Without Spillage

P
1157.4074
F
1326.2374

For Recycle @ Reactor

Distillation Column
Component
xF
MEK
0.8727
2 Butanol
0.0998
Total

Mass (kg)
1157.4074
132.3585
1289.7659

% mass
89.74
10.26
100.00

Moles
16.05
1.79
17.8363

% mol
89.99
10.01
100.00

Component
MEK

xF
1

Mass
1157.4074

% mass
99.90

Moles
16.05

% mol
100.00

Total

1157.4074

99.90

16.05

100.00

xF
0.0998
Total

Mass
132.3585
132.3585

% mass
99.90
99.90

Moles
1.79
1.7857

% mol
100.00
100.00

Solvent Recovery Column

Component
xF
MEK
0.1372
2-Butanol
0.00784
TCE
0.5412
Total

Mass (kg)
181.9598
10.3977
717.7597
910.1172

%
19.99
1.14
78.86
100.00

Moles
2.52
0.14
5.46
8.1265

%mol
31.05
1.73
67.22
100.00

Component
2-Butanol

Component
MEK
2-Butanol

xF
0.1372
0.00784
Total

Mass
181.9598
10.3977
192.3575

%
94.59
5.41
100.00

2.52
0.14
2.6636

94.73
5.27
100.00

Component
TCE

xF
0.5412
Total

Mass
717.7597
717.7597

%
100.00
100.00

5.46
5.4628

100.00
100.00

Extraction
Component
xF
MEK
0.1437
2-Butanol
0.00784
EtOH
1.2859
Total

Mass
190.5803
10.3977
1705.4087
1906.3867

% Mass
10.00
0.55
89.46
100.00

Moles
2.64
0.14
37.02
39.8010

% Mol
6.64
0.35
93.01
100.00

Component
MEK
EtOH

xF
0.006462
1.2859
Total

Mass
8.5701
1705.4087
1713.9788

% Mass
0.50
99.50
100.00

Moles
0.12
37.02
37.1366

% Mol
0.32
99.68
100.00

Component
MEK
2-Butanol
TCE

xF
0.1372
0.00784
0.5412
Total

Mass
181.9598
10.3977
717.7597
910.1172

% Mass
19.99
1.14
78.86
100.00

Moles
2.52
0.14
5.46
8.1265

% Mol
31.05
1.73
67.22
100.00

Component
TCE

xF
0.5412
Total

Mass
717.7597
717.7597

% Mass
100.00
100.00

Moles
5.46
5.4628

% Mol
100.00
100.00

Absorption
Component
xF
MEK
0.1401
2-Butanol
0.008
H2
0.0243
Total

Mass
185.8059
10.6099
32.2276
228.6433

% Mass
81.26
4.64
14.10
100.00

Moles
2.58
0.14
15.95
18.6741

% Mol
13.80
0.77
85.44
100.00

Non Condensate
F

Component
MEK
EtOH

xF
0.006462
1.2859
Total

Mass
8.5701
1705.4087
1713.9788

% Mass
0.50
99.50
100.00

Moles
0.12
37.02
37.1366

% Mol
0.32
99.68
100.00

Component
MEK
2-Butanol
H2

xF
0.002802
0.00016
0.0243
Total

Mass
3.7161
0.2122
32.2276
36.1559

% Mass
10.28
0.59
89.14
100.00

Moles
0.05
0.00
15.95
16.0086

% Mol
0.32
0.02
99.66
100.00

Component
MEK
2-Butanol
EtOH

xF
0.1437
0.00784
1.2859
Total

Mass
190.5803
10.3977
1705.4087
1906.3867

% Mass
10.00
0.55
89.46
100.00

Moles
2.64
0.14
37.02
39.8010

% Mol
6.64
0.35
93.01
100.00

Condensate
V

Non Condensate
L

Out

COOLER CONDENSER
Component
xF
MEK
0.8756
2-Butanol
0.1
H2
0.0243
Total
Component
MEK
2-Butanol
H2

