1
.................................................................................................................................1
1.1
..........................................................................................................................1
1.2
......................................................................................................1
1.3
..................................................................................................................2
...................................................................3
2.1
..........................................................................................................3
2.2
..........................................................................................................7
2.3
............................................................................................10
.....................................................................................12
3.1
........................................................................................................12
3.2
................................................................................................................13
.....................................................................................14
4.1
................................................................................................................14
4.2
....................................................................................................14
4.3
....................................................................................................15
4.4
....................................................................................................16
4.5
................................................................................................................16
4.6
............................................................................................17
4.7
................................................................................................................23
......................................................................................................25
5.1
................................................................25
5.2
................................................................................25
......................................................................27
1 ...........................................................................................................................27
2 .......................................................................................................................41
3 .....................................................................................44
4 ...........................................................................................................................48
5 ..............................................................................................................54
6 FUTURON .....................................................................................55
7 ..............................................................................................56
8 .....................................................................................58
9 .........................................................................65
1
1.1
1.2
1.2.1
1.2.2
1) .RoHS 2002/95/EC the Restriction of the use of certain hazardous
substances
2) IEEEInstitute of Electrical and Electronics Engineers
3) WEEEDirective2002/96/ECWaste Electrical and Electronic Equipment
1
4) Japanese Law Summary of Restricted Hazardous Chemical substance
5) 200540
6)
2002.06.29
7)
8)
9) (1995 10 30
)
10) 2002 1 26
344
11)
HJ/T314-2006
12)
13) DB44/26-2001
14) DB44/27-2001
15) GB18597-2001
16) GB18599-2001
1.3
2
2.1
2.1.1
()
121
23
2.1.2
1
()
()
(pH<10NaOH)
2.1.3
2.1.4
2.1.5
2.2
2.2.1
50%
2.2.2
(4050um)
Cu-NiCu-Ni-CrNi-Cu-Ni-CrCu-Cu-Ni-Cr
2.2.3
CP
-HEDP
HEDP
2.2.4
-
-
2.2.5
2.2.6
2.2.7
ABS
2.3
2.3.1
2.3.2
2.3.3
2.3.4
10
2.3.5
11
3
3.1
4
12
3.2
1
=(m)(m2)
(g/cm3)/(--)
(m3/m2)=(m3)/(m2)
(kwh/m2)=(kWh)/(m2)
3
(g/m2)=(g/y)/(m2/y)
(g/m2)=(g/y)/(m2/y)
(g/m2)=(g/y)/(m2/y)
4
(%)=/100%
(%)=/100%
(%)=/100%
=()/100%
%=/100%
=()/100%
5
13
4
4.1
4.2
4-1
4-1
pH
( 100% pH
70%)
ISO11469/
14
4.3
HJ/T420064-2
4-2
4.4
15
4-3
4-3
85
80
75
92
90
85
95
92
88
25
20
15
90
80
60
0.1
0.2
0.4
2t/m2
4.5
4-4
16
44
(
)
60%70%
30%40%
50%
3
10%20%
4.6
17
4-5
4-5
1(CN-)
g/m2
2.5
2.8
3.2
g/m2
0.4
0.6
0.8
g/m2
1.0
3.0
5.0
g/m2
0.6
1.8
3.6
g/m2
9.0
12.0
15.0
g/m2
1.0
3.0
6.0
DB44/26-2001
DB44/272001
4-6
4-6
1
2
1
2
18
0.5%
4.6.1
4-7
19
4-7 -
H2NH3
CO2
0.5%
4.6.2
()
20
4-8
4-8
S2-SO32-NO3-
Fe2+Mn2+Ni2+
Cr6+Cu2+Zn2+Ni2+
COD 1kg
30kg
-
- 99% 0.1mg/L
0.5mg/L2.0mg/LSS100mg/L1mg/L
CN- 00.5mg/L
CNCl
4.6.3
21
22
4.7
IEC
HSPM QC08000
ISO14000
ISO14000
RoHS
WEEE
ISO14020
4-9
49
ISO14001
,
,
95%
90%
80%
4.7.1
23
4.7.2
1
3
4
24
5
5.1
1
ISO14000
5.2
7 35 2
25
1 2
3 4
1 2
3 4
1
2
3 4
5 6
1 2
3 4
1 2
3
4
5
1
2
3
1
2
3
4
5
6
1
2
3
1
3
5
2
4
1
2
1
2
3
4
1
2
1
2
3
4
1
2
3
4
26
1
1.1
1)
g/L
40~50
60~70
50~60
50~70
60~80
60~90
g/L
200~230
200~220
180~220
180~220
180~210
180~210
25~30
30~35
25~35
25~35
25~35
25~35
g/L
CZ-96
14~16
3~4
g/L
CZ-96
ml/L
-8 ml/L
18~20
ZB-93Aml/L
15~20
ZB-93Bml/L
10~15
BZ-1ml/L
15~20
CKCL-92ml/L
10~16
AD-2000ml/L
pH
10~16
6.5~6.8
4.5~5.5
5~6
5~6
5~6
5~65
10~50
3~55
5~65
10~75
A/dm2
0.5~3
1~8
0.5~5
0.5~3
1~4
4.8~5.8
0.5~4
50~70g/L250~280g/L20~30g/L
10~15ml/LpH 4.5~5.55~401~2A/dm2
27
pH
pH pH
2)
30~50g/L
6r/min
3)
4)
28
1.2
1)
3~5
40~70g/L 180~220 g/L5~12 g/L
0.5~1.2 g/LZF-A15~20ml/LZF6~12 ml/LZF-B5~10 ml/LpH
3.5~5.50~60100~300A/8~10r/min
0.2%~0.8%
2)
3)
1L
5g/L
Fe3+ 0.2~0.5g/L Fe3+ Fe2+
pH
0.5~5 pH 5 4 4
29
1kAh
ZF-A30~60mlZF60~120mlZF-B70~80ml
4)
20 80 Zn-Co
Zn-Ni
Zn-Fe
1.3
1)
g/L
200~250
150~200
g/L
50~70
45~65
30~35
g/L
15~25
20~30
A/dm2
1~2
1~3
ii
15~35
30
0.1%~0.3%
1~21
iii
0.02~0.08g/L 0.08g/L
1~3g/L
2g/L
1~5g/L
2)
3)
4)
1.4
1)
i
g/L
150~220
180~240
160~240
g/L
50~70
45~60
40~80
g/L
0.0005~0.001
g/L
0.05~0.2
g/L
0.01~0.02
