t 3?u. -h0 thot ra ;hxi ,anh 55
2
%r
cE tL ;hFi hZi so =i 3)tan l? 1#1D9>. /0nh aP
Cu 2: Crac;inh ,utan thu :c hzn h:p t g13 > hirocac,on. Cho t ùa 55
2
%r
5# ,anh tnng >#*2 ga3
=? ;hFi l:ng
2
%r
tha3 gia phVn 7ng l? 2>#8 ga3# ;h0 thot ra ;hxi ,anh cE tL ;hFi so =i
2
H
l? 1#K82>.
/a3 hiu sut phVn 7ng crac;inh.
Cu *: au ;hi chng ct phn oOn 5Qu 3x# thu :c 1DA ^nng# 2>A 5Qu 5i)s)l =? ">A 5Qu 3a_ut. ])3
crac;inh tip:
G 5Qu 5i)s)l :c thR3 >6A ^nng =? ">A an;)n.
G BQu 3a_ut :c thR3 ">A ^nng =? "6A an;)n.
/y >66 tn 5Qu 3x thu :c ,ao nhiRu tn ^nng =? cc an;)nP Cc A :c t0nh th)o ;hFi l:ng.
{{{. C H{ /C $gH{<:
Cu 1: .hZng php hEa hWc ch yu @ ch ,in 5Qu 3x l?:
+. nhit phn %. chng phn oOn C. thy phn B. crac;inh =?
riho3inh
Cu 2: /h?nh phQn hEa hWc ch0nh ca 5Qu 3x l?:
+. hzn h:p hirocac,on %. 5Sn ût hirocac,on
C. h:p cht =b cZ hJa tan B. hirocac,on thZ3.
Cu *: pu tranh ;hM hiro =? gh}p =Jng cc an;an 3Och 5?i gWi l?:
+. Cra+)in/ %. c hiro hEa C. riho3inh B. 1ng phn
hEa
Cu ": $gu1n cung cp ch yu hirocac,on l?:
+. ;h0 thiRn nhiRn %. than C. 5Qu 3x B. ;h0 3x 5Qu.
Cu >: -h0 thiRn nhiRn
+. thu :c ;hi nung than %. cE trong cc 3x 5Qu
G/0 L1 Ch2 N)$3* - 9< - T&45) THPT N)$36 7.i
C. ;hai thc ty cc 3x ;h0 B. cE :c ;hi ch ,in 5Qu 3x.
Cu 8: ChW cu sai: Ch ,in hEa hWc 5Qu 3x nhH3 3ic 0chj
+. tnng sVn l:ng =? cht l:ng ^nng l?3 nhiRn liu.
%. thR3 ngu1n nguyRn liu cho cbng nghip hEa cht.
C. tinh luyn 5Qu 3x ;hxi cc tOp cht =b cZ.
B. $ng cao gi tro sM 5ing ca 5Qu 3x.
Cu 9: o =i crac;inh êc tc# tha crac;inh nhit:
+. cQn nhit 2 cao hZn %. ^nng tOo th?nh cE cht l:ng ;}3 hZn.
C. tOo ra nhicu hirocac,on cha no B. CV +# %# C
Cu D: BQu 3x )3 crac;inh nhit cQn nhit 2 ;hoVng:
+. 1D6
6
C %. "66 ~ ">6
6
C C. 966 ~ K66
6
C B. 1266
6
C
Cu K: /h?nh phQn ch yu ca ;h0 thiRn nhiRn =? ;h0 3x 5Qu l?:
+. 3)tan %. an;an C
2
~ C
"
C. 5Sn ût hirocac,on B. ;hi =b cZ
Cu 16: ChWn pht ,i@u ;hbng eng:
+. th?nh phQn hEa hWc 5Qu 3x g13 nhicu hirocac,on.
%. -h0 thiRn nhiRn =? ;h0 3x 5Qu ch yu l? ;h0 3)tan.
C. /h?nh phQn ;h0 thiRn nhiRn =? ;h0 3x 5Qu gQn giFng nhau.
B. -h0 3x 5Qu ch7a nhicu 3)tan hZn ;h0 thiRn nhiRn.
Cu 11: Chng ct 5Qu 3x [ 1D6
6
C =? p sut cao# thu :c cc hirocac,on lxng C
8
~ C
16
gWi l?:
+. )t) 5Qu hxa %. ;h0 hEa lxng C. ^nng B. 5i)s)l
Cu 12: -h0 lJ cFc thu :c ;hi nung than &[ nhit 2 cao# ;hbng cE ;hbng ;h0' ch yu ch7a:
+.
2
H
=?
4
CH
%. cc hirocac,on ;h0 C.
2
C!
#
2
$
#
2
O
B. hZi ,)n_)n# ;h0
*
$H
Cu 1*: /y nhTa than # ;hi chng ct ta cE th@ thu :c:
+. an;an th@ lxng %. cc ar)n =? ph)nol C. 5Qu n\ng B. 5Qu trung ,anh.
Cu 1": phn oOn sbi D6 ~ 196
6
C ;hi chng ct nha than ta thu :c 5Qu nh ch7a:
+. ,)n_)n# tolu)n# îl)nj %. naphtal)n# ph)nol# piri5inj
C. cr)_ol# îl)nol# ùinolinj B. cc îcloan;)n# an;anj
Cu 1>: .hVn 7ng n?o ;hbng phVi l? ù tranh riho3inh:
+.
0
xt!t
3 2 5 3 6 5 3 2
CH 9CH : CH C H CH 4H + %.
8 8
C H
I *
2
H

0
Ni!t

6 12
C H
C.
6 12
C H

0
xt!t !'

