M HP: CS115

Nhm: 3b

BI 1: PH V DUNG DCH IM
Ni dung phc trnh:
1. Phng php chun b 50ml dung dch im Na.Acetate.
(ph=4.4)

PH
A
B

Trong :

4.4
30.5
19.5

A: HAc 0.2M
B: NaAc 0.2M

a) Cch pha 30.5ml dung dch HAc 0.2M t HAc m c:

11.05ml dung dch HAc m c
HAc 0.2M
x

1000ml dung dch

30.5 dung dch HAc 0.2M

====>

x=

11.05 30.05
1000

= 0.337025ml

Quy trnh pha:

20ml
nc

0.377ml dd
HAc m c

30.5ml dd
HAc 0.2M

b) Cch pha 19.5ml dung dch NaAc t

C2H3O2Na.3H2O
116.4g C2H3O2Na.3H2O
n

CM = v

n=CM V = 0.2

1000ml dd NaAc 0.2M

19.5 10-3 = 3.9 10-3mol

m (C2H3O2Na.3H2O) = n.M = 3.9 136 = 0.5304g

Quy trnh pha:

Cho nc
ct vo
n khi dd
c

M HP: CS115

Nhm: 3b

0.5304g

C2H3O2Na.3H2

19.5ml dd
NaAc 0.2M

10ml nc
ct
Vy quy trnh pha dung dch m NaAc 0.2M pH= 4.4

50ml dd m
Na.Acetate
0.2M pH=4

Dd HAc
0.2M

dd NAc
0.2M

2. Phng php chun b 50ml dd m phosphate 0.2M

pH=6.5
pH
C
D

Trong :

6.5
34.25
15.75

C: NaH2PO4 0.2M
D: Na2HPO4 0.2 M

a) Cch pha 54.25ml dung dch NaH2PO4 0.2M t Na2HPO4

Ta c: 27.8g NaH2PO4 1000ml dd NaH2PO4 0.2M
x

x=

34.25ml dd NaH2PO4 0.2M

27.8 34.25
1000

= 0.95215g

Quy trnh pha:

0.95215
g
NaH2PO4

20ml
20ml
nc
nc
ct

Cho nc ct
vo cho n
khi dd c
34.25ml dd
NaH2PO4
0.2M

M HP: CS115

Nhm: 3b

b) Cch pha 15.75ml dd Na2HPO4 0.2M t Na2HPO4.7H2O

53.6g Na2HPO4.7H2O
n

CM = v

1000ml dd Na2HPO4 0.2M

n = CM V = 0.2 15.75.10-3 = 3.15.10-3 mol

m = n.M = 3.15 10-3 268 = 0.8442g

Quy trnh pha:

0.8442g

10ml
nc

Na2HPO4.7H2

Cho nc ct
vo cho n khi
dd c
15.75ml

15.75ml dd

Na2HPO4
0.2M

Vy quy trnh pha 50ml dd m phosphate 0.2M pH=6,5

34.25ml dd

NaH2PO4

50ml dd m
phosphate 0.2M
pH=6.5

15.75 ml dd

Na2HPO4 0.2M

M HP: CS115

3.
1. 7
2.
3.
4.
5.

Nhm: 3b

Bi tp v pH v dung dich m :
5
Is base solution
Rophilic
atomic

6. [H ][OH ] = 10 , [H ] = x [OH ] =
+

-14

1014
.
X

7. H+ / OH8. ion concentration and separation

9. phobic
10. micropipete
11.
12. chart
13. Interaction of hydrogen.
14.
15.
Buffer solution
16. Can give hydrogen ion
17.
18. is a proton acid residues, which can get hydrogen ion
19.
20. a phosphate
21. a carbonate
22.
23. pH l ch s o hot ng ca cc ion hir (H+) trong dung
dch v v vy l axt hay baz ca n.
pKa l mt i lng c trng cho mnh yu ca acid nh
Ka
S khc bit gia pH v pKa : pH l mt thc o nng ion
hydro trong khi pKa l thc o mc phn ly ca acid.
24.

Acid formic mnh hn acetic acid. Acid mnh c khuynh hng

cho proton d dng hn acid yu.

M HP: CS115

Nhm: 3b

M HP: CS115

Nhm: 3b