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T Erm Paper OF CHE-101: Topic Explain Surfactants
T Erm Paper OF CHE-101: Topic Explain Surfactants
T ERM PAPER
OF
CHE-101
SUBMITTED BY
SUBMITTED TO
NAME- BITTU KUMAR LECT. JYOTI
MAM
SECTION-E2801 (DEPARTMENT
OF CHEMISTRY.)
ACKNOWLEDGEMENT
At last but not the least I would like to thank seniors for
providing me their experience and being with me during
my work.
3
-:TABLE OF CONTENTS:-
1.1 INTRODUTION
1.2 PROPERTIES
1.3.1ANIONIC SURFACTANTS
1.3.2CATIONIC SURFCTANTS
1.3.3NONIONIC SURFACTANTS
1.3.4AMPHOTERIC SURFACTANTS
1.6 REFERENCES
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1.1 INTRODUCTION:-
The term surfactant (short for surface-active-agent) designates a substance which
exhibits some superficial Surfactants provide remarkable benefits in many textile
wet processes. A surface active chemical is one which tends to accumulate at a
surface or interface. An interface is the area of contact between two substances.
The surface tension (or inter-facial tension if the interface is not a surface)
determines the tendency for surfaces to establish contact with one another.
Therefore, surface tension is responsible for the shape of a droplet of liquid. If the
surface tension is high, the molecules in the liquid are greatly attracted to one
another and not so much to the surrounding air.
If the droplet of water is in contact with a solid such as a fabric, its shape will also
be affected by the surface tension at the solid/liquid interface. If the surface tension
in the liquid is lower, the droplet forms a more ellipsoidal shape.
The following are the surface tensions for some liquid substances:-
1. water 73 dynes/cm
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Because of its lower surface tension, ethanol will flow and form a larger area of
contact (surface) with a solid than with water. Mercury, with its very high surface
tension, does not flow but breaks into droplets if given the opportunity. Surface
active agents interfere with the ability of the molecules of a substance to interact
with one another and, thereby, lower the surface tension of the substance.
Surfactants used in industrial applications usually cause a dramatic decrease in
surface tension when used at low concentration.
1.2 PROPERTIES:-
Chemically, surfactants are amphipathic molecules. That is, they have two
distinctly different characteristics.
1. Polar
2. Non polar
“trailor”
Since surfactant molecules have both hydrophilic and hydrophobic parts, the most
attractive place for them in water is at the surface where the forces of both
attraction and repulsion to water can be satisfied. One other way that surfactants
interact to satisfy natural forces of attraction and repulsion between molecules is
by formation of micelles. Surfactant molecules aggregate in water forming
micelles (see Figure). Micelles consist of hydrophobic interior regions, where
hydrophobic tails interact with one another. These hydrophobic regions are
surrounded by the hydrophilic regions where the heads of the surfactant molecules
interact with water.
Schematic representation of
surfactant molecules at surface and
surfactant micelle
In solution, the head is negatively charged. This is the most widely used type of
surfactant for laundering, dishwashing liquids and shampoos because of its
excellent cleaning properties and high sudsing potential. The surfactant is
particularly good at keeping the dirt away from fabrics, and removing residues
of fabric softener from fabrics
Anionic surfactants are particularly effective at oily soil cleaning and oil/clay
soil suspension. Still, they can react in the wash water with the positively
charged water hardness ions (calcium and magnesium), which can lead to
partial deactivation. The more calcium and magnesium molecules in the water,
the more the anionic surfactant system suffers from deactivation. To prevent
this, the anionic surfactants need help from other ingredients such as builders
(Ca/Mg sequestrants) and more detergent should be dosed in hard water.
The most commonly used anionic surfactants are alkyl sulphates, alkyl
ethoxylate sulphates and soaps.
A). SULPHATES:-
B). SULPHONATES:-
Various fatty alcohols can be reacted with chlorosulfonic acid or sulfur trioxide to
produce their sulfuric acid esters. The properties of these surfactants depend on
the alcohol chain length as
D). XANTHATHES:-
E). DITHIOPHOSPHATE:-
2. Many cationic surfactants are bactericides. They are used to clean and aseptize
surgery hardware, to formulate heavy duty desinfectants for domestic and
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hospital use, and to sterilize food bottle or containers, particularly in the dairy
and beverage industries.
The long chain amine types are made from natural fats and oils or from synthetic
amines. They are soluble in strongly acidic medium but become uncharged and
insoluble in water at pH greater than 7. For example:-
Quaternary amine type cationic surfactants are very important as fabric softeners.
They absorb on the surface of fibers with their hydrophobic group oriented away
from the fibers. This reduces the friction between fibers and imparts a soft, fluffy
feel to the fabric.
Nonionic surfactants are compatible with other types of surfactants. Their low
foaming tendency can be an advantage or disadvantage depending on
requirements. They are good dispersing agents in many cases. They are more
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effective than sulfonate surfactants in removing s oil from hydrophobic fibers but
are inferior to anionic surfactants for soil removal from cotton.
It has been said previously that amines and amides can be ethoxylated. The first
EO group must be added at acid pH, whereas the other ones (from the second
group on) are added at alkaline pH.
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2. QUATERNIZED COMPOUNDS:-
Quaternized compound have similar structures. The most important are betaines
and sulfobetaines or taurines, which have a single methylene group between the
acid and the quaternary ammomium.
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These surfactants are amphoteric at neutral and alcaline pH, and cationic at acid
pH (at which the carboxylic acid is not ionized). Since the nitrogen atom is
quaternized, these surfactants always display a positive charge. They tolerate a
high salinity, particularly divalent cations, e.g. calcium and magnesium. They are
the most used class of amphoteric surfactants. They are found in softeners for
textiles, hair rinse formulas, and corrosion inhibition additives. They are good
foam boosters because of their cationic characteristics.
1.6REFERENCES:-
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BOOK
2. N.C.E.R.T CHEMISTRY
WEBSITE:-
1. http://docs.google.com/viewer?
a=v&q=cache:GRuHsFbjeDMJ:www.p2pays.org/ref/03/02960.pdf+PDF+ON+SURFAC
TANTS&hl=en&gl=us&pid=bl&srcid=ADGEEShZ92xRqa2WCuoKYRBNuptdnyGP3j
RhFVP8B87PBHCmmk_Rbti1Np8RCH-
biFcwfw7g8hCVum3CmyUTDaOquhyI0Z8BQ4Hnz7C5eqgICWjNOOmO9H0hMCFsU
w4h8CrEOmJLConV&sig=AHIEtbQq55O8F52ihJclEyhJG91bQvmLaA
2. http://en.wikipedia.org/wiki/Surfactant