Derive the given equation for ln :

ln =z1ln( zB)

B=

bP
RT

A
z +2.414 B
ln
z0.414
B
2 2 B

, where

A=

a (T ) P
R2 T 2

and

, by

combining

the
V

ln =z1ln z

following

( RTP V1 ) dV

thermodynamic

relationship

and the Peng-Robinson equation of state.

Use the working equation above to regenerate the fugacity and fugacity
coefficient data points of H2O at 300C by writing a suitable FORTRAN computer
program and redraw the given plot.
Answer:

a. Penurunan persamaan
V

ln =z1ln z

ln =z1ln z

ln =z1ln z

ln =z1ln z

( RTP V1 ) dV
( RTP VV V1 ) dV
( VZ V1 ) dV
Z1
1
d( )
1

( )

ln =z1ln z ( Z1 ) (
0

1
) d
2

ln =z1ln z+
0

( Z1)
d

b. Peng Robinson

P=

a(T )
RT

v b v ( v +b )+ b( vb)

a (T )
Pv
v
v
=

2
RT vb RT v +2 bvb 2
1

1
a (T )

Z=

1
RT 1 2
1
b
( ) +2 b b2

Z=

a(T )
1
1

1b
RT 1+ 2bb2 2

Diubah ke bentuk Z-1

Z 1=

a (T )
1
1
1b

2 2
1b
RT 1+2 bb 1b

Z 1=

a (T )
b
1

1b
RT 1+2 bb 2 2

c. Substitusi Persamaan Berwarna Cokelat

Z 1
d=
d (b)
Z1

0
0
b

( b1 )( 1b
0

a( T )
1
) d (b)
RT 1+ 2bb2 2

a( T )

1
1

) d (b)
( 1b
bRT 1+ 2bb2 2
0

a (T )
1
1
)d (b)
(
)d ( b)
( 1b

bRT 0 1+2 bb2 2

0

Integralkan persamaan berwarna hijau muda dengan persamaan ini:

1
1
2 ax +b b24 ac
dx=
ln
a x 2+ bx+ c
b 24 ac 2 ax +b+ b 24 ac

Dimana a = -1, b = 2, dan c = 1

b

1
)d (b)=
( 1+2 bb
2 2

1
2 b+ 22 2
ln
2
2 + 4 2 b+2+2 2

1
1
b1+1 2
)d (b)=
ln (
)
( 1+2 bb
2 2
2 2
b11 2 0

0
d. Pengintegralan
b

(
0

a (T )
1
1
)d (b)
(
)d ( b)

1b
bRT 0 1+2 bb2 2
ln ( 1b)

a (T ) 1
b1+1 2
ln (
)
bRT 2 2
b11 2 0

a (T ) 1
b1+1 2 1+ 2 12
ln ( 1b)
ln (
.
.
)
bRT 2 2
b11 2 1+ 2 12 0
b

( 1+ 2 ) b+1 1 2
a (T ) 1
ln ( 1b)
ln (
.
)
bRT 2 2
( 1 2 ) b+1 1+ 2 0

[(

) (

( 1+ 2 ) b+1 1 2
a (T ) 1
12
ln ( 1b)
ln
.
ln .
bRT 2 2
1+ 2
( 1 2 ) b+1 1+ 2

[(

)]

[(

)]

( 1+ 2 ) b+1
a (T ) 1
ln ( 1b)
ln
bRT 2 2
( 1 2 ) b+1

e. Substitusi Nilai A, B dan Z

BRT
( 1+ 2 )
+1
BRT
A 1
Pv
ln ( 1
)
ln
Pv
B 2 2
( 1 2 ) BRT +1
Pv

)]

[ ( )]

B
( 1+ 2 ) +1
B
A 1
Z
ln ( 1 )
ln
Z
B 2 2
( 1 2 ) B +1
Z

[(

( 1+ 2 ) B+ Z
ZB
A 1
ln (
)
ln
Z
B 2 2
( 1 2 ) B+Z

ln ( ZB ) + ln Z

)]

A 1
Z +2,414 B
ln
B 2 2
Z0,414 B

f. Substitusi ke persamaan akhir bagian a

ln =z1ln z+
0

( Z1)
d

ln =z1ln zln ( Z B )+ ln Z

ln =z1ln ( ZB )

A 1
Z+ 2,414 B
ln
B 2 2
Z0,414 B

A 1
Z +2,414 B
ln
B 2 2
Z0,414 B