i

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J. M. Smith
Professor Emeritus of Chemical Engineering
University of California, Davis
H. C. Van Ness
Institute Professor Emeritus of Chemical Engineering
Rensselaer Polytechnic Institute
M. M. Abbott
Professor of Chemical Engineering
Rensselaer Polytechnic Institute

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: Introduction to Chemical Engineering Thermodynamics,

Seventh Edition in SI Units
by J. M. Smith, H. C. Van Ness, M. M. Abbott
:

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Internet:
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Copyright 2012
Copyright 2012 by McGraw-Hill Inc.

ISBN 978-960-418-344-9

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.
No part of this publication may be reproduced or distributed in any form or by
any means, or stored in data base or retrieval system, without the prior written
permission of the publisher.

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.....................................................................................................vii
.......................................................................................ix
1: ........................................................................................... 1
1.1 .............................................................. 1
1.2 ............................................................................. 2
1.3 ............................................................ 4
1.4 ........................................................................................................... 4
1.5 ................................................................................................. 7
1.6 ................................................................................................................ 9
1.7 ................................................................................................................ 12
1.8 ........................................................................................................ 13
1.9 ................................................................................................... 21
2: O & 29
2.1 JOULE ........................................................................... 29
2.2 .................................................................................... 30
2.3 ............................................... 30
2.4 ........................................ 31
2.5 ........... 36
2.6 ..................................................................................................... 40
2.7 ............................................................................ 40
2.8 .......................................................................... 43
2.9 .............................. 51
2.10 ..................................................................................................... 52
2.11 () .......................................... 54
2.12 .................. 60
3: .................................. 87
3.1 PVT ...................................................... 88
3.2 ................................... 95
3.3 O E ........................................................................................ 99
3.4 ...................................................... 117
3.5 ............................................................ 122
3.6 VAN DER WAALS .............................................. 122
3.6 .................................................... 133
3.7 ..................................................... 145
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4: ...................................................................... 167
4.1 ................................................................ 168
4.2 ................................... 178
4.3 ......................................................... 181
4.4 ..................................................... 183
4.5 ................................................................. 186
4.6 H ........................................................ 187
4.7 ........................... 191
5: O ................................... 213
5.1 ...................................................... 214
5.2 ................................................................................... 215
5.3 ....................................... 219
5.4 ..................................................................................................... 225
5.5 ..................................... 229
5.6 ............................... 234
5.7 ................................... 238
5.8 ................................................................ 244
5.9 ........................................................................................... 250
5.10 ............................................ 255
5.11 ................................... 255
6: ..................................... 271
6.1 ........................................... 272
6.2 ...................................................................... 284
6.3 ..294
6.4 ................................................................................ 302
6.5 .............................................................. 308
6.6 ......................................... 310
6.7 ................................ 314
7: E .............. 347
7.1 ................................................ 350
7.2 () ............................................................................ 366
7.3 .............................................................................. 374
8: ............................................... 397
8.1 ............................................ 399
8.2 ................................................................ 413
8.3 , ..................................... 424
9: .................................................................... 433
9.1 H CARNOT ....................................................................... 434
9.2 .................................................................. 435

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9.3 ......................................................................... 439
9.4 ............................................................................. 442
9.5 ............................................................................. 445
9.6 ......................................................................... 446
10: I - : E ......................................... 459
10.1 ........................................................................ 460
10.2 . DUHEM .............................. 461
10.3 - (VLE): .................. 463
10.4 - ........................................ 472
10.5 RAOULT ............................................... 484
10.6 VLE .............................................................. 491
11: : ....................................... 509
11.1 ............................................................. 510
11.2 ........................... 512
11.3 ................................................................................... 513
11.4 .................................. 527
11.5 ..531
11.6 & : .539
11.7 ......... 547
11.8 ............................................ 552
11.9 ............................................................................. 555
12: : E ................................. 577
12.1 ......................................................................................................... 577
12.2 GIBBS ............................................... 597
12.3 ........................................ 602
12.4 ...................................... 609
13: .............................................. 643
13.1 ..................................................... 644
13.2 . 649
13.3 GIBBS ............................................................................................................ 651
13.4 ................. 654
13.5 .................................................. 659
13.6 ...................... 661
13.7 ........ 666
13.8 DUHEM ....................................................................................... 682
13.9 ................................................. 687
13.10 ............................................................................... 700

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14: ...................................................... 721
14.1 - VLE .............................................................. 721
14.2 - ... 735
14.3 ................................................................. 757
14.4 - (LLE) ............................................................... 765
14.5 -- (VLLE) ............................................... 775
14.6 - (SLE) ........................................................... 783
14.7 - (SVE) ......................................................... 789
14.8 .......... 794
14.9 ........................................ 813
15: ....................................... 831
15.1 ......................................................................................................... 831
16: E ................................... 843
16.1 ............................................................ 843
16.2 . 850
16.3 : .854
16.4 .................. 857
16.5 .............. 860
16.6 ......................................... 864
16.7 ..................... 867
16.8 - ............................................................................... 872

A: & .877
: .........................................................879
: E ...........883
: ............889
E: Lee-Kesler..............................897
: ..................................................................915
: ......................................................959
: UNIFAC....................................................................962
: NEWTON.................................................................969
..................................................................................................975

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J. M. Smith
H. C. Van Ness
M. M. Abbott

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