«2 United States Patent
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BATTERY PACK CONFI
REDUCE HAZARDS
GURATION TO
OCLATED WITH
INTERNAL SHORT CIRCUITS
Inventors: Weston Arthur Hermann, Palo Alo,
CA (US): Seott Ira Kohn, Redwood
City, CA (US); David G, Beek, Tiburon,
CATS)
Assignee: Tesla Motors, Ine, Palo Alto, CA (US)
Notice: Subject to any disctaimer,the term of this
pateat is extended or adjusted der
USC. 184(b) by 634 days
Appl. Now 137088444
Filed: Apr. 18, 2011
Prior Publica
US 20120034501 A1 Feb. 9, 2012
n Data
Related US. Application Data
CContinuaton-in-art of application No. 12/850.282,
filed on Aug. 4, 2010, now Pa, No. 8.133608.
Int. C1,
ois 1080 (2006.01),
HOM 226 (2006.01),
Ho2s 700 (2006.01),
us.c,
use 429/62; 429/120, 429/160; 429/161;
3200115; 3200133; 320/134
Field of Classification Search
Us 429/62, 120, 160-161; 320/118, 134
‘See application file for complete search history
301 305:
US 8,932,739 B2
Jan, 13, 2015
US008932739B2
(10) Patent No.:
(45) Date of Patent:
66) References Cited
US, PATENT DOCUMENTS
099.986 A $2000 Gashier ta
6548-206 BI 4.2003. Gatshr ta 29/100
20ODODNES7S AL* 72002 Thats 39500
oost233210 Al* 102005 Horie al. ‘2916
S0OTIISSIAT AL* 82007 Stael ea S204
Solomiasse4 AL* 62010 Kreer etl ‘29°50
FOREIGN PATENT DOCUMENTS
2 Horzss6s2 1011990,
2 2U8IS SOE
3 HIDTITO 101999,
» HLI320206 111909
2 2oossssed — "3/2008
OTHER PUBLICATIONS
uropean Paes Applicaton No. LIQ06442S, Extended European
‘Search Report dated Nov. 14,2011, 6 pages
* cited by examiner
Primary Examiner — Mibammad Sidiquee
(14) Attorney, Agent, or Firm — 1. Richard Soderberg,
on ABSTRACT
A battery pac, or battery pack module, is provided that is
‘configured to respond tos short circuit of moderate current in
‘amanner that minimizes therisk ofan inital thermal ranaway
‘event propagating throughout the battery pack/batery pack
‘module. In general, the battery packibattery module allows
pre-sclectionof which cell ofthe cells comprising the batery
ckrbattery pack mode willbe the last cell to respond tthe
short cecut. As a resul,a thermal isolation barrier may be
used to separate the preselected ell rom the other cells ofthe
batten packibattery pack modole, thereby minimizing the
risk of excessive heating and extensive collateral damage.
21 Claims, 6 Drawing Sheets
307
9
NY
501
To Load,
Additional Battery
Modules, etc.
303US. Patent Jan, 13,2015 Sheet 1 of 6 US 8,932,739 B2
cp
FIG. 1 PorUS. Patent Jan, 13,2015 Sheet 2 0f 6 US 8,932,739 B2
200
214 y 229
261
204
Prior
Art
J 207
202 attUS. Patent Jan, 13,2015 Sheet 3 of 6 US 8,932,739 B2
301
To Load,
Additional Battery
Modules, etc.
308
301
To Load,
Additional Battery
Modules, etc.
FIG. 4US. Patent Jan, 13,2015 Sheet 4 of 6 US 8,932,739 B2
To Load,
Additional Battery
Modules, etc.
Cell ‘B’
FIG. 5
301
To Load,
Additional Battery
Modules, etc.
\ 308
FIG. 6US. Patent Jan, 13,2015 Sheet Sof 6 US 8,932,739 B2
To Load,
Additional Battery
Modules, etc
To Load,
Additional Battery
Modules, etc
8015 203
Cell A
Cooling System
CellB
Cooling System
FIG. 8US. Patent Jan, 13,2015 Sheet 6 of 6 US 8,932,739 B2
801>)
Cell B Thermal
Quenching System
T 907
Heat Exchanger
301
Ne 903. Los
}
To Load,
Additional Battery
Modules, etc.
