B GIO DC V O TO

CHNH THC

( thi c 05 trang)

THI TUYN SINH I HC, CAO NG NM 2007

Mn thi: HO HC, Khi A
Thi gian lm bi: 90 pht.
M thi 429

H, tn th sinh:..........................................................................
S bo danh:............................................................................
PHN CHUNG CHO TT C TH SINH (44 cu, t cu 1 n cu 44):
Cu 1: Ha tan hon ton 12 gam hn hp Fe, Cu (t l mol 1:1) bng axit HNO3, thu c V lt (
ktc) hn hp kh X (gm NO v NO2) v dung dch Y (ch cha hai mui v axit d). T khi ca X
i vi H2 bng 19. Gi tr ca V l (cho H = 1, N = 14, O = 16, Fe = 56, Cu = 64)
A. 3,36.
B. 2,24.
C. 5,60.
D. 4,48.
Cu 2: -aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95
gam mui khan. Cng thc cu to thu gn ca X l (cho H = 1, C = 12, N = 14, O = 16, Cl = 35,5)
A. H2NCH2CH2COOH.
B. H2NCH2COOH.
D. CH3CH2CH(NH2)COOH.
C. CH3CH(NH2)COOH.
Cu 3: Cho 4,48 lt hn hp X ( ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt
dung dch Br2 0,5M. Sau khi phn ng hon ton, s mol Br2 gim i mt na v khi lng bnh
tng thm 6,7 gam. Cng thc phn t ca 2 hirocacbon l (cho H = 1, C = 12)
A. C2H2 v C3H8.
B. C3H4 v C4H8.
C. C2H2 v C4H6.
D. C2H2 v C4H8.
Cu 4: Cho hn hp X gm hai cht hu c c cng cng thc phn t C2H7NO2 tc dng va vi
dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm hai kh (u
lm xanh giy qu m). T khi hi ca Z i vi H2 bng 13,75. C cn dung dch Y thu c khi
lng mui khan l (cho H = 1, C = 12, N = 14, O = 16, Na = 23)
A. 8,9 gam.
B. 15,7 gam.
C. 16,5 gam.
D. 14,3 gam.
Cu 5: Nilon6,6 l mt loi
A. polieste.
B. t axetat.
C. t poliamit.
D. t visco.
Cu 6: Clo ho PVC thu c mt polime cha 63,96% clo v khi lng, trung bnh 1 phn t clo
phn ng vi k mt xch trong mch PVC. Gi tr ca k l (cho H = 1, C = 12, Cl = 35,5)
A. 6.
B. 5.
C. 3.
D. 4.
Cu 7: Dung dch HCl v dung dch CH3COOH c cng nng mol/l, pH ca hai dung dch tng
ng l x v y. Quan h gia x v y l (gi thit, c 100 phn t CH3COOH th c 1 phn t in li)
A. y = 100x.
B. y = x - 2.
C. y = 2x.
D. y = x + 2.
Cu 8: Dy gm cc ion X+, Y- v nguyn t Z u c cu hnh electron 1s22s22p6 l:
A. K+, Cl-, Ar.
B. Li+, F-, Ne.
C. Na+, F-, Ne.
D. Na+, Cl-, Ar.
Cu 9: Thu phn hon ton 444 gam mt lipit thu c 46 gam glixerol (glixerin) v hai loi axit
bo. Hai loi axit bo l (cho H = 1, C = 12, O = 16)
A. C15H31COOH v C17H35COOH.
B. C17H33COOH v C17H35COOH.
C. C17H31COOH v C17H33COOH.
D. C17H33COOH v C15H31COOH.
Cu 10: Hn hp X gm axit HCOOH v axit CH3COOH (t l mol 1:1). Ly 5,3 gam hn hp X tc
dng vi 5,75 gam C2H5OH (c xc tc H2SO4 c) thu c m gam hn hp este (hiu sut ca cc
phn ng este ho u bng 80%). Gi tr ca m l (cho H = 1, C = 12, O = 16)
A. 10,12.
B. 16,20.
C. 6,48.
D. 8,10.
Cu 11: Trong phng th nghim, iu ch mt lng nh kh X tinh khit, ngi ta un nng
dung dch amoni nitrit bo ho. Kh X l
C. N2O.
D. NO2.
A. NO.
B. N2.
Cu 12: Khi nung hn hp cc cht Fe(NO3)2, Fe(OH)3 v FeCO3 trong khng kh n khi lng
khng i, thu c mt cht rn l
A. Fe2O3.
B. FeO.
C. Fe3O4.
D. Fe.
Trang 1/5 - M thi 429

