Redox Pty Ltd - Material Safety Data Sheet GLYCER. Page 1 of & | MATERIAL SAFETY DATA [REDOX SHEET Revision Date JUNE 2008 Product Name GLYCERINE Other Names GLYCEROL ; GLYCERIN ; GLYCYL ALCOHOL ; | 1,28-PROPANETRIOL ; | ) Uses ‘Alkyd resins, dynamite, ester gums, pharmaceuticals, perfumery, Plasticizer for regenerated cellulose, cosmetics, foodstuffs, conditioning | tobacco, liquors, solvent, printers ink rolls, polyurethane polyols, ‘emulsifying agent, rubber stamp and copying inks, binder for cements and | mixes, special soaps, lubricant and softener, bacteriostat, penetrant, hydraulic fluid, humectant, fermentation nutrients, antitreeze mixtures. Contact Information Organisation Location Telephone Ask For Redox Pty Lid 2Swettenham +61 2 Technical Road 97333000 Officer Minto NSW: 2568 Australia 14 Mayo Road 4649 Wiri Auckland 2506222 2104. New Zealand Poison Information Westmead 181126 Centre NSW Australia Chemeall 24 Hour Australia 1800-127406 tbat elec Mbealiest Now Zealand — 0800-249622 National Poisons Centre New Zealand — 0800-764766 2. HAZARD IDENTIFICATION NOT Hazardous according to criteria of NOHSC/ASCO. Risk Phrases No data available. Safety Phrases No data available, ERMA New Zealand Approval Code: HSNO Hazard No data available. http://www.redox.com/msds/data/glycer.html 29/09/2009Redox Pty Ltd - Material Safety Data Sheet GLYCER, Page 2 of & Classification ‘This Material Safety Data Sheet may not provide exhaustive guidance for all HSNO Controls assigned to this substance. The ERMA Web Site should be consulted for a full list of triggered controls and cited regulations. 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients Chemical Entity CAS Number Proportions (%) GLYCERINE —[56-81-5) >970 4. FIRST AID MEASURES Description of necessary measures according to routes of exposure. ‘Swaltowed Rinse mouth with water. Give water to drink. Do NOT induce vomiting. It symptoms develop, seek medical attention. Eye Immediately flush eyes with plenty of water holding eyelids open. If lnrtation persists, seek modical attention Skin Remove contaminated clothing. Wash affected area with soap and plenty of water. I initation persists, seek medical attention, Inhaled Remove victim from exposure to fresh alr. Ifrapid recovery does not occur, seek medical attention. Advice te Doctor —_Treat symptomatically based on individual reactions of patient and judgement of doctor. NOTE: For advice in an emergency, contact a Poisons information Centro (Australia 13-11-26 or New Zealand 0800- 764-766). ‘Aggravated medical No information avaliable on medical conditions which are aggravated from conditions caused exposure to this product. by exposure 5. FIRE FIGHTING MEASURES Extingulshing Media In case of fre, appropriate extinguishing media include dry chemical, carbon dioxide, foam and water. Hazards from Combustible liquid. Incompatible with oxidizing agents, alkalies and ‘Combustion sources of ignition. When involved in a fra, this product may generate Products carbon monoxide. Special Protective Fite fighters should wear a positive-pressure self-contained breathing Precautions and apparatus (SCBA) and protective fie fighting clothing (includes fire Equipment for Fire fighting helmet, coat, trousers, boots and gloves). Clear fire area of all Fighters non-emergency personnel. Stay upwind. Keep out of low areas. Eliminate Jgnition sources. Flammability Products a combustible liquid. Conditions Additional Information Hazchem Code NA hitp://Awww.tedox.com/msds/data/glycer. html 29/09/2009Redox Pty Ltd - Material Safety Data Sheet GLYCER Page 3 of 8 Emergency Procedures ‘Methods and Materials for Containment and Clean Up 6. ACCIDENTAL RELEASE MEASURES Personnel involved in the clean up should wear full protective clothing. Eliminate all sources of ignition. Stop leak i! safe to do so. Increase ventilation. Avoid walking through spilled product as it may be slippary. Do not allow product to reach drains, sewers or waterways. If product does ‘enter a waterway, advise the Environmental Protection Authority or your local Waste Management. Use clean, non-sparking tools and equipment. ‘Soak up spilled product using absorbent non-combustible material such as ‘sand or soil. Avoid using sawdust or collulose. When saturated, collect the material and transfer to a suitable, labelled chemical waste container and dispose of promptly. 