Cell ‘A’
Cella’
801
311
| - 803
Cell A
Cooling System
Cell B
Cooling System
FIG. 9US 8,932,739 B2
1
BATTERY PACK CONFIGURATION TO.
[REDUCE HAZARDS ASSOCIATED WITH
INTERNAL SHORT CIRCUITS
(CROSS-REFERENCES TO RELATED 5
“APPLICATIONS.
This application is a continuationin-part of U.S. patent
application Ser, No. 12/850,282, filed Aug, 4, 2010, the di
closure af whichis incorporated erein by reference for any. 1°
and all purposes.
FIELD OF THE INVENTION
‘The present invention relates generally to battery packs 1s
‘and, moze paticulrly, to batery pack that is designed to
‘mitigate the effets of arcing due to an ternal short cect
BACKGROUND OF THE INVENTION
‘There is curently a tend inthe automotive industry to
replace combustion engines with electric motors ora com
nation of anlectric motor and a combustion engine, thereby
substantially reducing the environmental impaet af automo
biles by reducing (ie. hybrids) or completely eliminating 2
(ie, electric vehicles) car emissions. This switeh in drive
‘ean technology is not, however, without its technological
sburles asthe use of aa eletric motor translates tothe need
for inexpensive batteries with high energy densities, ong
‘operating lifetimes, and operable ina wide range of condi
tions. Additionally. ts imperative thatthe hatery pack of
vehicle pose noundue health heats, ier during vehicleuse
‘or during periods of storage
‘While current rechargeable battery technology is able to
‘meet the demands of the automate industry, the catvely
‘usable nature the chemistries used in such bateries often
leads to spevializedhandlingand operating requirements. For
«example, rechargeable batteries such as ithium-ion cells tend
fo be more prone (0 thennal runaway than primary eels,
thermal rnavay occurring when the internal reaction rate
‘nereases tothe point that more heat is being generated than
canbe withdraw, leading toa further increase in both reac-
tion rate and hext generation. Eventually the amount of gen
erated heat is peat enough to lead tothe combustion ofthe
‘battery as well as materials in proximity tothe battery. Ther-
‘mal runaway nay be initiated by ashort cineuit within thecel,
improper cell use, physical abuse, manvfacturing defects, ot
‘expose of the cell extreme external temperatures. In the
case of battery pack used ia an electric vehicle a severe car
crash may simultaneously send multiple cells within the bat-
tery pack into thermal runaway:
Inorder to prevent overeating due to an inadvertent short,
thereby hopefully preventing the occurrence of @ thermal
runaway event, conventional battery packs typically position
4 fuse 101 ia series with one, of both interconnects that ss
couple the attery pack 103 to the load 108 a shown in FIG.
1. Unfortunatly, as fuse 101 is designed to prevent low
resistance, high curent short, it may not open and interrupt
sustained current of moderate magnitude suchas that which
‘may oecur duriagan internal batery short lathes situations, 6
the aflecied battery will coatiaue to heat unit a cell-level
safety mechanism is activated
Conventional cells, especially those prone to thermal run
away, (ypically incorporate a variety of diferent safety
‘mechanisms into thecal tself as lustrated in the simplified
‘cross-sectional view provided in FIG. 2. Battery 200 includes
cylindrical case 201, an electrode assembly 203, and a cap
8
2
assembly 208. Case 201 stypclly mae ofa meta, such as
‘nickel plated to, that hasbeen selected sch hat it wll not
‘ec wih thebttery materials, eg theelecuoyt, lectnde
assembly ec. Typically el casing 201i fabricated in such
aay tat the bottom surface 202s integrated int the case,
resulting ina seuss lower eel casing. Eleetode assembly
203 is comprised ofan anode shes, a cathode sheet and an
Jterposed separator, wound around a center pin 204 to form
a jell Typically cater pin2Mishollo, i. itneades
avojdrunningitsentire length ths providing pth or gases
forme during an over-resstre vento escape the cell via
the vent contained within electrode cap assembly 208, An
anode lect ab 207 connects the anode electrode ofthe
‘wound electrode assembly tthe negative ermial which or
an 18650 ellis ese 201. A cathode tab 209 connects the
cathode eleetode ofthe wound eleetade assembly to the
stv terminal va cap assembly 208 Typically battery 200
tka includes pir of sults 211/213 located oa either
dof electrode assembly 203 0 avoid short iret hetween
assembly 208 an case 201
In cll 200, ab 209 is connected 10 cap assembly 208,
‘Which contains acurent interrupt device (C1D)- The purpose
ofthe CID isto break the electrical connection beeen the
electrode assembly andthe postive teminal 227 i the pres-
sure within the cell excedsapreetrmine level. Typically
sucha tat of over pressure is indicative of el overcharging
