P2

sat

P1sat

P (kPa)
15.79
17.51
18.15
19.3
19.89
21.37
24.95
29.82
34.8
42.1
60.38
65.39
69.36

x1

x2

y1

y2

y1.P
f1

0.0000
0.0932
0.1248
0.1757
0.2000
0.2626
0.3615
0.4750
0.5555
0.6718
0.8780
0.9398
1.0000

1.0000
0.9068
0.8752
0.8243
0.8000
0.7374
0.6385
0.5250
0.4445
0.3282
0.1220
0.0602
0.0000

0.0000
0.1794
0.2383
0.3302
0.3691
0.4628
0.6184
0.7552
0.8378
0.9137
0.9860
0.9945
1.0000

1.0000
0.8206
0.7617
0.6698
0.6309
0.5372
0.3816
0.2448
0.1622
0.0863
0.0140
0.0055
0.0000

0.0000
3.1413
4.3251
6.3729
7.3414
9.8900
15.4291
22.5201
29.1554
38.4668
59.5347
65.0304
69.3600

0.2000
0.0000
0.0000
-0.2000

0.2000

0.4000

0.6000

-0.4000
-0.6000
-0.8000
-1.0000
-1.2000
-1.4000

f(x) = - 0.422492344x - 0.7566003129

R = 0.9088658542

0.8000

1.0000

129

0.8000

y2.P
f2

f1/x1.P1sat
1

f2/x2.P2sat
2

ln 1

ln 2

15.7900
14.3687
13.8249
12.9271
12.5486
11.4800
9.5209
7.2999
5.6446
3.6332
0.8453
0.3596
0.0000

0.4693
0.4859
0.4997
0.5229
0.5292
0.5430
0.6154
0.6835
0.7567
0.8255
0.9776
0.9976
1.0000

1.0000
1.0035
1.0004
0.9932
0.9934
0.9860
0.9444
0.8806
0.8042
0.7011
0.4388
0.3784
0.3076

-0.7566
-0.7217
-0.6938
-0.6483
-0.6363
-0.6107
-0.4856
-0.3805
-0.2788
-0.1917
-0.0226
-0.0024
0.0000

0.0000
0.0035
0.0004
-0.0068
-0.0066
-0.0141
-0.0573
-0.1272
-0.2179
-0.3551
-0.8237
-0.9719
-1.1791

1.0000
ln 1
ln 2
Logarithmic (ln 2)
GE/RT
GE/x1x2RT
Linear (GE/x1x2RT)

GE/RT
0.0000
-0.0641
-0.0862
-0.1195
-0.1326
-0.1708
-0.2121
-0.2475
-0.2517
-0.2453
-0.1204
-0.0607
0.0000

GE/x1x2RT
-0.7582
-0.7896
-0.8253
-0.8285
-0.8820
-0.9188
-0.9924
-1.0194
-1.1128
-1.1237
-1.0735

P2

sat

P1sat

P (kPa)
15.79
17.51
18.15
19.3
19.89
21.37
24.95
29.82
34.8
42.1
60.38
65.39
69.36

x1

x2

y1

y2

y1.P
f1

0.0000
0.0932
0.1248
0.1757
0.2000
0.2626
0.3615
0.4750
0.5555
0.6718
0.8780
0.9398
1.0000

1.0000
0.9068
0.8752
0.8243
0.8000
0.7374
0.6385
0.5250
0.4445
0.3282
0.1220
0.0602
0.0000

0.0000
0.1794
0.2383
0.3302
0.3691
0.4628
0.6184
0.7552
0.8378
0.9137
0.9860
0.9945
1.0000

1.0000
0.8206
0.7617
0.6698
0.6309
0.5372
0.3816
0.2448
0.1622
0.0863
0.0140
0.0055
0.0000

0.0000
3.1413
4.3251
6.3729
7.3414
9.8900
15.4291
22.5201
29.1554
38.4668
59.5347
65.0304
69.3600

0.2000
0.0000
0.0000
-0.2000

0.2000

-0.4000
-0.6000
-0.8000
-1.0000
-1.2000

f(x) = - 1
R = 0

0.4000

0.6000

0.8000

1.0000

y2.P
f2
15.7900
14.3687
13.8249
12.9271
12.5486
11.4800
9.5209
7.2999
5.6446
3.6332
0.8453
0.3596
0.0000

