LAMPIRAN C

ANALISA PCC

C.1 AnalisaTitrasi Kompleksometri

Volume EDTA yang didapat (Duplo) = 0.5 ml dan 0.5 ml
Rata-rata = 0.5 ml
Konsentrasi EDTA = 0.1M
Volume sampel 1 = 10 ml
Volume sampel 2 = 10 ml
Rata-rata = 10 ml

= 200 ppm

C.2 Analisa X-Ray Diffraction

C.2.1 Kulit Telur Itik

Gambar C.1 Grafik XRD kulit telur itik

34

Tabel C.1 Data XRD untuk tampilan grafik diatas

Pos.[2Th.]
23.0796
29.4378
31.4466
35.9443
39.4067
43.1437
47.4953
48.4972
56.6189
57.4015
58.0289
60.6495
63.1368
64.6491
65.5707
70.3152
72.8611
77.2339
81.5088
83.8406
93.1218
94.6984
96.0693

Height [cts]
267.92
3582.48
320.86
203.23
396.57
431.22
1162.59
617.52
64.69
248.43
65.65
152.44
35.34
120.46
411.56
38.85
79.33
51.22
82.86
66.03
32.71
115.42
126.84

FWHMLeft[2Th.]
0.1279
0.1535
0.1023
0.1535
0.1791
0.1023
0.0768
0.1023
0.2558
0.0768
0.3070
0.0768
0.4093
0.2558
0.1023
0.3070
0.1535
0.4093
0.1535
0.3070
0.3070
0.0936
0.1560

d-spacing []
3.85375
3.03427
2.84487
2.49854
2.28663
2.09683
1.91438
1.87715
1.62565
1.60533
1.58946
1.52691
1.47261
1.44177
1.42372
1.33883
1.29821
1.23526
1.18094
1.15393
1.06174
1.04732
1.03598

Rel. Int. [%]

7.48
100.00
8.96
5.67
11.07
12.04
32.45
17.24
1.81
6.93
1.83
4.26
0.99
3.36
11.49
1.08
2.21
1.43
2.31
1.84
0.91
3.22
3.54

Tabel C.2 Data XRD referensi untuk kulit telur itik

No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27

h
0
1
0
1
1
2
0
0
1
2
1
1
2
2
1
1
3
0
2
0
1
3
2
1
2
1
3

k
1
0
0
1
1
0
2
1
1
1
2
0
1
0
1
2
0
0
1
2
2
0
2
1
2
3
1

l
2
4
6
0
3
2
4
8
6
1
2
10
4
8
9
5
0
12
7
10
8
6
0
12
3
1
2

d [A]
3.85480
3.03560
2.84350
2.49480
2.28460
2.09440
1.92740
1.91240
1.87530
1.62580
1.60410
1.58690
1.52520
1.51780
1.50940
1.47320
1.44040
1.42180
1.35680
1.33900
1.29670
1.28490
1.24740
1.23520
1.21840
1.19550
1.18680

2Theta[deg] I [%]
23.054
9.6
29.400
100.0
31.435
2.1
35.969
13.7
39.409
18.3
43.159
13.9
47.114
5.9
47.506
18.0
48.505
18.8
56.562
3.2
57.398
8.8
58.079
0.9
60.669
4.7
60.996
2.3
61.372
2.6
63.051
1.9
64.658
5.7
65.610
3.2
69.185
1.2
70.238
1.9
72.889
2.3
73.668
0.5
76.271
0.9
77.162
1.6
78.429
0.1
80.231
0.1
80.941
0.5

35

28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76

2
0
1
2
3
1
1
0
2
4
3
2
1
1
2
0
3
2
1
1
3
0
0
2
4
2
4
3
4
2
4
2
1
5
3
3
1
0
2
0
2
3
3
2
4
0
2
5
3

1
1
3
2
1
2
3
4
0
0
1
2
1
0
1
3
2
3
3
2
2
4
2
3
1
2
1
2
0
3
1
1
1
0
2
1
2
5
2
1
3
3
3
4
2
4
4
0
3

10
14
4
6
5
11
7
2
14
4
8
9
15
16
13
12
1
2
10
14
4
8
16
5
0
12
3
7
10
8
6
16
18
2
10
14
17
4
15
20
11
0
3
1
2
14
4
8
6

1.17980
1.17290
1.15380
1.14230
1.13080
1.12470
1.07550
1.07170
1.06140
1.04720
1.04480
1.04200
1.03530
1.03530
1.02300
1.01180
0.98970
0.98470
0.98070
0.97670
0.96560
0.96370
0.95620
0.95200
0.94290
0.93770
0.93020
0.91830
0.91270
0.89900
0.89500
0.89290
0.88600
0.85980
0.85710
0.85450
0.85450
0.84700
0.84050
0.83690
0.83530
0.83160
0.82280
0.81570
0.81290
0.80840
0.80200
0.80100
0.79820