31
g/L
0.03~0.05
ml/L
20~80
20~80
30~120
210ml/L
2~5
210Aml/L
0.3~1.5
210Bml/L
0.3~1.5
VMACIA ml/L
0.5~1
VBACIAml/L
1.5~2.5
10~25
20~40
18~40
A/dm
2~3
2.5~3
0.5~3
ii
150~220g/L
50~70g/L
1000Ah 0.05g
1000 Ah 0.3g
0.02~0.08g/L
32
iii
0.1%~0.3%
iv
2~3 0.1~0.2ml/L
1~2g/L
2~3g/L 1h
0.02~0.08g/L
1~3g/L 2g/L 1h
55
30% 1~2ml/L 0.5~1h 3~5g/L
0.5~1h
2)
33
3)
4)
1.5
1)
[Cu(P2O7)2]6-
g/L
70~100
70~90
50~60
g/L
300~400
300~380
350~400
g/L
g/L
15~20
25~30
g/L
20~30
25%ml/L
2~3
g/L
0.008~0.02
0.008~0.02
2-g/L
0.02~0.04
0.002~0.004
2-g/L
pH
0.008~0.02
0.002~0.004
8~8.8
8~8.8
8.4~8.8
20~50
30~50
30~40
A/dm
2~4
1.5~3
0.5~1
/min
25~30
25~30
34
25~35g/L 20~25g/L
P2O74-
Cu2+7~81 71
8.51
1~3ml/L
2- 2-
2-
2-
pH pH
pH
pH
pH 8.0~9.0 pH
pH
35
40~45 30~40
2~8s 1~2s
25~30 /min 100mm
15~25 /min
21
2)
3)
4)
1.6 HEDP()
1)
HEDP
1.5A/dm2 CuR-1
3 A/dm2
36
g/L
8~12
HEDPg/L
80~130
g/L
40~60
80~250
g/L
20~30
g/L
40~60
CuR-1ml/L
20~25
pH
9~10
8.5~9.5
30~50
20~40
A/dm
1~3.0
0.5~1
1~1.51
0.8~21
15~20 /min
15~20 /min
Cu2+
8~12g/L Cu2+
Cu2+
HEDP Cu2+
HEDP/Cu2+ 2
HEDP Cu2+ HEDP
HEDP/Cu2+3~41 pH 9~10
HEDP/Cu2+
HEDP/Cu2+
Cu2+ 8~12g/L HEDP100%
80~130g/L
40~60g/L
CuR-1
1.5A/dm2 CuR-1
3A/dm2. CuR-1 20~25ml/L
pH HEDP Cu2+ pH pH
9~10 pH pH
37
pH
HEDP
30~50
45~50
3050
50
CuR-1
1~1.5A/dm2
5015~25 /min
1.5 A/dm2 CuR-1
3A/dm2
HEDP/Cu2+
1
1~1.5
2)
3)
4)
1.7
1)
KAu(SO3)2
(AuCl3)/gL-1
[(NH4)2S03)/gL
-1
525
2535
1015
815
120150
140180
150180
200300
(Na2SO47H20)/gL-1
38
[(NH4)3C6H5O7H20]/gL-1
(K3C6H5O7H20)/gL
-1
7090
100150
(EDTA)/gL-1
(KH2PO4)/gL
5070
40
25
2035
-1
(CoSO47H2O)/gL-1
(CuSO4H2O)/gL
80100
0.51
0.5l
0.51
0.10.2
-1
(KCl)/gL-1
60100
pH
/
/Adm
-2
8.59.5
6.57.5
810
99.5
4565
2030
4060
4550
0.10.8
0.20.3
0.3O.8
0.10.4
2)
3)
( 100)
350HV
4)
1.8
1)
g/L
68
46
36
SbEDTAg/L
0.1O.5
6080
2028
g/L
80120
EDTAg/L
g/L
1020
2060
HD-961A g/L
0.10.3
HD-96lB g/L
24
pH
4.85.6
56
55.8
5060
4550
6070
39
A/dm2
0.10.7
0.50.7
l9
l00Hz
1(0.30.8)
SbEDTA
()
2)
pH 3 KAu(CN)2
3)
[Au(CN)2]-
4)
2
1)
1%
pH8Cr(OH)3
2
25%
0.15100A/dm2
40
3m
Cr()Cr()
TDK
pH
Canning
Cr()
Cr()
41
Alecra23
CrCl36H2O106gPL
DMF
CrCl36H2O 213gPL
Cl-+SO42-
CrCl36H2O
0.2molPL CrCl36H2O
0.4molPL
NH4Cl134gPL
NH4Cl
26gPL
NH4Cl
HCOONa2H2O62gPL DMF
400gPL
NaH2PO22H2O 2molPL
CH3COONa16gPL
NaCl
36gPL
H3BO3
0.2molPL NaCl
0.4molPL
KCl75gPL
H3BO3
2gPL
NaF
0.1molPL (NH2)2CO
2molPL
H3BO367gPL
NH4Br10gPL
0.01gPL TC21
12mLPL pH
1mLPL
pH
1.11.3
(255) Jk
Jk
10
15APdm2
2040
3molPL
Cr2(SO4)36H2O 0.2molPL
H3BO3
0.4molPL
HCOOH
20mLPL
3.00.2
10gPL
2030 pH
1.92.3
10
Jk
15APdm2
<11A/dm2
Jk712APdm2
6.4m
2)
3)
42
125250000L
3
3.1
1)
g/L
4050
3045
61
g/L
220
525
29
g/L
60
150
g/L
6090
g/L
40
g/L
60
6080
g/L
2530
20
g/L
50
EDTANa2g/L
(ml/L)
BD (ml/L)
3050
25100
15
15
YDZ-7 (ml/L)
16
YDZ-8 (ml/L)
16
56
56
()
1025
1030
(A/dm2)
0.52.5
12
l2
(Sn/Pb)
(9080)/(1020)
6/4
(Sn/Pb)
(9580)/(520)
7/3
pH
2)
3)
()
4)
43
3.2
1)
(91)
91
120200g/L
Sn2+()3065g/L
Pb2+()26g/L
A3050ml/L
B1525ml/L
()1418ml/L
1835
24A/dm2
SnPb91
2)
20 70
3)
4)
3.3
1)
(
)
44
2)
3)
4)
0.1~753053
0.22.0
3.4
1)
(
)10
4677g/L
0.81.2g/L
