Miguel Angel G.

Cantidades termodinmicas
de sustancias seleccionadas
a 298.15 K (25 C)

tu
u

ui
Cu
C

Sustancia

AHf

AG J

(kj/m ol)

(kj/ m ol)

(J/m ol-K)

Aluminio
Al(s)

A1C13(s)

-6 3 0 .0

AI2Chis)

-1 6 6 9 .8

-1 5 7 6 .5

Ss(g)
S2(g)

ah;

AG J

(kj/ m ol)

(kj/ m ol)

(J/m ol-K )

718.4

672.9

Carbono
0
-7 0 5 .6

Azufre
S(s, rmbico)

Sustanda

0
102.3
-2 9 6 .9

0
49.7
-3 0 0 .4

28.32
109.3
51.00

c (g)
C (s, diamante)
C(s, grafito)

1.88
0

c e k (g )

-1 0 6 .7

430.9

C C k(l)
C F 4(g)

2.84
0

158.0
2.43
5.69

-6 4 .0

309.4

-1 3 9 3

- 68.6

214.4

-6 7 9 .9

-635.1

262.3

248.5

CH (g)

74.8

-5 0 .8

186.3

C 2H 2(g)

226.77

209.2

200.8

31.88

S036)

-3 9 5 .2

-3 7 0 .4

256.2

SO42_(flc)
SOCl2(/)

-9 0 9 .3

-7 4 4 .5

20.1

C 2H 4{g)

52.30

68.11

-2 4 5 .6

C H<&)

-8 4 .6 8

-3 2 .8 9

229.5

205.6
20.1

C 3H 8(g)

-1 0 3 .8 5

-2 3 .4 7

269.9

C 4H Mfe)

-1 2 4 .7 3

-15.71

310.0

c 4h

10(0

-1 4 7 .6

-1 5 .0

231.0

CH 6(g)

82.9

129.7

269.2

C ^ O
CH3OH (g)

49.0

124.5

172.8

- 201.2

-1 6 1 .9

237.6

CH3OH (/)

-2 3 8 .6

-166.23

126.8

C 2HsOH (g)

-2 3 5 .1

-1 6 8 .5

282.7

H2S()
H2S 0 4(c)
h 2s o 4(/)

-2 0 .1 7
-9 0 9 .3
-8 1 4 .0

-3 3 .0 1
-7 4 4 .5
-6 8 9 .9

156.1

Bario
Ba(s)
BaCO^s)
BaO(s)

-1 2 1 6 .3

-1137.6

-5 5 3 .5

-5 2 5 .1

63.2
1 1 2 .1
70.42

C 2HsOH(/)

-2 7 7 .7

-174.76

160.7

-1273.02

-9 1 0 .4

2 12 .1

13.77

C n 0 6(s)
CO (g)

-11 0.5

-1 3 7 .2

197.9

50.21

C 0 2 (g)

-3 9 3 .5

-3 9 4 .4

213.6

CH3COOH(/)

-4 8 7 .0

-3 9 2 .4

159.8

Berilio
Be(s)
BeO(s)
Be(OH)2(s)

0
-6 0 8 .4
-9 0 5 .8

0
-5 7 9 .1
-8 1 7 .9

9.44

Bromo
Br(g)
Br~(ac)
Br2(g)
Br2(0
HBr(g)

111.8
-1 2 0 .9
30.71
0

82.38
- 102.8
3.14
0

174.9

C s (g)
Cs(D

152.3

Cs(s)
CsCl(s)

-5 3 .2 2

198.49

Ca(g)

179.3

145.5

154.8

Ca(s)

41.4

76.50

49.53

2.09

0.03

92.07
85.15

-4 1 4 .4

10 1.2

121.7

105.7

165.2

-1 6 7 .2

-1 3 1 .2

-4 4 2 .8

-1207.1

-1 1 28.76

-7 9 5 .8

-7 4 8 .1
-1 1 6 7 .3

92.88
104.6
68.87

c i (g)
cr(oc)
c i2(g)
HCl (fle)
HCl(g)

