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DR Wong Kinetics Study of The Hydrolysis of Methyl Acetate by Acid
DR Wong Kinetics Study of The Hydrolysis of Methyl Acetate by Acid
Name
0.93
0.92
0.92
0.91
0.91
24
26
28
30
32
34
36
Temperature (C)
In room temperature
t(min)
26.3 second
10 min 7.9 second
20 min 11.8 second
30 min 10.68 second
40 min 3.3 second
50 min 1.1 second
60 min 4.28 second
80 min 4.38 second
From the equation of graph,
V - Vt
13.8
12.8
12.1
11.8
11.1
10.8
10.3
10.1
ln (V - Vt)
2.6247
2.5494
2.4932
2.4681
2.4069
2.3795
2.3321
2.3125
y = -0.0013x + 0.9603
= -0.0013(25) + 0.9603
= 0.9278
d2 = 0.9278
Therefore,
V = 100Vx / Vs + 25000d2/NM2Vs
Where V is the volume of sodium hydroxide required to neutralize hydrochloric acid and acetic acid
Vx is the volume of sodium hydroxide required to neutralize hydrochloric acid in 5ml
d2 is the density of methyl acetate
N is the molarity of sodium hydroxide
M2 is the molecular mass of methyl acetate
V = 100(26.5) / (104.6) + 25000(0.9278)/(0.2)(74.08)(104.6)
= 25.33 + 14.97
= 40.3 ml
2.5
ln (V-Vt)
2.4
2.3
2.2
2.1
0
10
20
30
40
50
Time(min)
60
70
80
90
In high temperature
t(min)
30 second
5 min 30 second
10 min 30 second
15 min 30 second
20 min 30 second
30 min 30 second
40 min 30 second
50 min 30 second
70 min 30 second
V - Vt
14.0
12.0
11.2
10.7
10.1
9.5
8.1
7.6
6.0
ln (V - Vt)
2.639
2.484
2.416
2.370
2.313
2.251
2.092
2.028
1.792
2.3
In (V-Vt)
2.1
1.9
1.7
1.5
0
10
20
30
40
time(min)
Ea
R
(T2 T1 / T2T1)
ln (0.0111 / 0.004) =
1.021 =
Ea
8.3145
Ea
-4
8.3145 1.505 x 10
Ea = 56377.36 J/ mol
50
60
70
80