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VII.

CHLORINATED PE
CHLOROSULFONATED PE

580
THE RUBBER FORMULARY

FUEL HOSE
DuPont Dow

Hypalon 4085
Magnesium Oxide
N762
Atomite
PE-200
Carbowax 3350
DOS
Sundex 790
PE-617A
MBTS
NBC
Tetrone A
Kenflex A-1
HVA-2
Total
Physical Properties Original
Tensile Strength, psi
Elongation, %
Hardness, Shore A

100
5
60
90
3
3
7.5
22.5
3
1
1
1
5
1
303
1607
353
71

581
CHLORINATED PE, CHLOROSULFONATED PE

FUEL HOSE COVER


Starting Point Formulation
DuPont Dow

Ingredients
Tyrin CM 0136
Echo-S
Vanax 808
Marinco H
N-330
N-650
Atomite
TOTM
Wingstay 29
Irganox MD1024
Total
Processing
Min Mooney Viscosity MS 1 @ 121C (in.lbs.)
Mooney Scorch, MS 1 @ 121C/3 Pt. Rise (min.)
ODR Cure @ 160C
M-L, in-lbs.
M-H, in-lbs.
Torque, in-lbs.
Tc90, min.
Original Properties Cured @ 160C/20
M-100, MPa
M-200, MPa
Ultimate Tensile, MPa
Ultimate Elongaiton, %
Hardness, Shore A
C-Set @ 150C/20 hours, % Set
Tear, Die C, kN/m
LTB, C

phr
100
3
1
5
25
25
60
30
1
1
250.8
36.5
21.5
11.5
58.0
47.5
13.8
3.7
6.8
11.4
360
83
55
41.6
-31

582
THE RUBBER FORMULARY

FUEL HOSE COVER


Starting Point Formulation
Continued
Air Oven Aging @ 150C/70 hours
Tensile, %
Elongation, %
Hardness,
Oil Aging Oil #3 @ 150C/70 hours
Volume Swell, %
Tensile, %
Elongation, %
Hardness,
Fuel Aging ASTM Fuel B @ 23C/70 hours
Volume Swell, %
Tensile, %
Elongation, %
Hardness,

+9
-39
+7
47
-18
-63
-32
35
-20
-12
-29

583
CHLORINATED PE, CHLOROSULFONATED PE

GENERAL PURPOSE HYDRAULIC HOSE COVER


R.T. Vanderbilt

Tyrin CM-0836
N-762 Carbon Black
Catalpo Clay
Maglite D
Santicizer 711
VANAX 808
ECHO S
Total
Density, Mg/m3
Oscillating Disk Rheometer at 160C(320F)
ODR Cure Time, min.
ODR Torque, N.m (lb-in)
Physical Properties
Cured 20 min. @ 160C(320F)
100% Modulus, MPa (psi)
200% Modulus, MPa (psi)
Tensile Strength, MPa (psi)
Elongation, %
Hardness, Shore A

100.0
75.2
25.0
10.0
55.0
1.0
3.0
265.0
1.34
4.4
7.2(41)

3.7(540)
6.7(960)
11.8(1700)
510
70

584
THE RUBBER FORMULARY

POWER STEERING HOSE TUBE AND COVER


DuPont Dow

Hypalon 4085
Hypalon 6525
N762
TOTM
Magnesium Oxide
PE-200
Dicup 40C
TAC
PE-617A
Total
Physical Properties Original
Tensile Strength, psi
Elongation, %
Hardness, Shore A

