LAMPIRAN C

HASIL ANTARA
C.1. Kalibrasi Piknometer
Piknometer kosong (gr)
Piknometer + Aquadest (gr)
Massa Aquadest (gr)
Aquadest @ T=26.9 C (gr/mL)
V Piknometer sebenarnya (mL)

5.871
6.921
1.050
0.99654
1.053645614

C.2. Penentuan Densitas Methanol

Piknometer kosong (gr)
Piknometer + Methanol (gr)
Massa Methanol (gr)
Methanol (gr/mL)

5.871
6.690
0.819
0.777301

C.3. Kalibrasi Refraktometer

Sampel

Indeks Bias Literatur

Aquadest
Benzena
Methanol

1
1.332
1.327
1.49682

Indeks Bias
2
1.332
1.327
1.49682

3
1.332
1.327
1.49682

Rata-rata
1.332
1.49682
1.327

Data
Literatur
1.3325
1.501
1.3288

Kalibrasi Refraktometer
1.55
1.5
1.45

f(x) = 1.0179228769x - 0.0226680834

R = 0.9999500768

1.4
1.35
1.3
1.25
1.2
1.3

1.35

1.4

Indeks Bias Terbaca

1.45

1.5

C.4. Kalibrasi Pompa

Skala

Waktu (s)

0
10
20
30
40
50
60
70
80
90
100

45
45
45
45
45
45
45
45
45
45
45

1
0
69
170
240
310
350
390
410
410
440
460

Volume (mL)
2
0
72
180
240
310
350
390
410
430
440
460

Volume rata-rata (mL)

3
0
74
180
230
310
350
390
410
430
440
460

0
71.67
176.67
236.67
310.00
350.00
390.00
410.00
423.33
440.00
460.00

Kalibrasi pompa

Q (mL/s)

12.00

10.00

8.00

6.00

4.00

2.00

0.00

20

40

60

Skala pompa (%)

80

100

C.5. Indeks Bias Methanol Teknis

Sampel
Methanol
Teknis

Indeks Bias
3

1.327

1.327

1.327

Rata-rata

koreksi

1.327000

1.328053

120

C.6. Hubungan Inde

Volume (
No.
Metanol
1
0
2
1
3
2
4
3
5
4
6
5
7
6
8
7
9
8
10
9
11
10
Mr
Aquadest
Metanol

1.55

Q rata-rata
(mL/s)
0.00
1.59
3.93
5.26
6.89
7.78
8.67
9.11
9.41
9.78
10.22

120

Mr
18
34

In d e k s B ia s L it e ra t u r ( Te rko re k s i)

ngan Indeks Bias Dengan Konsentrasi

Volume (ml)
Massa (gram)
Aquadest Botol Kosong BK + aq BK +
10
6.368
16.346
9
6.437
15.445
8
6.453
14.453
7
6.489
13.502
6
6.436
12.453
5
6.318
11.331
4
6.059
10.077
3
6.322
9.325
2
6.342
8.353
1
6.349
7.356
0
6.088
6.088

aq + metanol
16.346
16.232
16.035
15.867
15.581
15.248
14.774
14.815
14.384
14.351
13.937

Indeks Bias Terbaca

1
2
3
1.332
1.332
1.332
1.3335
1.3335
1.3335
1.33502
1.33502
1.33502
1.33703 1.337035 1.337035
1.33904
1.33904
1.33904
1.34005
1.34005
1.34005
1.34005
1.34005
1.34005
1.33904
1.33904
1.33904
1.33702
1.33702 1.337025
1.332
1.332
1.332
1.327
1.327
1.327

Kurva Hubungan Antara Konsentrasi terhadap Indeks Bias

1.345
1.34
1.335
1.33
1.325
1.32

0.2

0.4

0.6

Fraksi mol Methanol (x)

0.8

1.

