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Lube Oil Purification PDF
Lube Oil Purification PDF
Lube Oil Purification PDF
Lubricating oil is an important resource and a petroleum base product. The high price of oil
and objective of saving valuable foreign exchange has resulted in efforts for regeneration of
used lube oil.
Mismanagement of waste lube oil is a serious environmental problem. Almost all types of
waste oil have the potential to be recycled safely, saving a precious non-renewable source
and at the same time minimizing environmental pollution. Unfortunately, most of used oil is
handled improperly. Some is emptied in to sewers for going directly into water waste,
adversely affecting water treatment plants. Some is dumped directly on to the ground to kill
weeds or is poured on to dirty roads or is dumped in deserts, where it can contaminate
surface and ground water.
Disposal of used lubricating oil into the eco system creates environmental hazards. Toughlaws are being enacted throughout the world for the disposal of waste petroleum products and
every genuine effort should be made for its re-use. In most cases, used oil can be re-used
after reconditioning with or without the addition of any additives resulting in huge saving and
conservation of precious oil. Thus regeneration, reclamation or recycling of spent lubricating
oils has become an important process industry, adopting various techniques for oil
purification.
Regeneration of used lubricating oils is based on the fact that, Petroleum lubricating oil are
almost indestructible. We can say, Lubricating oil never wears out. Lubricating oils are
impaired temporarily only because of accumulation during use or handling of contaminants
coming from extraneous impurities and products of oil deterioration, which can be separated
from the used oil by re-refining or re-conditioning. The treated oil, then, becomes almost
equivalent to fresh / virgin oil.
The major extraneous impurities in the waste oil are:
1.
2.
3.
4.
5.
6.
7.
Lube Oil Purification
2005.
Metallic Impurities
Non-metallic impurities
Water, moisture and untreated acid
Carboneous particles
Fuels, impaired additives and their by products.
Chemical contaminates
Polycyclic Aromatic hydrocarbons (PAHs)
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In India, re-recycling waste oil industry is mainly an un-organized one. Although some
public service units (PSU) also doing re-recycling but most of the market demand is
furnished by the small scale industrial units (SSIs). Most of the SSI units, till now, were
adopting Acid Clay Process, which now has been dis-approved by the pollution control
boards, resulting in their closure until they adopt new certified process.
Acid clay process:
In the conventional acid clay process the used lubricating oil is settled or filtered after
collection and is dehydrated. The oil is then treated with concentrated sulphuric acid to
remove polymers, asphalts, degraded additives and other products of degradation. The
sludge formed is allowed to settle and removed. The oil is neutralized with activated clay, at
elevated temperatures. The clay also bleaches the oil and adsorbs certain impurities not
removed by acid treatment. The clay-oil slurry is filtered to remove clay and other solids. If
the raw material contains more than one grade of lube oil product further processing may be
required.
Process
Characteristics
Advantages
1. Simple process
2. Low initial investment
3. Low energy input
1.
2.
3.
4.
Disadvantages
Unacceptable process to Pollution
Control Boards.
Generates large quantity of pollutants.
Unable to treat modern Multi-Grade
oils
Difficult to remove Asphaltic
impurities
Spent oils, which have not deteriorated to great extent, are often clay contracted or treated
with adsorbents without any acid treatment. They are generally given a preliminary settling,
filtering, centrifuging or vacuum dehydrating treatment. Insulating oils and Transformer oils
are often treated in this way.
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WATER AND
EVEREST
BOOSTER
LIGHT OIL
GR.3
BASE OIL
VACUUM DISTILLATION
COLUMN
DEHYDRATOR
STORAGE
GR-4
GR.5
COLUMN NO-III
VACUUM DISTILLATION
VACUUM DISTILLATION
COLUMN -II
RBO
Raw Base Oil
VACUUM DISTILLATION
COLUMN -I
USED/WASTE
OIL
COLUMN NO-III
OPERATES AT
757mmHg + 330C
EVEREST
BOOSTER
PRODUCT
ROTARY
OIL PUMP
WATERING
PUMP
OIL FIRED
HEATER
RESIDUE TO STORAGE TANK
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SPENT CLAY 2% TO 3%
January,
Gr.2
Gr.3 STORAGE
HEATING JACKET
VACUUM DISTILLATION
COLUMN
Gr.1
BASE OIL
PRODUCT
EVEREST
BOOSTER
EVEREST
BOOSTER
FILTERS
SPENT CLAY 2% TO 3%
USED OIL
IN
RESIDUE 12 TO 15%
ROTARY
OIL PUMP
WATERING
PUMP
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VACUUM PUMP
PRESSURE RANGE
600 mmHg
710-720 mmHg
Water Ejector
680 mmHg
740 mmHg
680-710 mmHg
750 mmHg
710-730 mmHg
750-755mmHg
Piston Pumps
710-730 mmHg
750-755mmHg
The last column, table 1 gives the approximate pressure regime a single stage Booster-Pump
combination can easily achieve. Further lower pressures (better vacuum) can be achieved by
multi-staging of boosters. With suitable combinations pressures in the range of 0.001 Torr
can easily be achieved. However, it is strongly advised that the system should be designed
for the required pressure since lower pressures than the desired by the process would only
add to initial and working costs without much benefit.
The table 2 gives the general pressure range essentially necessary for the successful
operations generally involved during the oil refining process. These are guidelines only and
may differ design to design.
Lube Oil Purification
2005.
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January,
Table2
Process
Dehydration
Vacuum Range
650-680mmHg
730-759 mmHg
0.1-0.005 Torr
Used motor oil can be re-refined to make to new lube oils. Re-refining is an efficient and
sophisticated process which removes contaminants and impurities producing premium grade
base oil. One gallon of used motor oil would yield about 0.7 gallons of re-refine oil. Lube
oils can be re-used indefinitely in an endless cycle from refinery to engine to refinery again.
The one main thing which is common in all three environmentally sound technologies (EST)
is that the vacuum requirement in each process, as per the specification furnished by Govt. of
India, is about 758mmHg (2 Torr) or better 2mm HG at the final distillation with temperature
of about 320 340 degree C. Whatever the process may be, the process vacuum demands a
combination of vacuum pumps.
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January,
REALITY
EVEREST TRANSMISSION
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January,