8 8
C H
I *
2
H
B.
0
xt!t
3 2 5 3 6 11 3 2
CH 9CH : CH C H CH H +
%?i 21: H /H$g H+ V H{]!C+C%!$.
{{. %{ /. . B$g.
Cu 1: Vit phZng tranh phVn 7ng th)o sZ 1 chuy@n hEa sau:
0
4 2 4
0
";nO / t H SO
<nO
600 C
B C
,n)an 8enzen etyl8enzen
= 'oli>e

Z
]
Cu 2: Vit phZng tranh phVn 7ng# gWi tRn cc cht:
a4 +
0
1500 C
la?>la%n/n/an/
B @ C
8/ B
0
600 C
=
+/ = @ C
0
Ni!t
A
B/ = @ C
trinitro8enzen (3NB)
e/ , @ D
a()t
" @ HCl
./ " @ =
E @ HCl
-/ E @ C
trinitrotol&en (3N3) @ F
Cu *: .hn ,it cc lW hEa cht 3t nhNn sau:
a4 h)ân# h)^ ~ 1 ~)n# h)^ ~ 1 ~ in# ,)n_)n# tolu)n.
,4 ,)n_)n# tolu)n# =inyl,)n_)n# ph)nyla^)til)n
c4 ,)n_)n# tolu)n# îcloh)ân# h)^ ~ 1 ~ )n# nitro,)n_)n
G/0 L1 Ch2 N)$3* - 9= - T&45) THPT N)$36 7.i
54 ,)n_)n# tolu)n# )tyl,)n_)n.
Cu ": Hzn h:p % g13
2 8
C H
#
2 "
C H
#
3 4
C H
. Cho 12#2" ga3 % tc 5ing =i
*
+g$!
4
*
$H
5# thu :c
1"#9 ga3 ;t ta. <\t ;hc "#2>8 l0t % &;tc' phVn 7ng =ya =i 1"6 3l 55
2
%r
1<. /0nh ;hFi l:ng 3zi
cht trong 12#2" ga3 % ,an Qu. Cc phVn 7ng ho?n to?n.
Cu >: Hzn h:p ;h0 + g13
2
H
# 32t parahin# 2 ol)hin 1ng ng liRn tip. Cho >86 3l + i ùa bng ch7a
$i nung nEng :c ""D 3l hzn h:p ;h0 %. Cho % ùa ,anh ch7a 55
2
%r
# thy phai 3?u =? ,anh ch7a
2
%r

tnng 6#*"> ga3. Hzn h:p B i ra ;hxi ,anh chi3 th@ t0ch 2D6 3l# cE tL ;hFi hZi so =i ;hbng ;h0 l? 1#2D*.
tc onh cbng th7c phn tM hirocac,on# A th@ t0ch 3zi ;h0 trong +. Cc phVn 7ng ^Vy ra ho?n to?n# cc
ol)hin phVn 7ng =i =qn tFc ,Hng nhau &ngha l? tL l =i A th@ t0ch ca cheng'. Cc ;h0 cu o [ ;tc.
Cu 8: <2t hzn h:p + g13 6#12 3ol
2 2
C H
=? 6#1D 3ol
2
H
. Cho + i ùa $i nung nEng# phVn 7ng ;hbng
ho?n to?n =? thu :c hzn h:p ;h0 %. Cho % ùa ,anh 55
2
%r
5# thu hzn h:p ;h0 thot t. ]Ft chy ho?n
to?n t r1i cho to?n ,2 sVn ph3 =?o ,anh ch7a 55
2
Ca&!H'
5# thu :c 12 ga3 ;t ta =? ;hFi l:ng
ca ,anh tnng lRn D#DD ga3. /0nh 2 tnng ;hFi l:ng ,anh ch7a 55
2
%r
.
Cu 9: Hzn h:p g13 2 hirocac,on 3Och h[ &thu2c an;an# an;)n ho\c an;in'# sF cac,on 3zi cht 9. ]Ft
chy ho?n to?n 6#6> 3ol hzn h:p thu :c 6#2> 3ol
2
C!
=? 6#2* 3ol
2
H !
. /a3 cbng th7c phn tM ca 2
hirocac,on.
{{{. C H{ /C $gH{<.
Cu 1: Hirocac,on + Ft chy ho?n to?n thu :c sF 3ol
2
C!
=?
2
H !
,Hng nhau. + thu2c 5Ny 1ng
ng
+. an;an %. an;)n C. an;in B. an;)n ho\c
îcloan;an.
Cu 2: ]Ft chy ho?n to?n a 3ol hirocac,on + 3Och h[# thu :c hiu sF 3ol
2
C!
=?
2
H !
l? a 3ol. +
thu2c 5Ny 1ng ng
+. an;an %. an;)n ho\c i)n C. an;in ho\c i)n B. an;in ho\c
an;yl,)n_)n.
Cu *: ]Ft chy hzn h:p + g13 nhicu hirocac,on thu :c 1*#"" l0t
2
C!
&;ct' =? 12#8 ga3
2
H !
.
-hFi l:ng ca + l?:
+. D#8 ga3 %. 9#K ga3 C. 9#2 ga3 B. K#8 ga3.
Cu ": Vn ph3 Ft chy hzn h:p hirocac,on + hp thi ,[i 55 =bi trong 5 thu :c 12 ga3 ;t ta =?
,anh ch7a tnng 9#D ga3. /h@ t0ch oî cQn &;tc' l?:
+. 2#9DD l0t %. "#2>8 l0t C. 8#292 l0t B. 2#K12 l0t
Cu >: ChWn 5Ny h:p cht cu cE th@ tha3 gia phVn 7ng trfng h:p:
+. prop)n# îclo,utan# a^)til)n. %. )til)n# ,uta G1#*Gi)n# stir)n
C. ,)n_)n# =inyl,)n_)n# )til)n. B. a^)til)n# )tyl,)n_)n# tolu)n.
Cu 8: .hn ,it a^)til)n =? ph)nyl)til)n cE th@ 5fng:
+. 55
2
%r
%. 55 $a!H C. 55
*
+g$!
4
*
$H
B. 55
*
H$!
Cu 9: BNy h:p cht cu cE th@ tha3 gia phVn 7ng th halog)n ;hi cE nh sng ho\c un nEng:
+. propan# ,)n_)n# îclopropan# a^)til)n.
%. ,utan# tolu)n# )tyl,)n_)n# stir)n# )til)n.
C. ph)nyla^)til)n# )tyl,)n_)n# stir)n# )til)n
B. ,uta ~ 1#* ~ i)n# ,)n_)n# îclop)ntan# =inyla^)til)n.
Cu D: /ch riRng hzn h:p g13 a^)til)n# )tan# ;h0
2
C!
cE th@ 5fng hEa cht n?o sau y &th)o th7 tT'P
+.
2
%r
# $a!H#
*
+g$!
4
*
$H
%.
2
Ca&!H'
#
*
H$!
# HCl
C. $a!H# HCl#
*
+g$!
4
*
$H
B.
2
Ca&!H'
#
*
+g$!
4
*
$H
# HCl
Cu K: C\p cht n?o sau y cE th@ 1ng trfng h:p =i nhauP
+. a^)til)n# ,uta ~ 1#* ~ i)n. %. stir)n# ,uat ~ 1#* ~ i)n.
C. =inyla^)til)n# )tyl,)n_)n. B. prop)n# a^)til)n.
Cu 16: -hi crac;inh 5Qu 3x# thu :c 3? hirocac,on 3? ;hi Ft chy ho?n to?n tkng sF 3ol sVn ph3
,Hng tkng sF 3ol cc cht tha3 gia phVn 7ng. Cbng th7c phn tM ca hirocac,on l?:
G/0 L1 Ch2 N)$3* - 9> - T&45) THPT N)$36 7.i
+.
4
CH
#
2 "
C H
%.
3 4
C H
#
4 4
C H
C.
4
CH
#
5 4
C H
B.
3 4
C H
#
5 4
C H
Cu 11: ]@ phn ,it ,)n_)n# )tyl,)n_)n =? stir)n# ta chL cQn 5fng:
+. 55
2
%r
%. 55
"
-<n!
C. 55
*
H$!
\c B. 55
2 "
H !
\c.
Cu 12: Cc cht trong nhE3 n?o cu cE th@ tha3 gia phVn 7ng c2ng =i 55
2
%r
P
+. îclopropan# )til)n# stir)n %. îclo,utan# propil)n# ,)n_)n.
C. ,)n_)n# stir)n# propin B. îclopropan# ,utan# i=inyl.
Cu 1*: ]Ft chy hzn h:p 2 hirocac,on thu2c 5Ny 1ng ng n?o sau y# ta lubn lubn :c sF 3ol
2
C!

