Table 1: The concentration of hydrochloric acid varied with time

Concentration of acid (mol.dm 3) 0.2 0.4 0.6 0.8 1.0

Time to collect 10cm 3 hydrogen (s) 60 30 20 15 12
i) State the rate expression of the reaction process.
(5 Marks)
ii) Plot the data to determine the order of reaction and the rate constant.
(8 Marks)
QUESTION 4
a) The nitrogen oxide production through an oxidation process of ammonia occurs
efficiently at 298C. The chemical reaction of the process is as follows:
02 (g) + 4 NH3 (g) -) 6 H20 (I) + 4 NO (g)
i) Calculate the standard Gibbs energy change for the oxidation process at 298C.
(12 Marks)
(ii) Estimate the equilibrium constant, Kofthe process.
(5 Marks)
b) One of the criteria that offer response to the equilibrium conditions is temperature.
Interpret the relationship between the equation below with the equilibrium constant, K at
two different temperature.
A-G' = ArH - TArS

(8 Marks)
END OF QUE