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QM2ISM
QM2ISM
J(x, t) x
J(x, t).
page 11, Problem 1.14(a), line 1: |(x, t)2 |(x, t)|2 ; line 2: t
h2
h2
.
2mkB
3mkB
3(1.7
(6.6 1034 )2
= 6.2 1014 K.
1023 )(102 )2
1027 )(1.4
page 14, Problem 2.1(b), lines 1, 2, and 4: d (6 times); part (c), lines 1 and 2: d (5 times).
page 15, Problem 2.2, line 6: requuire require.
page 15, Problem 2.3, line 4: eia ea .
page 16, Problem 2.4, second line in the calculation of hx2 i: y 3 /4 should be y 2 /4.
page 16, Problem 2.5(a): in the first line, change 2 to .
page 18, Problem 2.7(b), last line (in box): eEn t/h eiEn t/h .
page 20, Problem 2.11(a), line five, first integral: e
page 21, Problem 2.11(a), second line of hp2 i: e
/2
/2
e .
2
e .
dV
V
.
dx
x
page 75, Problem 3.29, 4 lines from the end: zero finite (2h/).
page 76, Problem 3.31, lines 2 and 3:
dV
V
(four times).
dx
x
f
y
f
x ;
d2 Y
d2 X
.
2
dy
dy 2
page 90,
comment at the end: [In truth, this is not as decisive as it appears,
R Problem 4.4, 2attach the following
2
since 0 [(ln[tan(/2)]) sin d = /6, which is perfectly finite; itself blows up at 0 and , but sin tames
it.]
page 91, beginning of line 2: P3 P3 (x).
page 95, Problem 4.11, line 3: Eq. 4.15 Eq. 4.74.
page 98, Problem 4.15(b), second line, first term in big parentheses: a2 a in denominator.
page 100, Problem 4.19(d): insert period after p2 , and replace the rest with the following:
Lz also commutes with r, as we can show using a test function f (r):
h
h
(rf )
f
f
r
(rf )
r
[Lz , r]f =
y ,r f =
y
rx
+ ry
y
x
x
= ih x
f.
i
y
x
i
y
x
y
x
y
x
But
r
p 2
x
=
x + y2 + z2 = ,
x
x
r
so
r
r
x
y
y
x
= 0,
and hence [Lz , r] = 0 (and the same goes for the other two components). So L commutes with
H = p2 /2m + V (r). QED
page 104, Problem 4.27(b), first line: (12i + 12i) (12i + 12i).
page 104, Problem 4.27(c), second line, after the second equals sign:
h
2
4 .
page 107, Problem 4.32(b), line 2, third term: sin 2 eiB0 t/2 sin 2 eiB0 t/2 .
page 108, Problem 4.34(a), line 2: (Eq. 4.143) (line above Eq. 4.146).
page 109, Problem 4.36 (a): after the second comma in the box, it should read or 0 (probability 6/15).
page 111, Problem 4.39, third line from bottom: in the second term, (l + 2) (l + 1).
page 112, Problem 4.40(a), line 3: (iij ) (ihij ).
page 112, Problem 4.40(b), last line: change hT i = hV i to hT i + hV i.
5
3
s
3a
3a
3a
page 115, Problem 4.43(c), second line: in the last two terms,
and
.
2
2
2
3
page 116, Problem 4.44(a): remove cos in the middle term; Problem 4.44(c): change 4(5) to 3(4) and 11 to 3.
page 118, Problem 4.48(b): 4.113 4.118.
page 119, Problem 4.51(a), line 1: Eqs. 4.136 and 4.144 Eq. 4.136 and line after Eq. 4.146; line 7: in the
second square brackets, S2 s2 .
page 120, Problem 4.51(a), line beginning where a . . . : Multiply by (a b) Multiply by (a m).
page 121, Problem 4.51(a), penultimate line: insert = 1 before the period.
page 123, Problem 4.54, line 1: begin with For positive upper index:; Ylm1 Ylm+1 .
page 123-124, Problem 4.54, bottom of page 123 to top of page 124, replace For m < 0 to just before Now,
Problem 4.22 with the following:
For negative upper index: write Ylm = Blm eim Plm and (Problem 4.18)
p
L Ylm = Am
Ylm1 = h (l m)(l + m + 1) Ylm1 .
l
Noting (Eq. 4.27) that Plm = Plm , we have (Eq. 4.130)
p
hei
i cot
Blm eim Plm = h (l m)(l + m + 1)Blm1 ei(m+1) Plm+1 ,
or
p
d
m cot Plm Blm = (l m)(l + m + 1) Blm1 Plm+1 .
d
As before,
d
m cot Plm = Plm+1 ,
d
so
Blm1 = p
(l m)(l + m + 1)
Blm .