Component
MEK
2-Butanol
H2

Reactor
Component
MEK
2-Butanol
H2

Mass
1161.2535
132.6237
32.2276
1326.1048

% Mass
87.57
10.00
2.43
100.00

Moles
16.10
1.79
15.95
33.8475

% Mol
47.58
5.29
47.14
100.00

Total

Mass
975.4476
122.0138
0.0000
1097.4615

% Mass
88.88
11.12
0.00
100.00

Moles
13.53
1.65
0.00
15.1734

% Mol
89.15
10.85
0.00
100.00

xF
0.1401
0.008
0.0243
Total

Mass
185.8059
10.6099
32.2276
228.6433

% Mass
81.26
4.64
14.10
100.00

Moles
2.58
0.14
15.95
18.6741

% Mol
13.80
0.77
85.44
100.00

xF
0.8756
0.1
0.0243
Total

Mass
% Mass
1161.2535 87.57
132.6237
10.00
32.2276
2.43
1326.1048 100.0000

Moles
16.10
1.79
15.95
33.8475

% Moles
0.48
0.05
0.47
1.00

xF
0.7355
0.092

Molecular Wt (kg/kgmol)
MEK
2-Butanol
TCE
EtOH
H2

72.11
74.12
131.39
46.07
2.02
With .05% Spillage
P
F

in
out

Component
MEK

For Recycle @ Reactor

Component
2-Butanol

1289.7659
1289.7659

in
out

910.1172
910.1172

Distillation Column
Component
MEK
2 Butanol

Solvent Recovery Column

Component
MEK
2-Butanol
TCE

Component
MEK
2-Butanol

Component
TCE

in
out
fugitive losses

2624.1464
2624.0960
0.0504

Component
MEK
EtOH

Component
MEK
2-Butanol
TCE

Component
TCE

Non Condensate
F

in
out
Fugitivie Losses

1942.6222
1942.5426
0.0796

Extraction
Component
MEK
2-Butanol
EtOH

Absorption
Component
MEK
2-Butanol
H2

Component
MEK
EtOH

Component
MEK
2-Butanol
H2

Component
MEK
2-Butanol
EtOH

in
out

1326.1048
1326.1048

Condensate
V

Component
MEK
2-Butanol
H2

Non Condensate
L

Component
MEK
2-Butanol
H2

Out
In
Out

1326.1048
1326.1048

COOLER CONDENSER
Component
MEK
2-Butanol
H2

Reactor
Component
MEK
2-Butanol
H2

With .05% Spillage

1157.4074
1332.8686

Distillation Column
xF
0.8727
0.0998
Total

Mass (kg)
1163.1944
133.0203
1296.2147

% mass
89.74
10.26
100.00

Moles
16.13
1.79
17.9255

% mol
89.99
10.01
100.00

xF
1

Mass (kg)
1157.4074

% mass
99.90

Moles
16.05

% mol
100.00

Total

1157.4074

99.90

16.0506

100.00

xF
0.0998
Total

Mass (kg)
133.0203
133.0203

% mass
99.90
99.90

Moles
1.79
1.7947

% mol
100.00
100.00

Solvent Recovery Column

xF
Mass
0.1372
182.8696
0.00784
10.4497
0.5412
721.3485
Total
914.6678

% Mass
19.99
1.14
78.86
100.00

Moles
2.54
0.14
5.49
8.1671

% Moles
31.05
1.73
67.22
100.00

xF
0.1372
0.00784
Total

Mass
182.8696
10.4497
193.3193

% Mass
94.59
5.41
100.00

Moles
2.54
0.14
2.6770

% Moles
94.73
5.27
100.00

xF
0.5412
Total

Mass
721.3485
721.3485

% Mass
100.00
100.00

Moles
5.49
5.4901

% Moles
100.00
100.00

in
out

in
out

Extraction
xF
0.1437
0.00784
1.2859
Total

Mass
191.5332
10.4497
1713.9357
1915.9187

% Mass
10.00
0.55
89.46
100.00

Moles
2.66
0.14
37.20
40.0000

% Moles
6.64
0.35
93.01
100.00

xF
0.006462
1.2859
Total

Mass
8.6130
1713.9357
1722.5487

% Mass
0.50
99.50
100.00

Moles
0.12
37.20
37.3223

% Moles
0.32
99.68
100.00

xF
0.1372
0.00784
0.5412
Total

Mass
182.8696
10.4497
721.3485
914.6678

% Mass
19.99
1.14
78.86
100.00

Moles
2.54
0.14
5.49
8.1671

% Moles
31.05
1.73
67.22
100.00

xF
0.5412
Total

Mass
721.3485
721.3485

% Mass
100.00
100.00

