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PHIU AN TON HA CHT

CHLORUA CANXI DIHYDRATE

S CAS : 10035-04-8
S UN : cha c thng tin
S ng k EC : cha c thong tin
S ng k danh mc quc gia khc: cha c thng tin
S ch th nguy him ca cc t chc xp loi : HMIS
- Nguy him n sc khe : 1
- Nguy him v chy : 0
- hot ng : 0
Bin php bo v c nhn : E

I. NHN DNG HA CHT
- Tn thng gi ca cht:
Chlorua canxi 2 hydrate
M sn phm :
- Tn thng mi: Calcium chloride dihydrate
- Tn khc (khng l tn khoa hc): cha c thng
tin
- Tn nh cung cp hoc nhp khu:
Cng ty TNHH Mt thnh vin Ha Cht C Bn
Min Nam
a ch: 22 L T Trng, phng Bn Ngh, qun
I, Tp. H Ch Minh, Vit Nam.
a ch lin h trong trng hp khn cp:
1.Cng ty TNHH mt thnh vin Ha Cht
C Bn Min Nam
a ch: 22 L T Trng , phng Bn Ngh,
qun I, Tp.H Ch Minh , Vit Nam.
Tel: (84.8) 38296620,
Fax: (84.8)38243166
Email: sbcc@sochemvn.com
2. Nh my Ho cht ng Nai
a ch: ng s 1 , Khu Cng nghip Bin
Ho 1, Bin Ho, ng Nai, Vit Nam
Tel:(84.61) 3836197
Fax: (84.61) 3836198
- Tn nh sn xut : Nh my Ha Cht ng Nai
a ch: ng s 1 , Khu Cng nghip Bin Ho I,
Bin Ho, ng Nai, Vit Nam
Tel:(84.61) 3836197 Fax: (84.61) 3836198
Email: dongnai@sochemvn.com

- Mc ch s dng: cng nghip vi sinh , thc
phm, cng nghip du kh
II. THNG TIN V THNH PHN CC CHT
Tn thnh phn
nguy him
S CAS
Cng thc
ha hc
Hm lng
(% theo trng
lng)
Calcium chloride dihydrate 10035-04-8 CaCl
2
.2H
2
O 100
III. NHN DNG C TNH NGUY HIM CA HA CHT
1. Mc xp lai nguy him :
GHS: khng c d liu
EU : Xi ( Kch thch )
R : 36 37 38
S : 2 22 24
2. Cnh bo nguy him :
- Trnh tip xc trc tip
3. Cc ng tip xc v triu chng:
- ng mt : kch thch mt, mt.
- ng da : da kh , .
- ng th: ho, au c hng, lot c hng .
- ng tiu ha : c cm gic bng rt, bun nn , nn .
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IV. BIN PHP S CU V Y T
1. Tip xc theo ng mt : ra ngay mt vi nhiu nc trong vi pht (tho knh st trng nu
ly d dng ) . Nu khng dng kch thch mt a ngay n bc s.
2. Tip xc trn da : ci b qun o b nhim ho cht. Loi b ho cht bm trn da bng cch ra
vi nc v x phng.
3. ng h hp : a ra ni khng kh sch, ngh ngi .
4. ng tiu ha : ra ming , ung tht nhiu nc , ngh ngi.
Lu : Nut vo bng c th gy nn axt ho huyt thanh ( MSDS Mallinckrodt Baker, inc)
V. BIN PHP X L KHI C HA HON
1. Xp loi v tnh chy : Khng chy.
2. Sn phm to ra khi chy : CaO , Cl
2