ln hZn sF 3ol
2
H !
P
+. îcloan;an =? an;)n %. an;)n =? an;in
C. an;an =? an;in B. an;)n =? an;an.
Cu 1": .hVn 7ng ;hbng l?3 giV3 3Och cac,on:
+. crac;inh. %. trfng h:p C. c2ng ho\c oî hEa B. c2ng ho\c th.
Cu 1>: BNy h:p cht cu cE th@ tha3 gia phVn 7ng c2ng =? phVn 7ng th:
+. ,)n_)n# îclopropan %. îcloh)ân# tolu)n# stir)n.
C. prop)n# propan# propin. B. ,)n_)n# îclopropan# prop)n.
Cu 18: /hTc hin phVn 7ng ;hM &tch' cht n?o sau y thu :c )til)nP
+. )tan %. ancol )tylic
C. a^)til)n ho\c )tyl clorua B. )tan ho\c ancol )tylic.
Cu 19: -hi Ft chy 3 ga3 cht hYu cZ t# cQn n 3ol
2
O
chL thu :c a 3ol
2
C!
=? , 3ol
2
H !
# pht
,i@u n?o sau y ;hbng engP
a. t l? hirocac,on %. 2n 2a I ,
C. 3 I *2n C ""a I 1D, B. 3 12a I 2,
Cu 1D: ]Ft chy hirocac,on t =? ,)n_)n# thu :c th@ t0ch
2
C!
=?
2
H !
,Hng nhau. t thu2c 5Ny 1ng
ng n?o sau y:
+. an;ai)n %. stir)n C. an;in ho\c îcloan;an B. an;)n ho\c
an;an
Cu 1K: ChWn h:p cht ;hbng tha3 gia phVn 7ng c2ng =i H%r:
+. îclopropan %. stir)n C. îclo,utan B. isopr)n
Cu 26: /ong icu ;in th0ch h:p# h)ptan cE th@ chuy@n hEa th?nh tolu)n# ù tranh n?y :c gWi l?:
+. 1ng phn hEa %. riho3inh. C. c hiro hEa B. sT nhit phn.
%{ 2": .H$!X
C H{ /C $gH{<:
Cu 1: ChWn pht ,i@u sai: .h)nol =? ancol thZ3
+. trong phn tM cu cE ch7a =Jng ,)n_)n %. ;hc nhau =c =o tr0 ~!H Fi =i =Jng thZ3
C. cu tOo :c liRn ;t hiro giYa cc phn tM B. ]cu phVn 7ng :c =i 55 $a!H.
Cu 2: Cht n?o sau qy ;hbng phVi l? ph)nol
+.
Cu *: H:p cht thZ3 ;hbng phVn 7ng =i 5ung 5och $a!H l?:
+.
6 5 2
C H CH OH
CHNG F: AN,QHIT 3 XQT*N 3 AXITCACB*XRLIC
BI 22: AN,QHIT 3 XQT*N
I. Ph !" #$%
Cu 1:
a. ]Ft chy ho?n to?n 16#Dg 32t an5)hit + thu :c 1*#"" l0t
2
C!
&;c' =? 16#Dg
2
H !
. /a3
cbng th7c phn tM +
G/0 L1 Ch2 N)$3* - 9? - T&45) THPT N)$36 7.i
,. ]Ft chy ho?n to?n 32t an5)hit % Zn ch7c thu :c 6#* 3ol
2
C!
=? 6#2 3ol
2
H !
.%it <
%

K6 =c. /a3 cbng th7c phn tM %
Cu 2: ]Ft chy ho?n to?n 2>#"g t g13 1 ancol Zn no =? 1 an5)hit Zn no thu :c 28#DD l0t
2
C!
&;tc'
=? 29g
2
H !

a. /a3 th@ t0ch oî cQn &;c'
,. tc onh cbng th7c phn tM =? ;hFi l:ng 3zi cht trong hzn h:p t
Cu *: Cho 16#Dg an;anal tc 5ing =i +g$!
*
I
*
$H
&5'# l:ng +g tOo th?nh tan ht trong 55
*
H$!