Thus (using m = 0, m = 1, m = 2, . . . ):
1
Bl1 = p
l(l + 1)
Bl0 ;
Bl2 = p
(l 1)(l + 2)
Evidently
Blm = (1)m Blm ,
and in general,
s
Blm
where
=
(l |m|)!
C(l),
(l + |m|)!
(
(1)m , for m 0,
1,
for m 0,
Bl1 = p
(l + 2)(l + 1)l(l 1)
Bl0 , . . . .
Ax
y
Ax
z .
page 129, Problem 4.60(b), line 4 (the boxed equation): (A) ( A).
page 129, Problem 4.60(b), line 12 (starting with Now let . . . ): before the colon, insert (you can also do it in
Cartesian coordinates).
page 130, Problem 4.60(b), beginning of penultimate line: open parentheses after E =.
1
=
page 133, Problem 5.1(b), end of penultimate line: + m1 +m
2
1
m1 +m2 .
page 134, Problem 5.2(b), beginning of penultimate line: insert equals sign before
5
36 R.
1
24
d
24 .
1
0) 0
0
0 0
0
0 1 0.
1 0
1
1
2
h0
h
0
2 .
page 182, at end of Problem 6.31, insert the following: [There is an interesting fraud in this well-known problem.
If you expand H 0 to order 1/R5 , the extra term has a nonzero expectation value in the ground state of H 0 , so
there is a non-zero first-order perturbation, and the dominant contribution goes like 1/R5 , not 1/R6 (as desired).
The model gets the power right in three dimensions (where the expectation value is zero), but not in one. See
A. C. Ipsen and K. Splittorff, ArXiv: 1401.8144.]
page 188, last line: R31 R32 .
page 190, Problem 6.38, line 6: (Eq. 6.98) (Eq. 6.93).
page 192, line 3 of Off-diagonal elements: h|y 2 i h|y 2 |i.
page 194, Problem 6.40(a), penultimate line of (i): second-order first order; 2 lines below: 6.11 6.14.
2
h
2b
h
2b
page 197, line 3: hT i = 2m
hT i = 2m 4.
3
3
page 197, Problem 7.3, line 2: a3 a2 .
page 198, Problem 7.4(b), 3 lines from the end: in the expression for hHi, 2 .
page 200, line 1: in front of both integrals, a3 a2 .
page 200, line 4, inside first integral: e2R/a e2r/a .
page 203, last line, first term inside square brackets: 4n 1 4n + 1 (twice).
page 210, Problem 7.18, line 1: remove spurious extra equals sign.
page 211, mid-page, line beginning The term in . . . : (Z22 + Z12 ) (Z22 + Z12 )E1 .
page 211, last line: second (Z1 1) (Z2 1).
page 212, line 2 of hHi: 4E1 A2 4E1 A2 .
page 212, mid-page (three lines following hVee i): e e2 (3 times); in the first of these three lines, 2 (r1 ) + 1 (r2 )
2 (r1 )1 (r2 ) (i.e. remove the plus sign).
h
i
R
R0
0
0
0
0
0
i
i
1
Ae h x p(x ) dx + Be h x p(x ) dx
(x < 0)
p
p(x)
h
i
WKB (x) =
R
R
x
x
0
0
0
0
1
1
1
p
Ce h 0 |p(x )| dx + De h 0 |p(x )| dx
(x > 0)
|p(x)|
...
h
i
3/2
3/2
2
2
1
In overlap region 1, Eq. 8.43 becomes WKB 1/2
Aei 3 (x) + Bei 3 (x)
,
h 3/4 (x)1/4
...
r
r
h ia + b i/4
h ia + b i/4
A=
e
; B=
e
. Putting in the expressions above for a and b :
2
C
C
i/4
+ iD e
; B=
iD ei/4 .
A=
2
2
...
A=
C
i i/4
e
+ iD ei/4 =
e e
F + ie ei/4 F ei/4 =
+ e F.
2
4
4
2
F
1
e2
T = =
=
2.
A
(e + e 4 )2
[1 + (e2 /4)]
...
e2
40
e
4
; same at beginning of the next line.
0
page 235, Problem 8.17, insert the following at the end: [Actually, to tunnel all the way through the classically
forbidden region, the center of mass must not only rise from 0 to x0 , but also drop back to 0. This doubles ,
and makes the final exponent 1 1031 .]
page 236, Problem 9.1, line 3, last expression: er/2a er/2a .
page 236, Problem 9.1, last three lines: remove the minus signs in front of all 6 expressions.
page 237, line 6: Aei(0 +)/2 + Bei(0 )/2 Aei(0 +)t/2 + Bei(0 )t/2 .
page 237, end of Problem 9.2, add the following:
[In light of the Comment you might question the initial conditions. If the perturbation includes a
factor (t), are we sure this doesnt alter ca (0) and cb (0)? That is, are we sure ca (t) and cb (t) are
continuous at a step function potential? The answer is yes, for if we integrate Eq. 9.13 from to
,
Z
i 0
ca () ca () = Hab
ei0 t cb (t) dt.
h
0
But |cb (t)| 1, so the integral goes to zero as 0, and hence ca () = ca (). The same goes for cb ,
of course.]