andlorofthe cell temperature increasing beyond the intended
operating range ofthe cel for exarsple due to an extemely
highexteral temperature or duetoa flue within the batery
co charging system, Although other CID configurations are
‘Kowa, inthe llusrotd ell he CID i comprised of lower
smember 218 and an upper member 216. Members 218 and
216 are elecrally connected, for example via crimping
along their ernery witha pot weld. Lower member 215
includes moltipl openings 217, thus insuring that ny res
ste changes Within ease 201 are immediately transmitted 9
upper CID member 216. The cenal region of upper CID
‘member 216s cored (not visible EG 2)so that when the
presse within the cll exoods the predetemined level the
Scored portion of member 216 beaks re thereby disrupting
te contimity between the electrode assembly 208 and the
‘raters tering
‘Under arma presse conitons, lower CID masher 218
‘scouped by a weld 219 to elect ab 209 and upper CID
‘member 216s coupled hy a weld 221 to safety ven 223. ln
auton to disrupting the electrical connection to the elec-
trode assembly during an overpressure even, the CID in
conjuction with safety ven 223i designed to allow the gas
to escape the celina somewhat comtlled mannet. Salty
vent 228 may include seoring 225 to promote the vent rp-
‘uring inthe event of over pessue
“The pepe of CID member: 218216 is eletcally
‘soloed rom he periphery of safety vent 229 by an insulating
gasket 226, As aconsoquence the only electrical connection
between CID members 218/246 and salty veat 228 is
through wekd 21
Solty vent 223i coupled to ator teeming! 227 via a
postive temperature coelcient (PTC) current imiting ele
ment 229. PTC 229 is designed such that its resisince
‘becomes very high wen the temperature exceeds predeer.
ined level, iereby ining shot ier current How. Cap
assembly 205 further include second insulating gasket 291
that insulates the elecnaly conductive element ofthe cap
assembly from ease 201, Cap assembly 208 shed in place
‘itn case 201 using cimpod region 238,
Inadditon tothe incision ofa CID, a PEC and salty
reste vent, many cells abo utlize a Separator wiki theUS 8,932,739 B2
3
clectrode assembly 208 that is capable of impeding current.
flaw once a predetermined temperature is reached. In such a
separatorthe material comprising the separators designedto
soften upon resching he preset tempertuze (eg, 130°C.) at
‘hich poit the pores close and impede ion and cureat low. $
Unfortunately ifthe temperature of the eell continues to
increase, the material comprising the separator will com-
pletely melt and break-down, resulting n'a massive internal
short that can aecelorte heating,
While individual cells may include one or more builtin 10
safety mechanisms, s noted above these safety mechanis
‘are not always elective when the cell is one ofa rge group,
ofcells, ie, the batery pack of FIG. 1, Forexample, the CID
‘within a cell typically has a relatively low voltage rating and
therefore may besubject to arcing and fre when itatlempsto. 1S
‘open ina igh voltage battery pack. As a sult the coll may
eter into state of thermal minaway. Additionally, due tothe
‘excessive heat generated by suchan event, the temperature of
adjacent cells within the battery pack will also increase,
potentially leading toa cascading effect where the initiation
of thermal runaway within a single ell propagates through-
‘out the entre battery pack. In such a situation, not only is
power from the battery pack interrupted, but the system,
‘employing the battery pack is more likely to incur extensive
collateral damageducto the scaleof thermal rmaway andthe 2
associated release of thermal energy. While itis possible to
design a battery pack that minimizes the risks of arcing or
«excessive heating, such an approach leads to inereased cost,
complexity and weight, all of which may be quite significant
ina lage Battery pack such as that employed ina hybrid or an
allleirc vehicle. Accordingly: whats nooded isa meansof
‘minimizing the risks associated with an intemal shot cgcuit
within a battery pack, while not significantly impacting bat-
tery pack manufacturing cost, complexity and weight. The
present system provides such a means
x“
8
SUMMARY OF THE INVENTION
‘The present invention provides «battery pac, ora battery
pockimodule, that is configured to respond to ashor circuit
‘moderate current in a manner that minimizes the risk of an
inital thermal runaway event propagating thoughout the
battery pack/hatery pack module, In general, the disclosed
systemallows pre-selotionof whichcell or cells)ofthe cells
‘comprising the bartery packbattry pack module will be the
lastcells to respond theshor circuit. As result, athermal
isolation barrier may be used to separate the presclected cel.