75
25
75
20
10
5
6
3.3
3
222.3
3001
180
77

585
CHLORINATED PE, CHLOROSULFONATED PE

POWER STEERING RETURN HOSE


Starting Point Formulations
DuPont Dow

PEROXIDE

THIADIAZOL
E

Tyrin CM0136
Tyrin CM0730
Echo-S
Vanax 808
Vulcup 40KE
Trigonox 17/40
DAP
TAC
Maglite D
Magnesium Hydroxide
N-762
N-990
TOTM
Agerite Resin D
Wingstay 29
Irganox MD1024
Total
Processing
Min. Mooney Viscosity MS 1 @ 121C (in.lbs.)
Mooney Scorch, MS 1 @ 121C/3 Pt. Rise
ODR Cure @ 160C
M-L, in-lbs.
M-H, in-lbs.
Torque, in-lbs.
Tc90, min.
Original Properties Cured @ 160C/20
M-100, psi
M-200, psi
Ultimate Tensile, psi
Ultimate Elongation, %
Hardness, Shore A
C-Set @ 150C/20 hours, % Set
Tear, Die C, ppi
LTB, C

--100
----4
4
3.5
2
10
--55
55
40
0.2
----273.7

100
--3
1
----------5
100
--40
--1
1
251

23
25

37
>25

10
78
68
20

14
51
37
13

760
--2100
230
77
33
---38

1210
1600
1690
260
88
72
230
-34

586
THE RUBBER FORMULARY

POWER STEERING RETURN HOSE


Starting Point Formulations
Continued
Air Oven Aging @ 150C/70 hours
Tensile, %
Elongation, %
Hardness,
Oil Aging Oil #3 @ 150C/70 hours
Volume Swell, %
Tensile, %
Elongation, %
Hardness,

PEROXIDE
-5
-19
+3

Thiadiazole
+2
-46
+8

55
-23
-23
-22

49
-22
-58
-21

587
CHLORINATED PE, CHLOROSULFONATED PE

GENERAL PURPOSE COVER


R.T. Vanderbilt

Hypalon 40
Hypalon 4085
Budene 1207
A-C 617 A Polyethylene
VANWAX H
Magnesium Oxide
Admex 746
VANOX NBC
Aromatic Plasticizer
Ester Plasticizer
THERMAX FLOFORM (N-990)
FEF Black (N-550)
Laminar Whiting
METHYL TUADS
Sulfur
Total
Density, Mg/m3
Properties, Cured 30 Minutes at 153C(307F)
Tensile Strength, MPa (psi)
Elongation, %
Hardness, Shore A

70.0
30.0
3.0
3.0
3.0
5.0
5.0
1.0
30.0
20.0
50.0
25.0
150.0
2.0
1.0
398.0
1.66
9.3(1350)
240
65

588
THE RUBBER FORMULARY

AUTO IGNITION WIRE


R.T. Vanderbilt

Tyrin 566
100.0
Maglite D
5.0
TAC
2.0
N-550 Carbon Black
30.0
Atomite Whiting
125.0
DIDP
30.0
VAROX 802
4.0
Mooney Viscosity ML (1+10) @ 121C
Minimum
50
Maximum
65
Oscillating Disk Rheometer (3C), 30 min. @ 177C
Maximum Torque, N-m(in-lb)
13.0(110)
Minimum Torque, N-m(in-lb)
1.2(10)
Scorch Time, min.
1
Optimum Cure Time, min.
5
Optimum Torque, N-m(in-lb)
11.8(100)
Press Cure
Steam Cure
Vulcanizate Properties
20 min. @ 160C 60 sec. @ 240 psi
100% Modulus, MPa (psi)
3.8((555)
3.2(470)
Tensile Strength, MPa (psi)
11.4(1655)
10.3(1500)
Elongation, %
295
300
Hardness, Durometer A
78
76
Tear Strength, kN/m(pli)
2.8(16)
3.5(20)
-30(-22)
Brittle Point C(F)
Moisture Absorption, 7 days @ 70C
Water, mg.cm2 (mg/in2)
22(140)
28(180)
Aged 70 hr. @ 136C
100% Modulus, MPa (psi)
7.3(1065)
6.6(965)
Hardness Change, Points
+11
+4
Tensile Retention, %
100
100
Elongation Retention, %
80
80
Aged ASTM Oil No. 2, 18 hr. @ 121C
100% Modulus, MPa (psi)
4.9(715)
4.6(670)
Hardness Change, Points
-4
+2
Tensile Strength Retention, %
310
110
Elongation Retention, %
95
90

