Unit 10: Kinetics

Clicker Quiz 2
Use experimental data to:
Determine order of reaction
Determine rate constant
Relate reaction order to rate laws.
Perform rate calculation with respect to
reactant concentration and time

Multiple experiments were conducted for the reaction

below. Which experiments should be used to determine
the order of the reaction with respect to oxygen?

2NaCl +O2 Na2O + Cl2

Experimen Initial Rate
Initial
Initial
t#
mol/(L s) concentrati concentrati
on
on
[NaCl]o
[O2]o
1
2
3
4

A) 1 & 4
D) 1 & 2

0.75x10-2
0.12
0.75x10-2
0.30x10-1

B) 1 & 3
E) 2 & 3

1.20
4.80
2.40
1.20

C) 3 & 4
F) 2 & 4

0.25
1.00
0.25
0.50

What is the order of the reaction with respect to oxygen?

2NaCl +O2 Na2O + Cl2

Experimen Initial Rate
Initial
Initial
t#
mol/(L s) concentrati concentrati
on
on
[NaCl]o
[O2]o
1
2
3
4

0.75x10-2
0.12
0.75x10-2
0.30x10-1

1.20
4.80
2.40
1.20

0.25
1.00
0.25
0.50

Numerical Answer (Whole number)

What is the order of the reaction with respect to sodium

chloride?

2NaCl +O2 Na2O + Cl2

Experimen Initial Rate
Initial
Initial
t#
mol/(L s) concentrati concentrati
on
on
[NaCl]o
[O2]o
1
2
3
4

0.75x10-2
0.12
0.75x10-2
0.30x10-1

1.20
4.80
2.40
1.20

0.25
1.00
0.25
0.50

Numerical Answer (Whole number)

What is the overall order of the reaction?

2NaCl +O2 Na2O + Cl2

Experimen Initial Rate
Initial
Initial
t#
mol/(L s) concentrati concentrati
on
on
[NaCl]o
[O2]o
1
2
3
4

0.75x10-2
0.12
0.75x10-2
0.30x10-1

1.20
4.80
2.40
1.20

0.25
1.00
0.25
0.50

Numerical Answer (Whole number)

What is the rate constant for this reaction?

2NaCl +O2 Na2O + Cl2

Experimen Initial Rate
Initial
Initial
t#
mol/(L s) concentrati concentrati
on
on
[NaCl]o
[O2]o
1
2
3
4

0.75x10-2
0.12
0.75x10-2
0.30x10-1

1.20
4.80
2.40
1.20

0.25
1.00
0.25
0.50

Numerical Answer (Correct Sig Figs)

What is the rate constant units for this reaction?

2NaCl +O2 Na2O + Cl2

Experimen Initial Rate

Initial
Initial
t#
mol/(L s) concentrati concentrati
on
on
[NaCl]o
[O2]o
1
2
3
4

0.75x10-2
0.12
0.75x10-2
0.30x10-1

A) L2/(mol2s)
C) mol2/(L2s)
E) mol3/(L3s)

1.20
4.80
2.40
1.20

B) L/(mols)
D) mol2/L2
F) mol3/L3

0.25
1.00
0.25
0.50

Which integrated rate law is expressed by

the following graph?

A) Zero order
B) First order
C) Second order
D) Third order
E) Not enough information given

An experiment is carried out to measure

the rate of a reaction, which is first
order. After 10 minutes, the
concentration of the reactant drops from
5.50x10-2 M to 8.90x10-3 M. Calculate the
initial rate in Mmin-1 of the reaction.
Numerical Answer (Correct Sign and Sig Figs)

Multiple experiments were conducted for the reaction

below. Which experiments should be used to determine
the order of the reaction with respect to oxygen?

2NaCl +O2 Na2O + Cl2

Experimen Initial Rate
Initial
Initial
t#
mol/(L s) concentrati concentrati
on
on
[NaCl]o
[O2]o
1
2
3
4

A) 1 & 4
D) 1 & 2

0.75x10-2
0.12
0.75x10-2
0.30x10-1

B) 1 & 3
E) 2 & 3

1.20
4.80
2.40
1.20

C) 3 & 4
F) 2 & 4

0.25
1.00
0.25
0.50

What is the order of the reaction with respect to oxygen?

2NaCl +O2 Na2O + Cl2

Experimen Initial Rate
Initial
Initial
t#
mol/(L s) concentrati concentrati
on
on
[NaCl]o
[O2]o
1
2
3
4

0.75x10-2
0.12
0.75x10-2
0.30x10-1

1.20
4.80
2.40
1.20

Numerical Answer (2)

0.25
1.00
0.25
0.50

What is the order of the reaction with respect to sodium

chloride?

2NaCl +O2 Na2O + Cl2

Experimen Initial Rate
Initial
Initial
t#
mol/(L s) concentrati concentrati
on
on
[NaCl]o
[O2]o
1
2
3
4

0.75x10-2
0.12
0.75x10-2
0.30x10-1

1.20
4.80
2.40
1.20

Numerical Answer (0)

0.25
1.00
0.25
0.50

What is the overall order of the reaction?

2NaCl +O2 Na2O + Cl2

Experimen Initial Rate
Initial
Initial
t#
mol/(L s) concentrati concentrati
on
on
[NaCl]o
[O2]o
1
2
3
4

0.75x10-2
0.12
0.75x10-2
0.30x10-1

1.20
4.80
2.40
1.20

Numerical Answer (2)

0.25
1.00
0.25
0.50

What is the rate constant for this reaction?

2NaCl +O2 Na2O + Cl2

Experimen Initial Rate
Initial
Initial
t#
mol/(L s) concentrati concentrati
on
on
[NaCl]o
[O2]o
1
2
3
4

0.75x10-2
0.12
0.75x10-2
0.30x10-1

1.20
4.80
2.40
1.20

Numerical Answer (0.12)

0.25
1.00
0.25
0.50

What is the rate constant units for this reaction?

2NaCl +O2 Na2O + Cl2

Experimen Initial Rate

Initial
Initial
t#
mol/(L s) concentrati concentrati
on
on
[NaCl]o
[O2]o
1
2
3
4

0.75x10-2
0.12
0.75x10-2
0.30x10-1

A) L2/(mol2s)
C) mol2/(L2s)
E) mol3/(L3s)

1.20
4.80
2.40
1.20

B) L/(mols)
D) mol2/L2
F) mol3/L3

0.25
1.00
0.25
0.50

Which integrated rate law is expressed by

the following graph?

A) Zero order
B) First order
C) Second order
D) Third order
E) Not enough information given

An experiment is carried out to measure

the rate of a reaction, which is first
order. After 10 minutes, the
concentration of the reactant drops from
5.50x10-2 M to 8.90x10-3 M. Calculate the
initial rate in Mmin-1 of the reaction.
Numerical Answer (0.00461)

Heres your goal for the following

AP question.
Complete the question independently (6 minutes)
Compare your answer with your table partner.
Which answer is more convincing and why?
Choose the best answer (6 minutes)
Find another table and compare answers. Which
answer is more convincing and why? Choose the
best one. 75% of group must agree on the
answer. (6 minutes)
ALL ANSWERS MUST COME WITH
JUSTIFICATION USING SCIENCE!

2012 #3