(6) from the other cells ofthe battery packbattery pack mosl-
tule, thereby minimizing the risk of excessive heating and
extensive collateral damage.
In one aspect of the iaveaton, a battery pack short circuit
‘management system is provided that includes battery pack
‘comprised of (i) a plurality of ells characterized bya st of
‘operating characteristics, wherein each cell i electrically
connected to a fst collector plate and a second collector
plate, and wherein each cell includes first internal short
circuit safety mechanism configured to aetivate ata fist em
perature; and (i) a preselected cell distinguishable from the
plurality of cells, wherein the preselected cells electrically
connected to the first and second collectors plates, and
‘wherein the preselected cel includes a second intemal shor.
circuit safety mechanism configured to sctivate at second
temperature, the second temperature being greater than the
firttemperatue (for example, by at eat 10°C.) The batery
pocksshort circuit management system also includesa thermal
isolation system that thermally separates the preselected cell
from the plurality of cells, When ativate, the first intertal
s
4
shor circuit safety mechanism may decouple the cell with the
ctvated safety mechanism from at least one ofthe ist and
second collector plates. When activate, the second internal
short circuit safety mechanism may prevent curent ow
‘berweea the anode electrode andthe cathode electrode ofthe
electrode assembly of the preselected cel. In at least one
‘embodiment, he fis intemal short circuit safety mechanism
associated with each ofthe plurality of ellsis comprised of a
current intorup device (CID) while the second internal short.
circuit safety mechanism associated with the preselected cel
is comprised of a separator shutdown melanism, In this
cersbodiment, the preselectd cell does notineludeaCID.Inat
least one other embodiment, a CID ofa first configuration is
{integrated within each of the plurality of cells and a CID of
second configurations integrated within the preselected cell,
‘where the CID of the first configuration opens atthe first.
‘temperature andthe CID ofthe second configuration opens a
the second, higher temperature. The plurality of cells may be
electrically connected in parallel with the preselected cell
clectically connected in parallel with te plurality of cel
‘The thennal isolation system may utilize an enclosure, for
example an enclosure that is ()febricated from a ceramic
‘material; (ji fabricated inthe form ofa double-walled strue~
ture, for example where the outer wal fabricated from &
‘metal andthe inner wall is fabricated from a non-metal such
asa ceramie; (i fabricatedto include an innersurface coated
‘with an intumescent material; (iv) fabricated to include an
interior volume a least partially filled witha thermally non-
ccondvetive material such as loose ceramic fibers, woven
ceramic fibers, loose fiberglass fibers or woven fiberglass
fibers; oF (x) fabricated to include a phase change material
Te battery pack shor circuit management system may fur-
ther include (frst battery cooling system comprised of a
first guid coolant contained within a frst coolant line in
thermal communication with the plurality of cells and (i) a
sevond battery cooling system comprised of «second liquid
coolant contained within second coolant lin in thermal
‘communication with the presoleted el, whore the ist and
second battery cooling systems are independent of one
another. The second coolant Fine may be integrated within at
least one wall of the thermal isolation enclosure, The hatery
pock shor circuit management system may’ further include a
thermal runaway quenching system coupled to the prese=
lected cel, for example via the thermal isolation system, and
preferably not coupled tothe plurality of call
A futher understanding of te nature and advantages ofthe
present invention may be realized by reference tothe remain
ing portions ofthe specification and the drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG, 1 illystates a battery pack utilizing a fase in the
{ntereonneet between the battery pack and the load in accor.