.
3
3
page 244, line 8: 1 0 0i |1 0 0i.
page 245, line 5: insert 2i
h right after {.
2
4V0
4V0
.
page 250, Problem 9.18, line 4:
3
3
B0 a
Brf eit b
B0 a + Brf eit b
page 250, Problem 9.20(b), line 2, last term:
.
Brf eit a
B0 b
Brf eit a B0 b
page 253, Problem 9.22:
l0 = l + 1
From Eq. 9.69, hn0 l0 m0 |z|nlmi = 0 unless m0 = m, so the only nonzero z term is
Z
m 2
r dr sin d d
hn0 l0 m|z|nlmi =
Rn0 l0 (Ylm
0 ) r cos Rnl Yl
s
s
Z
(2l0 + 1) (l0 |m|)! (2l + 1) (l |m|)!
m
= I
Plm
cos sin d.
2
0 Pl
4
(l0 + |m|)!
4 (l + |m|)!
0
(1)
This is independent of the sign of m, so we might as well assume m 0. The integral (changing variables to
x cos ) is (using Eq. 9.99)
Z
Int =
m
x Pl+1
(x)Plm (x) dx
Z 1
Z 1
1
m
m
m
m
Pl+1 Pl+1 dx .
=
Pl+1 Pl1 dx + (l m + 1)
(l + m)
(2l + 1)
1
1
Now, it follows from Eq. 4.33 that the associated Legendre functions satisfy the orthogonality relation
Z 1
(l + |m|)!
2
m
Plm
ll0 ,
0 (x)Pl (x) dx =
(2l
+
1)
(l |m|)!
1
so
Int =
(2)
(l m + 1)
2
(l + 1 + m)!
2
(l + 1 + m)!
=
.
(2l + 1) (2l + 3) (l + 1 m)!
(2l + 1)(2l + 3) (l m)!
m)!
(l m)!
2
(l + 1 + m)!
hn0 (l + 1)m|z|nlmi =
(2l + 3)
(2l + 1)
2
(l + 1 + m)!
(l + m)! (2l + 1)(2l + 3) (l m)!
s
(l + 1)2 m2
.
= I
(2l + 1)(2l + 3)
(3)
d
cos ei(m+1) eim d. (4)
0
l
4
(l0 + m + 1)!
4 (l + m)! 0 l
0
1
Int =
2
2
i
(e
+e
)e
1
d =
2
(1 + e2i ) d = .
(5)
=
1
p
m+1
1 x2 Pl+1
(x)Plm (x) dx =
1
(2l + 1)
2
(l + m + 2)!
.
(2l + 1)(2l + 3) (l m)!
Z
m+1 m+1
Pl+1
Pl+1
dx
1
m+1 m+1
Pl+1
Pl1
dx
hn (l + 1)(m + 1)|x|nlmi =
I
2
I
2
(l m)!
(2l + 3)
(l + m + 2)!
s
(2l + 1)
(l m)!
1
(l + m + 2)!
(l + m)! (2l + 1)(2l + 3) (l m)!
(l + m + 2)(l + m + 1)
.
(2l + 1)(2l + 3)
(6)
d
cos ei(m1) eim d. (7)
= I
0
l
4
(l0 + m 1)!
4 (l + m)! 0 l
0
Int =
1
2
(ei + ei )ei d =
1
2
(e2i + 1) d = .
(8)
=
1
m1
1 x2 Pl+1
(x)Plm (x) dx =
Z
1
(2l + 3)
1
m
Pl+2
Plm dx
Plm Plm dx
(l + m)!
2
,
=
(2l + 1)(2l + 3) (l m)!
and (7) becomes
I
hn (l + 1)(m 1)|x|nlmi =
4
I
=
2
(l m + 2)!
(2l + 3)
(l + m)!
s
(2l + 1)
(l m + 2)(l m + 1)
.
(2l + 1)(2l + 3)
(l m)!
2
(l + m)!
(l + m)! (2l + 1)(2l + 3) (l m)!
(9)
10
|2 (summed over the three allowed transitions) is e2 I 2 (l + 1)/(2l + 1), and the spontaneous emission
Therefore, |
rate (Eq. 9.56) is
e2 3 I 2 (l + 1)
.
