This document analyzes the chemical reactions that form hydrogen peroxide and hydrogen in gliding arc reactors with water spray. Gliding arc discharges in flowing gases with water droplets lead to the generation of these species, but the formation mechanisms are not fully understood. The present work uses kinetic modeling of high-temperature water reactions to study possible pathways. The mathematical model simulates a plug flow reactor with specified temperature profiles including reactions studied in pulsed corona discharges. The modeling results are compared to recent experimental data.
This document analyzes the chemical reactions that form hydrogen peroxide and hydrogen in gliding arc reactors with water spray. Gliding arc discharges in flowing gases with water droplets lead to the generation of these species, but the formation mechanisms are not fully understood. The present work uses kinetic modeling of high-temperature water reactions to study possible pathways. The mathematical model simulates a plug flow reactor with specified temperature profiles including reactions studied in pulsed corona discharges. The modeling results are compared to recent experimental data.
This document analyzes the chemical reactions that form hydrogen peroxide and hydrogen in gliding arc reactors with water spray. Gliding arc discharges in flowing gases with water droplets lead to the generation of these species, but the formation mechanisms are not fully understood. The present work uses kinetic modeling of high-temperature water reactions to study possible pathways. The mathematical model simulates a plug flow reactor with specified temperature profiles including reactions studied in pulsed corona discharges. The modeling results are compared to recent experimental data.
Bruce R. Locke Department of Chemical and Biomedical Engineering Florida State University Tallahassee, FL 32310 USA
Selma Mededovic Department of Ecological Engineering Toyohashi University of Technology Toyohashi, JAPAN
Gliding arc discharges Iormed in Ilowing gases containing water droplets sprayed into the plasma leads to the generation oI hydrogen peroxide and molecular hydrogen as well as other species 1 . Such discharges may be import Ior a number oI applications in energy and the environment. It is currently known that the temperature oI the active plasma in such discharges can be very high and that the temperature can vary Irom 7000K to 2000K as the gas Ilows through the plasma zones. However, the mechanisms Ior the Iormation oI the resulting chemical species in the presence oI water spray are not well understood. The present work seeks to utilize kinetic modeling oI high temperature water reactions 2 to study possible routes Ior the Iormation oI hydrogen peroxide, hydrogen, and oxygen in gliding arc plasma. The mathematical model utilizes a plug Ilow reactor approach with speciIied temperature proIiles and it includes high temperature water reactions previously studied in aqueous phase pulsed corona discharges 2 . The modeling results are compared to recent experimental data 3 .
1. R. Burlica, M. J. Kirkpatrick, and B. R. Locke, 'The Formation oI Reactive Species in Gliding Arc Discharges with Liquid Water, Journal oI Electrostatics, 64, 2006, pp. 35-43. 2. S. Meedovi and B. R. Locke, 'Primary Chemical Reactions in Pulsed Electrical Discharge Channels in Water, Journal oI Physics D: Applied Physics, 40, 2007, pp. 7734- 7746. 3. D. Porter, M. D. Poplin, F. Holzer, W. C. Finney, and B. R. Locke, 'Formation oI Hydrogen Peroxide, Hydrogen, and Oxygen in Gliding Arc Electrical Discharge Reactors with Water Spray, 42nd IEEE Industry Applications Society Annual ConIerence, September 23-27, 2007.