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e


, 23.05.2009.
II

.
! .
a
..

!
:
: H=1; Li=7; B=11; C=12; N=14; O=16; F=19; Na=23;
Mg=24; Al=27; Si=28; P=31; S=32; Cl=35,5; K=39; Ca=40; Cr=52 ; Mn=55; Fe=56;
Co=59; Ni=59; Cu=64; Zn=65; Ge=73; As=75; Br=80; Rb=85; Sr=88; Mo=96;
Ag=108; Cd=112; Sn=119; I=127; Cs=133; Ba=137; Pt = 195; Hg=201; Pb=207;
Bi=209; Ra=226; U=238
: = 00C; 101,3 kPa.
: 22,4 dm3/mol .
: 6x1023
: 8,314 J/K mol
: 96500 C
: 6,62 x 10-34 J s
150

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1. (c)
(A, B, C D)
(t).

.

2. ( kJ/mol)
X, Y Z.
, (
)
?

Ei(1)

Ei(2)

Ei(3)

Ei(4)

577

1816

2744

11580

496

4563

6913

9541

737

1450

7731

10545

3. 100,00 g
153,33 g 12,00 g .
.

g/mol
( )

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4.
(CH3CN) 65 : 35.
,

( , CH3CN : H2O = 4 : 1 () 3
: 2 ()). , ( ),
, ?
: H2O =

:1

(2 .)
5. 200 cm3 - 18,0
% ( = 1,20 g/cm3), 5,00 ,
- 22,0 % ( = 1,25 g/cm3).
)

m = __________ g
( )
) (..) .

V = __________ dm3
(1 .)
) ?
t = ___________ h
(1 .)

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6. (A, B C)
(IV).
: 1- , 2-
, 3-

A=
B=
C=

7. -, .
, .
, .

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8. , 10 cm3,
10 g.
, 10,10 g.
, , 10 g,
9,44 g.
?

9. , = 1,049 g/cm3,
500 cm3
0,1 mol/dm3,
10 % ?
1,00 g/cm3 ,
1,8 10-5.

V = ______________cm3
(1 .)
10. 0,7000 g
,
100 cm3 . je 25,00 cm3
- .
,
.

0,02

mol/dm .

18,00 cm . % .
_________________ %
(2 .)

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11. 30 %- -
: , .
20 %- .
)

.
)
.
(, ) .

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12. ,
.
.

_________________

13. /
NaH2PO4 0,1 mol/dm3
- 0,1 mol/dm3.
K1 (H3PO4) = 1x10-2
K2 (H3PO4) = 1x10-7
K2 (H3PO4) = 1x10-12

1) -

1,22,8

2) -

3,14,4

3) -

4,26,2

4)

5,57,5

5)

8,010,1

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14. :
) ________Fe + ________Cl2 = __________________________
) ________Fe + ________ HBr = __________________________
) ________Fe + ________ I2 = _____________________________
- (

:
Cl2 (g) + 2e 2 Cl- (aq)

Eo = + 1,36 V

Br2 (l) + 2e 2 Br- (aq)

Eo = + 1,08 V

I2 (s) + 2e 2 I- (aq)

Eo = + 0,54 V

Fe3+ (aq) + e Fe2+ (aq)

Eo = + 0,77 V

Fe2+ (aq) + 2e Fe (s)

Eo = 0,44 V

2 H3O+ (aq) + 2e H2 (g) + 2 H2O (l)

Eo = 0,00 V

15. - ,
0,100 mol/kg, -0,345C.
1,86 K kg mol-1.
= ____________
(2 .)
16. (II)-
8 % (
80 % () 20 % ).

. (II)-
?
n(CO)/n(O2) = ________________
(1 .)

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17. .

?
) n=1 n=2
) n=3 n=1
) n=2 n=1
) n=1 n=3
) n=4 n=1

18.

H2 (g) + I2 (g)

2 HI (g)

= 0,105 472 .
1,0 mol H2, 1,0 mol I2 3,0 mol HI
10 dm3

472 , HI

= _____________ mol/dm3
(4 .)

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19.

250

cm3

0,01 mol/dm3 250 cm3

0,05 mol/dm3.
[Ca2+] = ______________ mol/dm3
(1 . .)

[NO3-] = ______________ mol/dm3

(1 . .)

[H+] = ______________ mol/dm3

(1 . .)

[OH-] = ______________ mol/dm3

(1 . .)
20.
PbCl2 (s) + Cl2 (g) = PbCl4 (l).

Pb (s) + Cl2 (g) = PbCl2 (s)

Ho = 359,4 kJ/mol,

Pb (s) + 2 Cl2 (g) = PbCl4 (l)

Ho = 329,3 kJ/mol.

Ho = ____________kJ/mol
( 1 .)

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II

1.

2 + 3D 3A + C

2.

23

3.

98 g/mol

4.

A : H2O = 4,33 : 1

1+2

5.

a) 197 g

b) 27,3 dm3

v) 25,9 h

A = SiO32-

B = Si4O116-

C = Si2O52-

6.

7.

ZnBr2 + 2 NaOH Zn(OH)2 + 2 NaBr

Zn(OH)2 + 2 NaOH Na2[Zn(OH)4]
8.

Cu

9.

0,6 cm3

10.

20,57%

11. )

3x0,5

Al + KOH + 3 H2O K[Al(OH)4] + 3/2 H2

Si + 2 KOH + 4 H2O K2[Si(OH)6] + 2 H2 ( K2SiO3)
Br2 + 2 KOH KBr + KBrO + H2O 3 Br2 + 6 KOH 5 KBr + KBrO3 +
3 H 2O
)

3x0,5

K[Al(OH)4] + HCl KCl + Al(OH)3 + H2O

Al(OH)3 + 3 HCl AlCl3 + 3 H2O
K[Al(OH)4] + 4 HCl KCl + AlCl3 + 4 H2O
K2SiO3 + 2 HCl 2 KCl + H2SiO3
KBr + KBrO + 2 HCl Br2 + 2 KCl + H2O

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12.

+2

13.

14.

a) 2 Fe + 3 Cl2 = 2FeCl3

) Fe + 2 HBr = FeBr2 + H2

) Fe + I2 = FeI2

15.

0,85

16.

10,3

17.

v)

18.

0,0698 mol/dm3

19.

[ Ca2+] = 5,0 x 10-3 mol/dm3

0,75

[ NO3-] = 2,5 x 10-2

0,75

[H+]= 1,5 x 10-2

0,75

[OH-]= 6,7 x 10-13

0,75

30,1 kJ/mol

20.