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Chemistry HELP-SHEET
STRUCTURAL ISOMERISM
Definition

When compounds having the

SAME MOLECULAR FORMULA

but

DIFFERENT STRUCTURAL FORMULA

Chain

different arrangements of the carbon skeleton


similar chemical properties
slightly different physical properties
more branching = lower boiling point

butane

Positional

2-methylpropane

same carbon skeleton


Br

same functional group

Br

functional group is in a different position


similar properties

1-bromopropane

pent-1-ene

Functional
Group

2-bromopropane

pent-2-ene

different functional group


different chemical properties
different physical properties

ethanol
ALCOHOL

methoxymethane
ETHER

Examples
ALCOHOLS - ETHERS
ALDEHYDES - KETONES

CARBOXYLIC ACIDS - ESTERS

propanal
ALDEHYDE

propanoic acid
CARBOXYLIC
ACID

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propanone
KETONE

methyl ethanoate
ESTER

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