30 hc3 (2l + 1)
All+1 =
(11)
l0 = l 1
Return to Eq. (1). This time the integral is
Z 1
Z 1
1
m
m
m
m
Pl1 Pl1 dx + (l m + 1)
Pl1 Pl+1 dx
=
(l + m)
(2l + 1)
1
1
1
(l + m)
2
(l 1 + m)!
2
(l + m)!
=
.
(2l + 1) (2l 1) (l 1 m)!
(2l 1)(2l + 1) (l m 1)!
Z
Int
=
=
m
x Pl1
(x)Plm (x) dx
Therefore
s
s
2
(l + m)!
I
(l
m)!
(l m)!
hn0 (l 1)m|z|nlmi =
(2l 1)
(2l + 1)
2
(l 1 + m)!
(l + m)! (2l 1)(2l + 1) (l m 1)!
s
l2 m2
= I
.
(2l 1)(2l + 1)
(12)
From hn0 l0 m0 |x|nlmi with m0 = m + 1, Eqs. (4) and (5) are unchanged; this time
Z
Int
=
1
1
(2l + 1)
Z
(l m 2)!
(2l 1)
(l + m)!
s
I (l m)(l m 1)
.
=
2
(2l 1)(2l + 1)
p
m+1
1 x2 Pl1
(x)Plm (x) dx =
m+1 m+1
Pl1
Pl+1 dx
m+1 m+1
Pl1
Pl1 dx
2
(l + m)!
,
(2l 1)(2l + 1) (l m 2)!
(2l + 1)
(l m)!
1
(l + m)!
(l + m)! (2l 1)(2l + 1) (l m 2)!
(13)
Now we do the same for m0 = m 1. Eqs. (7) and (8) are unchanged, the integral is
Z
Int
=
1
p
m1
1 x2 Pl1
(x)Plm (x) dx =
(l + m)!
2
,
(2l 1)(2l + 1) (l m)!
11
1
(2l 1)
Z
Plm Plm
dx
1
m
Pl2
Plm
dx
hn (l 1)(m 1)|x|nlmi =
I
2
I
2
(l m)!
(2l 1)
(l + m 2)!
s
(2l + 1)
(l m)!
1
(l + m)!
(l + m)! (2l 1)(2l + 1) (l m)!
(l + m)(l + m 1)
.
(2l 1)(2l + 1)
(14)
Thus
|hn0 (l 1)(m + 1)|r|nlmi|2 + |hn0 (l 1)m|r|nlmi|2 + |hn0 (l 1)(m 1)|r|nlmi|2
s
#2 " s
#2
" s
#2
"
l2 m2
I (l + m)(l + m 1)
I (l m)(l m 1)
+2
+ I
.
= 2
2
(2l 1)(2l + 1)
(2l 1)(2l + 1)
2
(2l 1)(2l + 1)
I 2 (l m)(l m 1) + 2(l2 m2 ) + (l + m)(l + m 1)
=
2
(2l 1)(2l + 1)
2
(2l
l)
l
= I2
= I2
,
(2l 1)(2l + 1)
(2l + 1)
(15)
l
e2 3 I 2
.
30 hc3 (2l + 1)
(16)
imb
h
w
imv
h
w .
page 255, Problem 10.1(b), line 3, upper limit of second integral: a; end of that line: c0n cn0 .
page 255, penultimate line, sin n
sin n
a
a x .
page 256, in the first box: Te a/v Te = a/v.
page 256, Problem 10.1(c), penultimate line:
mva2
2
ha
mva
2
h
mv(2a)2
2
h(2a)
mva
h
.
1 (1 )
i1 (1 )
.
dn
dz
dn
dz .
m 2
h
2k
V0
k
h
2
sin(2ka) R =
m 2
h
2k
V0
k
i2
sin(2ka) .
0 1 0
0 1
i = j 0 ; j = i0 ; k = k0 , so (Eq. A.61) S = 1 0 0 . S1 = 1 0
0 0 1
0 0
STx S1
0
0 .
1
0 1
= 1 0
0 0
0 1
= 1 0
0 0
0
1
0
0
0 1 0
0 0 cos sin 1 0 0
1
0 sin
cos
0 0 1
0
1
0
cos 0 sin
0
1
0 = Ty ().
0 cos 0 sin = 0
sin 0
cos
sin 0 cos
1
0
cos 0 sin
0 1 0
0 0
1
0 1 0 0
1
sin 0 cos
0 0 1
0
0 cos sin
1
0
0
0 1
0
0 = 0 cos sin = Tx ().
1
0
sin
cos
0 sin
cos
STy S1
0 1
= 1 0
0 0
0 1
= 1 0
0 0
Is this what we would expect? Yes, for rotation about the x axis now means rotation about the y 0 axis, and
rotation about the y axis has become rotation about the x axis.
page 297, Problem A.28(a), first line of part (ii): M3 = 3 M M3 = 2 M.
13