loNng nEng thu :c 2 l0t ;h0 $! &1#2*2 at3 29#*
6
C'. %it an;anal cE cu tOo 3Och cac,on phn nhnh.
tc onh cbng th7c cu tOo =? gWi tRn an;anal trRn
Cu ":
a. $Ru 2 =0 5i ch7ng tx an5)hit a^)tic cE th@ l? cht oî hEa# cE th@ l? cht ;hM
,. Ho?n th?nh sZ 1 ,in hEa sau# =it phZng tranh phVn 7ng
+
2
Cl 4 as
%
$a!H +
C
6
Cu!4 t
B
* *
+g$! $H +
&ch7a 2 C'
Cu >: Vit cbng th7c cu tOo ca
a. 2G)tylG*G3)tyl,utanal
,. 2G3)tyl,utan5ial
c. %utG 2G )nal
5. *Gisopropylp)ntanal
). tan5ial
h. 2#*G ihi5roîpropanal
Cu 8: .hn ,it cc 3Su thM &trong tyng 5Ny' sau y
a. )tanol# ph)nol &lxng'# 55 ho3an5)hit# ,)n_)n
,. a^)ton# an5)hit propionic# propanolG1# )tyi)n glicol
c. gli^)rol &gli^)rin'# )tnnol# propanal
Cu 9: Cho 3 ga3 55 )tanal 16A tc 5ing =i
2
Cu&!H'
5 tOo ra >#98g Cu
2
! &hiu sut 166A'. /0nh 3
=? ;hFi l:ng +g thu :c ;hi cho 23 ga3 55 trRn thTc hin phVn 7ng trng gZng
Cu D: ;hi l?3 ,ay hZi ho?n to?n >#Dg 32t cht hYu cZ t thu :c "#"D l0t hZi [ 16K#2
6
C =? 6#9 at3. <\t
;hc cho >#Dg t tc 5ing =i +g$!
*
&5' trong
*
$H
thy tOo th?nh "*#2g +g
a. tc onh cbng th7c phn tM# cbng th7c cu tOo ca t. gWi tRn
,. Vit phZng tranh phVn 7ng ca t =i
2
Cu&!H'
&un nEng'# =i
2
H
&$i4t
6
'. Vit phZng tranh
phVn 7ng 5icu ch t ty
2 2
C H

Cu K: Cho >#1D"g an;anal + phVn 7ng ho?n to?n =i 55 +g$!
*
4
*
$H
&5' sinh ra 3uFi a3oni ca aît %
=? +g. /o?n ,2 l:ng +g tc 5ing =i 55
*
H$!
\c 5 thu :c *#8" l0t
2
$!
&29
6
C =? 9"6 33Hg'. $u
cho + tc 5ing =i
2
H
&$i4t
6
' thu :c ancol Zn ch7c C cE 3Och cac,on phn nhnh. tc onh cbng
th7c cu tOo ca +# %# C.
Cu 16: Hi5ro hEa ho?n to?n 1#8g hzn h:p 2 an5)hit no ta thu :c 2 ancol. ]un hzn h:p 2 ancol n?y =i
2 "
H !
\c# tha thu :c hzn h:p 2 ol)hin l? 1ng ng ; tip. /r2n hzn h:p 2 ol)hin =i *#*8 l0t
2
!
&5#
;c' r1i Ft chy. Hzn h:p sau phVn 7ng sau ;hi 5Sn ùa
2 "
H !
\c# tha cJn lOi 2#D l0t & o [ >"
6
C
1#6>8at3' . tc onh cbng th7c phn tM =? t0nh ;hFi l:ng 3zi an5)hit
Cu 11: ]Ft chy ho?n to?n *#1Dg hzn h:p 2 an;anal &cu cE sF cac,on "# 3Och thng'. /o?n ,2 sVn
ph3 :c hp thi =?o ,anh Tng Ca! ;han# ,anh tnng#>"g
a. tc onh cbng th7c phn tM 2 an;anal
,. /a3 cbng th7c cu tOo eng =? A ;hFi l:ng ca 3zi an;anal# ,it rHng ncu *#1D g hzn h:p 2
an;anal y phVn 7ng ht =i 55
*
+g$!
4
*
$H
tOo ra 12g +g
Cu 12: an5)hit +# cE ;hFi l:ng D#"g# chi3 th@ t0ch 1#*"" l0t &*at3# 1*8#>
6
C' tc 5ing ht =i
*
+g$!
4
*
$H
tOo th?nh 2>#K2g +g . tc onh cbng th7c cu tOo +# ,it + cE 3Och cac,on phn nhnh
G/0 L1 Ch2 N)$3* - :@ - T&45) THPT N)$36 7.i
Cu 1*: Chuy@n hEa ho?n to?n "#2g an5)hit + 3Och h[ ,Hng phVn 7ng trng gZng =i
*
+g$!
4
*
$H
5.
$u cho to?n ,2 +g tOo th?nh tc 5ing =i
*
H$!
\c tOo ra 1#D"D l0t
2
$!
&29#*
6
C =? 2at3'. /L ;hFi hZi
+ so =i
2
$
nhx hZn ". + )3 hi5ro hEa ho?n to?n tha :c %
a. Vit phZng tranh phVn 7ng. /a3 cbng th7c phn tM# +#%
,. Vit phZng tranh phVn 7ng icu ch + ty ,utan
II. Ph !&'( )hi*+
Cu 1: ChWn cbng th7c phn tM an5)hit no 3Och h[
a.
n 2n 1
C H CH!
+
,. C
^
H
y
&CH!'
3
c.
n 2n 2 3 3
C H &CH!'
+
5. C
n
H
2n
&CH!'
3
Cu 2: gWi tRn th)o 5anh php ùFc t h:p cht cE cbng th7c sau:
CH
3
!CHSC
2
H
2
T!CHSCH
3
T!CHSCH
3
T!CH
2
!CH*
a. *#"Gi3)tylG>G)tylh)ânal ,. *#"#>Gtri3)tylh)ptanal
c. *#"#>Gtri3)tylh)ânal 5. *#"Gi3)tylG"G)tylpantanal
Cu *: F l:ng 1ng phn &ch7a nhE3 cac,onyl' cE cbng th7c C
"
H
8
!
a. > ,. 8 c.9 5. D
Cu ": ]Ft chy 1 an5)hit &3Och h[' thu :c sF 3ol
2
C!
,Hng sF 3ol
2
H !
# chWn cbng th7c phn tM
chung cho phf h:p =i an5)hit trRn
a. C
n
H
2n
! ,. C
n
H
2n2
c. C
n
H
2n
&CH!'
2
5.
n 2n 1
C H CH!