589
CHLORINATED PE, CHLOROSULFONATED PE

AIR INTAKE DUCT


Starting Point Formulation
DuPont Dow

Tyrin CM 0136
Echo-S
Vanax 808
Marinco H
N-550
Hi-Sil 233
TOTM
Wingstay 29
Irganox MD1024
Total
Processing
Min. Mooney Viscosity MS 1 @ 121C(in-lbs.)
Mooney Scorch, MS 1 @ 121C/3 Pt. Rise (min.)
ODR Cure @ 160C
M-L, in-lbs.
M-H, in-lbs.
Torque, in-lbs.
Tc90, min.
Original Properties Cured @ 160C/20
M-100, MPa
M-200, MPa
Ultimate Tensile, MPa
Ultimate Elongation, %
Hardness, Shore A
C-Set @ 100C/22 hours, % Set
Tear, Die C, kN/m
LTB, C

100
3
1
5
50
10
35
1
1
206
38.0
25.0
12.5
52.0
39.5
13.0
3.8
7.6
18.0
530
78
26
52.9
-34

590
THE RUBBER FORMULARY

AIR INTAKE DUCT


Starting Point Formulation
Continued
Air Oven Aging @ 150C/70 hours
Tensile, %
Elongation, %
Hardness,
Oil Aging Oil #3 @ 150C/70 hours
Volume Swell, %
Tensile, %
Elongation, %
Hardness,
Fuel Aging ASTM Fuel C @ 23C/70 hours
Volume Swell, %
Tensile, %
Elongation, %
Hardness,

-9
-48
-12
50
-51
-71
-35
74
-51
-44
-35

591
CHLORINATED PE, CHLOROSULFONATED PE

ACID RESISTANT ROLL COMPOUND


DuPont Dow

Hypalon 40
Carbowax 4000
AC Polyethylene
SRF Carbon Black
Hysafe 510
TOTM
DiCup 40KE
TAC-DLC
Total
Physical Properties Original
Cured 30 minutes @ 307F
Tensile Strength, psi
Elongation, %
Hardness, Shore A

100
3
3
70
10
30
7
5
228

2000
250
65

592
THE RUBBER FORMULARY

POWER CABLE JACKET


DuPont Dow

Hypalon 40
Litharge 90% D
N550
N908
Calcined Clay
Vanwax H
Kenflex A-1
Aromatic Process Oil
Vanox NBC
MBTS
Tetrone A
HVA-2
Total
Physical Properties Original
Cured 1 minute @ 115 psi Steam
Tensile Strength, psi
Elongation, %

100
44
5
22
40
6
20
15
3
1
1
1
258

1875
620

593
CHLORINATED PE, CHLOROSULFONATED PE

HPN CORD
R.T. Vanderbilt

Tyrin 566
Maglite D
Atomite Whiting
Buca Clay
DIDP
AGERITE RESIN D
SR-350 (TMPTM)
VAROX 802
Mooney Viscosity ML (1+10) @ 100C
Minimum
Maximum
Mooney Viscosity ML (1+10) @ 121C
Minimum
Maximum
Oscillating Disk Rheometer (3C), 30 min. @ 177C
Maximim Torque, N-m(in-lb)
Minimum Torque, N-m(in-lb)
Scorch Time, min.
Optimum Cure Time, min.
Optimum Torque, N-m(in-lb)
Vulcanizate Properties:
Press Cure, 20 min. @ 160C
100% Modulus, MPa (psi)
Tensile Strength, MPa (psi)
Elongation, %
Hardness, Durometer A
Aged 10 Days @ 113C
100% Modulus, MPa (psi)
Hardness Change, Points
Tensile Retention, %
Elongation Retention, %
Aged ASTM No. 2 Oil, 18 hr. @ 121C
100% Modulus, MPa (psi)
Hardness Change, Points
Tensile Retention, %
Elongation Retention, %

