Isotherm adsorbs karbob aktif

1. Standarisasi NaOH
V1 N1 = V2 N2
0.1 x 10 = 10.2 x V2
V2 = 0.098 N
2. Konsentrasi asam lorida sebelum penambahan arang
Disini M = N
Konsentrasi 0.500 N
V1 x
N1 = V2 x N2
37.7 x 0.098 = 5 x N2
N2 = 0.74 N
Konsentrasi 0.250 N
V1 x
N1 = V2 x N2
14.8 x 0.098 = 5 x N2
N2 = 0.29 N
Konsentrasi 0.125 N
V1 x
N1 = V2 x N2
7.4 x 0.098 = 10 x N2
N2 = 0.072 N
Konsentrasi 0.0625 N
V1 x
N1 = V2 x N2
8.5 x 0.098 = 10 x N2
N2 = 0.08 N
Konsentrasi 0.0313 N
V1 x
N1 = V2 x N2
4.0 x 0.098 = 10 x N2
N2 = 0.04 N
Konsentrasi 0.0156 N
V1 x
N1 = V2 x
2.30 x 0.098 = 10 x
N2 = 0.022 N

N2
N2

3. Konsentrasi asam klorida setelah penambahan arang

Konsentrasi 0.500 N
V1 x
N1 = V2 x N2
36.5 x 0.098 = 5 x N2
N2 = 0.715 N

Konsentrasi 0.250 N
V1 x
N1 = V2 x N2
16.7 x 0.098 = 5 x N2
N2 = 0.327 N
Konsentrasi 0.125 N
V1 x
N1 = V2 x
15.7 x 0.098 = 10 x
N2 = 0.154 N

N2
N2

Konsentrasi 0.0625 N
V1 x
N1 = V2 x N2
7.1 x 0.098 = 10 x N2
N2 = 0.069 N
Konsentrasi 0.0313 N
V1 x
N1 = V2 x N2
3.4 x 0.098 = 10 x N2
N2 = 0.033 N
Konsentrasi 0.0156 N
V1 x
N1 = V2 x N2
1.6 x 0.098 = 10 x N2
N2 = 0.0157 N

4. Penghitungan zat terdisosiasi (C)

C1 = Cawal Cakhir
= 0.74 0.715
= 0.025
C2 = Cawal Cakhir
= 0.29 0.327
= - 0.037
C3 = Cawal Cakhir
= 0.072 0.154
= -0.082
C4 = Cawal Cakhir
= 0.08 0.069

C5
C6

= 0.011
= Cawal Cakhir
= 0.04 0.033
= 0.007
= Cawal Cakhir
= 0.022 0.057
= 0.0063

5. Jumlah zat teradsorbi

X1 =

C1 x Mr x

0.025 x 36.5 x

= 45.625 x 10-3
X2 =

C2 x Mr x

C3 x Mr x

X4 =

C4 x Mr x

X5 =

C5 x Mr x

X6 =
=

C6 x Mr x

50
1000

v
1000

0.007 x 36.5 x

= 0.12775

50
1000

v
1000

0.011 x 36.5 x

= 0.20075

50
1000

v
1000

0.082 x 36.5 x

= 0.14965

50
1000

v
1000

0.037 x 36.5 x

= 67.525 x 10-3
X3 =

v
1000

50
1000

v
1000

0.0063 x 36.5 x

50
1000

= 0.114975
6. Log C
Log C1 = log 0.025 = - 1.602
Log C2 = log 0.037 = - 1.4318
Log C3 = log 0.082 = - 1.0862
Log C4 = log 0.011 = - 1.9586
Log C5 = log 0.007 = - 2.1549
Log C6= log 0.0063 = - 2.2006
7. Log x/m
a. Log

x
m

= log

0.045625
0.5

= - 1.0397

b. Log

x
m

= log

0.067525
0.5

= - 0.8695

c. Log

x
m

= log

0.14965
0.5

= - 0.5239

d. Log

x
m

= log

0.20075
0.5

= - 0.3963

e. Log

x
m

= log

0.12775
0.5

= - 0.5926

f. Log

x
m

= log

0.114975
0. 5

= - 0.6392

Tabel 1. Data hasil pengamatan

Konsentrasi HCl
(N)
0.500
0.250
0.125
0.0625
0.0313
0.0156

volume titrasi awal (ml)