Cu >: ]Ft chy ho?n to?n 6#1 3ol an5)hit Zn ch7c &3Och h[' thu :c 6#* 3ol
2
C!
=? 6#2 3ol
2
H !
.
/h@ t0ch
2
!
&;c' l?
a. 8#92 l0t ,. 9#D" l0t c. "#"D l0t 5. 9#18D l0t
Cu 8: Xy a 3ol an5)hit Zn no &3Och h[' Ft chy thu :c D#68" l0t
2
C!
&;c'. $u )3 hi5ro hEa
ho?n to?n a 3ol an5)hit trRn r1i Ft chy thu :c D#8"g
2
H !
. gi tro ca a l?
a. 6#12 ,. 61" c. 618 5. 6#1D
Cu 9: +n5)hit Zn ch7c c2ng hi5ro cE $i4t
6
C# sF oî hEa ca C trong nhE3 ch7c an5)hit
a. tnng 1 Zn =o ,. tnng 2 Zn =o c. giV3 1 Zn =o 5. giV3 2 Zn =o
Cu D: -hi tha3 gia phVn 7ng trng gZng &=i
*
+g$!
4
*
$H
'# an5)hit Eng =ai trJ cht:
a. oî hEa ,. ;hM c. tT oî hEa ;hM 5. nhqn )
Cu K: 6#12 3ol an5)hit + tc 5ing ht =i
*
+g$!
4
*
$H
# l:ng +g )3 hJa tan trong
*
H$!
\c 5 thu
:c 16#9>2 l0t
2
$!
&;c'. /L ;hFi hZi + so =i
2
!
ln hZn 1. Cbng th7c phn tM ca +
a. HCH! ,. CH
*
CH! c. &CH!'
2
5. C
2
H
>
CH!
Cu 16: Cho 6#2 3ol hzn h:p + g13 an5)hit Zn ch7c tc 5ing ht =i
*
+g$!
4
*
$H
# thu :c 8"#Dg +g.
ChWn c\p cbng th7c phn tM phf h:p
a. HCH! =? CH
*
CH! ,. CH
*
CH! =? CH
*
CH
2
CH!
c. &CH!'
2
=? CH
*
CH! 5. CH
2
CCHCH! =? CH
*
CH
2
CH!
Cu 11: +n)hit + &3Och h['# tc 5ing =i 55
*
+g$!
4
*
$H
# 5 thu :c
+g +
n 2n >
. ]Ft chy 6#1 3ol +
thu :c 6#* 3ol
2
C!
. Cbng th7c phn tM +
a. CH
2
CCHCH! ,. C
2
H
"
&CH!'
2
c. CH
2
&CH!'
2
5. CH
*
CH
2
CH!
Cu 12: ]Ft chy ho?n to?n an5)hit + 3Och h[# thu :c tL l sF 3ol
2
C!
=?
2
H !
l? ":*. ChWn cbng
th7c phn tM +
a. CH
*
CH
2
CH! ,. C
2
H
"
&CH!'
2
c. C
*
H
9
GCH! 5. CH
2
&CH!'
2
Cu 1*: >#Dg an)hit + 3Och h[ tc 5ing ht =i 55
*
+g$!
4
*
$H
thu :c "*#2g +g. /L ;hFi hZi so =i
2
H
nhx hxn *2. Cbng th7c phn tM +
a. CH
*
CH
2
CH! ,. CH
*
CH! c. &CH!'
2
5. CH
2
&CH!'
2
Cu 1": Hzn h:p 2 an)hit cE phn tM ;hFi ,Hng nhau. Xy 8#K8g 1 trong 2 an)hit trRn thTc hin phVn
7ng trng gZng ho?n to?n tha :c 2>#K2g +g. Cbng th7c phn tM ca an)hit th7 2 l?
a. . CH
*
CH
2
CH! ,. &CH!'
2
c. CH
*
CH! 5. CH
2
&CH!'
2
Cu 1>: F l:ng 1ng phn cE cbng th7c phn tM C
"
H
8
!# cE th@ cE phVn 7ng trng gZng l?
a. 2 ,. * c. " 5. >
G/0 L1 Ch2 N)$3* - :1 - T&45) THPT N)$36 7.i
Cu 18: -hi hi5rat hEa a^)til)n &Hg
2I
# D6
6
C'# thu :c
a. CH
*
CH! ,. CH
2
CCHG!H c. C
2
H
"
&CH!'
2
5.H!GCH
2
GCH!
Cu 19: +n)hit ho3ic cE th@ icu ch trTc tip &,Hng 1 phVn 7ng' ty:
a. CH
"
,. CH
*
G!H c. CH
*
Cl 5. CH
"
ho\c CH
*
G!H
Cu 1D: $hTa ph)nolho3an5)hit :c icu ch ,Hng cch un nEng ph)nol &5' =i 55
a. CH
*
CH! trong 3bi trdng aît
,. HCH! trong 3bi trdng aît
c. HC!!H trong 3bi trdng aît
5. CH
*
C!!H trong 3bi trdng aît
Cu 1K: cho 6#1 3ol hzn h:p 2 an)hit Zn ch7c# ; tip nhau trong 5Ny 1ng ng phVn 7ng ht =i
*
+g$!
4
*
$H
5# un nEng# thu :c 2>#K2g +g. Cbng th7c cu tOo ca hai an)hit l?
a. HCH! =? C
2
H
>
CH! ,. HCH! =? CH
*
CH!
c. C
2
H
>
CH! =? C
*
H
9
GCH! 5. CH
*
CH! =? C
2
H
>
CH!
Cu 26: Cho 6#K2g 32t hzn h:p g13
2 2
C H
=? CH
*
CH! tc 5ing =i
*
+g$!
4
*
$H
thu :c >#8"g hzn
h:p rUn. A ;hFi l:ng ca
2 2
C H
=? CH
*
CH! tZng 7ng l?
a. 2D#28A =? 91#9"A ,. 28#9"A =? 9*#28A c. 2>#9*A =? 9"#29A 5. 29#K>A =? 92#6>A
Cu 21: !î hEa K#2g an;anol t :c 9#6"g an)hit u tZng 7ng. Hiu sut phVn 7ng l? D6A. Cbng th7c
t =? u l?
a.
*
CH
G!H# HCH! ,.
2 >
C H
G
2
CH
G!H#
2 >
C H
GCH!
c.
*
CH
G
2
CH
G!H#
*
CH
GCH! 5.
" K
C H
G!H#
* 9
C H
GCH!
Cu 22: ]Ft chy ancol Zn ch7c =? an)hit Zn ch7c no &cu 3Och h[' thu :c 1*#"" l0t &;tc'
2
C!
=?
Kg
2
H !
. F 3ol ancol l?
a. 6#23ol ,. 6#13ol c. 6#1>3ol 5. 6#2>3ol
Cu 2*: Cho cc cht
*
CH
G
2
CH
GCH!#
2
CH
CCHGCH!#
2
CH
CCHG
2
CH
G!H#
*
CH
GC!G
*
CH
. $hYng
cht n?o tc 5ing ho?n to?n =i
2
H
5 &$i4t
6
C' cho cfng 32t sVn ph3
a.
*
CH
G
2
CH
GCH!#
2
CH
CCHGCH!#
2
CH
CCHG
2
CH
G!H#
*
CH
GC!G
*
CH
.
,.
*
CH
G
2
CH
GCH!#
2
CH
CCHGCH!#
*
CH
GC!G
*
CH
.
c.
2
CH
CCHGCH!#
2
CH
CCHG
2
CH
G!H#
*
CH
GC!G
*
CH
.
5.
*
CH
G
2
CH
GCH!#
2
CH
CCHGCH!#
2
CH
CCHG
2
CH
G!H.
Cu 2": CE th@ phn ,it 2 cht ;h0
2 2
C H
=? HCH! ,Hng
a. 55 %r
2
,. 55 -<n!
"
4
2 "
H !
c. 55
*
+g$!
4
*
$H
5. 55
2
Ca&!H'