Moles
5.49
5.4901

% Moles
100.00
100.00

Absorption
xF
0.1401
0.008
0.0243
Total

Mass
186.7349
10.6629
32.3887
229.7865

% Mass
81.26
4.64
14.10
100.00

Moles
2.59
0.14
16.03
18.7675

% Moles
13.80
0.77
85.44
100.00

xF
0.006462
1.2859
Total

Mass
8.6130
1713.9357
1722.5487

% Mass
0.50
99.50
100.00

Moles
0.12
37.20
37.3223

% Moles
0.32
99.68
100.00

xF
0.002802
0.00016
0.0243
Total

Mass
3.7347
0.2133
32.3887
36.3367

% Mass
10.28
0.59
89.14
100.00

Moles
0.05
0.00
16.03
16.0887

% Moles
0.32
0.02
99.66
100.00

xF
0.1437
0.00784
1.2859
Total

Mass
191.5332
10.4497
1713.9357
1915.9187

% Mass
10.00
0.55
89.46
100.00

Moles
2.66
0.14
37.20
40.0000

% Moles
6.64
0.35
93.01
100.00

in
out
fugitive losses

in
out
Fugitivie Losses

COOLER CONDENSER
xF
0.8756
0.1
0.0243
Total
xF
0.7355
0.092

Mass
1167.0598
133.2869
32.3887
1332.7353

% Mass
87.57
10.00
2.43
100.00

Moles
16.18
1.80
16.03
34.0167

% Mol
47.58
5.29
47.14
100.00

Total

Mass
980.3249
122.6239
0.0000
1102.9488

% Mass
88.88
11.12
0.00
100.00

Moles
13.59
1.65
0.00
15.2493

% Mol
89.15
10.85
0.00
100.00

xF
0.1401
0.008
0.0243
Total

Mass
186.7349
10.6629
32.3887
229.7865

% Mass
81.26
4.64
14.10
100.00

Moles
2.59
0.14
16.03
18.7675

% Mol
13.80
0.77
85.44
100.00

Mass
1167.0598
133.2869
32.3887
1332.7353

% Mass
87.57
10.00
2.43
100.00

Moles
16.18
1.80
16.03
34.0167

% Mol
47.58
5.29
47.14
100.00

in
out

Reactor
xF
0.8756
0.1
0.0243
Total

In
Out

1296.2147
1290.4277

914.6678
914.6678

2637.2671
2637.2165
0.0506

1952.3353
1952.2553
0.0800

1332.7353
1332.7353

1332.7353
1332.7353

With .05% Spillage

P
1157.4074
F
1332.8686

For Recycle @ Reactor

Distillation Column
Component
xF
MEK
0.8727
2 Butanol
0.0998
Total

Mass (kg)
1163.1944
133.0203
1296.2147

Component
MEK

xF
1

Mass (kg)
1157.4074

Total

1157.4074

xF
0.0998
Total

Mass (kg)
133.0203
133.0203

Solvent Recovery Column

Component
xF
MEK
0.1372
2-Butanol
0.00784
TCE
0.5412
Total

Mass
182.8696
10.4497
721.3485
914.6678

Component
2-Butanol

Component
MEK
2-Butanol

xF
0.1372
0.00784
Total

Mass
182.8696
10.4497
193.3193

Component
TCE

xF
0.5412
Total

Mass
721.3485
721.3485

Extraction
Component
MEK
2-Butanol
EtOH

xF
0.1437
0.00784
1.2859
Total

Mass
191.5332
10.4497
1713.9357
1915.9187

Component
MEK
EtOH

xF
0.006462
1.2859
Total

Mass
8.6130
1713.9357
1722.5487

Component
MEK
2-Butanol
TCE

xF
0.1372
0.00784
0.5412
Total

Mass
182.8696
10.4497
721.3485
914.6678

Component
TCE

xF
0.5412
Total

Mass
721.3485
721.3485

xF
0.1401
0.008
0.0243
Total

Mass
186.7349
10.6629
32.3887
229.7865

Component
MEK
EtOH

xF
0.006462
1.2859
Total

Mass
8.6130
1713.9357
1722.5487

Component
MEK
2-Butanol
H2

xF
0.002802
0.00016
0.0243
Total

Mass
3.7347
0.2133
32.3887
36.3367

Component
MEK
2-Butanol
EtOH

xF
0.1437
0.00784
1.2859
Total

Mass
191.5332
10.4497
1713.9357
1915.9187

Non Condensate
F

Absorption
Component
MEK
2-Butanol
H2

Condensate
V

Non Condensate
L

Out

COOLER CONDENSER
Component
xF
MEK
0.8756
2-Butanol
0.1
H2
0.0243
Total
Component
MEK
2-Butanol
H2