Cu 13: Tng h s (cc s nguyn, ti gin) ca tt c cc cht trong phng trnh phn ng gia
Cu vi dung dch HNO3 c, nng l
A. 11.
B. 10.
C. 8.
D. 9.
Cu 14: Nh t t cho n d dung dch NaOH vo dung dch AlCl3. Hin tng xy ra l
A. ch c kt ta keo trng.
B. khng c kt ta, c kh bay ln.
C. c kt ta keo trng, sau kt ta tan.
D. c kt ta keo trng v c kh bay ln.
Cu 15: Ho tan 5,6 gam Fe bng dung dch H2SO4 long (d), thu c dung dch X. Dung dch X
phn ng va vi V ml dung dch KMnO4 0,5M. Gi tr ca V l (cho Fe = 56)
A. 40.
B. 60.
C. 20.
D. 80.
Cu 16: chng minh trong phn t ca glucoz c nhiu nhm hiroxyl, ngi ta cho dung dch
glucoz phn ng vi
A. Cu(OH)2 nhit thng.
B. Cu(OH)2 trong NaOH, un nng.
C. kim loi Na.
D. AgNO3 (hoc Ag2O) trong dung dch NH3, un nng.
Cu 17: Cho m gam hn hp Mg, Al vo 250 ml dung dch X cha hn hp axit HCl 1M v axit
H2SO4 0,5M, thu c 5,32 lt H2 ( ktc) v dung dch Y (coi th tch dung dch khng i). Dung
dch Y c pH l
A. 7.
B. 6.
C. 2.
D. 1.
Cu 18: Cho t t dung dch cha a mol HCl vo dung dch cha b mol Na2CO3 ng thi khuy
u, thu c V lt kh ( ktc) v dung dch X. Khi cho d nc vi trong vo dung dch X thy c
xut hin kt ta. Biu thc lin h gia V vi a, b l:
A. V = 11,2(a - b).
B. V = 22,4(a + b).
C. V = 11,2(a + b).
D. V = 22,4(a - b).
Cu 19: Pht biu khng ng l:
A. Phenol phn ng vi dung dch NaOH, ly mui va to ra cho tc dng vi dung dch HCl li
thu c phenol.
B. Dung dch natri phenolat phn ng vi kh CO2, ly kt ta va to ra cho tc dng vi dung
dch NaOH li thu c natri phenolat.
C. Axit axetic phn ng vi dung dch NaOH, ly dung dch mui va to ra cho tc dng vi kh
CO2 li thu c axit axetic.
D. Anilin phn ng vi dung dch HCl, ly mui va to ra cho tc dng vi dung dch NaOH li
thu c anilin.
Cu 20: Trong phng th nghim, ngi ta thng iu ch clo bng cch
A. cho dung dch HCl c tc dng vi MnO2, un nng.
B. in phn dung dch NaCl c mng ngn.
C. cho F2 y Cl2 ra khi dung dch NaCl.
D. in phn nng chy NaCl.
Cu 21: Cho lung kh H2 (d) qua hn hp cc oxit CuO, Fe2O3, ZnO, MgO nung nhit cao.
Sau phn ng hn hp rn cn li l:
A. Cu, Fe, ZnO, MgO.
B. Cu, Fe, Zn, Mg.
C. Cu, Fe, Zn, MgO.
D. Cu, FeO, ZnO, MgO.
Cu 22: Mnh khng ng l:
A. CH3CH2COOCH=CH2 tc dng vi dung dch NaOH thu c anehit v mui.
B. CH3CH2COOCH=CH2 tc dng c vi dung dch Br2.
C. CH3CH2COOCH=CH2 c th trng hp to polime.
D. CH3CH2COOCH=CH2 cng dy ng ng vi CH2=CHCOOCH3.
Cu 23: Trn dung dch cha a mol AlCl3 vi dung dch cha b mol NaOH. thu c kt ta th
cn c t l
A. a : b > 1 : 4.
B. a : b = 1 : 4.
C. a : b = 1 : 5.
D. a : b < 1 : 4.
Cu 24: Khi tch nc t mt cht X c cng thc phn t C4H10O to thnh ba anken l ng phn
ca nhau (tnh c ng phn hnh hc). Cng thc cu to thu gn ca X l
A. CH3CH(OH)CH2CH3.
B. (CH3)3COH.
C. CH3OCH2CH2CH3.
D. CH3CH(CH3)CH2OH.
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Cu 25: Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn
khi lng clo l 45,223%. Cng thc phn t ca X l (cho H = 1, C = 12, Cl = 35,5)
B. C3H6.
C. C2H4.
D. C4H8.
A. C3H4.
Cu 26: Cho 0,1 mol anehit X tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3,
un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6
gam Na. Cng thc cu to thu gn ca X l (cho Na = 23, Ag = 108)
A. HCHO.
B. CH3CH(OH)CHO. C. OHC-CHO.
D. CH3CHO.
Cu 27: Ho tan hon ton hn hp gm 0,12 mol FeS2 v a mol Cu2S vo axit HNO3 (va ), thu
c dung dch X (ch cha hai mui sunfat) v kh duy nht NO. Gi tr ca a l
A. 0,06.
B. 0,04.
C. 0,075.
D. 0,12.
Cu 28: Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l
A. propen v but-2-en (hoc buten-2).
B. eten v but-1-en (hoc buten-1).
C. 2-metylpropen v but-1-en (hoc buten-1). D. eten v but-2-en (hoc buten-2).
Cu 29: Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z
gp i khi lng phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung
dch Ca(OH)2 (d), thu c s gam kt ta l (cho H = 1, C = 12, O = 16, Ca = 40)
A. 30.
B. 10.
C. 20.
D. 40.
Cu 30: Dy cc ion xp theo chiu gim dn tnh oxi ho l (bit trong dy in ha, cp Fe3+/Fe2+
ng trc cp Ag+/Ag):
A. Fe3+, Ag+, Cu2+, Fe2+.
B. Ag+, Cu2+, Fe3+, Fe2+.
+
3+
2+
2+
C. Ag , Fe , Cu , Fe .
D. Fe3+, Cu2+, Ag+, Fe2+.
Cu 31: Hp th hon ton 2,688 lt kh CO2 ( ktc) vo 2,5 lt dung dch Ba(OH)2 nng a mol/l,
thu c 15,76 gam kt ta. Gi tr ca a l (cho C = 12, O = 16, Ba = 137)
A. 0,04.
B. 0,048.
C. 0,06.
D. 0,032.
2+
Cu 32: Anion X v cation Y u c cu hnh electron lp ngoi cng l 3s23p6. V tr ca cc
nguyn t trong bng tun hon cc nguyn t ha hc l:
A. X c s th t 17, chu k 4, nhm VIIA (phn nhm chnh nhm VII); Y c s th t 20, chu
k 4, nhm IIA (phn nhm chnh nhm II).
B. X c s th t 17, chu k 3, nhm VIIA (phn nhm chnh nhm VII); Y c s th t 20, chu
k 4, nhm IIA (phn nhm chnh nhm II).
C. X c s th t 18, chu k 3, nhm VIIA (phn nhm chnh nhm VII); Y c s th t 20, chu
k 3, nhm IIA (phn nhm chnh nhm II).
D. X c s th t 18, chu k 3, nhm VIA (phn nhm chnh nhm VI); Y c s th t 20, chu k
4, nhm IIA (phn nhm chnh nhm II).
Cu 33: Cho dy cc cht: Ca(HCO3)2, NH4Cl, (NH4)2CO3, ZnSO4, Al(OH)3, Zn(OH)2. S cht trong
dy c tnh cht lng tnh l
A. 5.
B. 4.
C. 3.
D. 2.
Cu 34: nhn bit ba axit c, ngui: HCl, H2SO4, HNO3 ng ring bit trong ba l b mt nhn,
ta dng thuc th l
A. CuO.
B. Al.
C. Cu.
D. Fe.
Cu 35: t chy hon ton a mol axit hu c Y c 2a mol CO2. Mt khc, trung ha a mol Y
cn va 2a mol NaOH. Cng thc cu to thu gn ca Y l
A. CH3-COOH.
B. C2H5-COOH.
D. HOOC-COOH.
C. HOOC-CH2-CH2-COOH.
Cu 36: Cho 6,6 gam mt anehit X n chc, mch h phn ng vi lng d AgNO3 (hoc Ag2O) trong
dung dch NH3, un nng. Lng Ag sinh ra cho phn ng ht vi axit HNO3 long, thot ra 2,24 lt kh NO
(sn phm kh duy nht, o ktc). Cng thc cu to thu gn ca X l (cho H = 1, C = 12, O = 16)
A. CH3CHO.
B. HCHO.
C. CH2 = CHCHO.
D. CH3CH2CHO.