Cu 2>: Cho sZ 1 phVn 7ng sau: /olu)n
2
Cl
1:1
t
$a!H
u
6
Cu!4 t
v
* *
+g$! 4 $H
/. %it t# u# v#
/ l? nhYng sVn ph3 ch0nh. Cbng th7c cu tOo ca / l?
a.
8 >
C H
GC!!H ,.
*
CH
G
8 "
C H
GC!!$H
"
c.
8 >
C H
GCH!5.pGH!!CG
8 "
C H
GC!!$H
"
Cu 28: Hzn h:p g13 2 cht +# % cE phn tM ;hFi ,Hng nhau. Xy + tc 5ing
*
+g$!
4
*
$H
5 :c
+g
t
n
2
n
>
. ]Ft chy ho?n to?n 6#1 3ol % cQn 6#" 3ol
2
!
. Cbng th7c +# % l?
a.
*
CH
GCH!# C
*
H
D
%.
2 >
C H
GCH!# &CH!'
2
C. HCH!# C
2
H
8
B.
2
CH
&CH!'
2
#
* 9
C H
GCH!.
BI 2A: AXIT CACB*XRLIC
I. Ph !" #$%
Cu 1: Vit cbng th7c cu tOo ca cc aît cE tRn sau y
a. +ît 2G3)tylpropanoic
,. +ît 2#2Giclopropanoic
c. +ît 2GcloG*G3)tyl,utanoic
5. +ît *#*GicloG2G3)tylp)ntanoic
Cu 2:
G/0 L1 Ch2 N)$3* - :8 - T&45) THPT N)$36 7.i
a. giVi th0ch t0nh aît ca cc aît cac,o^ylic 5Ta =?o cu tOo. giVi th0ch =a sao phn tM
2 >
C H
!H =?
*
CH
GC!!H cu ch7a nhE3 hy5ro^yl &G!H' nhng chL cE
*
CH
GC!!H l? cE t0nh aît
,. o snh 2 3Onh cc aît trong 3zi 5Ny sau
I HC!!H#
*
CH
GC!!H#
*
CH
GCHClGC!!H#
2
CH
ClG
2
CH
GC!!H
I
*
CH
GC!!H# ClG
2
CH
GC!!H. %rG
2
CH
GC!!H# CCl
*
GC!!H
Cu *:
a. Vit phZng tranh phVn 7ng ;hi cho cc 1ng phn ca C
2
H
"
2
!
tc 5ing =i $a# $a!H# Cu!#
2 *
$a C!
.
,. +ît ho3ic cE th@ tha3 gia phVn 7ng trng gZng =i
*
+g$!
4
*
$H
&tOo th?nh +g' =? phVn 7ng
=i
2
Cu&!H'
tOo th?nh 55 ânh la3. +n)hit ho3ic phVn 7ng =i
2
Cu&!H'
trong $a!H tOo
;t ta x gOch. Vit cc phZng tranh phVn 7ng
Cu ": /y aît propionic# hNy =it cc phZng tranh phVn 7ng chuy@n hEa th)o sZ 1 sau:
2 >
C H
&C!!'
2