Indeks
Bias
Terbaca
Rata-Rata
1.332
1.3335
1.33502
1.337033
1.33904
1.34005
1.34005
1.33904
1.337022
1.332
1.327

as

1.2

Mol
Aquadest Metanol
0.553633
0
0.49827 0.022862
0.442907 0.045724
0.387543 0.068585
0.33218 0.091447
0.276817 0.114309
0.221453 0.137171
0.16609 0.160033
0.110727 0.182894
0.055363 0.205756
0
0.228618

Fraksi Mol
(Metanol)
0
0.043869516
0.093575047
0.15036413
0.215867159
0.292256453
0.382491827
0.490713002
0.622892635
0.787977052
1

Indeks
Bias
Literatur
(Terkoreks
1.333143
i)
1.33467
1.336217
1.338266
1.340309
1.341337
1.341337
1.340309
1.338254
1.333143
1.328053

C.8. Distilasi Refluks Parsial

Pengukuran
Massa Botol Kosong 1 (gram)
Massa Botol 1 + Cuplikan 3 (gram)
Massa Cuplikan 3 (gram)
Massa Botol Kosong 2 (gram)
Massa Botol + Cuplikan 5 (gram)
Massa Cuplikan 5 (gram)
Massa Botol Kosong 3
Massa Botol 3 + Cuplikan 8 (gram)
Massa Cuplikan 8 (gram)
Massa Botol Kosong 4
Massa Botol 4 + Bottom (gram)
Massa Sample Bottom (gram)
Massa Wadah (gram)
Massa Wadah + Distilat (gram)
Massa Distilat (gram)
Volume Distilat (ml)
Indeks Bias Cuplikan 3
Indeks Bias Cuplikan 3 Rata-Rata
Indeks Bias Cuplikan 3 Terkoreksi
Fraksi mol metanol di cuplikan 3
Indeks Bias Cuplikan 5
Indeks Bias Cuplikan 5 Rata-Rata
Indeks Bias Cuplikan 5 Terkoreksi
Fraksi mol metanol di cuplikan 5
Indeks Bias Cuplikan 8
Indeks Bias Cuplikan 8 Rata-Rata
Indeks Bias Cuplikan 8 Terkoreksi
Fraksi mol metanol di cuplikan 8
Indeks Bias Bottom
Indeks Bias Bottom Rata-Rata
Indeks Bias Bottom Terkoreksi
Fraksi mol metanol di Bottom
Indeks Bias Distilat
Indeks Bias Distilat Rata-Rata
Indeks Bias Distilat Terkoreksi
Fraksi mol metanol di Distilat
Temperatur Kolom di titik 3 (0C)
Temperatur Kolom di titik 5 (0C)
Temperatur Kolom di titik 8 (0C)
Temperatur Bottom (0C)

10
6.453
10.162
3.709
6.059
6.435
0.376
6.342
7.832
1.49
6.437
10.426
3.989
82.382
128.493
46.111
59
1.33603
1.336025
1.336025
1.336027
1.337242
0.63
1.33302
1.33302
1.33302
1.333020
1.334181
0.75
1.329
1.329
1.329
1.329000
1.330089
0.79
1.333
1.333
1.333
1.333000
1.334161
0.02
1.327
1.327
1.327
1.327000
1.328053
0.98
67
60
61
71

20
6.453
7.461
1.008
6.436
9.065
2.629
6.342
9.288
2.946
6.437
8.75
2.313
69.935
117.332
47.397
61
1.339045
1.33904
1.33904
1.339042
1.340311
0.52
1.33402
1.33402
1.33402
1.334020
1.335199
0.72
1.333
1.333
1.333
1.333000
1.334161
0.75
1.34005
1.34005
1.34005
1.340050
1.341337
0.2
1.328
1.328
1.328
1.328000
1.329071
0.96
69
62
63
73

30
6.453
7.371
0.918
6.088
8.08
1.992
6.342
6.38
0.038
6.437
8.711
2.274
69.935
92.845
22.91
29
1.33804
1.33804
1.33804
1.338040
1.339291
0.57
1.33502
1.33502
1.33502
1.335020
1.336217
0.69
1.331
1.331
1.331
1.331000
1.332125
0.82
1.34045
1.34005
1.34005
1.340183
1.341473
0.21
1.328
1.328
1.328
1.328000
1.329071
0.96
66
61
69
68

Waktu (Menit)
40
50
6.453
6.453
8.82
7.015
2.367
0.562
6.436
6.436
8.145
6.878
1.709
0.442
6.342
6.342
7.307
7.352
0.965
1.01
6.437
6.437
8.305
7.946
1.868
1.509
69.935
69.935
96.825
104.907
26.89
34.972
35
45
1.33703
1.33603
1.33703
1.33603
1.33703
1.33603
1.337030 1.336030
1.338263 1.337245
0.63
0.68
1.33401
1.332
1.33401
1.333
1.33401
1.333
1.334010 1.332667
1.335189 1.333821
0.72
0.76
1.329
1.329
1.33
1.329
1.33
1.329
1.329667 1.329000
1.330768 1.330089
0.91
0.92
1.34005
1.34005
1.34005
1.34005
1.34005
1.34005
1.340050 1.340050
1.341337 1.341337
0.21
0.21
1.328
1.327
1.328
1.327
1.328
1.327
1.328000 1.327000
1.329071 1.328053
0.96
0.98
69
69
63
66
65
64
73
74