7. HANDLING AND STORAGE Precautions for Safe Ensure an eye bath and safety shower ave available and ready for use. Handling Conditions for Safe Storage (Including ‘Any Incompatibles) Container Type National Exposure Standards Biological Limit Values Engineering Controls Personal Protection ‘Observe good personal hygiene practices and recommended procedures. Wash thoroughly aftor handling. Take precautionary measures against static discharges by bonding and grounding equipment. Avoid contact with eyes, skin and clothing. Do not inhale product vapours. Store in a cool, dry, well-ventilated area. Keop containers tightly closed when not in use. Inspect regularly for deficiencies such as damage or leaks. Protect against physical damage. Store away from incompatible materials including oxidizing agents, alkalies and saurces of ignition. Protect from direct sunlight and static charges. Store bulk product at about 10°C above the melting point. Temperature higher than necessary degrades quality at rale dependent of time and exposure. This product is classified as 'C2' Combustible Liquid for the purpose of storage and. handling, in accordance with the requirements of AS1940. Store in original packaging as approved by manufacturer. 8, EXPOSURE CONTROLS / PERSONAL PROTECTION “The following exposure standard has been established by The Australian Safety and Compensation Council (ASCO); Glycerin (mist) cas no: 56-81- 5 TWA = 1Omgim3 'No information available on biological limit values for this product. ‘A system of local and/or general exhaust is recommended to keep temployee exposures as ow as possible. Local exhaust ventiation is generally preferred because it can control the emissions of the Contaminant at ts source, preventing dispersion of it into the genoral work area. RESPIRATOR: Wear an approved respirator where vapours are generated and engineering controls are inadequate (AS1715/1716). EYES: Chemical goggles to pravent splashing in the eyes (AS1336/1337). HANDS: Rubber gloves (AS2161). CLOTHING: Long-sleeved protective clothing and safety footwear (AS3765/2210). http://www.redox.com/msds/data/glycer.html 29/09/2009Redox Pty Ltd - Material Safety Data Sheet GLYCER Page 4 of 8 9, PHYSICAL AND CHEMICAL PROPERTIES Appearance clear, colourless liquid Formula c3H803 Odour odourless Vapour Pressure < 1mmHg (20°C) Vapour Density Not applicable. Bolling Point >280 deg C Melting Point 18 degC Solubility in Water Soluble Specific Gravity 1.26 (Water = 1) Flash Point Test Unknown >198.9 pH Not applicable, Lower Explosion —_Not applicable, Limit Upper Explosion _Not applicable. Limit Ignition Temperature Not applicable. ‘Specific Heat Value Not applicable. Particle Size Not applicable. Volatile Organic Not applicable. ‘Compounds (VOC) Content Evaporation Rate Not applicable. Viscosity Not applicable. Percent Volatile Not applicable. ‘OctanoWWater Not applicable. partition coefficient Saturated Vapour —_Not applicable, Concentration Additional Not applicable, Characteristics Flame Not applicable, Propagation/Burning Rate of Solid Materials Properties of Not applicable, Materials That May Initiate or Contribute to Fire Intensity Potential for Dust Product is a liquid. Explosion hutp://www.redox.com/msds/data/glycer.html 29/09/2009Redox Pty Ltd - Material Safety Data Sheet GLYCER Page 5 of 8 Reactions that Release Flammable Gases Fast of Intensely Burning Characteristics Non-flammables That Could Contribute Unusual Hazards to a Fire Release of invisible Flammable Vapaurs and Gases Decomposition ‘Temperature Additionat Information Not applicable. Not applicable. Not applicable. Not applicabio, Not applicable. Solubility: Soluble in water and alcohol. insoluble in ether, benzene and chioroform, Chemical Stability Conditions to Avold Incompatible Materials Hazardous Decomposition Products Hazardous Reactlons 10, STABILITY AND REACTIVITY Product is stable under normal conditions of use, storage and temperature. Combustible liquid. Avoid excessive heat, temperatures. Incompatible with oxidizing agents, alkalies and sources of ig ct sunlight, moisture, static discharges and high When involved in a fire, this product may generate carson monoxide. 