Component
MEK
2-Butanol
H2

Reactor
Component
MEK
2-Butanol
H2

xF
0.7355
0.092

Mass
1167.0598
133.2869
32.3887
1332.7353

Total

Mass
980.3249
122.6239
0.0000
1102.9488

xF
0.1401
0.008
0.0243
Total

Mass
186.7349
10.6629
32.3887
229.7865

xF
0.8756
0.1
0.0243
Total

Mass
1167.0598
133.2869
32.3887
1332.7353

% mass
89.74
10.26
100.00

Moles
16.13
1.79
17.9255

% mol
89.99
10.01
100.00

% mass
99.90

Moles
16.05

% mol
100.00

99.90

16.0506

100.00

% mass
99.90
99.90

Moles
1.79
1.7947

% mol
100.00
100.00

% Mass
19.99
1.14
78.86
100.00

Moles
2.54
0.14
5.49
8.1671

% Moles
31.05
1.73
67.22
100.00

% Mass
94.59
5.41
100.00

Moles
2.54
0.14
2.6770

% Moles
94.73
5.27
100.00

% Mass
100.00
100.00

Moles
5.49
5.4901

% Moles
100.00
100.00

in
out

1296.2147
1290.4277

in
out

914.6678
914.6678

% Mass
10.00
0.55
89.46
100.00

Moles
2.66
0.14
37.20
40.0000

% Moles
6.64
0.35
93.01
100.00

% Mass
0.50
99.50
100.00

Moles
0.12
37.20
37.3223

% Moles
0.32
99.68
100.00

% Mass
19.99
1.14
78.86
100.00

Moles
2.54
0.14
5.49
8.1671

% Moles
31.05
1.73
67.22
100.00

% Mass
100.00
100.00

Moles
5.49
5.4901

% Moles
100.00
100.00

% Mass
81.26
4.64
14.10
100.00

Moles
2.59
0.14
16.03
18.7675

% Moles
13.80
0.77
85.44
100.00

% Mass
0.50
99.50
100.00

Moles
0.12
37.20
37.3223

% Moles
0.32
99.68
100.00

% Mass
10.28
0.59
89.14
100.00

Moles
0.05
0.00
16.03
16.0887

% Moles
0.32
0.02
99.66
100.00

% Mass
10.00
0.55
89.46
100.00

Moles
2.66
0.14
37.20
40.0000

% Moles
6.64
0.35
93.01
100.00

in
out
fugitive losses

2637.2671
2637.2165
0.0506

in
out
Fugitivie Losses

1952.3353
1952.2553
0.0800

% Mass
87.57
10.00
2.43
100.00

Moles
16.18
1.80
16.03
34.0167

% Mol
47.58
5.29
47.14
100.00

% Mass
88.88
11.12
0.00
100.00

Moles
13.59
1.65
0.00
15.2493

% Mol
89.15
10.85
0.00
100.00

% Mass
81.26
4.64
14.10
100.00

Moles
2.59
0.14
16.03
18.7675

% Mol
13.80
0.77
85.44
100.00

% Mass
87.57
10.00
2.43
100.00

Moles
16.18
1.80
16.03
34.0167

% Mol
47.58
5.29
47.14
100.00

in
out

1332.73532
1332.73532

In
Out

1332.73532
1332.73532

Cp
nCpT

Table 2-156 for compounds

in=out
Ti (K)
To (K)
T

Cp
nCpT

673
773
100

C1
C2
C3
C4
C5

MEK
7.84E-06
2.10E-05
1.55E-03
1.19E-05
6.93E+02

Component
MEK
2-Butanol
H2
2 Butanol
9.09E-06
2.55E-05
1.89E-03
1.85E-05
8.32E+02

H2
2.76E-06
9.56E-07
2.47E-03
3.76E-07
5.68E+02

Component
MEK
2-Butanol
H2

Cp(kJ/mol-K)
673 K
773 K
3.39E-05
3.35E-05
4.27E-05
4.26E-05
3.86E-06
3.84E-06
Mass (kg)
1167.0598
133.2869
32.3887

n (mol)
16.18
1.80
16.03

Cp(kJ/mol-K)
3.37252E-05
4.26592E-05
3.84988E-06

Hf (kJ/mol)

Ti (K)
To (K)
T

673
773
100

C1
C2
C3
C4
C5

MEK
2 Butanol H2
7.84E-06 9.09E-06 2.76E-06
2.10E-05 2.55E-05 9.56E-07
1.55E-03 1.89E-03 2.47E-03
1.19E-05 1.85E-05 3.76E-07
6.93E+02 8.32E+02 5.68E+02
#REF!