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Autothermic Process
Autothermic Process
1)
+ +
2)
2 +
R
T
8.3145
298.15
Reaction 1)
T (K)
1)
298
i
reactants
products
C(s)
H2O(g)
CO(g)
H2(g)
h,r 289.15K=
-1
-1
1
1
cp at T
hf 298.15K (kJ/mol) (J/(mol*K))
0
-242
-110.62
0
131.38
8.67
33.58
29.14
28.85
T (K)
1)T=
900 K
298
i
reactants
products
C(s)
H2O(g)
CO(g)
H2(g)
h,r 289.15K=
-1
-1
1
1
cp at T
hf 298.15K (kJ/mol) (J/(mol*K))
0
8.67
-242
33.58
-110.62
29.14
0
28.85
131.38
T (K)
1)T=
1200 K
298
i
reactants
products
C(s)
H2O(g)
CO(g)
H2(g)
h,r 289.15K=
-1
-1
1
1
cp at T
hf 298.15K (kJ/mol) (J/(mol*K))
0
-242
-110.62
0
131.38
8.67
33.58
29.14
28.85
T (K)
1)T=
1500 K
i
reactants
C(s)
H2O(g)
298
cp at T
hf 298.15K (kJ/mol) (J/(mol*K))
-1
0
8.67
-1
-242
33.58
products
CO(g)
H2(g)
1
1
-110.62
0
131.38
h,r 289.15K=
29.14
28.85
0.244
n
298.15
900
1200
1000
0.231997175
0.241312561
0.242977535
0.242682773
0.242
0.24
0.238
0.236
0.234
0.232
0.23
0
200
400
600
J/(mol*K)
K
Reaction 1)
T(K)
1000
cp at T (J/(mol*K)) intercept
16.55
5.32
40.86
30.49
30.78
28.44
29.65
28.51
T (K)
900
cp at T (J/(mol*K))
15.42749288
39.82296296
30.54638177
29.53603989
T (K)
1200
cp at T (J/(mol*K))
18.79501425
42.93407407
31.24723647
29.87792023
T (K)
1500
slope
0.0112
0.0104
0.0023
0.0011
T(K)
900
cp average
(J/(mol*K)) h,r T (kJ/mol)
12.0487464
36.7014815
137.57
29.8431909
29.1930199
T(K)
1200
cp average
(J/(mol*K)) h,r T (kJ/mol)
13.7325071
38.257037
138.21
30.1936182
29.3639601
T(K)
1500
cp average
cp at T (J/(mol*K)) (J/(mol*K)) h,r T (kJ/mol)
22.16253561 15.4162678
46.04518519 39.8125926
137.21
T (K)
T (K)
T (K)
900
cp at T
(J/(mol*K))
15.4274929
39.822963
30.5463818
29.5360399
1200
cp at T
(J/(mol*K))
18.7950142
42.9340741
31.2472365
29.8779202
1500
cp at T
(J/(mol*K))
22.1625356
46.0451852
31.9480912
30.2198006
31.94809117 30.5440456
30.21980057 29.5349003
137.21
Series1
800
1000
1200
1400
T (K)
2)
i
reactants
products
CO(g)
O2(g)
CO2(g)
h,r 289.15K=
298
hf 298.15K cp at T
(kJ/mol)
(J/(mol*K))
-2
-110.62
29.14
-1
0
29.39
2
-393.77
37.14
-566.3
T (K)
2)T=
900 K
i
reactants
products
CO(g)
O2(g)
CO2(g)
h,r 289.15K=
T (K)
298
900
hf 298.15K cp at T
(kJ/mol)
(J/(mol*K))
-2
-110.62
29.14
-1
0
29.39
2
-393.77
37.14
cp at T
(J/(mol*K))
30.5463818
31.8511681
46.8646154
1200 K
i
reactants
products
CO(g)
O2(g)
CO2(g)
h,r 289.15K=
T (K)
298
1200
hf 298.15K cp at T
(kJ/mol)
(J/(mol*K))
-2
-110.62
29.14
-1
0
29.39
2
-393.77
37.14
cp at T
(J/(mol*K))
31.2472365
33.0776638
51.7107692
1200 K
i
reactants
CO(g)
O2(g)
cp average
(J/(mol*K))
30.1936182
31.2338319
44.4253846
-566.3
T (K)
2)T=
cp average
(J/(mol*K))
29.8431909
30.620584
42.0023077
-566.3
T (K)
2)T=
Reaction 2)
T(K)
1000
cp at T
(J/(mol*K)) intercept
30.78
28.44
32.26
28.17
48.48
32.33
T (K)
298
1500
hf 298.15K cp at T
(kJ/mol)
(J/(mol*K))
-2
-110.62
29.14
-1
0
29.39
cp at T
(J/(mol*K))
31.9480912
34.3041595
cp average
(J/(mol*K))
30.5440456
31.8470798
products
CO2(g)
h,r 289.15K=
-393.77
-566.3
slope
0.0023
0.0041
0.0162
T(K)
900
h,r T (kJ/mol)
-570.09
T(K)
1200
h,r T (kJ/mol)
-568.80
T(K)
1500
h,r T (kJ/mol)
-565.38
T (K)
T (K)
T (K)
900
cp at T
(J/(mol*K))
30.5463818
31.8511681
46.8646154
1200
cp at T
(J/(mol*K))
31.2472365
33.0776638
51.7107692
1500
cp at T
(J/(mol*K))
31.9480912
34.3041595
56.5569231
-565.38
i
C2H5OH(l)
CO2(g)
Glc
hr,308
hf 298.15K cp at T
hf 308.15K
(kJ/mol)
(J/(mol*K)) (kJ/mol)
2
-235.47
73.65
-234.7335
2
-393.77
37.14
-393.3986
-1
-1032.525
226.08 -1030.2642
-225.955
-4.5
-226 kj/mol
i
H2O(g)
CO2(g)
Glc
O2
-6
-6
1
6
hr,T
T
278.15
288.15
298.15
308.15
yield
hf 298.15K cp at T
hf 5C
hf 15C
hf 35C
(kJ/mol)
(J/(mol*K)) (kJ/mol)
(kJ/mol)
(kJ/mol)
-242
33.58
-242.6716
-242.3358
-241.6642
-393.77
37.14
-394.5128
-394.1414
-393.3986
-1032.525
226.08 -1037.0466 -1034.7858 -1030.2642
0
29.39
-0.5878
-0.2939
0.2939
2782.095
2782.533
2782.314
2781.876
15456.0833
15458.5167
15457.3 15454.8667
hr,T kj/mol
2782.533
2782.314
2782.095
2781.876
3.55555556 molglc
4.97777778 mol etoh
228.977778 gEtOH/m2
6361.94844
6307200
0.10086803
0.01783285
kj/m2*a
energy invest
kj/m2*a
energy input
%
%enbioet/ensun
2782.6
2782.5
2782.4
2782.3
Series1
2782.2
Linear (Series1)
2782.1
2782
y = -0.0219x + 2788.6
R = 1
2781.9
2781.8
270
280
290
300
310