LNG Plant Project 4 PEAU LNG CB&! Limited Document Titie: Document Number: , PERU LNG Peru LNG S.R.L. 157883-011-CG-MA-0001 Operating Manual - Acid Gas Removal & Hot Oil Revision: ci . DCC L.D.: 9039 Pages: 1 of 52 | S| oe Las ci_| st Julos Client Comment Gs JM JM Rev Date Purpose of Issue By Check ‘CBal Client Approved | Approved J Uncontrolled if printedLNG Plant Project d Operating Manual - Acid Gas Removal & Hot, 2 157883-011-CG-MA-0001 Revision C1 ee INPUTS Document Number Title Status 157883-01 1-PR-TN- Operating Guideline Acid Gas Removal Rev C1 0001 157883-041-PR-TN- | Operating Guideline Hot Oil System Rev D1 0001 L REVISION NOTES AND HOLDS: Revision Description of Changes & Holds HOLDS: ct 1. Controller Set Points, Alarm Points and Trip Settings Note: The latest version of this document is stored in EDM. Any prints of this document are uncontrolled. Uncontrolled if printed Page 2 of 52LNG Plant Project , Operating Manual - Acid Gas Removal & Hot Oil 157883-011-CG-MA-0001 Re PERU LNG Executive Summary ‘The Peru LNG Plant Project is to be constructed in Pampa Melchorita, situated on the west coast of Peru, approximately 170 km South of Lima. CB&l's work encompasses treatment of the inlet gas, liquefaction, LNG storage, ship loading facilities, power generation, plant utilities, and related ancillary buildings and systems, Feed gas will arrive by a high pressure pipeline to the site from the Camisea Gas Project in the Camisea region, 500 km east of Lima. The gas delivery pressure at the plant inlet ranges from 81 bara to a maximum of 150.2 bara under line pack conditions. The feed gas to the LNG facility has been processed to remove virtually all propane and heavier components at the Malvinas facility located upstream near the gas production in the Camisea region. The Acid Gas Removal Unit (AGRU) is used to remove the CO, from the feed gas to give a ‘sweet gas’ with acceptable levels of CO, (less than 50 ppm(v)) for the downstream LNG liquefaction process. This Operating Manual describes the commissioning, operations and maintenance requirements for the Acid Gas Removal Unit (AGRU) facilities supplied on the Peru LNG site. Health and Safety aspects are also considered. Uncontrolled if printed Page 3 of 52LNG Plant Project b Operating Manual - Acid Gas Removal & Hot Oil sgau' LNG 157883-011-CG-MA-0001 Revision C1 Contents. 1. INTRODUCTION 1.1. Acid Gas Removal (AGR) 1.2 Amine Regeneration. 1.3 Amine Storage/Reco\ 1.4 Hot Oi 2. OVERVIEW OF THE PROCESS.. 2.1 Feed Gas Conditions and Compositions. 2.2 Dehydration Spent Regeneration Gas Recycle Stream . 2.3 Treated Gas Conditions 2.4 Turndown, Flexibility and Run Length.. 2.5 Design Information for Hot Oil System (Unit 4100) . 2.6 Environmental. 2.7 Reference Document: 3. UTILITIES AND CHEMICALS. 3.1 Hot Oil. 3.2 Cooling Mediu 3.3 Wash Water/Make Up Water. 3.4 Nitrogen.. 3.5 Chemicals. 4. PROCESS AND OPERATING PRINCIPLES 4. Equipment Des n, AG! 42 Piping. 4.3 Equipment Description, Hot Oi 4.4 Controller Set Points, Alarm Poi 5. OPERATING PHASES 5.1 Prior to Initial Start-up. 5.2 Hot Oil System. 5.3 Acid Gas Removal 6. SAFETY AND HEALTH CONSIDERATIONS. 6.1 General 6.2 Material Safety Information for aMDEA. 6.3 Material Safety Information for Hot Oi APPENDIX 1 ~ PFD & UFD. APPENDIX 2 - P2IDS... APPENDIX 3 ~ C&E DIAGRAMS. Uncontrolled if printed Page 4 of 52LNG Plant Project ? Operating Manual - Acid Gas Removal & Hot Oil 157883-011-CG-MA-0001 Revision C1 Kista Ca} 1 INTRODUCTION Acid Gas Removal (AGR) ‘The AGR unit is used to remove carbon dioxide (CO;) from the feed gas to give a ‘sweet gas’ with acceptable levels of CO: (less than 50 ppm(y)) for the downstream LNG liquefaction process. The process is a licensed proprietary design from BASF using a proprietary solvent solution of activated Methyl-Di-Ethanol-Amine (aMDEA) which reacts with the CO> in the gas in an exothermic reaction. The process has a continuous circulation loop of aMDEA solvent where the clean ‘lean’ solvent is contacted with the process gas at high pressure and reaction with CO, takes place giving a ‘rich’ aMDEA solvent solution. The ‘rich’ aMDEA solvent is then regenerated at low pressure using heat to boil off the CO, and revert back to a lean solution. The design of the AGR unit allows for a possible future design condition where the regeneration gas from the dehydration unit is recycled and mixed with the inlet feed stream. Acid gas contaminants in the natural gas (principally CO;) are removed to acceptable levels by amine absorption. Acid gas contaminants are removed by counter-current contact of the feed gas with the circulating amine solution in the AGR Absorber (C-1101). The inlet feed gas at 18°C and 75.4 bara is cross exchanged in the Inlet Gas Heat Exchanger E-1105 with the treated gas leaving the AGR Absorber to raise the feed gas temperature to 35°C. The higher gas temperature is required to promote the reaction of the CO> in the feed gas with the amine solution in the absorber. The sweet treated gas exits the absorber at 58°C and 74.8 bara. C-1101 has two beds of packing to contact the gas and circulating solvent. The column also has a hydrocarbon skimming compartment in the liquid sump section which can be used occasionally to collect any oil/heavy hydrocarbon liquid layer that may accumulate in the column. This occasional operation would be carried out manually by the operators by adjustment of the fevels in the bottom of the column to allow overflow into the compartment. The compartment is drained manually to the Amine Solvent Sump Drum (V-1106). Alter the CO, is removed the treated gas is cooled to between 11°C and 34°C by cross exchange with the feed gas in E-1105. This also condenses water from the gas stream that is picked up in the amine absorber. The cooled gas enters the Treated Gas Wash Drum (V-1105) where make-up water is used to wash the gas stream and remove amine carryover from the sweetened gas. The vessel has three trays to contact the treated gas with the demineralised water. The wash water is supplied from the Demineralised water system and the flow is controlled by the adjustable stroke reciprocating type AGR Water Make-up Pumps (P-1 105A/B) which operate on a duty and standby basis. The make-up water and the condensed water from the Treated Gas Wash Drum (V-1105) are sent under level control to the HP Flash Vessel (C-1103) to act as water make-up to the amine unit. The treated sweet feed gas from V-1105 at 43°C and 74.2 bara is then sent to the Dehydration unit Treated Gas Air Cooler (E-1301). The sweet gas quality is monitored by a CO; gas analyzer AT-111001 in the outlet line from V-1105. Page 5 of 52LNG Plant Project , Operating Manual - Acid Gas Removal & Hot Oil peau LNG 157883-011-CG-MA-0001 Revision C1 1.2 ‘Amine Regeneration The rich amine solvent leaves the bottom of the AGR Absorber (C-1101) at 74.9 bara and 39.7°C under level control and is flashed to 5.5 bara in C-1103. The vessel has 3 trays at the top to wash the flash gas with the reclaimed wash water stream from V-1105 and a section of packing for degassing the flashed aMDEA below the aMDEA inlet The column also has a hydrocarbon skimming compartment in the liquid sump section which can be used occasionally to collect any oil/heavy hydrocarbon liquid layer that may accumulate in the column. This occasional operation would be carried out manually by the operators by adjustment of the levels in the bottom of the column to allow overflow into the compartment. The compartment is drained manually to the Amine Solvent Sump Drum (V-1106). Flash gas from the HP Flash Vessel is fed