3. Cc tc nhn gy chy n : khng c.
4. Cc cht dp chy thch hp : tt c tc nhn lm tt la c cho php .
5. Phng tin , trang phc bo h cn thit khi cha chy : Trang phc cha chy b sung qun o
kn kh chng ho cht, mt n th oxy.
6. Cc lu c bit v chy n :
- Khi chy hnh thnh khi c c tnh n mn .
- Phn ng vi km trong nc to kh H2 d chy n.
Khng nc cha chy c CaCl2 chy vo h thng nc mt , nc ngm .
VI. BIN PHP PHNG NGA, NG PH KHI C S C
1. Khi trn , r r mc nh :
Trnh lm pht sinh bi, qut dn thu gom lng CaCl2.2H2O ri vi vo ch cha cht thi,
lau sch ch bm dnh ho cht , c th ra nu iu kin mi trng cho php.
2. Khi trn , d r ln din rng :
X l thu gom nh trng hp r r nh, v phi bo cho ngi c trch nhim bit .
Ch :Trnh ho cht gy nhim cng thi, sng sui phi thng tin cho chnh quyn bit
trong trng hp s c lm nhim mi trng.
VII. YU CU V CT GI
1. Bin php, iu kin cn p dng khi s dng thao tc :
- Trnh tip xc trc tip , tip xc phi c trang b bo v c nhn ( knh che mt, khu trang
lc bi ho cht, gng tay ).
- Thng gi, ht bi khi thao tc
2. Bin php , iu kin cn p dng khi bo qun :
- Bao b phi bn , kn kh. Khng chung vi cc cht xung khc. Khng ln vi thc
phm v cc dng n ung .
- Ni lu cha phi thong mt , kh ro, c du hiu cnh bo ho cht nguy him.
VIII. TC NG LN NGI V YU CU V THIT B BO V C NHN
1. Cc bin php hn ch tip xc cn thit:
- Khi vo kho phi lm thng thang kho, tip xc phi c trang b bo v c nhn, khng n
ung ht thuc khi lm vic.
- Trang b bo v c nhn, phng tin lm vic phi lm sch trc v sau khi s dng.
2. Cc phng tin bo h c nhn khi lm vic :
- Bo v mt : knh che mt.
- Bo v ng th : khu trang lc bi ho cht, mt n lc bi ho cht.
- Bo v thn th : qun o .
- Bo v tay : gng cao su, nha khng thm nc.
- Bo v chn : giy , ng khng thm nc.
3. Phng tin bo h trong trng hp x l s c:
- Phng tin bo h c nhn
- Thng gi cng bc
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4. Cc bin php v sinh :
- Dng nhiu nc di vo ch c bm CaCl
2
.2 H
2
O .
- Ra ch tip xc vi CaCl
2
.2 H
2
O bng nc.
IX. C TNH L, HA CA HA CHT
Trng thi vt l : rn , hoc chy lng im si : 1500
o
C
Mu sc : khng mu hoc mu trng im nng chy : 176
o
C
Mi c trng : khng mi im bng chy : cha c thng tin
p sut hi : khng ph hp Nhit t chy : cha c thng tin
T trng hi : cha c thng tin Gii hn nng chy n trn: khng ph hp
Tan trong nc: 74,5g CaCl
2
/100ml 20
o
C Gii hn nng chy n di: khng ph hp
Ph dd 5% : 5 - 8 T l ha hi : cha thng tin
Khi lng ring :2,0 kg/dm
3
20
o
C Cht ht m.
X. MC N NH V KH NNG HOT NG CA HA CHT
1. Tnh n nh : bn trong iu kin thng, d ht m .
2. Kh nng phn ng :
- Phn ng phn hy:
2[CaCl
2
.2 H
2
O] + O
2
= 2 CaO +2 Cl
2
+
- Phn ng nguy him:
CaCl
2
.2 H
2
O +H
2
SO
4
= CaSO
4
+2 HCl +2 H
2
O
CaCl
2
.2 H
2
O + Zn = ZnCl
2
+ Ca(OH)
2
+ H
2

- Cc cht xung khc: Methyl vinyl ether, nc, km, nhm v hp kim, ng v hp kim.
- Phn ng trng hp : cha thng tin .
XI. THNG TIN V C TNH
Tn thnh phn Loi ngng Kt qu ng tip xc
Sinh vt
th
CaCl
2