0
-1 6 7 .2

0
-1 3 1 .2

56.5
222.96
56.5

-9 2 .3 0

-9 5 .2 7

186.69

179

CaF2(s)

-1 2 1 9 .6

CaO(s)

-6 3 5 .5

-6 0 4 .1 7

39.75

Ca(OH)2(s)
CaSO 4(s)

-9 8 6 .2

-8 9 8 .5

83.4

Co(g)

439

393

-1 4 3 4 .0

-1 3 2 1 .8

106.7

Co(s)

1112

175.6

Cloro

Caldo

CaCl2(s)

Cesio

245.3

80.71

-3 6 .2 3

CaCC^s, calata)

219.4

Cobalto
28.4

Miguel Angel G.

A P N D IC E C

Sustancia

C a n tid a d e s te rm o d in m ica s de s u sta n cias sele c c io n a d a s a 29 8.15 K (25 C )

AH j
(kj/mol)

A GJ
(kj/mol)

338.4

298.6

S
(J/mol-K)

Cobre
Cu (g)
Cu(s)

166.3
33.30

CuCl2(s)

-2 0 5 .9

-1 6 1 .7

108.1

CuO(s)

-1 5 6 .1

-1 2 8 .3

42.59

CU2 0 (S)

-1 7 0 .7

-1 4 7 .9

92.36

397.5

352.6

174.2

23.6

Cromo
Cr(g)
Cr(s)
Cr20 3(s)

0
-1 1 3 9 .7

-1058.1

81.2

Sr(g)

F2(g)
HF(g)

P4(g)
P4(s, rojo)
P4(s, blanco)

-3 3 4

FeO(s)

-2 7 1 .9

-2 5 5 .2

F e^ s)
Fe30 4(s)
FeS2(s)

-8 2 2 .1 6

-7 4 0 .9 8

-1117.1

-1 0 1 4 .2

-1 7 1 .5

-1 6 0 .1

159.3

126.6

Li(s)
L iV )
L i+(g)
LiCl(s)

-4 0 8 .3

-3 8 4 .0

112.5

Mg(s)

80.0

61.9

158.7

-3 3 2 .6

-2 7 8 .8

-1 3 .8

0
-268.61

0
-2 7 0 .7 0

202.7
173.51

316.4

280.0

163.2

144.3

103.7

218.1

58.9

24.4

-1 7 .4 6

-1 2 .0 3

280
22.85
41.08

29.09
12.2

147.1

164.6

138.8

133.0

Mg (g)

110.0

52.92

648.5

34.6

164.4

89.96
146.4

-2 7 3 .4

54.9

60.75

685.7

561.9

142.3

-2 7 8 .5

Magnesio

-5 9 2 .0

S
(J/mo

litio

174.7

Fsforo
P(g)
P2(g)

-4 0 0

336.1

Flor
F(g)
F((zc)

FeCl3(s)

377.8

Estroncio
SrO(s)

AG j
(kj/mol)

Li(g)

Escandio
Se (g)
Sc(s)

AHf
(kj/mol)

Sustancia

59.30

148.6
32.51

MgCl2(s)

-6 4 1 .6

-5 9 2 .1

89.6

MgO(s)

-6 0 1 .8

-5 6 9 .6

26.8

Mg(OH)2(s)

-9 2 4 .7

-8 3 3 .7

63.24

280.7

238.5

173.6

32.0

Manganeso
M n (g)
Mn(s)

MnO(s)

-3 8 5 .2

-3 6 2 .9

M nO js)

-5 1 9 .6

-4 6 4 .8

M n 0 4(ac)

-5 4 1 .4

-4 4 7 .2

59.7
53.14
191.2

Mercurio
Hg (g)

60.83

31.76

174.89
77.40

H g(0
HgCl2(s)

-2 3 0 .1

-1 8 4 .0

144.5

Hg2Cl2(s)

-2 6 4 .9

-2 1 0 .5

192.5

PCI3(g)