81.522
82.105
83.767
84.806
85.875
86.455
91.487
91.905
93.061
94.713
94.999
95.335
96.153
96.153
97.699
99.161
102.213
102.938
103.526
104.124
105.830
106.130
107.334
108.024
109.561
110.466
111.808
114.034
115.126
117.927
118.784
119.241
120.781
127.250
127.983
128.702
128.702
130.858
132.833
133.975
134.495
135.726
138.844
141.588
142.738
144.679
147.674
148.171
149.613

2.1
0.3
3.7
1.9
0.1
0.4
0.1
0.1
0.7
2.2
3.4
1.3
1.3
1.3
0.3
2.2
0.3
1.0
0.3
0.9
0.7
1.7
0.3
0.2
1.5
0.7
0.1
0.2
0.1
0.6
0.5
0.9
0.8
0.1
0.8
0.6
0.6
0.6
0.1
0.6
0.4
0.3
0.1
0.1
0.7
0.1
0.6
0.6
0.6

Primary reference: Calculated from ICSD using POWD-12++, (2004)

Structure: Effenberger, H., Mereiter, K., Zemann, J., Z. Kristallogr., 156, 233, (1981)

36

C.2.2 PCC Kulit Telur Itik

Gambar C.2 Grafik XRD PCC kulit telur itik

Tabel C.3 Data XRD untuk tampilan grafik diatas
Pos.[2Th.]
20.9794
24.8612
27.0545
32.7829
42.7135
43.8458
49.1135
50.1440
55.8730
59.9420
63.0688
68.7042
71.9724
73.5339
88.2493

Height [cts]
208.12
1063.71
1708.17
1319.22
114.88
809.43
260.78
609.47
215.07
30.08
46.35
44.77
70.31
87.00
34.89

FWHMLeft[2Th.]
0.1279
0.2047
0.2303
0.3326
0.2047
0.3326
0.3582
0.1791
0.4605
0.8187
0.4093
0.6140
0.3070
0.6140
0.8187

d-spacing []
4.23456
3.58148
3.29590
2.73190
2.11695
2.06487
1.85502
1.81929
1.64557
1.54323
1.47404
1.36624
1.31203
1.28798
1.10732

Rel. Int. [%]

12.18
62.27
100.00
77.23
6.73
47.39
15.27
35.68
12.59
1.76
2.71
2.62
4.12
5.09
2.04

Tabel C.4 Data XRD referensi untuk PCC kulit telur itik
No.
1
2
3
4
5
6

h
0
1
1
1
1
0

k
0
0
0
0
0
0

l
2
0
1
2
3
4

d [A]
4.24500
3.57670
3.29610
2.73520
2.21930
2.12250

2Theta[deg] I [%]
20.910
10.3
24.874
66.4
27.030
100.0
32.714
82.8
40.619
2.0
42.559
4.3

37

7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65

1
1
1
2
2
2
1
2
1
0
2
2
2
1
2
2
2
3
3
1
3
1
2
2
3
0
2
3
2
1
2
2
3
2
3
1
3
2
2
3
1
2
3
4
4
4
3
4
3
0
2
2
2
1
4
3
3
3
3

1
1
0
0
0
0
0
0
1
0
0
1
1
0
1
0
1
0
0
1
0
0
1
0
0
0
1
0
2
0
2
0
1
1
1
1
1
2
0
0
0
1
1
0
0
0
1
0
0
0
0
1
2
0
0
2
2
1
2

0
2
4
0
1
2
5
3
4
6
4
0
1
6
2
5
3
0
1
6
2
7
4
6
3
8
5
4
0
8
2
7
0
6
2
8
3
4
8
6
9
7
4
0
1
2
5
3
7
10
9
8
6
10
4
0
1
6
2

2.06500
1.85690
1.82530
1.78830
1.74990
1.64810
1.53390
1.51180
1.48010
1.41500
1.36760
1.35190
1.33500
1.31580
1.28810
1.23140
1.21980
1.19220
1.18060
1.16720
1.14780
1.14780
1.14020
1.10970
1.09870
1.06120
1.05760
1.03950
1.03250
1.01740
1.00320
1.00320
0.99200
0.97750
0.96600
0.94390
0.93610
0.92850
0.91260
0.91170
0.91170
0.90280
0.89870
0.89420
0.88930
0.87500
0.85650
0.85260
0.85020
0.84900
0.83480
0.83480
0.83410
0.82600
0.82400
0.82050
0.81670
0.81230
0.80560

43.805
49.017
49.923
51.030
52.233
55.730
60.289
61.264
62.723
65.965
68.562
69.471
70.480
71.666
73.455
77.445
78.321
80.499
81.455
82.593
84.306
84.306
84.999
87.919
89.031
93.084
93.496
95.638
96.499
98.423
100.321
100.321
101.885
104.004
105.767
109.389
110.749
112.119
115.145
115.324
115.324
117.130
117.991
118.957
120.037
123.367
128.148
129.236
129.923
130.270
134.659
134.659
134.890
137.677
138.401
139.708
141.187
142.990
145.952

42.4
13.5
29.9
2.6
0.5
11.2
0.1
0.7
1.6
0.1
2.2
0.9
0.6
1.6
3.5
0.1
0.1
0.5
0.1
0.4
0.7
0.7
1.0
0.5
0.1
0.2
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.3
0.3
0.2
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1

38