2
Cl
+
$a!H +
%
2 "
H ! +
C
$a +
B .
Cu >:
1. $hqn ,it cc 3Su hEa cht sau
a.
*
CH
GC!!H#
2
CH
CCHGC!!H#
2 >
C H
G!H# C
2
H
"
&!H'
2
#
*
CH
GCH!
,. ,Hng 1 thuFc thM: )tanol# )tanal# )tanoic# propantriol
2. /ch riRng tyng cht ra ;hxi hzn h:p:
*
CH
GC!!H#
*
CH
G!H#
8 >
C H
G!H
Cu 8: Vit cbng th7c cu tOo =? gWi tRn cc aît +# %# C# B# ;hi:
a. ]Ft chy ho?n to?n D#Dg aît Zn ch7c no &3Och h[' + cQn 11#2 l0t ;h0
2
!
&;c'
,. /rung hJa 6#1 3ol % &tZng Zng 16#"g' cQn Dg $a!H.
c. /rung hJa 2#2>g iaît C cQn 263l 55 -!H 2#><
5. /rung hJa 8#92g aît Zn ch7c B cQn 18#K>3l 55 $a!H 22#"A &5C1#1Dg43l'
). 9#2g l?3 ,ay hZi cE th@ t0ch ,Hng th@ t0ch ca *g )tan trong cfng icu ;in =c nhit 2 p
sut.
Cu 9: 1#18g 32t aît hYu cZ phVn 7ng =ya =i 1663l 55 $a!H 6#2<. tc onh cbng th7c phn tM#
cbng th7c cu tOo ca aît# ,it ;hFi l:ng phn tM ca nE 1>6 =c.
Cu D: <2t aît no a ch7c# 3Och h[ &<126'# :c trung hJa ,[i $a!H# cb cOn hzn h:p sau phVn 7ng
:c 2"#*g 3uFi ;han. %it ;hFi l:ng aît 5fng l? 19#9g. tc onh cbng th7c phn tM ca aît
Cu K: Cho a ga3 hzn h:p 2 aît Zn ch7c no + =? % &1ng ng liRn tip' tc 5ing chq3 =i 6#> l0t
2 *
$a C!
1< &5' &;hbng tOo ;h0
2
C!
'. ]@ phn hy ht 3uFi cac,onat trong 55 thu :c cQn *>63l 55
HCl 2<. $u )3 Ft chy a ga3 hzn h:p 2 aît trRn tha hiu sF ;hFi l:ng
2
C!
=?
2
H !
l? *8#"g. tc
onh cbng th7c phn tM =? tL l sF 3ol +# % trong hzn h:p.
Cu 16: >6g 55 aît hYu cZ Zn ch7c no + tc 5ing =i 2#Dg 32t ;i3 loOi % thu :c 1#12 l0t ;h0 &;c'# @
trung hJa aît 5 phVi 5fng >63l 55 $a!H 1<# cb cOn :c sVn ph3 rUn C cE ;hFi l:ng 16#9g. tc
onh ;i3 loOi %# cbng th7c phn tM ca +# n1ng 2 A aît.
Cu 11: <2t hzn h:p t g13
2
H !
=? 2 aît hYu cZ Zn ch7c no +# %. %it rHng 2 ga3 t trung hJa =ya
,[i *>3l 55 $a!H 1<.Cb cOn :c 2#88g 3uFi ;han.
a. /a3 A ;hFi l:ng
2
H !
trong hzn h:p t
,. Xy 3uFi ;han thR3 $a!H 5# nung ;hb :c hzn h:p ;h0 u. /0nh tL ;hFi hZi u so =i
2
H
.
/a3 ;hFi l:ng
2
C!
=?
2
H !
;hi Ft chy ho?n to?n u. $u +#% l? 2 cht liRn tip trong 5Ny
1ng ng hNy ^c onh cbng th7c phn tM ca +# %.
Cu 12: HJa tan 1*#"g hzn h:p 2 aît an;anoic trong nc r1i chia th?nh 2 phQn ,Hng nhau. .hQn 1 phVn
7ng ho?n to?n =i 55
*
+g$!
4
*
$H
cho 16#Dg +g. ]@ trung hJa phQn 2 cQn 1663l 55 $a!H 1<. $u cho
hZi ca 1 trong 2 aît E =?o ,anh ch7a clo r1i chiu sng# sau phVn 7ng ta chL thu :c * aît 3onoclo
&ch7a 1 nguyRn tM clo'
a. tc onh cbng th7c cu tOo ca 2 aît
,. /0nh A =c ;hFi l:ng ca 3zi aît trong hzn h:p
G/0 L1 Ch2 N)$3* - :9 - T&45) THPT N)$36 7.i
c. o snh lTc aît ca * aît 3onoclo =? aît ,an Qu.
II. Ph !&'( )hi*+
Cu 1: +ît hYu cZ l? h:p cht cE ch7a nhE3
a. cac,onyl ,. cac,o^yl c. cac,o^ylic 5. cac,onyl =? hi5ro^yl
Cu 2: &$hYng' cbng th7c phn tM n?o sau y 5fng cho cc aît Zn ch7c P
a. C
^
H
y
2
!
. ,. C
^
H
y
GC!!H c. C
^
H
y
! 5. + ho\c %
Cu *: ChWn cbng th7c phn tM p 5ing cho aît hYu cZ no# 3Och h[
a. C
n
H
2nI2
!
3
. ,. C
n
H
2nI2
!
23
. c. C
n
H
2nI2G23
&C!!H'
3
5. C
n
H
2nI2G3
&C!!H'
3
Cu ": /Rn gWi ca aît cE cbng th7c cu tOo sau:
*
CH
GCH&
*
CH
'GCCl&
*
CH
'GC!!H
a. +ît 2#*Gi3)tylG2Gclo,utanoic ,. +ît 2GcloG2#*Gi3)tyl,utanoic
c. +ît 2#*Gi3)tylG*Gclo,utanoic 5. +ît *GcloG2#*Gi3)tyl,utanoic
Cu >: ]Ft chy 32t loOi aît hYu cZ thu :c sF 3ol
2
C!
=?
2
H !
,Hng nhau# aît E thu2c loOi
a. Zn ch7c no ,. Zn ch7c c. thZ3# Zn ch7c 5. Zn ch7c no# 3Och h[
Cu 8: Cht hYu cZ t 3Och h[ cE cbng th7c phn tM C
*
H
8
2
!
# t cE th@ l?
a. aît Zn ch7c no ,. an5)hit 2 ch7c c. ancol 2 ch7c cE CCC 5. ancol 2 ch7c no
Cu 9: ]Ft chy 6#6* 3ol 32t aît Zn ch7c thu :c 6#12 3ol
2
C!
=? 6#6K3ol
2
H !
. F 3ol oî cQn @
phVn 7ng chy ^Vy ra ho?n to?n l?
a. 6#22> ,.6#1"> c. 6#1*> 5. 6#12>
Cu D: &$hYng' nguyRn nhn tOo ra t0nh aît ca aît hYu cZ trong nc
a. $hE3 CC! gia tnng sT phn cTc liRn ;t !H
,. Bo Vnh h[ng ca cc phn tM 5ung 3bi nc lwng cTc
c. $hE3 ~C!!H cE ;hV nnng phn li th?nh
H
+
.
5. CV + =? %
Cu K: Cc aît Qu 5Ny Zn ch7c no &3Och h[' tan nhicu trong nc 5o nguyRn nhn ch0nh sau
a. .hn tM ;hFi nhx ,. XiRn ;t !GH phn cTc
c. CE liRn ;t hi5ro =i nc 5. CE t0nh aît 3Onh
Cu 16: o =i ancol &cfng sF nguyRn tM cac,on' tha aît cE nhit 2 sbi cao hZn# =a
a. +ît ;hE ,ay hZi hZn ,. +ît cE ;hFi l:ng phn tM cao hZn