-2 8 8 .0 7

-2 6 9 .6

311.7

PCl3()

-3 1 9 .6

-2 7 2 .4

217

PF5(g)
PH 3(g)

-1 5 9 4 .4

-1 5 2 0 .7

300.8

Ni (g)

429.7

384.5

182.1

5.4

13.4

210.2

Ni(s)

29.9

P 40 6(s)

-1640.1

P4O10(s)
POCl3(g)

-2940.1

-2 6 7 5 .2

-5 4 2 .2

-5 0 2 .5

325

-5 9 7 .0

-5 2 0 .9

222

-1 2 8 8 .3

-1142.6

p o c i 3(o

H3P 0 4(ac)

228.9

158.2

Hidrgeno
H(g)
V )
H +(g)
h

H 2(g)

217.94
0
1536.2
0

203.26
0
1517.0
0

114.60
0
108.9
130.58

Hierro
Fe(g)
Fe(s)

415.5

369.8

180.5
27.15

Nquel

NiCl2(s)

-3 0 5 .3

-2 5 9 .0

97.65

NiO(s)

-2 3 9 .7

-2 1 1 .7

37.99

472.7

Nitrgeno
455.5

153.3

N2(g)
NH3(ac)

191.50

-8 0 .2 9

-2 6 .5 0

111.3

NH 3(g)

-4 6 .1 9

-1 6 .6 6

192.5

N (g)

NH 4+(ac)
N2H 4(g)
NH4CN(s)

0.0

-7 9 .3 1

113.4

159.4

238.5

-3 1 4 .4

-2 0 3 .0

NH4N0 3 (s)

-3 6 5 .6

-1 8 4 .0

94.6
151

NO (g)

90.37

86.71

210.62

33.84

51.84

240.45

81.6

103.59

220.0

98.28

304.3

Fe2+(oc)

-8 7 .8 6

-8 4 .9 3

113.4

Fe3+(oc)
FeCl2(s)

-4 7 .6 9

-1 0 .5 4

293.3

N2 0 (g)

117.9

N20 4(g)

-3 0 2 .3

95.40

NH4C1(s)

N O j (g)

-3 4 1 .8

-1 3 2 .5

9.66

1113

Miguel Angel G.

1114

A P N D IC E C

C a n tid a d e s te rm o d in m ica s d e s u s ta n c ia s sele ccio n a d a s a 2 98.15 K (25 C)

AHJ
(kj/mol)

AG J
(kj/mol)

52.6

66.3

HNO 3(ac)

-2 0 6 .6

-1 1 0 .5

HNO 3(g)

-1 3 4 .3

Sustancia

S
(J/mol-K)

Nitrgeno (cont.)
NOCI (g)

Sustancia

ah;
(kj/mol)

a g;
(kj/mol)

29.7

15.9

219.0

368.2

323.9

167.8

18.7

S
(J/mol-K)

Selenio

-7 3 .9 4

264

H2Se(g)

146
266.4

Oxgeno

n
Si (g)
Si (s)

O (g)

247.5

230.1

161.0

SiC(s)

O 2(g)

205.0

Sici4(0

-6 4 0 .1

-5 7 2 .8

SiO ^s, cuarzo)

-9 1 0 .9

-8 5 6 .5

107.7

77.3

-7 3 .2 2

-7 0 .8 5

16.61
239.3

o 3(g)
OH-(oc)

142.3

163.4

237.6

-2 3 0 .0

-1 5 7 .3

-1 0 .7

H20(g )

-2 4 1 .8 2

-2 2 8 .5 7

188.83

H20 ( )

-2 8 5 .8 3

-2 3 7 .1 3

69.91

H A
H202(g)

-1 3 6 .1 0

-1 0 5 .4 8

232.9

Na+(?c)

-2 4 0 .1

-1 8 7 .8

-1 2 0 .4

109.6

Na+(g)
NaBr (ac)
NaBr(s)

-3 6 1 .4

-3 4 9 .3

-1130.9

-1 0 4 7 .7

136.0

NaCl(flc)
NaCl(g)

