2548 ()

4

4 ( 160 )
1. ( 10 6 : 10 )
1.1 Phenolphthalein
pKin Phenolphthalein 9.6 Fibroin -
pH
- Fibroin 0C (): Structure of silk yarn 228
pH
1.083
1.131
1.553
2.046
2.331
2.468
2.950
3.522

(M-eq/g)
0.132
0.130
0.117
0.091
0.074
0.044
0.031
0.003

pH
9.01
9.63
10.40
12.18
12.43
12.76
13.61
14.25

(M-eq/g)
0.033
0.034
0.052
0.147
0.203
0.514
0.798
0.904

1.2 Surface excess ( ) 2.0

10000 M-1 (mN/m) (mM)
= -0.5486c + 70.524
( 25C)
1.3 cotton n-nonafluorobutane phosphonic acid
30 50 mN/m Reactive
()
1.4 -
500 g/mol 0.005 %w/v max
70% Molar extinction coefficient
0.002 %w/v
1.5 ( 2 ) 30 (
OH 10.3 )
1.6 Kubelka-Munk
K K

S
K
= 0.6286(c %owf.) + 0.4857
S

S
K
,
S

0.5, 1, 4% owf. 80%

1.7 cotton fT 10 fA fC 7 15 cotton

DSC
1.8 Surface potential
Surface potential

1.9 WLF
-
1.10 Spinerette ,
dry
spinning / wet spinning
2.
( 20 5 )
2.1
2.2
2.3
2.4
3. Solubility parameter ( )
? (20 )
4. 60 70C t1/ 2 70 20
( 10 )
4.1
4.2 k 0
4.3 t1/ 2 80C
4.4 t1/ 2 50

 2549 ()

2 ()

8 ( 150 )
1. Methyl Orange indicator pH 3.1 4.4 Azo yellow
p-Quinone red ( 10 )
-

O 3S

N N
Yellow

N(CH3)2

OH

HO 3S

N N
Red

N (CH3)2

1.1 Methyl Orange

1.2 1.1
2.
(10 )
3.
(10 )
4. Diacetate Disperse
(10 )
5.
(10 )
6. WLF equation
(10 )
7. 60 70C t1/ 2 70 20
( 10 )
7.1
7.3 t1/ 2 80C
7.2 k 0
7.4 t1/ 2 50
8. Adsorption isotherm ( 10 )
A

[D]( x 10-3
0.112
0.125
0.138
0.154
0.171
0.190
0.212
0.235
0.262

[D]( x 10 -2
0.625
0.652
0.680
0.710
0.741
0.773
0.806
0.841
0.878

[D]( x 10-3
0.112
0.125
0.138
0.154
0.171
0.190
0.212
0.235
0.262

[D]( x 10 -2
0.904
0.923
0.943
0.963
0.984
1.005
1.026
1.048
1.071

[D]( x 10-3
0.112
0.125
0.138
0.154
0.171
0.190
0.212
0.235
0.262

[D]( x 10 -2
0.729
0.798
0.871
0.949
1.032
1.121
1.215
1.314
1.417

8.1 Adsorption isotherm

8.2 C.I. Direct Red 23

8.3
8.4 Freundlich constant x k

 2548 ()

2 ()

9 ( 200 )
1. 3 (30 10 )
Adsorption isotherm (A)
[D] 103
mol/l

0.0011
0.0023
0.0046
0.0095
0.0194
0.0398
0.0816
0.1674
0.3431
0.7034
1.4419
2.9559

[D] 102
mol/kg
0.0132
0.0269
0.0550
0.1116
0.2244
0.4426
0.8422
1.5047
2.4417
3.5070
4.4551
5.1319

Adsorption isotherm (B)

[D] 103
mol/l

[D] 102
mol/kg
0.0271
0.0447
0.0740
0.1222
0.2021
0.3340
0.5520
0.9123
1.5079
2.4923
4.1193
6.8085

0.0012
0.0025
0.0050
0.0103
0.0212
0.0434
0.0891
0.1826
0.3743
0.7673
1.5730
3.2246

Adsorption isotherm (C)

[D] 103
mol/l

0.0004
0.0008
0.0017
0.0034
0.0071
0.0145
0.0297
0.0609
0.1248
0.2558
0.5243
1.0749

[D] 102
mol/kg
0.0040
0.0082
0.0168
0.0344
0.0704
0.1438
0.2925
0.5906
1.1744
2.2677
4.1542
6.9913

1.1
1.2 x k
1.3 3 Congo Red

2. 4 1000
2 %owf. 20 LR 30:1 40C
10 25%
90% 80C
20 70%
30
80
0.26 / (50 10 )

02 =

T2
( 10 H0 ) + H0
T1

1/ 2

[D] Z Z2 [Na] [Cl] V 2

[Na] =
+
+

V 2 4
[D]2

0 = RT ln[D]

[Na]z
V z +1

RT ln[D] .[Na]z


C
C
0.980
0.958
0.887
0.816
0.796
0.776
0.752
0.729
0.698

C
C

Dt
2

l
0.40
0.30
0.20
0.15
0.14
0.13
0.12
0.11
0.10

0.666
0.631
0.593
0.552
0.504
0.450
0.391
0.319
0.225

Dt
2

l
0.09
0.08
0.07
0.06
0.05
0.04
0.03
0.02
0.01

C
C
0.215
0.202
0.189
0.176
0.159
0.142
0.124
0.102
0.071

Dt
l2
0.009
0.008
0.007
0.006
0.005
0.004
0.003
0.002
0.001

C
C
0.998
0.988
0.961
0.932
0.878
0.782

C
C

Dt
r2
1.000
0.700
0.500
0.400
0.300
0.200

0.708
0.606
0.524
0.453
0.410
0.361

Dt
r2
0.150
0.100
0.070
0.050
0.040
0.030

C
C
0.299
0.216
0.183
0.159
0.130
-

Dt
r2
0.020
0.010
0.007
0.005
0.003
-

2.1
2.2
2.3
2.4
2.5

3.
4.
5.

6.

7.

60 100C
100C
t1/ 2 60C
2 60C 32
/ 2 80C

(15 )

V (15 )

(15 )

(30 )
(15 )
lnD =

ln 02 ln
H
AB
+
lnK

T B + (T Tg )

8.

(15 )

9.

(15 )