dance wih the prior at,
FIG, 2 isa simplified cross-sectional view of « conven
‘ional batey, for example a thium ion battery wi
18650 fomn-fatoe;
FIG. 3 provides high-level view of a battery pockw
thermal soltion enclosure surrounding the cell
‘been preselected tobe the last coll toresponditoashor cect.
event
FIG. 4 provides high-level view of battery pack similar
to that shown in FIG. 3 except thatthe thermal isolation
cnelosure is mounted outside of the battery pack:
FIG. § provides high-level view ofa attry pack similar
to that shown in FIG. 3 except thatthe thermal isolation
enclosure utilizes a double-walled structure:US 8,932,739 B2
5
FIG. 6 provides a high-level view ofa battery pack similar
to tat shown in FIG. 3 except that the interior volume of the
‘thermal isolation enclosure is filled with a thermally non-
conductive material;
FIG. 7 provides ahigh-level view of battery pack similar $
‘o that shown in FIG. 3 except thatthe interior surfaces of the
thermal jsolation enclosure are coated with an intumescent
materia;
FIG. 8 provides s high-level view ofa battery pack similar
to that shown in FIG. 3 that includes an exemplary cooling. 10
system: and
IG. 9 provides shigh-Level view ofa battery pack similar
to that shown in FIG. 3 that includes an exemplary thermal
runaway quenching system,
DESCRIPTION OF THE SPECIFIC
EMBODIMENTS
In the following text the terms “battery”, “ell”, and “ba
‘ery cell” may be used interchangeably and may efe to any
of a variety of cilferet cell types, chemistries and configu
‘ations including, bu not Kimite to, ithium ion (etiam,
iron phosphate, lithium cobalt oxide, other lithium metal
oxides, et), lithium ion polymer, nickel metal hydride,
nickel cadmium, nicks! hydrogen, nickel zinc iver zine, or 2
‘other battry type/confguraton. The term “battery pack” as
sed herein refers to multiple individual batteries eletially
interconnected o achieve he desired voltage and capacity for
4 pantcular application, where the multiple batteries may be
contained within a single piece or mult-piove housing. It
should he understood that identical element symbols use on
multiple figures refer to the sume component, or compeneats
of equal funetionlity: Additionally, the accompanying fig
‘ures are only meant to illustrate, not limi, the scope ofthe
invention and should not be considered tobe to scale.
As previously described, when a short circuit event does
‘ot cause a system or batery puck level fuse to blow and
interrupt the fo of current, for example because the shorts
of'a moderate current level, then the system must rely onthe
safety mechanisms integrated within te individual cells to
couple the cells from the circuit. Unfortunatly, as these
safety mechanisms typically have @ relatively low voltage
railing in a high voltage battery pack the last safety mecha
nism to trigger is likely to subject the corresponding cel to
arcing and fire. This, in tum, is likly to cause the cell to enter
{ntoastateof thermal runaway, an event which may propagate
‘throughout a conventional battery pack. Accordingly, the
present invention allows.ahatery pack, o battery pack mod
‘le, tobe designed so tha particular, prdteined cell of
the plurality of clls comprising the pack/module will be the
last cello respond tothe short cecut event. By predetermin-
ing which of the batery pack’s cells willbe the last cell 0
respond tothe short eieuit, special precautions may be taken
‘o insure that even hiscell enters int thermal runaway, that
thermal runaway event will not propagate throughout the s
batterypack. Additionally, tisapproach allows the sytem to
‘be designed with minimal precautions takea fr the eemsin-
‘ng cells within the battery pak, thereby potentially offering
‘weight and cost savings.
FIG. 3 provides a highevel view of a battery pack 301
utilizing the invention, As deseeibed in further detail below,
the present invention may be wlized inany group ofcellsthat
are arranged in a parallel configuration, rogardless of the
‘number of ces or whether the group of ells forms te entire
batteny pack or only one module ofa plorality of serially
interconnected battery modules. Within battery pack 301 are
plurality of cells 303, labeled Cell ‘A that are of substan
6
‘ally the same design and harceriadby the same st of
pening characteristic, i, same barley chery, same
enemy’ density, same coniguration, same votageeureat
charctrinics, te. Adionally thee elle the same
internal safety mechanisms, ncling aD. Fach cel 33s
electrically conned 1 a pir of eolleior ples 308/306
‘Tecollsor plats arlectclly connect tothe nnd
toad or to anther btery pack module via ines 307308
Altough not shown, ise may be connected to one or bth
Tins 307 and 308, for example prior to connection with
another tery pci module.