-4 0 7 .1
-1 8 1 .4

-3 9 3 .0
-2 0 1 .3

115.5
229.8

NaCl(s)

-4 1 0 .9

-3 8 4 .0

N a H C 0 3(s)

-9 4 7 .7

-8 5 1 .8

102.1

N a N 0 3(flc)

-4 4 6 .2

-3 7 2 .4

207

N a N 0 3(s)

-4 6 7 .9

-3 6 7 .0

116.5
49.8

Plata
Ag(s)
Ag+(c)
AgCl(s)
AgjO s)
AgNOss)

0
105.90
-1 2 7 .0
-3 1 .0 5
-1 2 4 .4

42.55

77.11

73.93

-1 0 9 .7 0

96.11

-1 1 .2 0

121.3

-3 3 .4 1

140.9

Plomo
Pb(s)

68.85

Sodio
N a(g)
Na (s)

Na2C0 3 (s)

609.3

574.3

148.0

-3 6 0 .6

-3 6 4 .7

-2 6 0 .7

161

NaOH(flc)

-4 6 9 .6

-4 1 9 .2

PbCOj(s)

-6 9 9 .1

-6 2 5 .5

131.0

Pb(N0 3 )2(c)

-4 2 1 .3

-2 4 6 .9

303.3

NaOH(s)
Na2OH4(s)

-4 2 5 .6
-1387.1

-3 7 9 .5
-1 2 7 0 .2

Pb(N0 3 )2(s)

-4 5 1 .9

PbO(s)

-2 1 7 .3

-1 8 7 .9

468

422

Potasio
K(g)
K(s)

89.99
0

61.17
0

160.2
64.67
82.7

Ti(g)
Ti(s)

86.82

72.33

64.46
149.6

180.3
30.76

T iC k(g)

-7 6 3 .2

-7 2 6 .8

354.9

riCi4(/)
Tl0 2 (s)

-8 0 4 .2

-728.1

221.9

-9 4 4 .7

-8 8 9 .4

514.2

453.1

182.2

28.9

-4 3 5 .9

-4 0 8 .3

KClOss)

-3 9 1 .2

-2 8 9 .9

143.0

Vanadio

KClO^flC)

-3 4 9 .5

-2 8 4 .9

265.7

K 2C 03(s)

-1150.18

-1 0 64.58

155.44

V(g)
V(s)

KNO^s)

-4 9 2 .7 0

-3 9 3 .1 3

132.9

K20(S)

-3 6 3 .2

-3 2 2 .1

KOjs)

-2 8 4 .5

-2 4 0 .6

122.5

K 202(s)

-4 9 5 .8

-4 2 9 .8

113.0

KOH(s)

-4 2 4 .7

-3 7 8 .9

78.91

KOH(flc)

-4 8 2 .4

-4 4 0 .5

91.6

Rb(g)

85.8

55.8

170.0

Rb(s)

Rubidio

141.00

Titanio

KCl(s)

94.14

51.45
59.0

-2 7 7 .4

68.70

153.7

-2 6 1 .9

PbBr2(s)

41.84

50.29

Yodo
106.60

70.16

-5 5 .1 9

-5 1 .5 7

h (g )
I2(s)

62.25

19.37

HI(g)

25.94

%)
n :)

180.66
111.3
260.57

116.73

1.30

206.3

Zinc
130.7

95.2

160.9

76.78

Z n (g)
Zn(s)
ZnCl2(s)

-4 1 5 .1

-3 6 9 .4

111.5

ZnO(s)

-3 4 8 .0

-3 1 8 .2

43.9

RbCl(s)

-4 3 0 .5

-4 1 2 .0

92

RbC103(s)

-3 9 2 .4

-2 9 2 .0

152

41.63

Miguel Angel G.