LD 50
LD 50
LD 50
LD 50
1000 mg/kg
823 mg/kg
42 mg/kg
>5000 mg/kg
Ming
Tim di da
Tim tnh mch
Da
Chut
Chut
Chut
Th
Gii hn tip xc ngh nghip :
DOW IHG : ( CaCl
2
) 10 mg/m
3
TWA
NGA : (CaCl
2
) 2 mg/m3 STEL
TCVN 5938 2005 : khng quy nh
BYT (3733/2002 ) : khng quy nh
1. Cc nh hng mn tnh vi ngi : NIOSH, IARC khng xp vo loi ha cht gy ung th.
2. Cc nh hng c khc : cht ny gy d ng cho da v ph nang. Tip xc ko di hay lp li
vi da c th b vim da. Cht ny c th tc ng n mng nhy mi gy nn lot
XII. THNG TIN V SINH THI
1. c tnh vi sinh vt
Tn thnh phn Loi sinh vt Chu k nh hng Kt qu
CaCl
2
C
C (bluegill)
B cht Daphnia magna
LC50/96 gi
LC 50
LC 50
100mg/l
8350 10650 mg/l
759 - 3005 mg/l
2. Tc ng trong mi trng
- CaCl
2
tan d dng trong nc to thnh ion canxi v clor . Canxi ch yu to thnh khung xng ,
dn truyn thn kinh, co bp c, lm ng mu, v s pht trin ca cy, to . Clor th cng cn
thit cho hot ng bnh thng ca t bo trong ng vt v con ngi v cung cp nh vi cht
dinh dng cho thc vt , gi v tr quan trng trong s quang hp v iu ho thm thu .
- CaCl
2
c xem khng c cho sinh vt sng trong nc v khng c tch ly sinh hc.
- Mc phn hy sinh hc : cha c thng tin
- Ch s BOB v COD : cha c thng tin
- Sn phm ca qu trnh phn hy sinh hc : cha c thng tin
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- Mc c tnh ca sn phm phn hy sinh hc : cha c thng tin
XIII. YU CU TRONG VIC THI B
1. Thng tin quy nh tiu hy :
TCVN 5945 2005 : - Ct A ch tiu nc thi Cl
-
= 500 mg/l
- Ct C ch tiu nc thi Cl
-
= 1000 mg/l
2. Xp loi nguy him ca cht thi :
Q 23/2006/Q-BTNMT : M cht thi 19 03 01
M EC : 16 03 03
M Basel A : A 4140
Tnh cht nguy hi chnh : khng
3. Bin php tiu hy :
Tinh ch li thnh sn phm .
Mt lng nh c th vo cng vi tht nhiu nc nu tiu chun nc thi cho php.
4. Sn phm ca qu trnh tiu hy, bin php x l : cha c thng tin
XIV. YU CU TRONG VN CHUYN
Tn quy nh S UN
Tn vn
chuyn
ng bin
Loi, nhm
hng nguy
him
Quy cch
ng gi
Nhn vn
chuyn
Thng tin
b sung
Quy nh v vn chuyn hng
nguy him ca Vit Nam:
- Ngh nh s 104/2009/N-
CP ngy 09/11/2009 ca CP
quy nh Danh mc hng
nguy him v vn chuyn
hng nguy him bng phng
tin giao thng c gii ng
b;
- Ngh nh s 29/2005/N-
CP ngy 10/3/2005 ca CP
quy nh Danh mc hng ha
nguy him v vic vn ti
hng ha nguy him trn
ng thy ni a.

Khng
qui nh
Quy nh v vn chuyn
hng nguy him quc t ca
EU, USA

Cha c
thng tin
XV. QUY CHUN K THUT V QUY NH PHP LUT PHI TUN TH
1. Tnh trng khai bo, ng k cc quc gia khu vc trn th gii : cha c thng tin
2. Phn loi nguy him theo quc gia khai bo ng k: cha c thng tin
XVI. THNG TIN CN THIT KHC
Ngy thng bin son Phiu: thng 02 nm 2012
Ngy thng sa i, b sung gn nht: thng 02 nm 2012
Tn t chc, c nhn son tho: Cng ty TNHH MTV Ha cht C cn Min Nam
Lu ngi c:
Nhng thng tin trong Phiu an ton ha cht ny c bin son da trn cc kin thc hp l v
mi nht v ha cht nguy him v phi c s dng thc hin cc bin php ngn nga ri ro,
tai nn.
Ha cht nguy him trong Phiu ny c th c nhng tnh cht nguy him khc ty theo hon cnh
s dng v tip xc