via a back pressure control valve to the LP fuel gas system, which operates at 5 bara. The rich amine solution from the HP Flash Vessel is then heated against lean amine in the plate type exchanger AGR Rich / Lean Solvent Cooler (E-1103), before being passed under fevei contro! to the top of the AGR Regenerator (C- 1102). In the AGR Regenerator the acid gases are thermally stripped from the amine solution. The AGR Regenerator has 3 trays at the top to aid reflux then two sections of packing with each bed having a liquid distributor, a chimney tray for the reboiler liquid draw-off and liquid sump at the bottom of the column for the reboiler liquid return. The AGR Regenerator also has a hydrocarbon skimming compartment in the bottom liquid sump section which can be used occasionally to collect any oil/ heavy hydrocarbon liquid layer that may accumulate in the column. This occasional operation would be carried out manually by the operators by adjustment of the levels in the bottom of the column to allow overtiow into the compartment. The compartment is drained manually to the Amine Solvent Sump Drum (V-1 108). The kettle type AGR Regenerator Reboilers (E-1104A & B) use 170°C hot oil from the hot oil system to reboil the amine at the bottom of the AGR Regenerator (C- 1102). The hot oil system operates with a maximum oil temperature of 170°C to avoid degradation of the amine solution in the reboiler. The water in the overheads gas from the AGR Regenerator is condensed in the AGR Regenerator Overhead Condenser (E-1102) air cooler at 50°C. The water is retumed from the AGR Regenerator Reflux Drum (V-1104) as reflux under level control to the stripper tower by the AGR Regenerator Reflux Pumps (P-1102 A/B) which operate on a duty/standby basis. The overhead vapour from the AGR Regenerator Reflux Drum is vented directly to the atmosphere by a back pressure controller. The lean amine solution from the AGR Regenerator bottoms is cooled from 114°C. to 58°C by cross exchange with the rich amine solution in the AGR Rich / Lean Solvent Cooler (E-1103). The lean amine solution is then pumped to 10.4 bara by the AGR Lean Solvent Booster Pumps (P-1101A/B) to the AGR Lean Solvent Charge Pumps (P-1103A/B) where it is raised in pressure to 81.4 bara. The high pressure lean amine satution from the AGR Lean Solvent Charge Pump is cooled in the AGR Lean Solvent Cooler (E-1101) to 50°C, and returned to the top of the AGR Absorber. Both sets of pumps are operated on a duty/standby basis. Page 6 of 52LNG Plant Project ) Operating Manual - Acid Gas Removal & Hot Oil 157883-011-CG-MA-0001 Revision C1 ee 13 14 A slipstream of the amine solution from the discharge booster pumps is passed under flow control through a set of filters to remove solids and hydrocarbons from the lean amine solution and returned back into the pump suction. The filtration is required to maintain the performance of the AGA primarily fo reduce foaming caused by build-up of heavier hydrocarbon fractions in the aMDEA to reduce erosion. There are three filters in series, these being; 2 S101 AGR Lean Solvent Filter _- particulate filter * §-1102 AGR Solvent Carbon Filter - activated carbon filter © $1103 AGR Solvent Afterfilter - activated carbon fines filter Provision is made for the injection of antifoam using portable containers at the AGR Regenerator Reflux Pumps (P-1102A/B) and the AGR Lean Solvent Charge Pumps (P-1103/B). Amine Storage/Recovery The aMDEA solution is made up/stored in the Solvent Tank (T-1101) which has a nitrogen blanket gas arrangement to prevent degradation of the solvent by oxygen and corrosion in the AGR circuit. The aMDEA solvent will be supplied in drums or containers and transferred by portable pumps in to the tank. Demineralised water is added manually to the tank to dilute the solvent to the desired concentration. The contents of the tank can be mixed by circulation or transferred to the AGR Regenerator (C-1102) by the AGR Solution Make-up Pump (P-1 106). . The AGR unit has a dedicated closed drain system allowing recovery of the aMDEA solvent to the AGR Solvent Sump Drum (V-1106). This vessel is located in an in-ground sump and is provided with a nitrogen blanket system to avoid the ingress of any air to the circuit and a demineralised water connection for solvent dilution. The vessel contents can be transferred to the Solvent Tank by the AGR Solvent Drum Pump (P-1104) through the Solvent Drum Sump Filter (S-1104) which removes any particulate contamination. V-1106 also has a connection for complete emptying via a vacuum truck for inspection which also can be used for solvent make-up. The drum also has a hydrocarbon compartment which can be used to skim off any layers of oil residue that may accumulate in the drum. This skimming operation would be manual by adding demineralised water to fill the compartment and induce overflow into the compartment. Any recovered oil would be removed by vacuum pump. Hot Oil General process heating, primarily for AGR regeneration reboilers, inlet gas heating, and fuel gas heating is provided from a circulating hot oil system using two direct fired heaters. The direct fired heaters are rated for 96 GW/hr for the normal operating case and 118 GJ/hr for the start-up case to provide reliability and adequate capacity for all potential scenarios. The hot oil system provides heat to: * Inlet Gas Hot Oil Heater, E-1001. AGRU Regeneration Reboilers, E-1104A/B. * HHP Fuel Gas Heater, E-5203. The equipment associated with the Hot Oil system, Unit 4100, is located within the Common area of the plant. The hot oil storage facility (T-4101 & P-4102) is provided for charging and making up losses (from leakage and maintenance drains) for the hot oil system. Uncontrolfed if printed Page 7 of 52LNG Plant Project a Operating Manual - Acid Gas Removal & Hot Oil 187883-011-CG-MA-0001 Re! PERU ING 24 OVERVIEW OF THE PROCESS The Acid Gas Removal Unit (AGRU) is located between the Infet Area (Unit 1000) and the Dehydration unit (Unit 1300). The AGRU is required to remove CO, contained in the feed gas supply to less than 50 ppmvy, in the treated gas stream, to prevent freezing of CO; and blockage in the downstream liquefaction unit. ‘The proprietary BASF aMDEA (activated MDEA) has been selected as the solvent for CO, removal. During initial plant operation the feed gas to the LNG plant will contain 0.57 mol% CO,. However, it is anticipated that the CO, concentration may increase up to a maximum of 1.5 mol% in the future. Therefore the AGRU is designed for a CO, concentration of 1.5 mol%, The AGRU is designed to operate with the CO, concentration ranging from 0 to 1.5 mol% in the feed gas supply. The unit is also designed to turn down to 15% of design feed gas flow during start-up. Feed Gas Conditions and Compositions The feed gas supply to the LNG plant is from the Camisea Gas Plant, an NGL facility, where the heavy hydrocarbons, propane and heavier, are Separated and removed from the natural gas. In this process the natural gas is dried such that it contains less than 1 — 2 ppmy of water. : The CO, concentration in the feed gas supply will vary over the life of the project. The feed gas supply is not expected to contain any elemental sulphur nor any sulphur compounds. The acid gas removal unit design is based on two main operating cases, the normal case with a CO, concentration of 0.57 mol%, and a design case with a CO, concentration of 1.5 mol%. The feed gas supply temperature at the LNG plant battery limit will vary between 11 and 21°C. As the pressure is let down in the inlet area from the supply pressure to the LNG plant operating pressure there will be a cooling effect, significantly cooling the gas to well below the supply temperature. The gas supply temperature to the AGRU will be controlled to approximately 18 °C by the inlet gas hot oil heater. In addition to the natural gas feed, the AGRU will also be required to treat the spent regeneration gas recycled from the downstream molecular sieves. The design case for the AGRU includes the addition of spent regeneration gas to the natural gas feed. Details of both the normal and design cases are given below: Uncontrolled if printed Page 8 of 52LNG Plant Project d Operating Manual - Acid Gas Removal & Hot Oil ae 187883-011-CG-MA-0001 Revision C1 ENG Units fcnaee moo: Design Case Feed Temperature °c 1B 18 18 Feed Pressure bara 75.4 75.4 75.4 Feed Gas Total Mass Flow * kg/h 600,262 615,080 645,910 (Note 1) (Note 2) (Note 2) (Note 3) Feed Gas Molecular Weight 1772 1797 17.95 ‘Component: Nitrogen mol% 054 053 0531 ‘Carbon Dioxide mol% O57 1.50 1.427 Methane mol% 88.54 8771 87.775 Ethane mol% 10.33 10.24 10.247 Propane mol% 0.02 002 0.02 Total mol% 100.00 100.00 to000 | Notes: . 