ALKENE PREPARATION

PHYSICAL
PROPS
CHEM.
PROPS
NAMING
B.P INCREASE WITH
MOLECULAR SIZE(DUE TO
STRONGER VDW FORCES)
SOLUBILITY INSOLUBLE IN
WATER, BUT SOLUBLE IN
ORGANIC SOLVENT.
OXIDATION
RXN
ADDITION
RXN
FORMATION OF HALOHYDRIN
(+ X
2
, H
2
O HALOHYDRIN +
DIHALOALKANE)
HYDROGENATION
(+ H
2,
Ni/Pt/Pd) ALKANE)
HALOGENATION
(+ X
2
DIHALOALKANE)

HYDROHALOGENATION
(+ HX HALOALKANES
HYDRATION
(+H
2
0, H
+
ALCOHOL)
RXN WITH CONC.H
2
SO
4
(+ H
2
SO
4
, H
+
ALCOHOL )
ANTI-
MARKONIKOV
MARKONIKOV
MARKONIKOV
RXN WITH COLD & DILUTE KMnO
4
(+ KMnO
4
COLD/RT, DILUTE DIOL)
RXN WITH HOT &CONC. KMnO
4
(+KMnO
4
CONC., COOH/ALDEHYDE
+KETON
OZONOLYSIS
(+O
3
,Zn, H
+
ALDEHYDE + KETON)
DEHYDROHALOGENATION OF HALOALKANES
HALOALKANE + KOH/EtOH, ALKENE +HX

DEHYDRATION OF ALCOHOL
(ALCOHOL + H2SO4(CONC), ALKENE + H
2
O
MAJOR PRODUCT-
USE SAYTZEFFS
RULE
MAJOR PRODUCT-
USE SAYTZEFFS
RULE