Home Assignment (1)

1. What do you mean by Hybridization? How is it different from Bonding? Is there any
possibility of having sp hybridization between 1s and 2p? Explain (briefly to the point). Does
s-orbital form -bond? Give brief explanation to support your answer.

2. Show the occupancy of molecular orbital and find bonding order and then the magnetic
property of the following molecules Ne
2
, N
2
(Given Ne: 1s
2
2s
2
2p
6
, N: 1s
2
2s
2
2p
3
).

3. I-V characteristic of a Al/polymer/Al system of area 4 mm
2
and thickness 136 nm is given
below.








(a) Find the voltage at which there is transition from Ohms law to SCLC or vice-versa.
Al
Al
Polymer
4 mm
2

236 nm
Al
(b) Find the charge density.
(c) Find the mobility in Ohmic and SCLC regime. Compare.
(d) Comment on the nature of the polymer (metallic, semiconducting or insulating).
Consider dielectric constant of the polymer is 3.

4. I-V characteristic of Al/polymer/Al film (d=150 nm) with effective area 2 mm
2
is given
below

(a) Find the trap free mobility.
(b) Find trap free voltage limit and trap density and hole density
Consider dielectric constant is 3.
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whichever you prefer