1. Flow rates are based on plant in holding mode, with minimum Boil Off Gas (806) generation 2. Total flow to the AGRU to achieve 100% LNG rundown not including the spent regeneration gas recycle. 3. Total design flow to the AGRU to achieve 100% LNG rundown including the regeneration gas recycle. The regeneration gas recycle flow (30,830 kg/hour) ties into the feed downstream of the Inlet Gas Heat Exchanger (E-1105). The feed gas may also contain the following contaminants: Water content 1-2 ppmv Hydrogen Sulphide ‘3mg/Sm' (2.2 ppmv) Total sulphur 15mg/Sm° (11 ppmv) Benzene 0.6mg/Sm° (0.2 ppmv) Uncontrolled if printed Page 9 of 52LNG Plant Project ¢ Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 157883-011-CG-MA-0001 Revision C1 22 23 231 2.3.2 Dehydration Spent Regeneration Gas Recycle Stream (Based on the installation of a regeneration gas compressor) Feed Temperature °C 87 Feed Pressure bara 749 Feed Gas Total Mass Flow kgh 30,830 Feed Molecular Weight kg/kmol 17.57 Component Mole % Nitrogen 0.54 Carbon Dioxide 0.00 [Methane 88.93 Ethane 10.37 Propane 0.02 Water 0.14 Total 100.00 ‘ Notes: 1. The dehydration recycle stream is the regeneration gas from the downstream dehydration unit. The source of the dehydration unit regeneration gas is treated gas from downstream of the molecular sieve beds 2, The AGRU is designed to remove CO, from the feed gas to less than 50 ppmv. The molecular sieve bed may pick up some of the residual CO) in the treated gas. The CO; picked up by the molecular sieve may peak into the regeneration gas at some Point in the regeneration cycle, but is still expected to be only in the ppmy range. 3, The dehydration recycle stream is not dry. 4, The composition of the regeneration stream is very similar for all feed gas CO. concentrations. For design purposes it has been assumed to be the same for all feed gas CO, concentrations. Treated Gas Conditions ‘The AGRU treated gas shall be guaranteed to meet the following specifications: * CO; concentration to less than 50 ppmv The AGRU treated gas specification shall be satisfied for all natural gas feed compositions (as defined in section 2.1). Acid Gas Product The CO, waste gas stream is vented directly to atmosphere at a safe location, HP Flash Gas Product ‘The HP flash gas vessel operates at 5.5 bara and vents the flashed vapour into the LP Fuel Gas system. Uncontrolled if Printed Page 10 of 52LNG Plant Project d Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 157883-011-CG-MA-0001 Revision C1 234 235 2.3.6 24 241 2.4.2 The design lean amine flow rate is 309,110 kg/hr. The amine is a 40 weight % aqueous solution Design Case The design case for the AGRU is feed gas containing 1.5 mol % CO, at a feed temperature of 18°C plus the spent regeneration gas recycle stream. Equipment design is specified to enable plant operation at a tumdown to 60% of gas flow, and for the initial gas feed composition (0.57 mol% CO;) Equipment Design Margins The AGRU equipment has no design margin except for those items req BASF performance guarantees. These are: * Lean Solvent Booster Pump, 5% on flow * Lean Solvent Charge Pump, 5% on flow * Regeneration Reboiler, 5% on reboiler duty. Guarantees BASF gives the following guarantees on aMDEA for the AGRU: . Feed gas throughput for AGRU: —_ As specified in Section 2.1 CO, spec. in treated gas: 50 ppmy Solvent circulation rate: As calculated + 5% Reboiler duty: As calculated + 5% “As calculated” represents the maximum calculated value of all the design cases. No further margins (over and above the 5% for the solvent circulation pumps and the reboiler) have been added to BASF's heat and material balance for the controlling case for Acid Gas Removal Unit equipment and line sizing. Turndown, Flexibility and Run Length Turndown The AGRU is designed to 60 % turndown of the natural gas feed rate. The dehydration recycle stream flow remains unchanged at the 60% natural gas tumdown rate, However, the unit is capable of operating at 15% of the design feed gas flow during start up. Flexibility The AGRU design is sufficiently flexible ta handle the vatiations in the natural gas feed flow rate, composition, and temperature. The lean solvent circulation rate can be varied with respect to feed gas flow and feed gas CO, content to minimise the reboiler duty and hence reduce fuel gas consumption in the fired heaters. This is conditional on maintaining stable operation of the AGRU. Uncontrolled if Printed Page 11 of 52LNG Plant Project Operating Manual - Acid Gas Removal & Hot Oil PERU LNG 157883-011-CG-MA-0001 Revision C1 243 25 251 26 26.1 Run Length The AGRU is designed to operate continuously for 3 years based on equipment requirements defined in Section 4. Design Information for Hot Oil System (Unit 4100) ‘A maximum operating temperature of 180°C (normal operating temp. 170°C) will be used to prevent degradation of the solvent in the acid gas removal unit. The design of the Hot Oil System is based on Therminol-5§ consisting predominantly of hydrocarbons with carbon numbers in the range of C20 through C50. The hot oil is anticipated to last. 15 years and will only require make-up, no replacement. The hot oil design conditions tor the LNG Plant are as follows: * Pressure: 15 barg / Full Vacuum . Temperature: 200°C Hat Oil ‘The Hot Oil Unit consists of the following items: Hot Oil Storage Tank, T-4101 Hot Oil Transfer Pump, P-4102. Hot Oil Expansion Drum, V-4101. . Hot Oit Circufation Pumps, P-4101A/B. Hot Oil Heaters, H-4101 A/B. Hot Oil Slipstream Filter, S-4101 The Hot Oil Circulation Pump, P-4101A/B draws oil from the expansion drum to the hot oil heaters (H-4101A/B) where it is heated to 170°C. The hot oil outlet temperature controls the fuet gas to the heater. Each user has its own temperature control, varying the oil flow with process duty. A common bypass under pressure differential control maintains a constant flow through the heater. Each return combines into a common header back downstream of the expansion drum. The expansion drum provides a buffer for variations in the system volume and allows the removal of gasses generated from degradation of the hot cil or leaks into the hot oil system. The drum is blanketed with nitrogen to maintain a constant system pressure during changes in system volume and to exclude air. The hot oil circulation pump will start automatically on low differential pressure. The stand by pump is kept warm with a bleed around its check valve. The hot oi! from draining of equipment during maintenance will be discarded. Environmental ‘The AGRU meets or exceeds all environmental emission requirements established by the World Bank. Vapour Emissions The acid gas stream from the regenerator is routed to atmosphere at a safe location. Dispersion analysis of the acid gas stream has been performed, using PHAST, to demonstrate that vapour emissions are within the Workplace Exposure Limits. Uncontrolled it Page 12 of 52LNG Plant Project ? Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 157883-011-CG-MA-0001 Revision C1 2.6.2 2.6.4 27 274 Liquid Emissions Solvent drips and drains are collected in a closed drain system and sent to the Solvent Sump. Solvent storage tanks have a dyke. Solid Emissions Filtration systems are employed that minimize the amount of waste generation. Subject to environmental approval, spent filter cartridges shall be sent to a suitable landfill or thermally incinerated. Flare PSV releases from the Absorber, Regenerator and the Flash Vessels are sent to the Wet Gas Flare system. Reference Documents Acid Gas Removal (Unit 1100) . Process Flow Diagram, Unit 1100 - Acid Gas Removal, Drawing no. 157883- 011-PR-PF-0001 . P&ID, Unit 1000 - Inlet Gas Receiving, Inlet Gas Heater, Filter and Flash Drum, Drawing no. 157883-01 1-PR-PI-0021. * PID, Unit 1100 - Acid Gas Removal, Inlet Gas Heat Exchange and Wash, Drawing no. 157883-011-PR-PI-0025. © P&ID, Unit 1100 - Acid Gas Removal, Acid Gas Scrubber, Drawing no. 157883- 011-PR-PI-0026 . P&ID, Unit 1100 - Acid Gas Removal, HP Flash Vessel, Drawing no. 157883- 011-PR-PI-0027. + P&ID, Unit 1100 - Acid Gas Removal, Lear/Rich Coolers and Booster Pumps, Drawing no. 157883-011-PR-PI-0028. . P&ID, Unit 1109 - Acid Gas Removal, Solvent Regenerator, Drawing no. 187883-011-PR-P1-0029. © P&ID, Unit 1100 — Acid Gas Removal, Solvent Regenerator Reboilers, Drawing no. 157883-011-PR-PI-0030. © P&ID, Unit 1100 ~ Acid Gas Removal, Regenerator Reflux Drum, Drawing no. 157883-011-PR-PI-031. . P&iD, Unit 1100 - Acid Gas Removal, Lean Solvent Filtration, Drawing no. 157883-01 1-PR-PI-0032. © P&ID, Unit 1100 - Acid Gas Removal, Solvent Tank, Drawing no. 157883-011- PR-PI-0033. © PID, Unit 1100 - Acid Gas Removal, Lean Solvent Charge Pumps, Drawing no. 157883-01 1-PR-P!-0034. + P&ID, Unit 1100 - Acid Gas Removal, Lean Solvent Cooler, Drawing no. 157883-011-PR-PI-0035. . P&ID, Unit 1100 - Acid Gas Removal, Solvent Drain Drum, Drawing no. 157883- 011-PR-PI-0036. . P&ID, Unit 1100 - Acid Gas Removal, Solvent Drainage Collection, Drawing no. 157883-011-PR-PI-0037. Uncontrolled if Printed Page 13 of 52LNG Plant Project d Operating Manual - Acid Gas Removal & Hot Oil © PERU LNG 157883-011-CG-MA-0001 Revision C1 * Alarm and Trip Schedule Unit 1100, Doc No. 157883-011-PR-SH-0204 Cause and Effect Diagrams — LCR 1, Doc No. 157883-000-IN-CE-0001 Cause and Effect Diagrams — LCR 3, Doc No. 157883-000-IN-CE-0002 Cause and Effect Diagrams — CCR, Doc No. 157883-000-IN-CE-0003 CCR Fire and Gas Cause and Effects, Doc No. 157883-000-IN-CE-0005 LCRO1 Fire and Gas Cause and Effects, Doc No. 157883-000-IN-CE-0006 LCRG2 Fire and Gas Cause and Effects, Doc No. 157883-000-IN-CE-0007 * Amine System Circulation, Doc No. 157883-011-CG-IP-0001 2.7.2 Hot Oil (Unit 4100) * Process Flow Diagram, Unit 4100 — Hot Oil, Drawing no. 157883-011-PR-UF- 0001. + P&ID, Unit 4100 - Hot Oil System, Expansion Tank and Pumps, Drawing no. 157883-041-PR-PI-0170. * P&ID, Unit 4100 — Hot Oi System, Hot Oil Heater, Drawing no. 157883-041-PR- PI-0171. '* P&ID, Unit 4100 — Hot Oil System, Hot Oil Heater, Drawing no, 157883-041-PR- PI-0172, © P&ID, Unit 4100 - Hot Oil System, Storage, Drawing no. 157883-044-PR-Pl- 0173. * P&lD, Unit 4100 — Hot Oil System, Distribution, Drawing no. 157883-041-PR-Pl- 0174. * Alarm and Trip Schedule Unit 4100, Doc no. 157883-041-PR-SH-0204 + H4101A/B Cause and Effect Charts, Doc no. 134157883-PO-45301-EC2-004 * Technical Operating and Maintenance Manual, Doc no. 134157883-P0-45301- . NaOTA Control Philosophy and Block Diagram, Doc no. 134157883-PO- 45301-EC2-001 * Hot Oil System Circulation, Doc No. 157883-041-CG-IP-0001 Uncontrolled if Printed Page 14 of 52LNG Plant Project 4 Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 157883-011-CG-MA-0001 Revision C1 34 3.2 3.3 3.4 UTILITIES AND CHEMICALS Hot Oil Reboiler heating is provided by hot oil: Normal Hot Oil supply teraperature: 170°C Maximum Hot Oil supply temperature: 180 °C. Normal Hot Oil return temperature: 130°C, Cooling Medium All AGRU cooling requirements (Condenser, Lean Solvent Cooler etc) are performed using air cooling. The design air temperature for AGR lean solvent cooler is 19°C and 30°C for the AGR Regenerator Overhead Condenser. Both include an allowance of 1°C above the design air temperature to allow for the impact of hot air recirculation, The ambient air temperature ranges between: ‘Maximum: 29°C, Normal (plant design) 18°C Minimum: 11°C, Wash Water/Make Up Water The LNG facility does not have boiler feed water or steam condensate. The water used to replace losses in the AGRU or to dilute premix AGRU solvent to operating strengths must be free of minerals or contaminants that could increase solvent losses. The water make up quality should meet the tollowing specifications: max. 1 to 2 ppmw of Cl” max. 3 ppmw of Na* max. 3 ppmw of K* max. 5 ppmw of Si. max. 10 ppmw of dissolved Fe. max. 50 ppmw for total hardness, expressed in terms of Ca?" max. 100 ppmw of suspended solids, max. particle size 10ym, max. 35 % (wt.) of these, i.e. 35 ppm (wt. in range of 5 to 10 um, remainder below 5 ym. © Electrical conductivity @ 25°C should be less than 10uS/em. Plant demineralised water meets this requirement and will be used as make-up along with recycled water from the Dehydration Unit. Nitrogen Nitrogen is used in the AGRU to prevent air ingress and to blanket atmospheric equipment such as storage tanks or sump vessels. The nitrogen must be free of oxygen. Page 15 of 52LNG Plant Project ) Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 157883-011-CG-MA-0001 Revi: 35 44 444 4A2 Chemicals During normal operations, chemicals required are aMDEA (make up for amine losses) and antifoam agent. AMDEA for make up is stored in the Solvent Tank. The activator toss may be greater than the MDEA loss. Initial start-yp requires flushing of the plant with a 3% potash (KsCQ;) solution. If potash is not available, tr-sodium phosphate or sodium carbonate may be substituted. PROCESS AND OPERATING PRINCIPLES Equipment Description, AGR Inlet Gas Heat Exchanger (E-1105) The Inlet Gas Exchanger is a horizontal counter current flow shell and tube exchanger. The exchanger is designed to pre-heat the 1.5 mol% CO, feed gas at 18°C and 75.4 bara to 35°C by using the hot treated AGR Absorber overheads. The exchanger is designed with a fouling factor of 0.0018 m’K/W and a maximum allowable pressure drop of 0.5 bar for both the shell and tube side. The design condition of the Inlet Gas Heat Exchanger is 83 barg and 70°C. AGR Absorber (C-1101) The AGR Absorber is a 23m (tan to tan) carbon stee! column, with a maximum design pressure and temperature of 83 barg and 80°C. The column comprises of two packed sections (each 7m high). The CO, rich feed gas enters the AGR Absorber above the column maximum liquid level and below the bottom packed section. Each packed section comprises of high performance random packing (Koch-Glitsch’s Intalox Metal Tower Packing no. 50). The packing material is of stainless steel construction and is supported and held down by random packing grids, each with a minimum of 