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  • DEPRISTE3

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    FabioRangel
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    The document provides generalized equations to calculate the rate constant k for various hydrocarbons. It gives separate equations for methane, ethane, ethene, propane, propene, n-butane, isobutane, n-pentane, n-hexane, isopentane, n-heptane, n-octane, n-nonane, n-decane, where each equation expresses the natural logarithm of k as a second order polynomial in 1/T plus additional terms involving the pressure P. The equations allow calculating k over a range of temperatures T and pressures P for these hydrocarbons.

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    The document provides generalized equations to calculate the rate constant k for various hydrocarbons. It gives separate equations for methane, ethane, ethene, propane, propene, n-butane, isobutane, n-pentane, n-hexane, isopentane, n-heptane, n-octane, n-nonane, n-decane, where each equation expresses the natural logarithm of k as a second order polynomial in 1/T plus additional terms involving the pressure P. The equations allow calculating k over a range of temperatures T and pressures P for these hydrocarbons.

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    © All Rights Reserved
    Download as DOC, PDF, TXT or read online from Scribd
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    11 views1 page

    DEPRISTE3

    Uploaded by

    FabioRangel
    The document provides generalized equations to calculate the rate constant k for various hydrocarbons. It gives separate equations for methane, ethane, ethene, propane, propene, n-butane, isobutane, n-pentane, n-hexane, isopentane, n-heptane, n-octane, n-nonane, n-decane, where each equation expresses the natural logarithm of k as a second order polynomial in 1/T plus additional terms involving the pressure P. The equations allow calculating k over a range of temperatures T and pressures P for these hydrocarbons.

    Copyright:

    © All Rights Reserved
    Download as DOC, PDF, TXT or read online from Scribd
    Flag for inappropriate content
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    of 1

    ECUACIN GENERALIZADA PARA LA CONSTANTE K:

    METANO
    ln(k) =

    - 292860,0
    T

    ETILENO
    ln(k) =

    - 1166846,0

    n-BUTANO
    ln(k) =

    - 970688,5625

    ISOBUTANO
    ln(k) =

    0
    59,8465 0
    + 8,24450 - 0,89510 ln P +
    +
    2
    T
    P
    P

    - 923484,6875

    PROPANO
    ln(k) =

    - 687248,25

    PROPILENO
    ln(k) =

    - 600076,875

    ETANO
    ln(k) =

    - 1280557,0
    T

    - 1481583,0

    n-PENTANO
    ln(k) =

    - 1524891,0

    n-HEXANO
    ln(k) =

    0
    T

    n-NONANO
    ln(k) =

    0
    T

    0
    47,67624 0
    + 7,71725 - 0,87871 ln P +
    +
    2
    T
    P
    P

    0
    0
    6,90224
    + 7,15059 - 0,76984 ln P + 2 +
    T
    P
    P

    0
    0
    0
    + 7,72668 - 0,92213 ln P + 2 +
    T
    P
    P

    0
    0
    0
    + 7,94986 - 0,96455 ln P + 2 +
    T
    P
    P

    0
    0
    0
    + 7,58071 - 0,93159 ln P + 2 +
    T
    P
    P

    0
    0
    0
    + 7,33129 - 0,89143 ln P + 2 +
    T
    P
    P

    0
    0
    0
    + 6,96783 - 0,84634 ln P + 2 +
    T
    P
    P

    0
    0
    0
    + 6,52914 - 0,79543 ln P + 2 +
    T
    P
    P

    - 7646,81641
    0
    0
    + 12,48457 - 0,73152 ln P + 2 +
    T
    P
    P

    - 2551040,0

    n-DECANO
    ln(k) =

    - 2013803,0

    n-OCTANO
    ln(k) =

    - 1778901,0

    n-HEPTANO
    ln(k) =

    0
    49,02654 0
    + 7,90699 - 0,88600 ln P +
    +
    2
    T
    P
    P

    ISOPENTANO
    ln(k) =

    0
    42,94594 0
    + 7,90595 - 0,84677 ln P +
    +
    2
    T
    P
    P

    0
    0
    0
    + 5,69313 - 0,67818 ln P + 2 +
    T
    P
    P

    - 9760,45703
    0
    0
    + 13,80354 - 0,71470 ln P + 2 +
    T
    P
    P

    T,R; P,PSIA

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