In adton to eels 303, barry pack 301 inloes a el
8, labled Cel Cell 309s alo connected in pl
tothe lod vi olestoe pies 308306 fn gener, cel 309
sizes the sme design end is characterize hy these set
of operating carctritics (i, chemist, energy dni,
onfyuraion and vltagefcurent chances) as calls
$8, Cel 309s fom cells 33, however, in
the desi and confgution ofits intemal safety mech
tus, For expen prefered emedimen cel 309 does
tn inl «CID. As et while al af the els within
eck 30 wil faction similar unter normal operating con-
iionscell 309 wll not espondine same yay asco 303
ete ben down ofthe sparstornatrleadng tomas
Five electrical shot and typically thermal uy. Te te
erator at which th seartor experiences empl ek
dwn depends pon the material eomprising the separator
although pial itll beset within the range of 130° C.10
190°C. Adina. asthe separators pial only rato
4 votge in the range of 100 30 vos, and given tht his
‘elage maybe only sul ution ofthe voli tell
509 is sbjocted to once ell 8 open, sven afer tho sepa
‘ator shut-down arcing is ikl o oer, casing the tem
Pert of el 3091 continu fo increase, hereby esuling
In col 309 enfrng io ternal runaway. Noe that fhe
Separator within ol 309 is ot desiane to rekon at
predetermined temperature, x prceredthecel empertireUS 8,932,739 B2
1
‘will contin to increase until a different safety mechanism,
(ex, fse) is activated or until cell 309 enters into a state oF
thermal runaway.
‘By preselecting and identifying the cell within the battery
pack that wll respond last oa shor eicuit, special precat
‘ions may be taken to thermally isolate this cel, Thermally
isolating the cell ie. cell 309, substantially minimizes ifnot
altogether eliminates, the risk hat the increased temperature
ofthe cell during a short circuit may adversely affect neigh-
boring ells. Thermal isolation of cel 309 also eps to Kimi.
the type of collateral damage that offen occurs to adjacent
‘materials and components when a cell or cells undergo thet-
‘mal runaway. This aspect ofthe invention illustrated in FG.
3 invshich cell 309s shown housed within thermal isolation
fenelosure 311. It will be appreciated that thermal isolation
cnelosure M1 may be contsined within hatery pack enelo-
sure301, or mounted ouside of battery pack enclosure 301 as
shown it FIG. 4, Additionally, it should be understood that
While « thermal isolation enclosure 311 is prefered, other
‘means of themmaly isolating the cell are equally aplicableto
the invention, For example, the preselected cell may be thet-
‘mally isolating sing a combination of distance and thermal
barrios.
Thema! isolation enclosure 311 may be made of ay of 2
variety of materials utilizing a variety of enclosure designs,
the primary consideration being the design and material's
ability 0 thermally isolate cell 309 from is suroundings.
‘Secondary considerations applied othe enclosure design and
‘material selection for enclosure 311 are weight, manulactur-
ing complexity, fibrcation cost and material eost, Exemplary
cenelosure designs are provided below in FIGS. 7. It should
‘be understood that while these exemplary enclosures are
demonstrated on the system configuration shown in FIG. 3,
‘hey are equally applcableto the system configuration shown,
in FIG 4inhich thermal isolationenclosure311 is mounted
outside of hattery pack enclosure 301.