95% open area. ‘The other internals present within the AGR Absorber are as follows: + Demister — this is located at the top of the AGR Absorber. This provides a liquid separation efficiency of 99% at 15 um diameter droplets with a clean operating pressure drop less than 0.5 mbar. * Inlet distributor/teed pipe — this is designed to evenly distribute the lean solvent entering the AGR Absorber across the cross sectional area of the liquid distributor, which in turn provides good distribution of liquid to the packed bed below, + Liquid distributor — this is located at the top of each packed bed section to evenly distribute Jean solvent across the cross sectional area of the packed beds. ‘* Bed limiters — this is located at the bottom of each section of packed bed and is designed to retain the individual packing pieces during any minor process upsets whilst not interfering with the liquid flow from the distributor above. * Feed Gas Inlet Device ~ a slotted device for flow distribution * Packing in hemispherical head — Intalox Metal Tower Packing no. 70 is located at the hemispherical head at the bottom of the column to avoid/minimise entrainment of gas and to provide a liquid residence time of 30 seconds. * Anti swirl baffle — located at the liquid outlet nozzle. The column also has a hydrocarbon skimming compartment in the liquid sump section which is used to collect any accumulation of hydrocarbon liquids. This occasional Uncontrolled if Printed Page 16 of 52LNG Plant Project ’ Operating Manual - Acid Gas Removal & Hot Oil © PERU LNG 157883-011-CG-MA-0001 Revision C1 413 414 44.5 operation requires manual operator intervention to adjust the column liquid level to allow overflow into the hydrocarbon skimming compartment. This compartment is then manually drained to the AGR Solvent Sump Drum, V-1106. Treated Gas Wash Drum (V-1105) Gas leaving the AGR Absorber is cooled down the 43°C by cross exchanging with the Inlet Feed Gas via E-1105. The treated gas is then washed with demineralised water to remove any amine carryover from the sweetened gas in the Treated Gas Wash Drum: The Treated Gas Wash Drum is a vertical, carbon stee! vessel designed for 83 barg and 70°C. This vessel is equipped with a 150mm thick stainless steel demister pad which provides a liquid separation efficiency of 99% at 15um diameter droplets and a clean operating pressure drop below 0.5 mbar. The vessel also contains three bubble cap wash water trays, constructed of stainless steel. The wash water at the bottom of the drum is removed under level control via LV- 111002 to the HP Flash Vessel. HP Flash Vessel (C-1103) Rich amine leaving the AGR Absorber under level control is sent to the HP Flash Vessel and flashed to 5.5 bara to recover any entrained gases in the solvent. Wash water from the Treated Gas Wash Drum and reject water from the Dehydration system is also routed to the HP Fiash vessel. This also aids washing of the flash gas recovered from the rich amine. Flash gas under pressure control is routed to the LP Fuel Gas system. The HP Flash Vessel is a vertical, carbon steel vessel with stainless steel cladding designed for 10.7 barg and 80°C. The vessel consists of a 3 m stainless steel packed bed and a vortex breaker located at the bottom liquid outlet. The HP Flash Vessel also contains a hydrocarbon compartment in the liquid sump section which can be used to collect any heavy hydrocarbon liquids that may accumulate in the vessel. This occasional operation requires manual operator intervention to adjust the column liquid level to allow overflow into the hydrocarbon skimming compartment. This compartment is then manually drained to the AGR Solvent Sump Drum, V-1106. AGR Lean/Rich Solvent Coolers (E-1103 A/B) Rich amine from the HP Flash Vessel is heated against the lean amine in a single pass, counter current plate and frame exchanger. There are two 100% exchangers, operating on a duty/standby basis and each exchanger is designed for 12 barg and 370°C. The temperature and pressure of the lean amine exiting the AGR Lean/Rich Solvent coolers are monitored via TI-111023 and PlI-111023. A high exit temperature from E- 1103A/B will initiate the AGR Absorber trip and AGR Lean Solvent Booster pump trip. AGR Regenerator (C-1102) Rich amine solution is removed from the bottom of the HP Flash Vessel under level control via LV-111013 and passed to the top of the AGR Regenerator. The top section of the AGR Regenerator consists of a demister pad with three calming section trays for washing the acid gas with the returning reflux. Below the wash trays there are two Uncontrolled if Pr ited Page 17 of 52LNG Plant Project > Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 157883-011-CG-MA-0001 Revision C1 4a7 41.8 419 4.4.10 packed sections, each 5m high, for stripping the acid gas out of the solvent and a total liquid draw off tray at the bottom. The packing material is of stainless steel construction The feed inlet arrangement and liquid distributor of the regenerator are designed to handle the fiashing liquid stream entering the column. The liquid sump section of the AGR Regenerator is designed for 6 minutes residence time at the design solvent flow rate. The AGR Regenerator also has a hydrocarbon skimming compartment in the liquid ‘sump section which is used to collect any accumulation of hydrocarbon liquids. Due to the high operating temperature this should only be used during start up or shutdown, whilst the system is relatively cold. The ‘quid level in the AGR Regenerator is manually adjusted to enable hydrocarbon skimming, with the hydrocarbons routed to V- 1106. AGR Regen, Overhead Condenser (E-1102) Saturated acid gas leaving the top of the AGR Regenerator is cooled to 50°C in the AGR Regenerator Overhead Condenser and returned to the AGR Regenerator Reflux drum, V-1104, The condenser is a stainless steel, finned fan air cooler consisting of a single bay with 2 fans. The exchanger is designed to operate with an ambient air temperature of 30°C, which includes a 1°C allowance for hot air recirculation and a maximum allowable pressure drop of 0.2 bar. . AGR Regen, Reflux Drum (V-1104) ‘The AGR Regenerator reflux drum is a vertical, stainless steel vessel designed for 9.3 barg and 100°C. The vessel collects vapour and liquids condensed in the upstream AGR Regenerator Overhead condenser, E-1102. The vapour is vented to atmosphere via a 12” butterfly valve, operating on back pressure control. The liquid reflux is retumed to the AGR Regenerator under level control, regulated by LIC-111045, by the AGR Regenerator Reflux Pumps, P-1102A/B. On low low liquid level, an independent level transmitter LT-111046 will stop the AGR Regenerator. AGR Regen. Reflux Pumps (P-1102 A/B) ‘The AGR Regenerator Reflux Pumps are two 100% stainless steel, centrifugal pumps with a rated flow of 8m’/h and differential head of 52.8m. These pumps are designed for the maximum reflux and operate on a duty/standby basis. AGR Regeneration Reboiler (E-1104 A/B) The AGR Regenerator Reboilers are horizontal, kettle type reboilers used to reboil the amine at the bottom of the AGR Regenerator. Each reboiler provides 50% of the total required duty and utilises hot oil from the hot oil system. The hot oil system operates with a maximum hot oil temperature of 170°C to avoid thermal degradation of the amine solution in the reboiler. The AGR Regenerator Reboilers are of carbon steel construction with stainless steel tubes. The design conditions for the reboilers are 10 barg and 200°C on the shelt side and 15 barg and 200°C on the tube side. Uncontrolled if Printed Page 18 