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    11 Rownania Maxwella

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    The document presents Maxwell's equations of thermodynamics, which relate changes in internal energy, enthalpy and Gibbs free energy to changes in temperature, pressure, volume and entropy. The equations define temperature, pressure, volume and entropy as partial derivatives of energy terms with respect to other variables. They also show relationships between derivatives that must be satisfied.

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    11 Rownania Maxwella

    Uploaded by

    api-3739618
    71 views5 pages
    The document presents Maxwell's equations of thermodynamics, which relate changes in internal energy, enthalpy and Gibbs free energy to changes in temperature, pressure, volume and entropy. The equations define temperature, pressure, volume and entropy as partial derivatives of energy terms with respect to other variables. They also show relationships between derivatives that must be satisfied.

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    The document presents Maxwell's equations of thermodynamics, which relate changes in internal energy, enthalpy and Gibbs free energy to changes in temperature, pressure, volume and entropy. The equations define temperature, pressure, volume and entropy as partial derivatives of energy terms with respect to other variables. They also show relationships between derivatives that must be satisfied.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as pdf or txt
    71 views5 pages

    11 Rownania Maxwella

    Uploaded by

    api-3739618
    The document presents Maxwell's equations of thermodynamics, which relate changes in internal energy, enthalpy and Gibbs free energy to changes in temperature, pressure, volume and entropy. The equations define temperature, pressure, volume and entropy as partial derivatives of energy terms with respect to other variables. They also show relationships between derivatives that must be satisfied.

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    of 5

    Dariusz Butrymowicz

    Politechnika Białostocka

    TERMODYNAMIKA
    Równania Maxwella

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    Równania termodynamiczne Maxwella:

    du  Tds  pdv

     u   u 
    du    ds    dv
     s  v  v s
     u   u 
    T    ; p   
     s  v  v s
    2 2
     u  u  T   p 
          
    sv vs  v s  s  v

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    dh  Tds  vdp

     h   h 
    dh    ds    dp
     s  p  p s
     h   h 
    T    ; v   
     s  p  p s
    2 2
     h  h  T   v 
          
    sp ps  p s  s  p

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    df  du  Tds  sdT  pdv  sdT

     f   f 
    df    dv    dT
     v  T  T  v
     f   f 
    p    ; s   
     v  T  T  v
    2 2
     f f  p   s 
        
    vT Tv  T  v  v  T

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    dg  dh  Tds  sdT  vdp  sdT

     g   g 
    dg    dp    dT
     p  T  T  p
     g   g 
    v    ; s   
     p  T  T  p
    2 2
    g  g  v   s 
          
    pT Tp  T  p  p  T

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