60
6.453
7.045
0.592
6.436
6.482
0.046
6.342
7.68
1.338
6.437
7.418
0.981
69.935
106.088
36.153
47
1.33403
1.33403
1.33403
1.334030
1.335209
0.72
1.33
1.333
1.333
1.332000
1.333143
0.79
1.329
1.329
1.329
1.329000
1.330089
0.92
1.339045
1.33905
1.33905
1.339048
1.340317
0.2
1.327
1.327
1.327
1.327000
1.328053
0.98
69
66
65
74

70
6.453
7.09
0.637
6.436
6.422
-0.014
6.342
7.632
1.29
6.437
7.808
1.371
69.935
108.285
38.35
49
1.33703
1.33703
1.33703
1.337030
1.338263
0.63
1.3301
1.3301
1.3301
1.330100
1.331209
0.87
1.328
1.328
1.328
1.328000
1.329071
0.96
1.34005
1.34005
1.34005
1.340050
1.341337
0.21
1.327
1.327
1.327
1.327000
1.328053
0.98
69
66
69
74

80
6.453
7.675
1.222
6.436
6.666
0.23
6.342
7.114
0.772
6.437
7.335
0.898
69.935
106.795
36.86
47
1.33703
1.338
1.33703
1.337353
1.338592
0.61
1.33401
1.33401
1.33401
1.334010
1.335189
0.72
1.329
1.329
1.329
1.329000
1.330089
0.92
1.339045
1.339045
1.339045
1.339045
1.340314
0.2
1.327
1.327
1.327
1.327000
1.328053
0.98
65
66
69
75

90
6.322
9.232
2.91
6.436
7.368
0.932
6.453
7.309
0.856
6.437
7.33
0.893
69.935
103.207
33.272
43
1.33803
1.33803
1.33803
1.338030
1.339281
0.57
1.333005
1.33402
1.33402
1.333682
1.334855
0.75
1.329
1.329
1.329
1.329000
1.330089
0.92
1.339045
1.339045
1.339045
1.339045
1.340314
0.2
1.327
1.327
1.327
1.327000
1.328053
0.98
70
66
64
75

100
6.453
6.885
0.432
6.436
7.329
0.893
6.342
7.754
1.412
6.437
8.55
2.113
69.935
106.566
36.631
47
1.33804
1.33804
1.33804
1.338040
1.339291
0.57
1.33401
1.33401
1.33401
1.334010
1.335189
0.72
1.329
1.329
1.329
1.329000
1.330089
0.92
1.339045
1.339045
1.339045
1.339045
1.340314
0.2
1.327
1.327
1.327
1.327000
1.328053
0.98
71
67
64
75

110
6.453
7.349
0.896
6.436
6.483
0.047
6.342
11.279
4.937
6.437
8.033
1.596
69.935
103.217
33.282
43
1.33904
1.33904
1.33904
1.339040
1.340309
0.52
1.33502
1.33502
1.33502
1.335020
1.336217
0.69
1.329
1.329
1.329
1.329000
1.330089
0.92
1.33804
1.33804
1.33804
1.338040
1.339291
0.18
1.327
1.327
1.327
1.327000
1.328053
0.98
71
66
63
77

C.9. Effisiensi Tahap ()

Tahap Kurva Kesetimbangan
8

120
6.453
8.862
2.409
6.436
9.295
2.859
6.342
7.796
1.454
6.437
8.17
1.733
69.935
101.31
31.375
40
1.33804
1.33804
1.33804
1.338040
1.339291
0.57
1.33502
1.333
1.333
1.333673
1.334846
0.75
1.32805
1.32805
1.32805
1.328050
1.329122
0.96
1.33804
1.33804
1.33804
1.338040
1.339291
0.18
1.327
1.327
1.327
1.327000
1.328053
0.98
71
66
65
80

