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MEL242 MEL242 Heat and Mass Transfer: Prabal Talukdar
MEL242 MEL242 Heat and Mass Transfer: Prabal Talukdar
=
&
In the limiting case of x 0, the equation above reduces to the
differential form
Fouriers law of heat
x x
The negative sign ensures that heat
conduction after J. Fourier,
who expressed it first in his
heat transfer text in 1822
(W)
dx
dT
kA Q
cond
=
&
The negative sign ensures that heat
transfer in the positive x direction is a
positive quantity
T
1
=
T
2
=
P.TALUKDAR/IITD
Thermal Conductivityy
Specific heat C
p
is a measure of a materials ability to store thermal
energy. For example, C
p
= 4.18 kJ/kgC for water and C
p
= 0.45 gy p ,
p
g
p
kJ/kgC for iron at room temperature, which indicates that water
can store almost 10 times the energy that iron can per unit mass.
Likewise the thermal conductivity k is a measure of a materials Likewise, the thermal conductivity k is a measure of a material s
ability to conduct heat. For example, k = 0.608 W/mC for water
and k = 80.2 W/mC for iron at room temperature, which indicates
that iron cond cts heat more than 100 times faster than ater can that iron conducts heat more than 100 times faster than water can.
Thus water is a poor heat conductor relative to iron, although
water is an excellent medium to store thermal energy
P.TALUKDAR/IITD
Range of Thermal Conductivity g y
The thermal conductivities of gases
such as air vary by a factor of 10
4
from those of pure metals such as
copper.
Note that pure crystals and metals
have the highest thermal
conductivities and gases and conductivities, and gases and
insulating materials the lowest.
P.TALUKDAR/IITD
A simple experimental setup to
determine the thermal conductivity
of a material of a material.
P.TALUKDAR/IITD
The range of
thermal conductivity thermal conductivity
of various materials
at room temperature
P.TALUKDAR/IITD
The thermal conductivity of a substance is
normally highest in the solid phase and lowest normally highest in the solid phase and lowest
in the gas phase.
Unlike gases, the thermal conductivities of
li id d i h i i most liquids decrease with increasing
temperature, with water being a notable
exception.
In solids, heat conduction is due to two
effects: the lattice vibrational waves induced
by the vibrational motions of the molecules by t e v b at o a ot o s o t e o ecu es
positioned at relatively fixed positions in a
periodic manner called a lattice, and the
energy transported via the free flow of energy transported via the free flow of
electrons in the solid .
The thermal conductivity of a solid is obtained by adding the lattice
and electronic components The relatively high thermal conductivities
P.TALUKDAR/IITD
and electronic components. The relatively high thermal conductivities
of pure metals are primarily due to the electronic component.
The lattice component of thermal conductivity strongly depends on The lattice component of thermal conductivity strongly depends on
the way the molecules are arranged
Unlike metals, which are good electrical and heat conductors,
lli lid h di d d i d h crystalline solids such as diamond and semiconductors such as
silicon are good heat conductors but poor electrical conductors. As a
result, such materials find widespread use in the electronics industry.
For example, diamond, which is a highly ordered crystalline solid,
has the highest known thermal conductivity at room temperature.
Even small amounts in a pure metal of foreign
molecules that are good conductors themselves
i l di t th fl f h t i th t t l seriously disrupt the flow of heat in that metal.
For example, the thermal conductivity of steel
containing just 1 percent of chrome is 62 W/m C,
while the thermal conductivities of iron
P.TALUKDAR/IITD
and chromium are 83 and 95 W/m C,
The variation of
the thermal the thermal
conductivity of
various solids,
liquids and gases liquids, and gases
with temperature
(from White)
P.TALUKDAR/IITD
Thermal Diffusivityy
The product C
p
, which is frequently encountered in heat transfer
analysis, is called the heat capacity of a material. Both the y p y
specific heat C
p
and the heat capacity C
p
represent the heat
storage capability of a material.
But C expresses it per unit mass whereas C expresses it per unit But C
p
expresses it per unit mass whereas C
p
expresses it per unit
volume, as can be noticed from their units J/kgC and J/m
3
C,
respectively.
