Mercado, Roger Jayson A.

2 B.S ChE

Compon
ent
(1) oxylene
(2) water

Thermodynamics
March 13,2015

14.04
15
16.38
72

3358.
79
3885.
7

212.0
41
230.1
7

I. Constant Temp: 50C.

X1

Tem
p.

X2
1

50

0.9

0.1

50

0.8

0.2

50

0.7

0.3

50

0.6

0.4

50

0.5

0.5

50

0.4

0.6

50

0.3

0.7

50

0.2

0.8

50

0.1

0.9

50

50

P1*
3.399
7
3.399
7
3.399
7
3.399
7
3.399
7
3.399
7
3.399
7
3.399
7
3.399
7
3.399
7
3.399
7

P2*
12.405
3
12.405
3
12.405
3
12.405
3
12.405
3
12.405
3
12.405
3
12.405
3
12.405
3
12.405
3
12.405
3

P1
P2
Ptotal
3.399
3.399
7 0.0000
7
3.059
4.300
8 1.2405
3
2.719
5.200
8 2.4811
8
2.379
6.101
8 3.7216
4
2.039
7.001
8 4.9621
9
1.699
7.902
9 6.2026
5
1.359
8.803
9 7.4432
0
1.019
9.703
9 8.6837
6
0.679
10.60
9 9.9242
42
0.340 11.164 11.50
0
7
47
0.000 12.405 12.40
0
3
53

Y1
Y2
1.000
0.00
0
00
0.711
0.28
5
85
0.523
0.47
0
70
0.390
0.61
0
00
0.291
0.70
3
87
0.215
0.78
1
49
0.154
0.84
5
55
0.105
0.89
1
49
0.064
0.93
1
59
0.029
0.97
6
04
0.000
1.00
0
00

II. Constant Pressure: 780mmHg

X1

X2
1

0.9
0.8

0.1
0.2

Temp. P1*
P2*
145.3 780.00 3151.3
84
0
96
135.7 600.39 2396.4
00
7
30
128.5 490.19 1939.2

P1
P2
780.0
00
0.000
540.3
239.6
57
43
392.1
387.8

Ptotal
780.0
00
780.0
00
780.0

Y1
1.00
0
0.69
3
0.50

Y2
0.00
0
0.30
7
0.49

0.7

0.3

0.6

0.4

0.5

0.5

0.4

0.6

0.3

0.7

0.2

0.8

0.1

0.9

49
122.9
11
118.2
74
114.3
48
110.9
52
107.9
65
105.3
04
102.9
06
100.7
28

8
415.21
5
360.69
6
319.17
3
286.44
1
259.94
6
238.04
1
219.61
6
203.89
5

08
1631.1
64
1408.9
56
1240.8
27
1109.0
39
1002.8
80
915.49
0
842.26
5
780.00
0

58
290.6
51
216.4
18
159.5
86
114.5
76
77.98
4
47.60
8
21.96
2
0.000

42
489.3
49
563.5
82
620.4
14
665.4
24
702.0
16
732.3
92
758.0
38
780.0
00

00
780.0
00
780.0
00
780.0
00
780.0
00
780.0
00
780.0
00
780.0
00
780.0
00

3
0.37
3
0.27
7
0.20
5
0.14
7
0.10
0
0.06
1
0.02
8
0.00
0

7
0.62
7
0.72
3
0.79
5
0.85
3
0.90
0
0.93
9
0.97
2
1.00
0

Pxy Diagram
14.0000
12.0000
10.0000
8.0000

Pressure (KPa)

BP
LINE
6.0000

DP LINE

4.0000
2.0000
0.0000
0

0.1 0.2

0.3 0.4

0.5

0.6 0.7

Mole Fraction O-Xylene

T=50C

0.8

0.9

Pxy Diagram
14.0000
12.0000
10.0000
8.0000

Pressure (KPa)

BP LINE

6.0000

DP LINE

4.0000
2.0000
0.0000
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Mole Fraction Water

T=50C

Txy Diagram
160.000
140.000
120.000
100.000

Temperature (C)

80.000

BP LINE

60.000

DP LINE

40.000
20.000
0.000
0 0.10.2 0.30.40.50.60.70.80.9 1

Mole Fraction O-X ylene

P= 780mmHg

Txy Diagram
160.000
140.000
120.000
100.000

Temperature (C)

80.000

BP LINE
DP LINE

60.000
40.000
20.000
0.000
0 0.1 0.20.30.4 0.50.60.7 0.80.9 1

Mole Fraction Water

P= 780mmHg

John Paul I. Rodriguez

Thermodynamics 2
B.S ChE

Componen
t
Acetic
Acid (A)
Iso-Butane
(B)

15.07
17
13.82
54

3580.
8
2181.
79

224.6
5
248.8
7

PXY Diagram @ T=50 C

X
a

X
b

1
0.
9

0
0.
1

Tem
p.