HCl
5
5
10
10
10
10

NaOH
37.7
16.7
15.7
8.5
7.0
2.3

Volume titrasi akhir (ml)

HCl
5
5
10
10
10
10

NaOH
36.5
14.8
7.4
7.1
3.4
1.6

Tabel 2. Data hasil perhitungan

Konsentrasi Asam
(M)
Awal
Akhir

C
(Cawa -Cakh)

x (Gram)

x/m

Log x/m

Log C

0.715

0.025

0.045625

0.09125

- 1.0397

- 1.602

0.290

0.327

0.037

0.067525

0.13505

- 0.8695

- 1.4318

0.5

0.154

0.072

0.082

0.14965

0.2993

- 0.5239

- 1.0862

0.5

0.069

0.080

0.011

0.20075

0.4015

- 0.3963

- 1.9586

0.5

0.040

0.033

0.007

0.12775

0.2555

- 0.5926

- 2.1549

0.5

0.022

0.0157

0.0063

0.114975

0.2299

- 0.6392

- 2.2006

No

Massa
(gr)

0.5

0.740

0.5

Y-Values
0.45
0.4
0.35
0.3
0.25
Axis Title

0.2
0.15

Y-Values
f(x) = - 0.08x + 0.24
R = 0

0.1
0.05
0
0 0.010.020.030.040.050.060.070.080.09
Axis Title

Linear (Y-Values)

Grafik 1. kurva log x/m vs log C

0
-2,000 -1,500 -1,000 -500
0
-0.2
-0.4
log x/m

-0.6
f(x) = 0x - 0.6
-0.8
R = 0.57

Grafik Hubungan
Antara log x/m vs log
C
Linear (Grafik
Hubungan Antara log
x/m vs log C)

-1
-1.2
log C

DISTRIBUSI ZAT TERLARUT

1. Standarisai asam oksalat :
V1 N1
= V2 N2
10.6 x N1

= 10 x 0.25 x 2

N2 = 0.47 N
2. Menentukan konsentrasi awal asam asetat
Konsentrasi 1 M
V1 x
M1 = V2 x M2

21.6 x 0.47 = 10 x M2
M2 = 1.0152 M
Konsentrasi 0.80 M
V1 x
M1 = V2 x M2
17,5 x 0.47 = 10 x N2
M2 = 0.8225 M
Konsentrasi 0.60 M
V1 x
M1 = V2 x M2
13,05 x 0.47 = 10 x M2
M2 = 0.6133 M
Konsentrasi 0.4 M
V1 x N1 = V2 x M2
8.65 x 0.47 = 10 x M2
M2 = 0.4065 M
Konsentrasi 0.2 N
V1 x
N1
= V2 x M2
4.4 x 0.47 = 10 x M2
M2 = 0.2068 M
3. Menentukan konsentrasi akhir asam asetat
Konsentrasi 1 M
V1 x
M1 = V2 x M2
14.1 x 0.47 = 10 x M2
M2 = 0.6627 M
Konsentrasi 0.80 M
V1 x
M1 = V2 x M2
11.5 x 0.47 = 10 x M2
M2 = 0.5405 M
Konsentrasi 0.60 M
V1 x
M1 = V2 x M2
9.1 x 0.47 = 10 x M2
M2 = 0.4277 M
Konsentrasi 0.4 M
V1 x M1 = V2 x M2
6.1
x 0.47 = 10 x M2
M2 = 0.2867 M
Konsentrasi 0.2 N
V1 x
M1 = V2 x M2
2.8 x 0.47 = 10 x M2
M2 = 0.1316 M

4. Selisih asam asetat awal dan akhir

a.
1.0152 0.6627
= 0.3525
b.
0.8225 0.5405
= 0.2820
c.
0.6133 0.4277
= 0.1856
d.
0.4065 0.2867
= 0.1198
e.
0.2068 0.1316
= 0.0752
5. Menghitung koefisien Distribusi (KD)
KD =

M awal
M awalM akhir

a. KD1 =

1.0152
0.3525

= 2.88

b. KD2 =

0.8225
0.2820

= 2.9166

c. KD3 =

0.6133
0.1856

= 3.3044

d. KD4 =

0.4065
0.1198

= 3.3931

e. KD5 =

0.2068
0.0752

= 2.75
Tabel 1. Data Pengamatan

Konsentrasi
No

CH3COOH
(M)

volume titrasi awal (ml)

CH3COOH

Volume titrasi akhir (ml)