0.8000

f1/x1.P1sat
1
0.4859
0.4997
0.5229
0.5292
0.5430
0.6154
0.6835
0.7567
0.8255
0.9776
0.9976
1.0000

f2/x2.P2sat
2
1.0000
1.0035
1.0004
0.9932
0.9934
0.9860
0.9444
0.8806
0.8042
0.7011
0.4388
0.3784

1.0000
ln 1
ln 2
Logarithmic (ln 2)
GE/RT
GE/x1x2RT
Linear (GE/x1x2RT)

ln 1

ln 2

-1.0000
-0.7217
-0.6938
-0.6483
-0.6363
-0.6107
-0.4856
-0.3805
-0.2788
-0.1917
-0.0226
-0.0024
0.0000

0.0000
0.0035
0.0004
-0.0068
-0.0066
-0.0141
-0.0573
-0.1272
-0.2179
-0.3551
-0.8237
-0.9719
-1.0000

GE/RT
0.0000
-0.0845
-0.1092
-0.1448
-0.1600
-0.1936
-0.2308
-0.2494
-0.2469
-0.2205
-0.1071
-0.0566
0.0000

GE/x1x2RT
-1.0000
-1.0000
-1.0000
-1.0000
-1.0000
-1.0000
-1.0000
-1.0000
-1.0000
-1.0000
-1.0000

P2

sat

P1sat

P (kPa)

x1

y1

ln 1

ln 2

15.79

0.0000

0.0000

-1.0000

0.0000

0.3679

17.51

0.0932

0.1794

-0.8302

-0.0853

0.4360

18.15

0.1248

0.2383

-0.7796

-0.1112

0.4586

19.3

0.1757

0.3302

-0.7049

-0.1503

0.4941

19.89

0.2000

0.3691

-0.6720

-0.1680

0.5107

21.37

0.2626

0.4628

-0.5946

-0.2117

0.5518

24.95

0.3615

0.6184

-0.4911

-0.2781

0.6119

29.82

0.4750

0.7552

-0.3941

-0.3565

0.6743

34.8

0.5555

0.8378

-0.3347

-0.4183

0.7155

42.1

0.6718

0.9137

-0.2558

-0.5237

0.7743

60.38

0.8780

0.9860

-0.1089

-0.7840

0.8968

65.39

0.9398

0.9945

-0.0568

-0.8866

0.9448

69.36

1.0000

1.0000

0.0000

-1.0000

1.0000

80

0.0000
0.0000

70

-0.2000

60
50
40
30
20
10
0
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000 1.2000

-0.4000
P-x1
P-y1

-0.6000
-0.8000
-1.0000
-1.2000

0.2000

0.4000

0.6

0.2000

GE/RT

GE/x1x2RT

Raoult law

1.0000

0.0000

-1

0.9182

-0.0845

-1

6.464352

0.8948

-0.1092

-1

8.656128

0.8605

-0.1448

-1

12.186552

0.8454

-0.1600

-1

13.872

0.8092

-0.1936

-1

18.213936

0.7573

-0.2308

-1

25.07364

0.7001

-0.2494

-1

32.946

0.6581

-0.2469

-1

38.52948

0.5923

-0.2205

-1

46.596048

0.4566

-0.1071

-1

60.89808

0.4120

-0.0566

-1

65.184528

0.3679

0.0000

-1

69.36

0.4000

0.6000

0.8000

1.0000

1.2000

ln 1
ln 2
GE/RT
GE/x1x2RT -1

Senyawa
metana
etana
propana
n-butana

A
6.69561
6.83452
6.80398
6.84290

B
405.420
663.700
803.810
926.100

C
267.777
256.470
246.990
240.000

Tmin
-181
-143
-108
-81

Tmax
-152
-75
-25
13

No.
1
2
3
4

Senyawa
Metana
Etana
Propana
n-Butana

Zi

Ki

KiZi

Zi/Ki

50%
10%
20%
20%

10
2.04
0.67
0.2

5
0.204
0.134
0.04
5.378

0.05
0.04902
0.298507
1
1.397527

No.
1
2
3
4

Senyawa
Metana
Etana
Propana
n-Butana

Zi

Ki

yi

xi

50%
10%
20%
20%

10
2.04
0.67
0.2

V
0.841
0.841
0.841
0.841

0.5835
0.1088
0.1855
0.1222
1.0001

0.0584
0.0533
0.2768
0.6111
0.9997

Senyawa

T (C)

log Psat

kloroform
1,4 dioxane

6.93710
7.00630

1171.200
1288.500

227.000
211.010

50
50

2.7089412
2.0697075

P (mmHg)

P (kPa)

511.6125 68.19795
117.4107 15.65084