Molecular Computing SP 2002

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Molecular Computing

by Jason Bryant
and
Richard Overstreet

Why do we need smaller


computers?

Increased Complexity=Increased
Computing Power
To achieve this complexity, the
components of a computer must be
made smaller.
There are both practical and scientific
limitations on current silicon-based
technology (Moores Law)
One solution lies in molecular switches

What is a molecular
switch?

The use of molecules to construct


electronic components that
perform the same function as a
macroscopic counterpart.
Wires, logic gates, memory
circuits, etc.

What kind of molecule do


we need?

What do we need it to do?


Ideally, transmit or store electrons
Need an empty low energy orbital
Can create a "pi-conjugated
system"

Pi Conjugated system

These pi bonds act as wires by


allowing the passage of electrons

www.d.umn.edu/~pkiprof/chemweb/ Overlap/overlap2.html

Benefits of the Molecular


Switch

Obvious size advantage


High current flow generates little
heat
Self-Assembly=Cheap, identical
production in mass quantities
High potential circuit density
Non-volatile RAM

Need more than just wires

Need Transistors
Exploiting the pi orbital overlap
Now we have the concepts, how do
we use it?

Mark Reed and James Tour

Base molecule was the Benzine


Ring

http://www.sciam.com/2000/0600issue/0600reed.html

Properties of Benzine
Dithol

Allowed for
trapping of
electrons
Varying voltage
controlled
conductive and
nonconductive
state
http://www.sciam.com/2000/0600issue/0600reed.html

How could they turn it on and


off?

Addition of NO2 and NH2 to the


center ring created asymmetry
that allows for twisting with
applied voltage.

http://www.sciam.com/2000/0600issue/0600reed.html

So how did they build it?

Self assembly
Need to be able
to attach to metal
surfaces
Addition of thiols.

http://www.sciam.com/2000/0600issue/0600reed.html

Self Assembly Process

http://www.sciam.com/2000/0600issue/0600reed.html

Help from
Photolithography

For now, help from current


semiconductor technology
Creates selected regions for self
assembly
Now we have something
resembling current computer
architecture

Hurdles

The Molecular
Transistor- under
development
Connecting
molecular switches
Logic Gates

Notes

Mark A. Reed and James M. Tour


Computing with Molecules Scientific
American June 2000

http://www.sciam.com/2000/0600issue/0600reed.html

Ben Feringa, editor. Molecular Switches


(Wiley-VCH: New York) 2001
David Rotman Molecular Computing
Technology Review May/June 2000
University of Minnesota Inorganic
Chemistry Website www.d.umn.edu/~pkiprof/chemweb
/ Overlap/overlap2.html 2001

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