of 52LNG Plant Project d Operating Manual - Acid Gas Removal & Hot Oil = PERU_ LNG 157883-011-CG-MA-0001 Revision C1 antt 4.112 44.43 4414 4118 AGA Lean Solvent Booster Pumps (P-1101 A/B) Lean amine leaving the AGR Regenerator bottoms is cooled from 114°C by cross exchange with the rich amine in the AGR Rich/Lean Amine Solvent Cooler, E-1103. The lean amine solution is then pumped to 10.4 bara by the AGR Lean Solvent Booster Pumps, P-1101A/B to provide sufficient NPSH to the AGR Lean Solvent Charge Pumps, P-11034/B, These pumps are two 100% stainless steel, centrifugal pumps with a rated flow of 351m*%hr and differential head of 89.3m. The pumps are designed for the maximum solvent flow rate, including a 10% slip stream recycle through the solvent filters and operate on a duty/standby basis. AGR Lean Solvent Charge Pumps (P-1103 A/B) The AGR Lean Solvent Charge Pumps are two 100% stainless steel, centrifugal pumps with a rated flow of 320m*%hr and discharge head of 712m. The pumps are designed for the maximum solvent flow rate and operate on a duty/standby basis. AGR Lean Solvent Cooler (E-1101) Lean solvent being pumped into the AGR Absorber is finally cooled to 50°C in the AGR Lean Solvent Cooler, E-1101. The AGR Lean Solvent Cooler is a finned fan air cooler consisting of a single bay with two fans. The cooler is designed with a maximum allowable pressure drop of 2 bar to allow high tube velocities to promote heat transfer. The air cooler also has variable pitch fans, controlled by the lean amine solvent outlet temperature and manual adjustable louvers to ensure that the lean amine solvent temperature remains above 50°C AGR Lean Solvent Filter ($-1101) The AGR Lean Solvent Filter is the first in a series of three, used to remove solids, solvent degradation products and hydrocarbons. The filtration system is required (0 maintain the performance of the AGR by reducing foaming caused by build up of heavier hydrocarbon fractions and solids in the amine solution. The filter is a 150# carbon steel, cartridge type filter designed for 10% of the lean solvent flow rate. The filter is designed for a particulate separation efficiency of 99.5% of 5um or larger. The pressure drop across the filter is 0.1 bar during clean service, with a maximum pressure drop of 0.5 bar during dirty service. The design conditions of the filter are 17 barg and 80°C. AGR Solvent Carbon Filter (S-1102) The AGR Solvent Carbon Filter is a vertical, 150# carbon steel vessel with an ID of 2.8m and T/T height of 3.3m. The filter medium is Activated Carbon Norit 1-3 and is designed for a minimum residence time of 36 minutes. The pressure drop across the activated carbon bed during clean service is expected to be less than 0.1 bar, whilst the maximum dirty pressure drop across the filter bed is 0.5 bar. The AGR Solvent Carbon Filter is also designed for 17 barg and 80°C. Uncontrolled if Printed Page 19 of 52LNG Plant Project Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 187883-011-CG-MA-0001 Revision C1 4.4.16 4AA7 4.1.18 4.1.19 4.1.20 44.21 4.1.22 AGR Solvent After Filter (S-1103) The AGR Solvent After Filter is a carbon steel, cartridge type filter designed for 99.5% efficiency of activated carbon fines removal of 54m or large. Solvent Tank (T-1101) The Solvent Tank is a fixed roof tank with a nominal diameter of 6000mm and nominal height of 10900mm. The tank is nitrogen blanketed with a normal working capacity of 268m: (1685 bbl) and maximum capacity of 277m? (1740 bbl). The tank is designed for a maximum pump in rate of 294m3/h and maximum pump out rate of 12.7m¥h. The design external and internal pressure of the tank is Smbar and ‘16mbar respectively, with a maximum design temperature of 70°C. AGR Solution Make up Pump (P-1106) The AGR Solution Make-Up Pump is designed for a capacity of 12,7m‘%h and a differential head of 36m. The pump capacity is based on a loop filling time of 48 hours is not spared. AGR Solvent Sump Drum (V-1106) The AGR Unit has a dedicated closed drain system which allows recovery of the amine solution to the AGR Solvent Sump Drum, V-1106. The AGR Solvent Sump Brum is a horizontal, carbon steel vessel with an intemal diameter of 3000mm and T/T length of 10250mm. The drum has a capacity of 260m°. The AGR Solvent Sump Drum is located in a sump below grade, and provided with a nitrogen blanket to prevent air ingress. It is also provided with a demineralised water connection for solvent dilution as well as a connection for the removal of the contents by a vacuum truck. This same connection can also be used for solvent filling from drums. The drum also has a hydrocarbon compartment which can be used to skim off any oil residue which may accumulate. AGR Solvent Sump Pump (P-1104) The AGR Solvent Sump Pump is a submerged pump designed for a capacity of 25min, AGR Solvent Sump Filter {S-1104) The AGR Solvent Sump Filter is a carbon steel, cartridge type liquid particulate filter designed for a removal efficiency of 99.5% of 5jm or larger. ‘The pressure drop across the filter is 0.1 bar during clean service, with a maximum pressure drop of 0.5 bar during dirty service. The design conditions of the filter are 10.3 barg and 80°C. AGR Water Make up Pumps (P-1105 A/B) The demineralised water used to remove any amine carryover from the treated gas is supplied from the Demineralised Water system. The flow is controlled by a variable speed reciprocating type AGR Water Make-Up Pumps, P-1 105A/B. The AGR Water Make-Up Pumps are two 100% stainless steel positive displacement pumps which operate on a duty/standby basis and are designed for a maximum capacity of Sm. Uncontrolled if Printed Page 20 of 52LNG Plant Project d Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 157883-011-CG-MA-0001 Revision C1 42 4.24 4.2.2 423 4.2.4 425 4.26 427 43 434 The pump is a variable speed reciprocating type pump, where flow indication is determined by pump motor speed Piping Feed Gas Line to Absorber The feed gas line to the Absorber is a minimum of 5m above the absorber inlet in order to prevent any loss of aMDEA to equipment upstream of the absorber. HP Flash Vessel Off Gas Line The HP Flash Vessel Off-Gas Line is designed for 200% of the design flash gas flow rate. Rich Solution Line Vibrations, caused by 2-phase flow, may occur in the rich solution line downstream of the HP Flash Vessel. In order to avoid damage to the rich solution fine, it is designed for two phase flow. Solvent Velocities To avoid erosion corrosion, lines are sized such that solvent velocities do not exceed 2 m/s in lines made from carbon steel. An optimum velocity of approximately 1.5 m/s has been targeted. Corrosion Allowance For columns, vessels and piping of carbon steel, a corrosion allowance of 3 mm is used Analyser The treated gas line has a CO, analyzer. ‘Sampling Solvent samples (to measure solvent concentration, activator level or water content) should preferably be taken downstream of the Lean Solvent Cooler. Equipment Description, Hot Oil Hot Oil Storage Tank (T-4101) The conically roofed hot oil tank is constructed of carbon steel and is 8m in height and 3.6m in diameter. The maximum fil height of the tank is 5.6m giving a working capacity of 50m?, The tank operates at a pressure of Smbarg which is maintained using a nitrogen blanket and vent to atmosphere. The slight positive pressure is required to prevent air ingress which minimises oil degradation and prevents water ingress. A draw-off sump is provided in case water does accumulate in the tank. The tank is used to store make-up hot oil for the hot oil system. When make-up to the system