Pa*
Pb*
57.340 5116.6
50
14
48
57.340 5116.6
50
14
48

Pa
57.340
14
51.606
13

Pb

Ptotal
Ya
Yb
57.340
0
14
1
0
511.66 563.27 0.0916 0.9083
48
09
19
81

0.
8
0.
7
0.
6
0.
5
0.
4
0.
3
0.
2
0.
1

0.
2
0.
3
0.
4
0.
5
0.
6
0.
7
0.
8
0.
9

50
50
50
50
50
50
50
50
50

57.340
14
57.340
14
57.340
14
57.340
14
57.340
14
57.340
14
57.340
14
57.340
14
57.340
14

5116.6
48
5116.6
48
5116.6
48
5116.6
48
5116.6
48
5116.6
48
5116.6
48
5116.6
48
5116.6
48

45.872
11
40.138
1
34.404
09
28.670
07
22.936
06
17.202
04
11.468
03
5.7340
14

1023.3
3
1534.9
94
2046.6
59
2558.3
24
3069.9
89
3581.6
53
4093.3
18
4604.9
83
5116.6
48

1069.2
02
1575.1
32
2081.0
63
2586.9
94
3092.9
25
3598.8
55
4104.7
86
4610.7
17
5116.6
48

0.0429
03
0.0254
82
0.0165
32
0.0110
82
0.0074
16
0.0047
8
0.0027
94
0.0012
44

0.9570
97
0.9745
18
0.9834
68
0.9889
18
0.9925
84
0.9952
2
0.9972
06
0.9987
56

TXY Diagram @ P=780 mmHg

X
a

X
b

1
0.
9
0.
8
0.
7
0.
6
0.
5
0.
4

0
0.
1
0.
2
0.
3
0.
4
0.
5
0.
6

0.
3

0.
7

0.
2

0.
8

0.
1

0.
9

Temp.
118.75
33
62.658
04
38.031
66
24.177
72
14.906
64
8.0693
57
2.7137
63
1.6554
7
5.3257
5
8.4774
5
11.230
5

Pa*
780.00
1
101.84
04
31.657
54
14.820
41
8.4915
56
5.4734
65
3.8094
08

Pb*
20040.
94
6883.4
45
3773.3
7
2565.4
19
1937.2
63
1554.5
27
1297.4
61

Pa
Pb
Ptotal
Ya
780.00
1
0
780
1
91.656 688.34
0.1175
4
45
780
08
25.326 754.67
0.0324
03
41
780
69
10.374 769.62
29
57
780 0.0133
5.0949 774.90
0.0065
34
51
780
32
2.7367 777.26
0.0035
33
33
780
09
1.5237 778.47
0.0019
63
64
780
54

Yb

2.7979
64

1113.0
87

0.8393
89

779.16
1

2.1386
47

974.46
64

0.4277
29

1.6856
3

866.47
94

1.3613
3

780

0
0.8824
92
0.9675
31
0.9867
0.9934
68
0.9964
91
0.9980
46

780

0.0010
76

0.9989
24

779.57
32

780

0.0005
48

0.9994
52

0.1685
63

779.83
14

780

0.0002
16

0.9997
84

780

780

Pxy Diagram
6000
5000
4000
3000

BP Line
Pressure (mmHg)

DP Line

2000
1000
0
0

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

Mole Fraction Acetic Acid

Pxy Diagram
6000
5000
4000
3000

BP Line
Pressure (mmHg)

DP Line

2000
1000
0
0

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

1.1

Mole Fraction Iso-Butane

Txy Diagram
140
120
100
80
60
Temperature (C)BP Line

DP Line

40
20
0
-20

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

Mole Fraction Acetic Acid

Txy Diagram
140
120
100
80
BP Line

Temperature (C)

60

DP Line

40
20
0
-20

0 0.10.20.30.40.50.60.70.80.9 1 1.1

Mole Fraction Iso-Butane