103

H3-1 _____

_________

2 50
)1. H2PO4HPO42H2PO3HPO32H2PO2
(B) 2 (C) 3 (D) 4 (E) 5
C
(

H +
H +
H +
H2PO4HPO42H2PO3 H +

(
)2. (A) HC2O4C2O42 (B) H2C2O4C2O42 (C) CH3COOHCH3COO
NH4NH3 (E) HSO4SO42
B

(A) 1

(D)

(B)

(
)3. (A) (B) (C) (D)
D

(
)4. (A) (B) CO2 (C)
Al(OH)3 (D) 0.1 M pH 1
C

(
)5. 25 0.01 M pOH9 Ka (A) 108 (B) 105
(C) 109 (D) 1010
A

(
)6. H2SO4 Ka1 Ka21.2102 0.1 M H2SO4 [H] (A) 0.101 M (B) 0.11 M (C) 0.15 M
(D) 0.2 M
B
H2SO4HHSO4
0.1
0.1
0.1

HSO4 H SO42
0.1x 0.1x x
0.1xx
2

0.1x 1.210 x0.01[H ]0.10.010.11M

99 -

(
)7. HA CM CM Ka

(A)

(B)

(C)

(D)
1

HA H
CM(1)

CM

CM

(CM)2
Ka C (1) HA
M
1
KaCM2 CM 2 (B)

CM
(
)8. 108M NaOHaq pH (A) 8 (B) 7 (C) 6 (D) 5
B

pH
(
)9. 0.1 M KOH pH3 CH3COOH 25 mL KOH 15 mL Ka
104 B) 1.67105 (C) 6106 D) 5.4105

(A) 1.6

B
KaC20.06( 1.67)21.67105
99 -

(
)10. 25 NaOH 0.10 M 50 CH3COOH 0.10 M
NaOH

(A)

(B)

(C)

(D)

A
VNaOH 50 mL
99 -

(
)11. 2.04 KHP204 250 mL 50 mL NaOH
NaOH 20 mL NaOH M (A) 0.05 (B) 0.10 (C) 0.15 (D) 0.20
B
2.04 1
204 5 0.02CM1 CM0.1M

(
)12. HCl CH3COOH NaOH (A)
pH HClCH3COOH (B) pH HClCH3COOH (C) pH7
NaOHaqHClCH3COOH (D) NaOHaqHClCH3COOH
C
(A) HCl CH3COOH pH HClCH3COOH(B)HClNaOH
2

pH7
CH3COOHNaOH pH7 pH HClCH3COOH(C)(D) pH7 HClNaOH
CH3COOHNaOH
NaOHaq
NaOHaqHClCH3COOH

(
)13.
D

(A)

(B)

(C)

(D)

(A)(B)(C)

(
)14. 0.1 M (1) KNO3(2) NH4Cl(3) NaHSO4(4) Na2CO3 pH (A) (4)
(1)(3)(2) (B) (1)(2)(4)(3) (C) (3)(2)(1)(4) (D) (2)(3)(4)(1)
C
1014
Kw
(1)(2) NH4NH3HKa K 105 109
b

(3) HSO4SO42HKa2102

(4)

(
)15. HA 25 0.10 M NaA pH11 0.10 M HA pH
(B) 5

(C) 6

(D) 9

-3

(A) 3

NaA [OH ]10 M[OH ]

Kw
C K 103
a

1014
0.1 K Ka109HA [H] CKa
a

0.1109 10

pH5

(
)16. H2CO3HCO3 (A)
(C) (D)
B

(B)

(
)17. (A) 0.1 0.1 (B) 0.1 0.05
(C) 0.1 0.05 (D) 0.1 0.05
C

)18. Ka2105 CH3COOH CH3COONa pH 5.0 0.1 M CH3COOH

300 mL 0.2 M NaOH mL

(A) 50

(B) 100

(C) 150

(D) 200

B
0.2 M NaOH x mL CH3COOH 300.2 xmmolCH3COONa 0.2 x mmol[H]Ka
2105

nHA
n A-

105

300.2 x
0.2 x x100

(
)19.
B

(A) NF3

(B) HNO3

(C) NH3

(D) NO (E) CH3NH2

(A) NF3 N +3(B) HNO3 +5(C) NH3 N 3(D) NO N +2(E) CH3NH2

N 3 HNO3
3

(
)20.

