1

CBC422 (Chi Part)-Practice Quiz 1-Key

Student Name: (Last)_____________, (First)________________
Matriculation Number: ___ ___ ___ ___ ___ ___ ___ ___ ___
Question 1: The
1
H NMR chemical shifts of a proton is heavily affected by its covalently and/or spatially
neighboring atoms, groups, or non-covalent interactions. Please assign the observed chemical shifts to
each of the protons specified in the following molecules (1 mark each; 6 marks total)

Question 2: Rank the protons (a, b, c, and d) in the following molecule from shielding (low ppm) to
deshiedling (high ppm) (2 marks each, 4 marks total)

-End of Quiz 1-



answer: the order is ____________________
H
3
C
H
2
C
C
H
2
OH
N
CH
3
CH
3
H
a
b
d
c
answer: the order is ____________________
NO
2
H
H
a
b
OH
NO
2
8.1
7.6
7.0
7.2
OH
NO
2 7.2
7.0 ppm
7.6 ppm
8.1 ppm
H
H H
_____ppm
_____ppm
_____ppm
OH
6.8
7.2
6.9
6.8 ppm
6.9 ppm
7.2 ppm
OH
H
H
_____ppm
_____ppm
_____ppm
H
ab
abdc
7.6
7.0
8.1
6.8
6.9
7.2