Constantes de equilibrio
en disoluciones acuosas

CU
<

TABLA D-1 Constantes de disociacin de cidos a 25 C

Nombre

Frmula

Actico

CH3COOH (0 HC2H302)

1.8 X IO-5

Arsnico

H3A s 0 4

5.6 X 10" 3

Arsenoso

H3ASO3

5.1 X IO-10

Ascrbico

H 2C J W 6

8.0 X 10" 5

Benzoico

Q H 5COOH (0 HC7H502)

6.3 X 10" 5
5.8 X IO" 10

Brico

H3B0 3

Butanoico

C3H7COOH (0 H C 4HyO^

1.5 X 10-5

Carbnico

H2C 03

4 3 X 10" 7

Cianhdrico

HCN

4 9 X 10" 10

Cinico

HCNO

3.5 X 10" 4

*02

K b

1.0 X 10" 7

3.0 X 10" 12

1.6 X 10" 12

5.6 X 10" 11

Ctrico

HOOCC(OH)(CH2COOH)2 (0 H3C6H507)

7.4 X 10" 4

Cloroactico

CH2ClCOOH (0 HC2H202C1)

1.4 X 10" 3

1.7 X 10" 5

4 0 X 10-7

Cloroso

h c io 2

1.1 X 10" 2

Fenol

C6H5OH (0 H Q H sO )

1.3 X IO-10

Fluorhdrico

HF

6.8 X 10-4

Frmico

HCOOH (0 H C H 0 2)

1.8 X 10-4

Fosfrico

H3PO4

7.5 X 10" 3

Hidrazoico

hn3

1.9 X 10" 5

6.2 X 10" 8

4 2 X 10" 13

Hidrogenocromato, ion

H C r0 4"

3.0 X 10" 7

Hidrogenoseleniato, ion

H S e 0 4~

2 2 X 10-2

Hipobromoso

HBrO

2.5 X 10 9

Hipocloroso

HCIO

3.0 X 10" 8

Hipoyodoso

HIO

2 3 X 10" 11

Lctico

CH3CH(OH)COOH (0 HC3H5O3)

1.4 X 10" 4

Malnico

CH2(COOH)2 (0 H2C3H204)

1.5 X 10-3

Nitroso

HN O 2

4 5 X 10" 4

Oxlico

(C O O H k (0 H2C2Q4)

5.9 X 10" 2

6.4 X 10" 5

Paraperydico

h 5i o 6

2 8 X 10" 2

5.3 X 10-9

Perxido de hidrgeno

H202

2 4 X 10" 12

Piro fosfrico

H4P20 7

3.0 X 10" 2

2.0 X 10" 6

4.4 X 10" 3

Propinico

Q H 5COOH (0 HC3HSQ2)

1.3 X 10" 5

Selenioso

H2Se0 3

2 3 X 10" 3

5.3 X 10-9

Sulfhdrico

H2S

9.5 X 10" 8

1 X 10" 19

Sulfrico

h 2s o 4

ddo fuerte

1.2 X 10" 2

Sulfuroso

H2S03

1.7 X 10" 2

6.4 X 10 8

Tartrico

HOOC(CHOH)2CC)OH (0 H2C4H 406)

1.0 X 10" 3

4.6 X 10" 5

Ydico

h i c >3

1.7 X 10" 1

2 1 X 10" 7

1115

Miguel Angel G.

1116

A P N D IC E D

C o n s ta n te s de e q u ilib rio e n d iso lu cio n es a c u o s a s

I TABLA D-2

Constantes de disociadn de bases a 25 C

Nombre

Frmula

Kb

Amoniaco

nh3

1.8 X IO5

Anilina

Q jH sNH j

4.3 X IO"10

Dimetilamina

(C H & N H

5.4 X IO-4

Etilamina

C2H5NH2

6.4 X IO-4

Hidradna

H2NNH2

1.3 X 10"*

Hidroxilamina

honh2

1.1 X 10*

Meti lamina

CH3NH2

4.4 X IO4

Piridina

C5H5N

1.7 X IO-9

Trimetilamina

(CHsbN

6.4 X IO"5

TABLA D-3 Constantes del producto de solubilidad de com puestos a 25 C

Nombre

Frmula

K ps

N om bre

Frmula

Bromato de plata

A g B r0 3

5.5 X IO" 5

Hidrxido de calcio

Ca(OH)2

Bromuro de cobre(I)