is required, hot oil is pumped from the tank using the Hot Oil Transfer Pump (P- 4102) into the Hot Oil Expansion Drum (V-4101), Uncontrolled if Printed Page 21 of 52LNG Plant Project d Operating Manual - Acid Gas Removal & Hot Oil © PERU LNG 187883-011-CG-MA-0001 Revision C1 43.2 43.3 4.34 43.5 The tank is filled by road tanker from a connection fitted in the P-4102 suction line and is sized for 120% of truck volume. Hot Oil Transfer Pump (P-4102) The Hot Oil Transfer Pump (P-4102) is provided for filing the hot oi! system from Hot Oil Storage tank (T-4161). The transfer pump shall be started and stopped manually due to the intermittent service. The pump is a Flowserve centrifugal type unit powered by a 10 HP (7.5 kW) General Electric motor. The rated capacity of the unit is 14.7m%h with a differential head of 37.2m. Hot oil is drawn from T-4101 and pumped to the hot oil expansion drum (V-4101). Minimum flow protection is provided by a restriction orifice in the pump recycle line that returns to the tank T-4101. Hot Oil Expansion Drum (V-4101) The drum is a horizontally mounted, cylindrical, carbon stee! vessel located at the system high point which provides the buffer volume for hot oil as it expands and contracts with varying temperature. It is 10m (T/T) long with an 1D of 3.1m and a maximum liquid level of 2.8m to provide a working volume of approximately 65m? (3 times the expansion volume). The capacity allows time for operator correction due to losses, leaks, maloperation, expansion and contraction. The vessel operates at a pressure of 0.2 bary and under a nitrogen blanket to reduce the possibilty of hot oil degradation. The drum also provides separation of any gas from oil and process leaks, routing any gas to the wet gas flare. Initial fill and any make-up of the hot oil system is via the hot oil expansion drum inlet nozzle. In normal operation there is no flow through the drum; hot oil is circulated around the system with the hot oil expansion vessel located on a branch from the return header. Hot Oif Circulation Pumps (P-4101A/B) The Hot Oil Circulation Pumps (P-4101A/B) provide the driving force to circulate hot oil to. the hot oil heaters and then the users. The pumps are 2 x 100% with one operating continuously. The pump is a Flowserve centrifugal type unit powered by a General Electric motor with @ rated power of 331kKW. The rated capacity of the unit is 1420m%h with a differential head of 62m. Minimum flow protection is provided by flow control through FV-141046 which opens to allow a flow back to the pump suction via the retum header. A slipstream of hot oil is taken from the pump discharge upstream of the recycle line to flow through the Hot Oil Slipstream Filter (S-4101). Hot Oil Heaters (H-4101 A/B) Two 50% heaters are installed to provide heat to the hot oil for use in the inlet gas hot oil heater (E-1001), the AGR regeneration reboilers (E-1104A/B) and HHP fuel gas heater (E-5203). Hot oil is pumped to the heaters by the Hot Oil Circulation Pumps (P- 410148). The heaters are direct fired, natural draft, vertical cylindrical radiant type with a horizontal tube convection section and are manufactured by Boustead International Uncontrolled if Printed Page 22 of 52LNG Plant Project d Operating Manual - Acid Gas Removal & Hot Oil © PERU LNG 157883-011-CG-MA-0001 Revision C1 436 Heaters Limited. The heaters are fired with fuel gas from the low pressure fuel gas system which feeds 6 (per machine) Hamworthy low NOx burners. Each burner has an associated pilot which is electrically lit by a manual push button. Pilot flame detection is by ionisation rods; main burner flame detection is by fireeye. Under normal operating conditions the Hot Oil Heater, H-4101 A/B duty is based on heating the oil from 130°C to 170°C. A maximum operating temperature of 180°C is used to prevent degradation of the solvent in the acid gas removal unit. Temperature control valves within L-4101A/B control fuel gas flow rate to correct the fired heater duty and heater turndown. The heaters are controlled to remain within their minimum turndown by flow control on FIC-141011A&B which regulates the hot oil system by-pass valve FV-141011. The heaters are each rated for 38.3 Gu/hr (10.6 MW) for the normal operating case and 59.1 GJ/hr (16.4MW) for the start-up case to provide reliability and adequate capacity for all potential scenarios. Hot Oil Slip Stream Filter (S-4101) The Hot Oil Slip Stream Filter (S-4101) is @ woven glass filter provided to remove any accumulation of particulates over time. It is designed for 122m’/h (approximately 10% of the maximum hot oil circulation flow rate). The hot oil will be routed through a filter and back to the return header upstream of the outlet of the expansion drum. Flow to the filter is set by manual adjustment of a globe valve to meet the desired flow rate. Uncontrolled if Printed Page 23 of 52LNG Plant Project Operating Manual - Acid Gas Removal & Hot Oil PERU LNG 157883-011-CG-MA-0001 Revision C1 4.4 Controller Set Paints, Alarm Points and Trip Settings, 4.4.1 Controller Set Points - AGR Tag No. P&ID Units, Set-Point UiG-177002_| — 187883-011-PR-PI-0025 mm Hold TIC-111005 °C Hold 1 LIC-171006 157883-010-PR-P!-0026 = Hold 1 | PIC-111014 ancy a a PIg-1 11014 | 457889-011-PR-PL-0027 nat et FiC-111034 mh Hold 1 FiC-Tri935_| _157863-011-PR-PI-0030 misne Hold 1 LIC-111045 mm Hold 1 LIC-H11045_| 457689-011-PR-PI-0031 a He FIC-111050 | 157883-O11-PA-PI-0032_| mifhr Hold 1 TIC-111069 °C Hold 1 Fic-111068| _157889-011-PR-PI-0035 Thr Hold 1 4.4.2 Controller Set Points - Hot Oil Tag No. PaID Units Set-Point TIC-141014A 157883-04 1-PR-PI-0171 °C Hold 1 LTIC-141014B 157883-042-PR-PI-0172 “Cc Hold 1 Uncontrotied if Printed Page 24 of 52LNG Plant Project ) Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 157883-011-CG-MA-0001 Revision C1 4.4.3 Alarm and Trip Set Points - AGR ‘ SetPoint Tag No. PaID units | Z O = TE110031 | 157683-010-PR-PLooeT | “Cc Hold t_| Hold Al-111001 loom 60 157883-011-PR-PI-0025 ‘ aa 44 ; Lic-111002 mm ery | 2 300 Lit11007 mm | wore 2) 300 | 1800 Lic-111008 | 157883-011-PR-PI-0026 | mm fewer PDI-117005 bar 0.05 TOI-115073 °C 3 7000 L-111075 mm incase Mocanoa 300 | 4900 Lic-111013 | 157683-011-PR-PL-0027 | mm (nots) | (oe PIATI01S baig a PIG-111014 arg 3 FiC-111096 kg/hr] 207500 | 217500 PIA T1023, bag | 0.1 I-111100_| 157883-011-PR-PI-0028 [ — barg 03 Ti-111023 °C. 70 TEH1101 °C 7 PDI-111028 bar 0.05 PI-111029 arg 02] 06 980 4120 ee mm (Note 2) | (Note 2) 3 7800 Lertiog0 | 197888-011-PR-PLO029 |, | 300 Maes (Note 2) 3 77028 aa eo | 405 11029 °C ae 11030 ca 7o5_| 125 FIC-111034 ' gine 760000 | 470000 FiC=111035_| 187689-011-PR-PI-0080 [oar "160000 | 410000 FrAT 1064 kg/hr 2500 ‘400 | 700 Lic-111045, mm (Note 2) | (Note 2) 187883.011-PR-PI-0031 300 Lit11046 mm | ote 2). PIG-T11045 barg 03 TICT11045 *C 20 60 FIC-111050_| 157683-011-PA-PL-0032 | _kg/hr 32500 6009800 U111056 | 457¢83-011-PR-PL-0033 |_™™ (Note 2) | (Note 2) PLT 70568 arg 3 7 FIC-111095 , Keginr 746500 | 753500 PT eee | 157869-011-PR-PI-o0as | at 7 a FIC-171068_| 157883-011-PA-PL-0035 | _kg/hr 160000 F-11068 kgihr 140000 PDI-111095 barg | 07 Uncontrolled if Printed Page 25 of 52LNG Plant Project Operating Manual - Acid Gas Removal & Hot Oil © PERU LNG 157883-011-CG-MA-0001 Revision C1 Minimum liquid level is below BTL. Above BTL HH has no associated trip action. ‘Above tank base. Auto start pump, P-1103A/B on LL alarm. value on detection of 2 pumps in operation. 