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Cu 37: Cho cc phn ng sau:

a) FeO + HNO3 (c, nng)
b) FeS + H2SO4 (c, nng)
c) Al2O3 + HNO3 (c, nng)
d) Cu + dung dch FeCl3
Ni, t o
e) CH3CHO + H2

f) glucoz + AgNO3 (hoc Ag2O) trong dung dch NH3

g) C2H4 + Br2
h) glixerol (glixerin) + Cu(OH)2
Dy gm cc phn ng u thuc loi phn ng oxi ha - kh l:
A. a, b, c, d, e, h.
B. a, b, d, e, f, g.
C. a, b, d, e, f, h.
D. a, b, c, d, e, g.
Cu 38: in phn dung dch CuCl2 vi in cc tr, sau mt thi gian thu c 0,32 gam Cu catt
v mt lng kh X ant. Hp th hon ton lng kh X trn vo 200 ml dung dch NaOH ( nhit
thng). Sau phn ng, nng NaOH cn li l 0,05M (gi thit th tch dung dch khng thay
i). Nng ban u ca dung dch NaOH l (cho Cu = 64)
A. 0,15M.
B. 0,05M.
C. 0,2M.
D. 0,1M.
Cu 39: X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy ra
hon ton, c cn dung dch thu c cht rn khan c khi lng l (cho H = 1, C = 12, O = 16, Na = 23)
A. 3,28 gam.
B. 10,4 gam.
C. 8,56 gam.
D. 8,2 gam.
Cu 40: Cho m gam tinh bt ln men thnh ancol (ru) etylic vi hiu sut 81%. Ton b lng
CO2 sinh ra c hp th hon ton vo dung dch Ca(OH)2, thu c 550 gam kt ta v dung dch
X. un k dung dch X thu thm c 100 gam kt ta. Gi tr ca m l (cho H = 1, C = 12, O = 16,
Ca = 40)
A. 550.
B. 810.
C. 750.
D. 650.
Cu 41: Cho 15,6 gam hn hp hai ancol (ru) n chc, k tip nhau trong dy ng ng tc dng ht
vi 9,2 gam Na, thu c 24,5 gam cht rn. Hai ancol l (cho H = 1, C = 12, O = 16, Na = 23)
A. CH3OH v C2H5OH.
B. C3H7OH v C4H9OH.
C. C3H5OH v C4H7OH.
D. C2H5OH v C3H7OH.
Cu 42: Cho s
Cl2 (t l mol 1:1)
NaOH c (d)
axit HCl
C6H6 (benzen)
Y
Z.
X
o
o
t cao, p cao
Fe, t
Hai cht hu c Y, Z ln lt l:
A. C6H5OH, C6H5Cl.
B. C6H5ONa, C6H5OH.
C. C6H6(OH)6, C6H6Cl6.
D. C6H4(OH)2, C6H4Cl2.
Cu 43: Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO2, 1,4 lt kh N2 (cc
th tch kh o ktc) v 10,125 gam H2O. Cng thc phn t ca X l (cho H = 1, O = 16)
A. C3H7N.
B. C2H7N.
C. C3H9N.
D. C4H9N.
Cu 44: Cho tng cht: Fe, FeO, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3,
FeCO3 ln lt phn ng vi HNO3 c, nng. S phn ng thuc loi phn ng oxi ho - kh l
A. 8.
B. 6.
C. 5.
D. 7.
PHN RING: Th sinh ch c chn lm 1 trong 2 phn (Phn I hoc Phn II)
Phn I. Theo chng trnh KHNG phn ban (6 cu, t cu 45 n cu 50):
Cu 45: Mnh khng ng l:
A. Fe3+ c tnh oxi ha mnh hn Cu2+.
B. Fe kh c Cu2+ trong dung dch.
C. Fe2+ oxi ho c Cu.
D. Tnh oxi ha ca cc ion tng theo th t: Fe2+, H+, Cu2+, Ag+.
Cu 46: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton
hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H2SO4 c, thu c hn hp kh Z c t