11. TOXICOLOGICAL INFORMATION Toxicity Data Health Effects - Acute Swallowed Eye Skin Inhaled No toxicological information available for this product. Ingestion may cause gastro-intestinal pain, nausea, voriting and. diarrhoea. May cause eye discomfort May cause skin discomfort. Inhalation of vapours may cause respiratory tract discomfort http://www redox.com/msds/data/glycer.html 29/09/2009Redox Pty Ltd - Material Safety Data Sheet GLYCER Page 6 of 8 Ecotoxicity Persistence and Degardability ‘Mobility Environmental Fate (Exposure) Bloaccumulative Potential 12, ECOLOGICAL INFORMATION No data available, This material is biodegradable, No information available on mobility for this product, ‘Avoid contaminating waterways, drains and sewers. 'No information available on bioaccumulation for this product. 13. DISPOSAL CONSIDERATIONS Disposal Dispose of in accordance with all local, state and federal regulations. Special Precautions Contact a specialist disposal company or the local waste regulator for for Land Fill or Incineration advice. 14. TRANSPORT INFORMATION Land Transport UN Number Shipping Name Dangerous Goods Class ‘Subsidiary Risk Pack Group Precaution for User Hazchem Code Sea Transport UN Number Shipping Name Dangerous Goods Class. Subsidiary Risk Pack Group Precaution for User Hazchem Code Not applicable. GLYCERINE ©.2 Combustible Liquid Not applicable. Not applicable. No data available, NA Not applicable. GLYCERINE C.2 Combustible Liquid Not applicable. Not applicable. No data available. NA 15. REGULATORY INFORMATION http: www redox.com/msds/data/glycer html 29/09/2009Redox Pty Ltd - Material Safety Data Sheet GLYCER Page 7 of 8 ‘This product is classified as non-hazardous according to The Australian Safety and Compensation Council (ASC) and Annex | European Directive 67/548/EEC. EINECS No: 200-289-5 Poisons Schedule N/A EPG NA AICS Name 1,2,3-PROPANETRIOL NZ Toxic Substance N HSNO Hazard No data available, Classification ERMA Approval No data available. Code 16. OTHER INFORMATION QO Literature No data available. References Sources for Data No data available. Legend to Abbrevistions and Acronyms less than > ‘greater than Acs Australian Inventory of Chemical Substances cas ‘Chemical Abstracts Service (Registry Number) oma ‘square centimetres coz Carbon Dioxide cop ‘Chemical Oxygen Demand deg ¢('C) degrees Celsius ERMA Environmental Risk Management Authority 3 gram gfems ‘grams per cubic centimetre gf rams per litre HSNO Hazardous Substance and New Organism 1OLH Immediately Dangerous to Life and Health immiscible liquids are insoluble in each other kg Kilogram gina kilograms per cubic metre Leo LC stands for lethal concentration. LC5O is the concentration of a material in air which causes the death of 50% (one half) of a group of test animals. ‘The material is inhaled over a set period of time, usually 1 or 4 hours. p50 LD stands for Lethal Dose. LD50 is the amount of a material, given all at conce, which causes the death of 50% (one half} of a group of test animals tr Litre hitp://www.redox.com/msds/data/glycer.html 29/09/2009Redox Pty Ltd - Material Safety Data Sheet GLYCER Page 8 of 8 m3 mbar mg mg/2aH mohkg mgm Misc miscible mm mPas NA MOSH NoHSC OECD PEL ppb ug/24H UN @ ‘Guaily Endorsed Company cubic metro rnilibar ‘milligram milligrams per 24 hours nnligrams per kilogram milligrams per cubie metre miscible liquids form one homogeneous liquid phase regardless of the amount of either component present millimetre mili Pascal per second Not Applicable ‘National Institute for Occupational Satety and Heatth National Occupational Health and Salety Commission Organization for Economic Co-operation and Devolopment Permissible Exposure Limit Parts por bilfon parts per Parts per millon per 2 hours parts per millionper 6 hours Reciprocal Calculation Procedure Short Term Exposure Limit Threshold Limit Value tonne Time Weighted Average micrograms per 26 hours United Nations (number) weight esa so yey Oten Zenians slate Acland 2oveteman loeghone 682078000 Erabane Crisoruch Road focus spt 2ereottt Motecune HawosBay — MADNSW2566 yay ‘rw coco er nat imoaresoxcom sxe ‘This MSDS summarises Redox Ply L1s best knawledge ofthe haath and safety hazard information ofthe saluted substance ‘nd how to safely ane the selected substance inthe workolacy however Redox Ply Lid expressly dlecelms hat the MSDS Is 2 representation or guarantee ofthe chemical speciation fo the substance Each usor shoulé read the MSDS and concider te information inthe contoxt of how tho salected eubelance wif be handled and used the weekplace Insucing ts uss in conjunction with cer substances © Copyright 2000 Redox Py Lid hitp://www.tedox.com/msds/data/glycer.html 29/09/2009