100.0
5.0
50.0
60.0
20.0
0.2
5.0
3.0
70
95
45
70
5.9(50)
1.2(10)
2
8
5.9(50)

4.6(675)
10.5(1520)
540
74
8.0(1165)
+10
100
40
5.7(830)
-7
100
65

594
THE RUBBER FORMULARY

WHITE ROOFING COMPOUND


DuPont Dow

Hypalon 45
Atomite Whiting
TiPure R-960
Versamag DC
Irganox 1010
Kemamide
Carbowax 3350
Tinuvin 622
Total
Physical Properties Original
Tensile Strength, psi
Elongation, %
Hardness, Shore A

100
80
30
6
1
1
1.25
0.8
220.05
625
150
86

595
CHLORINATED PE, CHLOROSULFONATED PE

LOW DISCOLORATION TRANSLUCENT ARTICLE


R.T. Vanderbilt

Hypalon 40
ERL-4221 Epoxy Resin
Carbowax 4000
VAROX DBPH
TAC
Total
Properties, Cured 30 minutes @ 153C
Hardness, Shore A
Tensile, MPa (psi)
Elongation, %
Density, Mg/m3

100.0
2.8
1.0
4.0
4.0
111.8
50
25(3600)
500
1.16

596
THE RUBBER FORMULARY

DUROMETER 65 COMPOUND FOR BRASS ADHESION


PPG

CPE 0136
Silene 732D
Whiting
DOP
Magnesia
Stearic Acid
Sulfur
SR206
DCP 40%
Cure Rate MDR 160C, T50 minutes
Mooney Scorch 121C, T5 minutes
Mooney Viscosity, ML100
Cure: 30/40 @ 160C
Durometer @ 23C
@ 100C
Stress/Strain

100.0
60.0
20.0
40.0
12.0
2.0
0.1
4.0
6.0
10
17
50

Original

M300, MPa
Tensile
Elongation, %
Adhesion to Brass Coated Wire (6+3), ASTM 2224
Cure: 40/160C
Pull-Out, N/25 mm
% Rubber Cover
Dynamic Modulus, DMA: 1 Hz; 8%
-60C
-40
-20
0
10
20
30
Tg (E maximum)
Pendulum Rebound (Z), %
23C
100C

5.3
10
600
Steam
200
50

65
51
Aged 700 hrs.
@ 125C
Brittle

Press
480
100
E, Gpa
1.89
1.72
1.34
0.37
0.100
0.042
0.028
-8C
42
46

597
CHLORINATED PE, CHLOROSULFONATED PE

DUROMETER 75, FABRIC ADHESION & BRASS ADHESION


PPG

Banbury 1
100.0
60.0
40.0
10.0
2.0
3.0
6.0
Banbury 2
6.0
3.0
230.0
1.32
13 minutes
26 minutes
6.4 minutes
44

CPE 0236
Silene 732D
DOP
Magnesium Oxide
Stearic Acid
R-F Resin
SR 206
DCP 40%
HMMM 65%
Total
Specific Gravity
Cure Rate T90: 160C: T50
Mooney Scorch 130C T5
Viscosity ML100
Garvey Extrusion, 120C
Die Swell
Edge-Surface Rating
Cure: 40/160C

Original

Aged 4
Wks. 100C
91
-12(1750)
360%

Durometer
76
M300, MPa (PSI)
6.6(970)
Tensile
9.8(1430)
Elongation, %
635%
Compression Set, 3 Days 100C
Pendulum Rebound (Z)
At 100C
Adhesion to RFL Cord Sheet Laminated, 0.5 mm Skim
Strip Bond N/25 mm (PPI)
Adhesion to Brass Coated Wire (6 + 3)
Pull-Out, N/25 mm (PPI)

2%
8A
Aged 1
Wk. 125C
77
-9.9(1450)
480%
62.8%
34.6%
42.8%
130(30)
560(130)

598
THE RUBBER FORMULARY

Notes:

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