c. XiRn ;t hi5ro giYa cc phn tM aît ,cn hZn 5. $hE3 !H trong ancol ;}3 phn cTc hZn
Cu 11: 26#Dg aît hYu cZ + &3Och h['# tc 5ing =i
*
$aHC!
th)o tL l sF 3ol 1:2 tOo th?nh 2K#8g 3uFi.
Cbng th7c phn tM ca + l?
a. &C!!H'
2
. ,.
2
CH
&C!!H'
2
. c. C
2
H
"
&C!!H'
2
5. C
2
H
2
&C!!H'
2
Cu 12: ]2 3Onh ca aît &trong nc' phi thu2c ch yu =?o
a. $hE3 nguyRn tM liRn ;t =i ~C!!H ,. /0nh no ho\c cha no ca aît
c. -hFi l:ng phn tM ca aît 5. Cu tOo ;hbng gian ca phn tM aît
Cu 1*: t}t cc aît Zn no sau: ho3ic# a^)tic# propionic# ,utyric# 2 3Onh cc aît trRn &th)o th7 tT'
a. tnng 5Qn ,. giV3 5Qn c. ,Hng nhau 5. tnng ;hbng ng ;@
Cu 1": ]@ ch7ng tx H trong nhE3 ch7c cE 2 linh 2ng tnng 5Qn trong sF cc cht sau:
2 >
C H
G!H#
8 >
C H
G!H#
*
CH
GC!!H# ta 5fng phVn 7ng =i
a.
*
CaC!
=? $a!H ,.
*
CaC!
=? $a c. $a =? 55 %r
2
. 5. $a!H =? 55 %r
2
.
Cu 1>: ]Ft chy ho?n to?n 6#68 3ol aît Zn no 3Och h[ cQn =ya 8#92 l0t oî &;c'# cbng th7c phn tM
ca aît l?
a. C
*
H
8
2
!
. ,. C
"
H
D
2
!
c.C
2
H
"
2
!
. 5. C
>
H
16
2
!
.
Cu 18: ]Ft chy ho?n to?n aît + 3Och thng thu :c 6#68 3ol
2
C!
=? 6#6> 3ol
2
H !
. Cbng th7c ca
+ l?
a. H!!CG
2
CH
G
2
CH
GC!!H ,. H!!CG&
2
CH
'
"
GC!!H
c.
*
CH
G
2
CH
GC!!H 5. H!!CG&
2
CH
'
*
GC!!H
Cu 19: Cht hYu cZ t tc 5ing =i $a tOo
2
H
=i tL l 3ol 1:1. t cng tc 5ing =i $a!H th)o tL l 3ol
1:1 . ChWn cbng th7c cu tOo phf h:p cho t
G/0 L1 Ch2 N)$3* - :: - T&45) THPT N)$36 7.i
a. H!!CGCH&!H'GCH&!H'GC!!H ,. H!!CG
2
CH
GCH&!H'GC!!H
c.
2
CH
&!H'GCH&!H'GC!!H 5.
*
CH
GCH&!H'GC!!H
Cu 1D: .hn ,it cc 3Su: HC!!H#
*
CH
GCH!#
*
CH
GC!!H ta cE th@ 5fng 32t hEa cht
a. $a!H ,.
*
+g$!
4
*
$H
c.
2
Cu&!H'
5. %r
2
Cu 1K: Cho Kg aît no &<1>6' tc 5ing =ya =i -!H thu :c 18#8g 3uFi ;han. Cbng th7c ca aît
a. &C!!H'
2
. ,.
2
CH
&C!!H'
2
. c.
* 9
C H
GC!!H 5. C
2
H
"
&C!!H'
2
.
Cu 26: ChWn pht ,i@u sai
a. gi3 nn cE th@ l?3 x giy ù t03
,. ]un HC!!H =i
2
Cu&!H'
tOo ;t ta x gOch
c. HC!!H cE th@ tha3 gia phVn 7ng trng gZng
5. HC!!H in li yu hZn
*
CH
GC!!H
Cu 21: Xy 9#2g aît &3Och h[' tc 5ing =i $a 5 thu :c 1#12 l0t
2
H
&;c'. Cbng th7c phn tM ca
aît l?
a.
2 >
C H
GC!!H ,. C
2
H
*
GC!!H c.
* 9
C H
GC!!H 5. C
*
H
>
GC!!H
Cu 22: Cho ty ty 55
*
CH
GC!!H &a 3ol' =?o 55 ch7a , 3ol
2 *
$a C!
. %it a2,# sF 3ol ;h0
2
C!
thot
ra tFi a l?
a. a42 ,. &aG,' c. , 5. &aG,'42
Cu 2*: -hi cho aît propionic tc 5ing =i Cl
2
&tL l 1:1' cE nh sng# thu :c tFi a ,ao nhiRu sVn ph3
1 lQn th P
a. 1 ,. 2 c.* 5."
Cu 2": CE th@ icu ch trTc tip
*
CH
GC!!H ty cht n?o sau P
1.
*
CH
G
2
CH
G!H 2.
*
CH
GCH! *.
2
CH
C
2
CH
".
*
CH
GC!!$a
>.
*
CH
G
2
CH
G!na 8.
*
CH
G
2
CH
G
2
CH
G
*
CH
a. 2#*#"#> ,. 1#2#"#8 c. 1#2#*#" 5. 1#2#>#8
Cu 2>: & $hYng' cht n?o cE th@ tc 5ing =i 55 %r
2
P
a.
*
CH
GCH! ,.
8 >
C H
G
*
CH
c.
2
CH
CCHGC!!H 5. + =? C
Cu 28: /huFc thM @ nhqn ,it cc 55 aît acrylic# ancol )tylic# aît a^)tic Tng trong cc lW 3t nhNn l?
a. pu t03#
2
Cu&!H'
,. ù t03# 55 $a!H c. ù t03# 55
2 *
$a C!
5. ù t03# 55 %r
2
Cu 29: ChWn cu sai liRn ùan n aît acrylic &
2
CH
CCHGC!!H'
a. l? aît yu hZn aît propionic
,. cE th@ tha3 gia phVn 7ng c2ng =? trfng h:p
c. l?3 ù t03 3 hEa x
5. tan nhicu trong nc =? cE th@ ,o hi5ro hEa
Cu 2D: ]@ s?n ût gi3 nn# ngdi la lRn 3)n 55 ancol )tylic
a. ">
6
,. K6
6
c. DG16
6
5. >6
6
.
Cu 2K: +ît + cE tL ;hFi hZi so =i
2
!
l? 2#2>. Vqy + thu2c loOi aît
a. Zn ch7c# no 3Och h[ ,. Zn ch7c# 3Och cE CCC
c. Zn ch7c# =Jng no 5. Zn ch7c# 3Och cE C
C.
Cu *6: -hbng th@ phn ,it c\p cht n?o sau y ,Hng 55
*
+g$!
4
*
$H
P
a.
2 2
C H
# HCH! ,. HC!!H# HCH! &55'
c.
*
CH
GC!!H# HC!!H 5.
2
CH
CCHGC!!H# HC!!H
G/0 L1 Ch2 N)$3* - :; - T&45) THPT N)$36 7.i

Phuong Phap Lam BTTN Hoa 11 Nguyen Hien Hoang

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Phuong Phap Lam BTTN Hoa 11 Nguyen Hien Hoang

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TRCH TI LIU NGUYN HIN HONG- NGUYN CU PHC- L NGC T- khi 11

,4 til)n than gia phVn 7ng c2ng =i HCl:

thu :c isop)ntan. -hi c2ng HCl =?o t# sVn ph3 ch0nh cE Cl

" ~ 3)tylp)nt ~ 1 ~ )n I H%r. Cbng th7c cu tOo ca t l?:

C 5?i hZn liRn ;t C C C %. liRn ;t C

C ngUn hZn liRn ;t C C C.

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