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  • Ental Pi

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    Elisabeth Sonisora Wau
    14 views5 pages
    This document contains calculations of enthalpy changes (ΔH) for various processes in multiple systems labeled SHELL, Aliran E, Aliran F, Aliran G, and Aliran H. The ΔH values are calculated using integrals and given in kJ/mol or kJ/kmol. Temperatures for each system range from 25°C to 193°C. Species considered include urea, biuret, and karbamat.

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    This document contains calculations of enthalpy changes (ΔH) for various processes in multiple systems labeled SHELL, Aliran E, Aliran F, Aliran G, and Aliran H. The ΔH values are calculated using integrals and given in kJ/mol or kJ/kmol. Temperatures for each system range from 25°C to 193°C. Species considered include urea, biuret, and karbamat.

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    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
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    Download as docx, pdf, or txt
    14 views5 pages

    Ental Pi

    Uploaded by

    Elisabeth Sonisora Wau
    This document contains calculations of enthalpy changes (ΔH) for various processes in multiple systems labeled SHELL, Aliran E, Aliran F, Aliran G, and Aliran H. The ΔH values are calculated using integrals and given in kJ/mol or kJ/kmol. Temperatures for each system range from 25°C to 193°C. Species considered include urea, biuret, and karbamat.

    Copyright:

    © All Rights Reserved
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    of 5

    SHELL (INPUT)


    =
    *

    ( )

    )
    = 4,479601 kJ/mol
    = 4.479,601kJ/kmol

    (liq) =

    )
    = 8.369,4 kJ/kmol

    (gas)=


    =
    *

    ( )

    )
    = 4,019751 kJ/mol
    = 4.019,751 kJ/kmol
    H
    urea
    =
    * +


    = ( )

    )
    = ( ) kal/gr
    = 66,9752 kal/gr . 4,184 J/kal . 60 g/mol
    = 16.813,474 J/mol
    H
    karbamat
    = 1,3575 . (143,9
    o
    C 25
    o
    C)
    = 161,4067 kcal/kg. 78 kg/kmol. 4.184 kJ/kcal
    = 52.675,415 kJ/kmol

    H
    biuret
    = 131,3 J/mol
    o
    C (143,9
    o
    C 25
    o
    C)
    = 15.611,5 J/mol


    SHELL (OUTPUT)


    =
    *

    ( )

    )
    = 4,772926 kJ/mol
    = 4.772,926 kJ/kmol


    =
    *

    ( )

    )
    = 5,000183 kJ/mol
    = 5.000,183 kJ/kmol

    (liq) =

    )
    = 9.523,7 kJ/kmol

    (gas)=

    ( )

    )
    = 4,270731 kJ/mol
    = 4.270,731 kJ/kmol
    H
    urea
    =
    * +


    = ( )

    )

    = ( ) kal/gr
    = 71,81181 kal/gr . 4,184 J/kal . 60 g/mol
    = 18.027,6387 J/mol
    H
    karbamat
    = 1,3575 . (151,31
    o
    C 25
    o
    C)
    = 171,4568 kcal/kg. 78 kg/kmol. 4.184 kJ/kcal
    = 55.958,214 kJ/kmol

    H
    biuret
    = 131,3 J/mol
    o
    C (151,3
    o
    C 25
    o
    C)
    = 16.584,5 J/mol


    Aliran E (189,3
    o
    C)


    = *

    ( )

    )
    = 6,303016 kJ/mol
    = 6.303,016 kJ/kmol

    (gas)=


    =
    *

    ( )

    )
    = 5,555864 kJ/mol
    = 5.555,864 kJ/kmol


    =
    *

    ( )

    )
    = 6,615348 kJ/mol
    = 6.615,348 kJ/kmol


    Aliran F (193
    o
    C)

    ()
    =

    ()
    =
    H
    urea
    =
    * +


    = ( )

    )
    = ( ) kal/gr
    = 100,4507 kal/gr . 4,184 J/kal . 60 g/mol
    = 25.217,1492 J/mol

    H
    biuret
    = 131,3 J/mol
    o
    C (193
    o
    C 25
    o
    C)
    = 22.058,4 J/mol

    H
    karbamat
    = 1,3875 . (193
    o
    C 25
    o
    C)
    = 228,06 kcal/kg . 78 kg/kmol. 4.184 kJ/kcal
    = 74427,837 kJ/kmol


    = *

    ( )

    )
    = 6,4543891 kJ/mol
    = 6.454,3891 kJ/kmol

    (liq) =

    )
    = 12,667 kJ/kmol

    Aliran G (181
    o
    C)


    =
    *

    ( )

    )
    = 5,964970 kJ/mol
    = 5.964,970 kJ/kmol

    H
    urea
    =
    * +


    = ( )

    )
    = ( ) kal/gr
    = 91,9588 kal/gr . 4,184 J/kal . 60 g/mol
    = 23.085,348 J/mol

    H
    karbamat
    = 1,35 . (181
    o
    C 25
    o
    C)
    = 211,77 kcal/kg. 78 kg/kmol. 4.184 kJ/kcal
    =69.111,56 kJ/kmol

    H
    biuret
    = 131,3 J/mol
    o
    C (181
    o
    C 25
    o
    C)
    = 20.482,8 J/mol

    (liq) =

    )
    = 11.762 kJ/kmol
    Aliran H (181
    o
    C)


    =
    *

    ( )

    )
    = 5,964970 kJ/mol
    = 5.964,970 kJ/kmol


    =
    *

    ( )

    )
    = 6,258406 kJ/mol
    = 6.258,406 kJ/kmol

    ()
    =

    ( )

    )
    = 5,275396 kJ/mol
    = 5.275,396 kJ/kmol

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