CuBr

5.3 X IO 9

Hidrxido de cobalto(U)

Co(OH)2

1.3 X IO 15

Cu(OH)2

4.8 X IO20

Cr(OH)3

1.6 X IO30

6.5 X IO-6

Bromuro de plata

AgBr

5.0 X IO 13

Hidrxido de cobre(H)

Carbonato de bario

BaCOs

5.0 X IO 9

Hidrxido de cromo(III)

Carbonato de cadmio

CdCOs

1.8 X IO 14

Hidrxido de hierro()

Fe(OH)2

7.9 X IO 16

M g(OH )2

1.8 X 10 11

Carbonato de calcio (calcita)

CaCOj

4 5 X IO 9

Hidrxido de magnesio

Carbonato de cobalto(U)

C0CO3

1.0 X IO 10

Hidrxido de manganeso(II)

Mn(OH)2

1.6 X 10" 13

Ni(OH)2

6.0 X 10 16
3.0 X IO 16

Carbonato de cobre(II)

CuCOs

2 3 X IO 10

Hidrxido de nquel()

Carbonato de estroncio

SrCOs

9.3 X IO 10

Hidrxido de zinc

Zn(OH)2

Carbonato de hierro(II)

FeCOs

Z I X IO 11

Oxalato de bario

BaC20 4

1.6 X IO"6

MgC20 4

8.6 X IO5
2.7 X IO8

Carbonato de magnesio

M gC 03

3.5 X IO 8

Oxalato de magnesio

Carbonato de manganeso(H)

M nC 03

5.0 X IO 10

Oxalato de zinc

ZnC20 4

1.3 X IO 7

Sulfato de bario

B aS04

1.1 X IO 10

CaS04

2.4 X IO"5

Carbonato de nquel(II)

NCO3

Carbonato de plata

Ag2C 0 3

8.1 X IO 12

Sulfato de calcio

Carbonato de plomo(U)

P bC O j

7.4 X IO 14

Sulfato de plata

Ag2S 0 4

1.5 X IO5

P bS04

6.3 X IO7
8 X IO 28

Carbonato de zinc

ZnC03

1.0 X IO 10

Sulfato de plomo(II)

Cloruro de mercurio(I)

Hg2Cl2

1.2 X IO 18

Sulfuro de cadmio*

CdS

Cloruro de plata

AgCl

1.8 X IO 10

Sulfuro de cobalto(II)*

CoS

5 X IO 22

CuS

6 X IO 37

Cloruro de plomo(II)

PbCl2

1.7 X IO 5

Sulfuro de cobre(II)*

Cromato de bario

BaCr0 4

Z I X IO 10

Sulfuro de estao()*

SnS

1 X IO 26

MnS

2 X IO 53
2 X IO 53

Cromato de calcio

C aC r04

7.1 X IO 4

Sulfuro de manganeso(II)*

Cromato de plata

Ag2Cr0 4

1.2 X IO 12

Sulfuro de mercurio(II)*

HgS

Cromato de plomo(II)

P b C r0 4

1 8 X IO 13

Sulfuro de nquel(II)*

NiS

3 X IO 20

Ag2S

6 X IO 51

Fluoruro de bario

BaF2

1.7 X IO 6

Sulfuro de plata*

Fluoruro de calcio

CaF2

3.9 X IO 11

Sulfuro de plomo(II)*

PbS

3 X IO 28

ZnS

2 X IO 25
6.1 X IO 12

Fluoruro de lantano

u f3

2 X IO 19

Sulfuro de zinc*

Fluoruro de plomo(ll)

PbF2

3.6 X IO 8

Yodato de lantano

U(IC>3)3

Z0 X IO 29

Yoduro de mercurio(I)

Hg2I2

1.1 X IO28

Z5 X IO 14

Yoduro de plata

Agl

8.3 X IO" 17

Fosfato de calcio
Hidrxido de cadmio

Ca3(P0 4)2
Cd(O H )2

Para un equilibrio de solubilidad del tipo MS<$) + H2 CXO ;= = ; M2+(ac) + HS~(ac) + OH-(ac).