167294g/L
498664g/L
149g/L
20ml/L
0.35A/dm2
pH4.55.5
3
2)
(
1.0mg/L)
45
Pb2+
3)
0.1mg/L
4)
-
20
70
4
4.1
1)
g/L
140
100
75
55~85
g/L
200
140
120
75~85
46
200
g/L
g/L
200
g/L
10
220
50~60
200~220
20
25~30
0.05
g/L
g/L
0.01
2
0.05
g/L
721-3 g/L
SSA-85ml/L
pH
5.0
5.8~6.8
5.5
5~6
30
40~55
30~40
32~36
A/dm2
2~4
1~8
2~5
1~3
SZn:SNi=9:1
ZnNi
SZn:SNi=10:1
g/L
8~12
6~8
10~15
10
g/L
10~14
g/L
100~140
g/L
20~30
g/L
30~50
ml/L
ZQ20~40
6
80~100
100~150
8~12
ZN-1C20~30
120
0.1~0.2
g/L
ml/L
ZQ-18~14
ZN-11
0.5~1.0
ZN-1:5~10
ZN-1A:3~5
ZN-1B:3~5
NZ-918C:70
NZ-918A:6
NZ-918B:4
A/dm2
1~5
0.4~4
0.5~4
0.5~4.5
15~35
20~40
20~30
10~35
ZnNi
ZnNi
ZnNi
ZnNi
13
7~9
2~5
47
g/L
72
70
150
100
g/L
70
150
130
200
g/L
30
20
60
g/L
g/L
50~100
g/L
100~200
g/L
20~40
20
A/dm
1~2
30
1~10
10
60
50
35~45
40
pH
2~3
1~3
2)
3)
7%~18%
4)
4.2
1)
48
g/L
14~16
g/L
3
200~300
g/L
90~110
g/L
1~1.5
9~16
30~300
200~300
g/L
g/L
300
140~160
g/L
220~240
g/L
1.5
g/L
30
g/L
12
15
g/L
XTL40~60
g/L
XTT4~6
14~18
g/L
7~10
15~30
15~38
40
50
A/dm2
1~2.5
1~5
20~150
30
Zn:Fe=10:1
0.2~0.7
0.4~0.7
20
12
2)
3)
7%~25%
0.3%~0.6%
4)
49
4.3
1)
-
g/L
8~14
g/L
495
10
75
10
80~90
g/L
g/L
g/L
1.5~3.0
g/L
80~100
g/L
180~210
g/L
20~30
g/L
50
g/L
g/L
50
ZC g/L
30~50
ZCA ml/L
6~10
10~40
25~40
50
25~35
A/dm2
1~4
1~4
30
15~25
0.6~0.8
0.4~0.8
0.6~0.8
15~25
2)
3)
1% 0.6%~1%
20%
4)
50
4.4
1)
25%
g/L
35
38
28
110
g/L
32
36
24
110
g/L
80
30
g/L
110
90
g/L
g/L
20
25
g/L
g/L
5
60
70
g/L
80
g/L
10
ml/L
72
pH
80
ml/L
15
A/dm2
1~3
0.5~3
1~3
1.5
15~25
10~40
15~25
20~35
pH
6~7
5~6
5.8
4.5
25%
25%
25%
25%
g/L
27
37
30
40
g/L
g/L
36
22.5
45
g/L
110
120
160
40
150
g/L
20
g/L
15
g/L
g/L
26
75
51
g/L
g/L
0.5
1.0
g/L
0.04
A/dm2
1~2
4~6
1~3
25
20~30
40~60
25
pH
6~7
6~7
25
30
30
1.5
0.4
2)
3)
20%~30%
4)
5
5.1
1)
pH
2)
3)
4)
52
5.2
1)
70
510g/L1979
2g/L
()
2)
3)
1m2210g/L9g
0.043g7080mg/L
4)
30
6 Futuron
1)
()
()Futuron
()Futuron Cu-link
2)
()
3)
()30%
53
Futuron
4)
7
7.1 (DACRO)
1)
1993
1530
510
13
0.5
1.5
0.2
0.5
PH
0.5
1.8
15
a.
b.
c.
CrO3
d.pH pH 3.55.0
e.
54
f.
g.
h.
3
2)
(DACRO)
3)
(~2%) Cr6+
Cr3+
4)
2% Cr6+
Cr6+ Cr3+
7.2
1)
Geomet VOC
55
274~316 15min
2)
3)
Cr6+
4)
Cr6+
8
8.1
1)
(2050 )
(
23 )
()
2)
56
8.2
1)
2)
()
8.3
1)
( PR )
2)
57
8.4
1)
2)
58
8.5
1)
20~40g/L 30~65g/L
20~35g/L OP-102~3ml/L
60~80
36.5%120~180ml/L65%~68%
15~35ml/L
85%25~50ml/L1~5g/L
3~5g/L
15~40
20~40g/L
12~48min
3~5g/L
1~2g/L
0.5~1min
--
WP-982~3min
90s
59
WP-9860636061
85%95%~98% 70:25 WP-985~15g/L
10g/L
90~110
1~3min
WP-98
ml/L
400~480
440
Aml/L
60~80
70
OPml/L
0.5~1.5
1.0
30~50
40
s
10~20
15
ABAB
2)
8.6
1)
60
20~30g/L 20~30g/L30~50g/L
708~20A/dm2
5~10g/L
5~10min
25%
3~5g/L
25~30min
85%25%98%15%
0.8g/L 1g/L 4g/L 20ml/L
50~70 20~25A/dm2
1.6~1.65kg/dm3
85%10% 98% 60%
25% 5% 80~90
20~30A/dm21~3min 5cm
120 /min
85% 800ml/L HH991A 100ml/L
HH991B 100ml/L 6~8V 2.5~3.5
A/dm2
61
10~35 1:1
HH912
BTA
2)
9.1
1)
3~5
2)
62
3~4
9.2
1~2
9.3
1)
2)
10s
95%
3)
63
9.4
1) -
2) --
3) -
Zn2+Cu2+
4)
Lancy
64
9.5
24h
45
9.6
-
--
Zn2+Cu2+
65
9.7
1000
9.8
66
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