NaOH
V1

V2

Vrata

CH3COOH

NaOH
V1

V2

Vrata

10

21.4

21.8

21.6

10

14.1

14.1

0.8

10

17.6

17.4

17.5

10

11.5

11.5

0.6

10

13.1

13

13.05

10

9.1

9.1

0.4

10

8.6

8.7

8.65

10

6.1

6.1

0.2

10

4.5

4.3

4.4

10

2.8

2.8

Tabel 2. Data hasil perhitungan

No

Konsentrasi awal
CH3COOH

1
2
3
4
5

1.0152
0.8225
0.6133
0.4065
0.2068

Konsentrasi
CH3COOH dalam
air
0.6627
0.5405
0.4277
0.2867
0.1316

Konsentrasi CH3COOH
awal- konsentrasi dalam
air
0.3525
0.2820
0.1856
0.1198
0.0752

Koefisien distribusi (Kd)

2.880
2.9166
3.3044
3.3931
2.75

Garafik 1. konsentrasi CH3COOH dalam air vs dalam eter

0.7
f(x) = 1.8x + 0.05
R = 0.97

0.6
0.5
0.4

Y-Values

konsentrasi CH3COOH dalam eter 0.3

Linear (Y-Values)

0.2
0.1
0
0

0.2

0.4

konsentrasI CH3COOH dalam air

PERSAMAAN ARRHENIUS DAN ENERGI KTIVASI

1. Menghitung konsentrasi
mgrek H2O2 = M . V . x
= 0,04 x 5 x 2
= 0,4 mgrek
mgrek KI = M . V . x
= 0,1 x 10 x 1
= 1 mgrek
mgrek Na2S2O3 = M . V . val
= 0,001 x 1 x 2
= 0,002 mgrek (pereaksi batas)
Mgrek H2O2 yang bereaksi
[H2O2]Awal =

Mx ml
Vtotal

0.04 x 5
22

= 0.0091

0.04

[H2O2]bereaksi = 2 x 22 = 9.09 x 10-4

Menghitung nilai K
[ H 2 O2]bereaksi

K = [ H 2O 2 ] Awal X t

K1 =

9.09 x 104
9.09 x 103 x 18

= 5.55 x 10-3

K2 =

9.09 x 104
9.09 x 103 x 12

= 8.33 x 10-3

K3 =

9.09 x 104
3
9.09 x 10 x 10

= 0.01

K4 =

9.09 x 10
3
9.09 x 10 x 7.8

= 0.0128

Menghitung nilai ln K
Ln K1 = ln 5.55 x 10-3

= -5.1939

Ln K2 = ln 8.33 x 10-3

= -4.787

Ln K3 = ln 0.01

= -4.605

Ln K4 = ln 0.0128

= -4.358

Menghitung 1/T
T = 285.15

1
T

T = 294.15

1
T

= 285.15 = 0.0035069
=

1
294.15

= 0.0033996

T = 302.65

1
T

1
302.65

= 0.0033041

T = 316.15

1
T

= 316.15 = 0.0031631

Tabel 1. Data hasil pengamatan

Suhu awal (C)

Suhu akhir
No
Tabung 1 Tabung 2 campuran campuran(C)
1
2
3
4

10
20
30
44

10
20
30
44

10
20
30
44

14
22
29
42

Rata rata
suhu (C)
12
21
29.5
43

Waktu
reaksi
(secon)
18
12
10
7.8

Tabel 2. Data hasil perhitungan

No
1
2
3
4

Rata rata suhu (K)

285.15
294.15
302.65
316.15

1/T
0.0035069
0.0033996
0.0033041
0.0031631

K
5.55 x 10-3
8.33 x 10-3
0.01
0.0128

Ln K
-5.1939
-4.787
-4.605
-4.358

Grafik 1. ln K vs 1/T
-3.8
-4

-4.2
-4.4
ln K

-4.6

f(x) = - 2362.01x + 3.16

R = 0.96

Y-Values
Linear (Y-Values)

-4.8
-5
-5.2
-5.4
1/T

Menghitung Ea
Dari kurva diperoleh persamaanya y = -2362x + 3.1612 sehingga m = - 2362

Ln K = -

Ea
R

=-

Ea
R

Ea

=-m.R

x T

x ln A

= - (- 2362) . 8.3144 J/mol

= 19.6386 J/mol
Intercepe = ln A = + 3.1612