Miguel Angel G.

Potenciales estndar
de reduccin a 25 C

Ul
Cu
<
M ed ia reacci n

E (V )

M edia reacci n

E(V )

A g+(c) + e " ----- A g(s)

+ 0.799

2 H 20(/) + 2 e ----- H2(g) + 2 0 H " ( c )

- 0 .8 3

A gBr(s) + e- ----- A g(s) + Br"(oc)

+ 0.095

H C V iflc) + H 20 (/) + 2 e " ----- 3 0 H "( zc)

+ 0 .8 8

A gCl(s) + e " ----- A g(s) + C l"(ac)

+ 0.222

H H a c ) + 2 H V ) + 2 e " ----- 2 H20 (/)

+ 1.776

A g(C N )2"(ac) + e " ----- A g(s) + 2 C N "(ac)

- 0 .3 1

H g 22V ) + 2 e " ----- > 2 H g (/)

+ 0.789

Ag2C r 0 4(s) + 2 e " ----- * 2 A g(s) + C r 0 42"(ac)

+ 0.446

2 H g 2+(c) + 2 e " ----- H g22+(oc)

+ 0.920

A gl(s) + e ----- A g(s) + r ( a c )

-0 .1 5 1

H g2V ) + 2 e " ----- H g (/)

+ 0.854

A g(S 2Q 3)23"(oc) + e " ----- A g(s) + 2 S> 32~(ac)

+ 0.01

fc(s) + 2 e " ----- 2 T(flc)

+ 0.536

A l3+(ac) + 3 e ----- A l(s)

- 1 .6 6

2 I Q j" ( 0 + 12 t r V ) + 10 e " -----

I 2(s) + 6 H 20 (/)

+ 1.195

+ 0.559

K+(ac) + e " ----- K(s)

- 2 .9 2 5

Ba2V ) + 2 e ----- Ba(s)

-2 9 0

U > c ) + e " ----- Li(s)

- 3 .0 5

BiO +(flc) + 2 H+fac) + 3 e " ----- Bi(s) + H jO (/)

+ 0 .3 2

M g2V ) + 2 e " ----- M g(s)

- 2 .3 7

Bi^(/) + 2 e ~ ----- 2 B r(flc)

+ 1.065

M n2+(c) + 2 e " ----- M n(s)

- 1 .1 8

2 Br 0 3 (oc) + 12 H +(ac) + 10 e " -----

Br2(/) + 6H 20(/ )

+ 1 .5 2

M n 0 2(s) + 4 H+(ac) + 2 e " -----

M n2V ) + 2

+ 1.23

2 C 02(g ) + 2 H +(oc) + 2 e " ----- - H ^ O 4(ac)

- 0 .4 9

M n 0 4"(ac) + 8 H+(oc) + 5 e " -----

Ca2+(ac) + 2 e ~ ----- Ca(s)

-2 8 7

C d 2+(c) + 2 e " ----- Cd (s)

- 0 .4 0 3

M n2V ) + 4
M nO 4~(ac) + 2 H jO (!) + 3 e " -----

C e4V ) + e " ----- > C e 3+(flc)

+ 1.61

H j A s O ^ ac) + 2 H > c ) + 2 e " -----

H 3ASO 3(ac) + H >(!)