(A) Na2S2O3Na2SO4H2S S 2

Cr2O3 Cr 6 (C) KHHClH2O H 1

2 (E) NaClNa2O2NaO2 Na 1

(B) K2CrO4K2Cr2O7

(D) KMnO4OF2H2O2 O

(
)21. (A) (B)
(C) A
(D) 8
C
(B)(C) F VIIA F 0
1 O VIA O 2

(
)22. (A) BaO2 (B) OF2 (C) KO2 (D) H2SO4
B

(
)23. (A) (B) (C)
(D)
B
(A)(C)(D)
99 -

(
)24. 30.0 Sn2 10.0 KMnO4 (0.120M) Sn2
(A) 0.100 M (B) 0.200 M

(C) 0.360 M

(D) 0.900 M

Sn2Sn4 n2
MnO4Mn2 n5

N1V1N2V2
(M2)30.0(0.1205)10.0
M0.100(M)

(
)25. 500 mL 0.12 M KMnO4(aq) STP SO2(g)
1.12 (D) 4.9 (E) 1.23
B
MnO4 + 8 H + + 5 e Mn 2+ + 4 H2O
SO2 + 2 H2O SO42 + 2 e + 4 H +
STP x SO2
x
500
2 = 0.12
5
22.4
1000
x = 3.36 (L)

1 49
1.
4

(A) 2.45

(B) 3.36

(C)

(1) H2O(2) NaHCO3(3) NH3(4) CH3COOH(5) H3PO2

(1) OH
(2) CO32
(3) NH2
(4) CH3COO(5) H2PO2

2.
(1) HS(2) HCO3(3) H2O(4) NH3(4) HPO42

(1)
(2)

H2S

S2

2
H2CO3 CO3

(3)

H3O

OH

(4)

NH4

NH2

3
(5) H2PO4 PO4

3. (1)
(1) HClO2
(2) H3PO3
(3) Bi(OH) 3
(4) H2S2O5

(2)

(3)

(4)

(5)

(5) H3PO4

4.
(1) CrO2Cl2 (2) S2O32 (3) BaO2
(1)6(2)2(3)2

(4) ClF3

(5) CsO2

1
(4)3(5) 2

5.
(1)H3PO4H3PO3H3PO2
(2)H2SO4H2SO3
(3)Mg(OH) 2Ca(OH) 2
(4)CH3COOHCH2FCOOHCH2ClCOOH
(5)CrOCr2O3CrO3
(1) H3PO3H3PO2H3PO4(2) H2SO4H2SO3 (3) Ca(OH) 2Mg(OH) 2(4) CH2FCOOHCH2ClCOOHCH3COOH(5) CrO3
Cr2O3CrO

6.
(1) NaOH CH3COOH
(2) NaOH HCl
(3) HNO3

(1)
(2)
(3)