Another material property that appears in the transient heat
conduction analysis is the thermal diffusivity, which represents
how fast heat diffuses through a material and
is defined as
The larger the thermal diffusivity,
the faster the propagation of heat
into the medium. A small value of
thermal diffusivity means that heat
P.TALUKDAR/IITD
t e a d us v ty ea s t at eat
is mostly absorbed by the material
and a small amount of heat will be
conducted further
Note that the thermal diffusivity
ranges from 0.14 x 10
-6
m
2
/s for
water to 174 x 10
-6
m
2
/s for silver,
which is a difference of more than a
thousand times.
Also note that the thermal
diffusivities of beef and water are the diffusivities of beef and water are the
same. This is not surprising, since
meat as well as fresh vegetables and
fruits are mostly water and thus they fruits are mostly water, and thus they
possess the thermal properties of
water.
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Forced Convection Natural Convection
B ili C d i
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Boiling Condensation
Convection
Convection heat transfer involves both energy transfer due to random
molecular motions and by bulk motion of the fluid molecular motions and by bulk motion of the fluid
Convection heat transfer includes both forced convection and natural
convection
I i h f h f f h i b f In convection heat transfer, the transfer of heat is between a surface
and a moving fluid (liquid or gas), when they are at different
temperatures. The rate of transfer is given by Newtons Law of
Cooling.
) T T ( h q
s
' '
=
Moving fluid
T
T
s
q
T
s
> T
P.TALUKDAR/IITD
Typical values of convection
h t t f ffi i t heat transfer coefficient
Process h (W/ m
2
K) Process h (W / m
2
K)
Free Convection
Gases 2-25
Liquids 50 -1000
Forced Convection
Gases 35 -250 Gases 35 250
Liquids 50 -20,000
with Phase Change
Boiling or
Condensation
2500 -100,000
P.TALUKDAR/IITD
Radiation
All surfaces of finite temperature emit energy in the form of electromagnetic
waves
In the absence of an intervening medium, there is a heat transfer by radiation
between two surfaces at different temperatures
The maximum flux, E (W / m
2
), at which radiation may be emitted from a
bl kb d f i i b blackbody surface is given by:
Stefan Boltzmann Law
E
where
4
s b
T E =
E
b
T
s
E
b
or E = Surface emissive power (W / m
2
)
T = absolute temperature (K)
= Stefan-Boltzmann constant = 5.67 x 10
-8
(W / m
2
K
4)
P.TALUKDAR/IITD
For a real surface:
4
For a surface with absorptivity , the incident radiation (G, W/m
2
)
4
s
T E =
p y , ( , )
that is absorbed by the surface is given by:
G G
abs
=
G
where
G G
abs
G
abs
G = incident radiation (W / m
2
)
T = absolute temperature (K)
= surface emissivity (0 1)
= surface absorptivity (0 1) surface absorptivity (0 1)
P.TALUKDAR/IITD
For a gray surface =
When radiant energy is incident on a transparent surface, it can be
absorbed, reflected, or transmitted through the material. Hence,
( )G G G G G
reflected d transmitte absorbed
+ + = + + =
1 = + +
where
= materials surface reflectivity
1 = + +
= materials transmissivity
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Consider a small gray surface at temperature T
s
that is completely
enclosed by the surroundings at temperature T
sur
.
The net rate of radiation heat transfer from the surface is:
T
( )
4 4 ' '
T T h T T
q
q
q
sur
T
sur
4
sur
4
s sur s
' '
rad
T T G E q = =
( )
sur s r sur s rad
T T h T T
A
q = = =
q
s
T
s
Where h
r
is the radiation heat transfer coefficient, W / m
2
K
( )( )
2
sur
2
s sur s r
T T T T h + + = ( )( )
sur s sur s r
T T T T h + +
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Conduction example
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Convection example
Calculate the heat flux Calculate the heat flux
from your hand when it is
exposed to moving air
and water, assuming the
surface temperature of
your hand is 30C.
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Radiation ex.
An instrumentation package
has a spherical outer surface
of diameter D = 100 mm and
emissivity = 0 25 The emissivity = 0.25. The
package is placed in a large
space simulation chamber
whose walls are maintained
f f at 77 K. If the operation of
the electronic components is
restricted to the temperature
range of 40 T 85C, what range of 40 T 85 C, what
is the range of acceptable
power dissipation for the
package?
P.TALUKDAR/IITD