C l2(g) + 2 e " ----- 2 Cl"(fle)

+ 1.359

M n 02(s) + 4 OH~(oc)

+1.51
+ 0.59

H N 0 2(ac) + H +(oc) + e " ----- - N O (g) + H 0(1)

+ 1 .0 0

N 2(g) + 4 H 20 ( i) + 4 e " ----- 4 O H "(c) + N 2H 4(ac)

- 1 .1 6
- 0 .2 3

2 HClO(oc) + 2 H+(oc) + 2 e " ------

C l2(g) + 2 H 2 0 (/ )

+ 1.63

N 2(g) + 5 H V ) + 4 e " ----- > N 2H 5+(oc)

C 1 0 (ac) + H 20(/) + 2 e " ----- Cl"(flc) + 2 0 H "(o c )

+ 0.89

N C V iac) + 4 H +(ac) + 3 e " ----- - N O (g) + 2 HjO*/)

+ 0 .9 6

N a+(ac) + e " ----- * Na(s)

- 2 .7 1
- 0 .2 8

2 C 10 3 "(flc) + 12 H +(ac) + 10 e " -----

C\2(g) + 6 H 2 0 (/ )

+ 1 .4 7

N i2+(ac) + 2 e " ----- * Ni(s)

C o2+(oc) + 2 e " ----- Co(s)

- 0 .2 7 7

( h l g ) + 4 H+(ac) + 4 e " ----- - 2 H 20 (/)

+ 1.23

C o3+(oc) + e " ----- > C o 2+(ac)

+ 1.842

02(g ) + 2 H iP (l) + 4 e " ----- * 4 O H "(ac)

+ 0 .4 0

C t ^ ia c ) + 3 e " ----- Cr(s)

- 0 .7 4

O 2(g) + 2 H+iac) + 2 e " ----- H2Ch(ac)

+ 0 .6 8

C r ^ i :) + e " ----- C r2+(ac)

- 0 .4 1

O 3(g) + 2 H+(ac) + 2 e " ----- C^fg) + H ^ i/ )

+ 2 .0 7

Pb2+(flc) + 2 e " ----- P b(s)

- 0 .1 2 6

PbC^is) + H S 0 4"(ac) + 3 H+iac) + 2 e " -----

PbSO 4(s) + 2H 20(/ )

+ 1.685

Cr 0 7 2"(oc) + 14 H +{ac) + 6 e ~ -----

2 C r 3V ) + 7 H 20(/)

+ 1.33

C r 0 42"(ac) + 4 H20(/) + 3 e " -----

Cr(O H )3(s) + 5 0 H " ( a c )

- 0 .1 3

P b S 0 4(s) + H+ c) + 2 e " ----- Pb (s) + H S 0 4" (a :)

- 0 .3 5 6

C u 2+(oc) + 2 e " ----- C u (s)

+ 0.337

P tC lj2! : ) + 2 e " ----- P t (s) + 4 C l"(a c )

+ 0.73

C u 2+(c) + e " ----- C u +(oc)

+ 0.153

S(s) + 2 H +(ac) + 2 e " ----- H ^ (g )

+0.141

C u +(ac) + e " ----- * Cu(s)

+ 0.521

H ^ O 3(ac) + 4 H+(ac) + 4 e " ----- * S(s) + 3 H >(1)

+ 0 .4 5

C u l(s) + e " ----- Cu(s) + I~{ac)

- 0 .1 8 5

F2{g) + 2 e " ----- - 2 F~(ac)

+287

H S 0 4"(flc) + 3 H + (ac) + 2 e " -----

H ^ O 3(ac) + H20 (I)

+ 0 .1 7

F e2+(oc) + 2 e " ----- * Fe(s)

- 0 .4 4 0

Sn2+(ac) + 2 e " ----- Sn (s)

- 0 .1 3 6

F e^ io c) + e ----- Fe2+(oc)

+ 0.771

Sn4+(ac) + 2 e " ----- Sn2+(ac)

+ 0.154

Fe(CN)63-(flc) + e " ----- Fe(C N )64"(ac)

+ 0 .3 6

V 0 2+(flc) + 2 H+iac) + e " ----- VC +(ac) + H ^0(1)

+1.00

2 H > c ) + 2 e ~ ----- H 2(g)

0.000

Zn 2+(ac) + 2 e " ----- Zn(s)

- 0 .7 6 3

1117