7. 2.0 M 20 mL 1.0 M NaOH 30 mL

(1)__________
(2)__________M
(1) NaOH(2) 0.6 M
HCl NaOH NaCl H2O
0.04
0.03
0.01

0.03 mol
0.03
0

0.03

0.03
(2) [Na] 0.05 0.6 M

8.
(1) NaF
(2) NH4Cl
(1) FH2O
HFOH
(2) NH4H2O
H3ONH3 NH4
HNH3

9. 100 mL 0.20 M CH3COOH pH5 NaOH Na23CH3COOH Ka

2105
0.53 g
X mol
CH3COOHOH CH3COOH2O
0.02 mol
X
X
X
X
X
0.02X
X

CH3COOH(aq)
H(aq)CH3COO(aq)
0.02X
0.1 M

X
0.1

[CH3COOH]
[H]Ka [CH COO]
3

0.02X0.1
1052105
X0.1
X0.013 mol
0.01340=0.53 g

10. HClO ClO HClO 20HClO Ka2.7108 pH8

ClO HClO

2.7

11.
H2O2MnO4H O2Mn2H2O
5 H2O22 MnO46 H 5 O22 Mn28 H2O
7

52

H2O2MnO4H O2Mn2
H2O

125

5 H2O22 MnO46 H 5 O22 Mn28 H2O

12.
(1) Cl2(g)+ OH (aq) Cl (aq)+ OCl (aq)
(2) Cr2O72(aq)+ I (aq)+ H +(aq) Cr 3+(aq)+ I2(aq)+ H2O(l)
(3) Cu(s)+ HNO3(aq) Cu(NO3) 2(aq)+ NO2(g)+ H2O(l)
(1) Cl2(g)+ 2 OH (aq) Cl (aq)+ OCl (aq)+ H2O(l)
(2) Cr2O72(aq)+ 6 I (aq)+ 14 H +(aq) 2 Cr 3+(aq)+ 3 I2(aq)+ 7 H2O(l)
(3) Cu(s)+ 4 HNO3(aq) Cu(NO3) 2(aq)+ 2 NO2(g)+ 2 H2O(l)
(1)Cl2(g)+ 4 OH (aq) 2 OCl (aq)+ 2 e + 2 H2O(l) ( 1/2)
Cl2(g)+ 2 e 2 Cl (aq) ( 1/2)
Cl2(g)+ 2 OH (aq) Cl (aq)+ OCl (aq)+ H2O(l)
(2)2 I (aq) I2(s)+ 2 e ( 3)
Cr2O72(aq)+ 6 e + 14 H +(aq) 2 Cr 3+(aq)+ 7 H2O(l) ( 1)
Cr2O72(aq)+ 6 I (aq)+ 14 H +(aq) 2 Cr 3+(aq)+ 3 I2(aq)+ 7 H2O(l)
(3)Cu(s) Cu 2+(aq)+ 2 e ( 1)
NO3(aq)+ 2 H +(aq)+ e NO2(g)+ H2O(l) ( 2)
Cu(s)+ 2 NO3(aq)+ 4 H +(aq) Cu 2+(aq)+ 2 NO2(g)+ 2 H2O(l)
Cu(s)+ 4 HNO3(aq) Cu(NO3) 2(aq)+ 2 NO2(g)+ 2 H2O(l)

13.
(1) H2O2MnO4HO2Mn2H2O
(2) HMnO42MnO2nO4
(3) FeS2HNO3Fe3SO42NOH2O
(4) Na2Cr2O7FeSO4H2SO4Fe2(SO4) 3Cr2(SO4) 3Na2SO4H2O
(1) 5H2O22MnO46H5O22Mn28H2O
(2) 4H 3MnO42 MnO22MnO4 2H2O
(3) FeS25NO34HFe32SO425NO2H2O
(4) Na2Cr2O76FeSO47H2SO43Fe2(SO4) 3Cr2(SO4) 3Na2SO47H2O

14. 0.10 M CH3COOH

(1)[H]
(2)
(3) PH Ka1.8105 M
(1) 1.34103(2) 1.34(3) 2.87

(1) HA CH3COOH
HA(aq)
H(aq) A(aq)
0.1 M
X
X
0.1X X

X
X

X2
Ka 0.1X 1.8105
X2
X Ka 0.1 1.8105
X1.34103[H]
1.34103
(2)
1001.34
0.1
(3) PH log[H]2.87

15. 25 C H2CO3 Ka1 = 4.4 10 7Ka2 = 4.7 10 11 0.2 M H2CO3(aq)

(1) [H +] =
(2) [HCO3] =
(3) [CO32] =
(4) [H2CO3] =
(1) 2.97 10 4 M
(2) 2.97 10 4 M
(3) 4.7 10 11 M
(4) 0.2 M
0.2 M H2CO3(aq)

H2CO3
0.2 x

HCO3
xy

H+
+ HCO3
x+y
xy
H+

+ CO32
x+y

Ka1Ka2
x 0.2y x

x2
= 4.4 10 7
0.2
xy
= 4.7 10 11
x
[CO32] = y = 4.7 10 11( M )

[H +] = [HCO3] = x = 2.97 10 4( M )
[H2CO3] = 0.2 2.97 10 4 = 0.2( M )