Waktu (Menit)
130
140
6.368
6.453
6.987
8.995
0.619
2.542
6.349
6.436
8.538
6.653
2.189
0.217
6.088
6.342
7.294
7.675
1.206
1.333
6.437
6.437
8.29
9.232
1.853
2.795
69.935
69.935
101.298
101.066
31.363
31.131
40
40
1.33904 1.339045
1.33904 1.339045
1.33904 1.339045
1.339040 1.339045
1.340309 1.340314
0.52
0.52
1.33603
1.33703
1.33603
1.33703
1.33603
1.33703
1.336030 1.337030
1.337245 1.338263
0.66
0.63
1.33
1.329
1.33
1.329
1.33
1.329
1.330000 1.329000
1.331107 1.330089
0.87
0.92
1.33703
1.33703
1.33703
1.33703
1.33703
1.33703
1.337030 1.337030
1.338263 1.338263
0.15
0.15
1.327
1.327
1.327
1.327
1.327
1.327
1.327000 1.327000
1.328053 1.328053
0.98
0.98
73
74
66
69
65
65
80
83

Tahap Nyata
8

150
6.453
8.439
1.986
6.436
6.88
0.444
6.342
6.95
0.608
6.437
9.251
2.814
69.935
102.23
32.295
42
1.33704
1.33704
1.33704
1.337040
1.338273
0.63
1.33904
1.33904
1.33904
1.339040
1.340309
0.52
1.333
1.333
1.333
1.333000
1.334161
0.75
1.33603
1.33603
1.33603
1.336030
1.337245
0.12
1.327
1.327
1.327
1.327000
1.328053
0.98
80
74
65
84

160
6.453
10.925
4.472
6.436
8.401
1.965
6.342
7.719
1.377
6.437
7.57
1.133
69.935
96.179
26.244
34
1.33502
1.33502
1.33502
1.335020
1.336217
0.69
1.33603
1.33603
1.33603
1.336030
1.337245
0.66
1.33603
1.33603
1.33603
1.336030
1.337245
0.66
1.33502
1.33502
1.33502
1.335020
1.336217
0.11
1.327
1.327
1.327
1.327000
1.328053
0.98
83
79
67
88

170
6.453
9.761
3.308
6.436
9.41
2.974
6.342
8.316
1.974
6.437
8.231
1.794
69.935
80.486
10.551
14
1.33602
1.33602
1.33602
1.336020
1.337235
0.66
1.33804
1.33804
1.33804
1.338040
1.339291
0.58
1.33502
1.33502
1.33502
1.335020
1.336217
0.69
1.33406
1.33406
1.33406
1.334060
1.335240
0.06
1.327
1.327
1.327
1.327000
1.328053
0.98
84
78
69
89

180
6.453
8.61
2.157
6.436
7.994
1.558
6.342
7.502
1.16
6.437
8.264
1.827
69.935
94.202
24.267
31
1.333
1.333
1.333
1.333000
1.334161
0.75
1.33401
1.33401
1.33401
1.334010
1.335189
0.72
1.33904
1.33904
1.33904
1.339040
1.340309
0.76
1.333
1.333
1.333
1.333000
1.334161
0.03
1.327
1.327
1.327
1.327000
1.328053
0.98
85
78
70
89

Xb
0.16

Xd
0.98

C.7. Kurva Kesetimbangan

Data Antoine
A
M-OH
16.5785
Aquadest
16.3872
Senyawa
M-OH
Aquadest

B
3638.27
3885.7

C
239.5
230.17

P1 sat
P2 sat
95.400
23.127
115.980
28.875
140.123
35.789
168.285
44.052
200.965
53.864
238.694
65.446
282.043
79.041
333.127
95.400
alpha Rata-rata

alpha
4.1251
4.0166
3.9152
3.8202
3.7310
3.6472
3.5683
3.4919
3.7894

Ptot

T. didih
63.1741
98.3159

T
63.1741
68.1741
73.1741
78.1741
83.1741
88.1741
93.1741
98.3159

x1
1.00
0.76
0.57
0.41
0.28
0.17
0.08
0.00

y1
1.00
0.92
0.83
0.73
0.60
0.44
0.25
0.00

Kurva Kesetimbangan

1
0.9
0.8

0.7
0.6
0.5
0.4
0.3
0.2
0.1
0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

95.4 kPa

0
1

0.8

0.9

0
1