khi i vi hiro bng 19. Cng thc phn t ca X l (cho H = 1, C = 12, O = 16)
A. C3H4.
B. C3H8.
C. C3H6.
D. C4H8.
Cu 47: Dy gm cc cht u tc dng vi AgNO3 (hoc Ag2O) trong dung dch NH3, l:
A. anehit axetic, butin-1, etilen.
B. anehit fomic, axetilen, etilen.
C. anehit axetic, axetilen, butin-2.
D. axit fomic, vinylaxetilen, propin.
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Cu 48: t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2, 0,56 lt kh N2 (cc
kh o ktc) v 3,15 gam H2O. Khi X tc dng vi dung dch NaOH thu c sn phm c mui
H2N-CH2-COONa. Cng thc cu to thu gn ca X l (cho H = 1, C = 12, O = 16)
A. H2N-CH2-COO-C3H7.
B. H2N-CH2-COO-CH3.
C. H2N-CH2-COO-C2H5.
D. H2N-CH2-CH2-COOH.
Cu 49: Ho tan hon ton 2,81 gam hn hp gm Fe2O3, MgO, ZnO trong 500 ml axit H2SO4 0,1M
(va ). Sau phn ng, hn hp mui sunfat khan thu c khi c cn dung dch c khi lng l
(cho H = 1, O = 16, Mg = 24, S = 32, Fe = 56, Zn = 65)
A. 6,81 gam.
B. 4,81 gam.
C. 3,81 gam.
D. 5,81 gam.
Cu 50: Dy gm cc kim loi c iu ch trong cng nghip bng phng php in phn hp
cht nng chy ca chng, l:
A. Na, Ca, Zn.
B. Na, Ca, Al.
C. Fe, Ca, Al.
D. Na, Cu, Al.
Phn II. Theo chng trnh phn ban (6 cu, t cu 51 n cu 56):
Cu 51: Cho cc cht: HCN, H2, dung dch KMnO4, dung dch Br2. S cht phn ng c vi
(CH3)2CO l
A. 2.
B. 3.
C. 4.
D. 1.
Cu 52: Khi thc hin phn ng este ho 1 mol CH3COOH v 1 mol C2H5OH, lng este ln nht
thu c l 2/3 mol. t hiu sut cc i l 90% (tnh theo axit) khi tin hnh este ho 1 mol
CH3COOH cn s mol C2H5OH l (bit cc phn ng este ho thc hin cng nhit )
A. 0,342.
B. 2,925.
C. 0,456.
D. 2,412.
Cu 53: Mt este c cng thc phn t l C4H6O2, khi thu phn trong mi trng axit thu c
axetanehit. Cng thc cu to thu gn ca este l
A. CH3COO-CH=CH2.
B. CH2=CH-COO-CH3.
D. HCOO-CH=CH-CH3.
C. HCOO-C(CH3)=CH2.
Cu 54: thu ly Ag tinh khit t hn hp X (gm a mol Al2O3, b mol CuO, c mol Ag2O), ngi ta
ho tan X bi dung dch cha (6a + 2b + 2c) mol HNO3 c dung dch Y, sau thm (gi thit
hiu sut cc phn ng u l 100%)
A. 2c mol bt Al vo Y.
B. c mol bt Cu vo Y.
C. c mol bt Al vo Y.
D. 2c mol bt Cu vo Y.
Cu 55: Pht biu khng ng l:
A. Cc hp cht CrO, Cr(OH)2 tc dng c vi dung dch HCl cn CrO3 tc dng c vi
dung dch NaOH.
B. Cc hp cht Cr2O3, Cr(OH)3, CrO, Cr(OH)2 u c tnh cht lng tnh.
C. Hp cht Cr(II) c tnh kh c trng cn hp cht Cr(VI) c tnh oxi ho mnh.
D. Thm dung dch kim vo mui icromat, mui ny chuyn thnh mui cromat.
Cu 56: C 4 dung dch mui ring bit: CuCl2, ZnCl2, FeCl3, AlCl3. Nu thm dung dch KOH (d)
ri thm tip dung dch NH3 (d) vo 4 dung dch trn th s cht kt ta thu c l
A. 3.
B. 1.
C. 2.
D. 4.
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