In the enclosure embodiment lusrated in FIGS. 3 and 4,
the walls of the enclosure are fabricated from a thermally
‘hon-conductve material with a high meling point, Pefer-
ably the material is also elecsically non-condetve. In one
configuration, the selected material sa ceramic
Inthe embodiment ofthe thermal isolation enclosure ills-
‘rated in FIG. §, enclosure 31 uilizesa double-walled enclo-
sure, Preferably outer wall S01 providesa rigid, strong enclo-
sure that is relatively easy to incorporate into a vehicle or
other batery pack application while inner wall $03 provides
superior thermal isolation. In one exemplary design, outer
wall $01 is fabricated from a metal, eg, aluminum oF an
aluminum alloy, while inner wall $03 is fabricated from 3
‘material with the desired thermal properties such as a
ceramic. Note that walls 501 and S03 may be separate, for
‘example comprising inner and outer enclosures. Altemately,
walls $01 and 508 may be fall integrated, for example by
applying a coating ofa ceramic or other thermally non-con-
‘ductive material 303 to the iner surfaces ofthe outer enelo-
sure walls $01 Twill be appreciated that while FIG. illus
‘wate a dual wall structure, enclosure 311 may be comprised
‘of more than two walls.
‘The embodiment ofthe thermal isolation enclosure ilus-
trated in FIG, 6 is similar to that shown in FIGS, 3 and 4, «0
except thatthe interior volume of housing 601 is atleast.
parially filled with a thermally non-conductive material 603.
‘that surrounds cell 309 and at least paially fils the void
‘between cell 309 and the interior walls 605 of vessel 601
Material 603 may be comprised of loose ceramic fibers,
‘woven ceramic fibers, loose fibers fibers, woven fiber-
lus fibers, ete. Material 603 may be comprised of a phase
x“
s
8
change material Ifa woven materials used, preferably itis
‘wapped und cell 19. I loose material used, prefer
aby itisblown or injected into vesel 601 ater cel 309 and
it’s interonnets are in place within housing 601
Inthe embesinent othe thermal isolation enelosureilos-
trate in FIG. 7 the irr surfaces of housing. 701 are
coated with an intumescent material 708 Intuneseeat mate-
Fal 703 absorbs the thermal energy generated by cell 309 as
itoverheats. Once te intumescent material's aetation em-
perature is eache, also refered to a the material's sat
expansion temperate or “SET, layer 703 will expand snd
provide thermal barrier been cel 309 ad housing 704
Profembly the material selected for layer 788 has a SET
temperature greater than 150°. for example athe rangeot
200°C. 10 300°C. Iwill be appreciated tere area varity
of suitable intumescent materials, for example aaphite-
‘used inumescent material (eg, expandable arphite ina
polymere binder, hemmoplsic elastomer, cranie-ased
intumescent material, vermiulitelmineral fiber based int
escent material and asmoniupolyphospte hase ite
smescent materia.
By preselectng the cell within Battery pack that wil be
thelast cello the pack tobe affected by asbor crit event,
‘ot only ean he peselected cel he located within thermal
fsolaton enclosure as deseribed above, but the lected cll
com also be inked to a separate cooing system oF them
vet quenching system. An exemplary colin system on-
figuration is shown in FIG. Band an exesplary quenching
stemisshowa in FIG, 9. While the embodiments lutte
{in FIGS. 8 and 9 ar bse on the thermal isolation enclosure
OofFIG.3,itshoud be understood that they are equally appli
cable her enclosure designs (¢. those showin FIGS,
5-7) aswell as oler batterypack configurations such 8 that
show ia FIG. 4
As show ia FIG 8, while not rue the preset mene
tionallowsiwo diferent cell colng vystemstobe employed,
cone used with the mujoriyof ells wiki battery pock 3,
ice cells 303, anda diferent cooling systems with the prse-
levied eel ofptck 301 ie, cell 309. Alemately. one evoling
system may’ Be used wit lof the eal ofthe bate pk,
and second, adftonal cooing system may be used anly
‘with the preselected el. Uilzng separate cooling ystems
offers several advantages, First i allows the two cooling
stems 10 employ diferent cooling rates and, if desired,
different cooling methodologies (3 aireoolng versus lig.
uid evolng). For example, since cooing system 801i nly
‘ode to ool the cells wii a normal operational tempera
turerangeitmay be configured tohaveless cooling capacity,
cape cel basis, than cooling system 803 whichis intended
{6 coo! call, ie ell M9, experoncing thermal runs:
Second ven fooling sytem 803i damage when cel 309
enters into themal runaway, coling system 801 may be
conligured to coatiaue operation, this ping to matin
cells 308 within a reasonable range of temperatures Tic,
sinc the stem ofthe invention designed to maintain cells
$MBata loertemperstur than cell 309 during short eeu
te coolant conduits associated with cooling sytem 80 do
othaveto be designed to withstand the same emperatesas
the eolant conduits associated With cooing sytem B03. As
2 result ofthis desig exiblty, itis possible ows Tighter
‘weight materials plastic) fr cooling syste BOL con-
duis than fr cooing system 808 (emt. Similac the
conus associatd with voling system 808 may be provided
‘with ational protection, for example by being iterated
‘Within the walls of enclosure 311, thereby enabling evokingUS 8,932,739 B2
9
system 803 to continue to operate even after the temperature
‘of cel 39 increases well beyond the normal cel operational
range
Regardless of whether a single cooling system is used to
coo! all of the cells within battery pack 301, or one cooling. s
system is used To col ells 303 and another cooling system,
sed to coo! cel 309 as illustrated in FIG. 8 the present
invention also simplifies the use of a thermal runaway
quenching system since sucha system would only be neces
sary forthe preselevted cell or ces. For example, in the
present exemplary system, only cell 309 would have to be
coupled to the quenching system, thus minimizing cost,
‘weight and system complexity.
FIG. 9 shows the configuration iustrated in FIG. 8 with
the addition ofa thermal rusaway quenching system 901. It 1s
will be appreciated that the invention is not limited to a
specific type of quenching system and that the present
crsbodiment is merely intended wo illustate, aot limit, the use
of such a system with the present invention. As shown, the
quenching system 901 includes a plurality of nozees 903
‘mounted in proximity tothe preselected cll. ln this embod
‘ment, nozzles 908 are mounted within enclosure 311. Once
the temperature ofthe preselected cel, or the temperature
within enclosure 311 indicates either the onset of a thermal
runaway eventora thermal runaway event inprogress stem 2
901 pumps @ quenching fuid through nozzles 993 ont cel.
309. Altemately, system 901 may be wiggered based on volt-
‘age and current measurements that indicate thatthe CIDs of
the other cells have opened. Preferably system 901 recireu
lates the quenching id, for example sing pump 905, Typ
cally the quenching fluid passes through a heat exchanger
907, for example a radiator or a eat exchanger coupled to
‘nother vehicle cooling system, nat least one preferred con-
figuration, cooling system 808 and quenching system 901 are
combined into a single temperature control system comte=
sponding to cel 309,
In the preferred embodiment, and as described in detail
above alofthe cells comprising battery pack 301, excepteel.
309, clude a CID. Asa result, cel 309 is preselected to be
the lat cell of battery pack 301 to succumb to a moderate
current level short. By preselectng cell 309, special recat
tions may be taken to insure that ft does enter into thermal
runaway. that thermal event wll not propagate throughout the
remaining cells of pack 301 or cause undue collateral dam
‘age, While his approach of preselectng one cello bethe last.
cel to respond 10a short is preferred, the inventors envision
that other techniques may be employed to achieve the same
goal, For example, inan alternate embodiment, all ofthe ells
‘Within battery pock 301 include a CID. However, the CIDsin,
cells 303 are configured to open at lower temperature and
fressue than the CID that corresponds to cell 309. For
‘example, in one embodimeat the CIDs of cells 308 open at
pressure that corresponds to a cell temperature of appro
‘mately 120°C. while the CID of eel 309 opens ata pressure
that comesponds toa cell temperature of approximately 140°
CAs a resul, and as previously deserbed,all ofthe non-
isolated cells, i. cells 303, will open prior to cell 309,
thereby allowing special precautions tobe taken to thermally
isolate cell 309.
As willbe understood by those familiar with the at, the
present invention may be embodied in other specilic forms
‘without departing fom the spitt or essential characteristics
thereof. For example, while the invention has been described
{terms of fithium ion cell, the invention isnot so limited
Accordingly, the disclosures and descriptions herein are
{tended to be lluseative, but nt Limiting ofthe scope f the
‘vention which i et fort ia the following claims.
s
10
‘What i claimed is:
1. A hatter pack short circuit management system, com-
rising:
«battery pack, comprising
‘plurality of cells each ofwhich characterized bya set
‘ofoperating characterises, wherein eachofsid ells
iselectically connected toa first collector plateand a
second collector plate, and wherein exch of said plu-
rality of cells further comprises a fist intemal short