6. Above vessel bottom. gaone , SetPoint Tag No. Paid units Lp Z u = (ret 77088 | e “40 | 60 300 ‘2550 Lusti072 mm (Note 6) | (Note 6) I crattove ) 157883-011-PR-PI-0036 2400 Le111075 mm oy PI-141075 arg Of 1.5 Notes: Auto reset the alarms to double the 4.4.4 Alarm and Trip Set Points - Hot Oil System ‘ Set-Point Tag No. Paid Units i U a FI-141003 kgihr 00 FI-141046 mehr 550_| 1450 Li-41002 mm 735 | 2600 (Note 1) | (Note 1) _| Lr141048 mm | 435 187883-041-PR-PI-0170 (Nee PI-141002 barg o Hl PIat011 barg Hold PI-t41012 arg Holt Tht4t00T °C Hold 1 FLi410114, rantent kg/hr 780000 | 485000 ETON | 187883-041-PR-Plot7s 49 Bopp | ee FI-141011B aren kginr 180000_| 485000 Hee Ay] 157883-011-PR-PI-o172 ta spon Li141031__| 157683-041-PR-PLOT7S |_mm 00 | 5600. PDIC-141043_| 157883-041-PR-PI-0174 | barg 3 Notes: 1. Above bottom of vessel. Uncontrolled if Printed Page 26 of 52LNG Plant Project a Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 157883-011-CG-MA-0001 Revision C1 54 5A OPERATING PHASES Prior to Initial Start-up Prior to initial start up, all pre-commissioning activities must have been completed and the unit ready for operation. Pre-commissioning covers those activities required to bring the unit to a “ready for commissioning” condition following construction. In general, it consists of inspection, checking and testing activities required to ensure that all components of the unit are property installed and mechanically complete. The most important requirement is that the unit can be started up in a controlled, efficient and safe manner. The information and procedures described hereafter concer the preliminary operations for the first start up of a new unit. Procedures are slightly adapted for normal and subsequent start-up. Preparation Prior to Initial Start up The requited pre-commissioning activities include, but are not limited to, ensuring that the following requirements are satisfied: Step Activity Completed 1_| All safety equipment is in place and is fully operable, All pipe-work has undergone pressure testing, cleaning and/or flushing and draining. The caustic wash (see pre- 2 | commissioning procedures) must have been fully completed. This unit must be scrupulously cleaned to reduce the potential of foaming during normal operation. All tanks/vessels are clean and free of debris. All internals have 3. | been fitted according to the Mechanical Data Sheets (ie. filter elements, demisters etc.) Test equipment and special tools, if any, and facilities for their 4 | operation are available. ‘All rotating equipment and their associated drivers have been 5 |aligned, run in and lubricated, as required, following the manufacturers’ recommended procedures. All functional test procedures have been completed where possible. | Temporary strainers must be installed where specified and their locations properly recorded for future reference. Temporary electrical power systems have been checked out 7 | and commissioned. Power is available to all electric drivers and all contra! systems / panels where necessary. All instruments have been calibrated, loop checked and commissioned where necessary. All sensing elements which were removed from pipe-work prior to hydro-testing and flushing have been reinstated. Page 27 of 52LNG Plant Project ’ Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 157883-011-CG-MA-0001 Re: nt All ESD and ICSS functions have been fully tested. All active interlocks and trips should be cleared and the system fully available. 10 All Vendor equipment has been fully commissioned where possible and operators are fully acquainted with its use. " The commissioning leak test has been satisfactorily completed and test certification signed off. 12 The system has been inerted using utility nitrogen and remains under a slight positive nitrogen pressure (i.¢. <0.2barg). All vents and drains must therefore already be closed. A nitrogen (ie. oxygen free) atmosphere must be maintained to reduce degradation of the aMDEA solvent. Note: The aMDEA make up section of the unit has a lower design pressure than 0.2barg and will be inerted accordingly. (Commission PCV-111056 and establish the nitrogen bianket ‘on the system. This will require the hydraulic seal on the overflow line to be installed). 13 The system has been completely punch listed and all necessary punch items have been signed off. All pre- commissioning test documentation has been completed and signed off. Ensure that the following safety considerations are in plac - Step Activity ‘Completed 1 All necessary fire fighting equipment and facilities are available, Unit 7600. The Fire and Gas detection system has been fully commissioned and is available with all outstanding alarm and trip indications cleared. All pressure safety valves must be ‘in test’ and correctly lined Up. All temporary blinds must have been removed. All other pressure relief devices (i.e. bursting discs etc) must be correctly installed All personnel must be fully briefed on the start-up procedure and their responsibilities at this time 6 All necessary Risks Assessments, Method Statements and Permits to Work must be in place. The procedures described in this document shauld be taken only as an operating guide and may be subject to further development at site. 5.1.2 Commissioning of Utility Systems The following Utility Systems must be available (i.e. ready for imminent start-up) before Unit 1100 and 4100 can be started up. Uncontrolled if Printed Page 28 of 52LNG Plant Project Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 157883-011-CG-MA-0001 Revision C1 5.1.3 5.2 No. Utility Checked Power Generation, Unit 4000 (Note 1) Hot Oil System, Unit 4100 Fuel Gas System, Unit 5200 (Note 1) Flare and Liquid Disposal, Unit 6200 (Note 1) Demin. Water, Unit 6500 Plant and Instrument Air System, Unit 6600 (Note 1) Nitrogen System, Unit 6700 (Note 1) sJolalalolr 8 Waste Water Treatment and Disposal, Unit 7100 Notes: 1. These systems must be available before Unit 4100 can be started up. Pre-Start-up Process Requirements The following upstream process units must be available before Unit 1100 can be started up. No. Process Checked Upstream facilities supplying feed gas and liquids from the Pig 1 | Receiver up to the inlet area battery limit. 2__| Inlet Gas Receiving, Unit 1000 The following downstream process units must be ready for imminent start-up before Unit 1100 can be started up, No. Process Checked 1_| Dehydration, Unit 1300, 2 _| Liquefaction and Refrigeration, Unit 1400, 3__| Mercury Removal, Unit 1500, 4__| Retrigeration, Storage and Purification, Unit 3100. 5__ | LNG Storage and Loading, Unit 3400. Note: The front end of Unit 1100 as defined by table §.1.1.1 should already be pressurised to normal working pressure, as part of the initial start-up of Unit 1000, using the 2" by-pass valve in line NG-100012-24"(C6B)-N (P&ID:010-PR-PI-0021) upstream of V-1003. Hot Oil System The Hot Oil system is in continuous operation when the facility is operating so normal start-up of most equipment does not apply. Uncontrolled if Printed Page 29 of 52LNG Plant Project 4 Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 157883-011-CG-MA-0001 Revision C1 5.2.1 Initial Fill of Hot Oil System The initial charge of hot oif to the Hot Oil Storage Tank (T-4101) is carried out using the Hot Oil Transfer Pump (P-4102) in full recycle and the road tanker pumps. Step Description Checked Initial fill of the Hot Oil Storage Tank Ensure that all manual valves and spectacle blinds around T- 4101 and P-4102 are in their normal positions as per the P&iD 187883-041-PR-PI-0173 with the following exceptions: 1 * 3" manual gate valve on P-4102 discharge line, 041008: Closed * 3° manual gate valve on P-4102 recycle line, O- 41038: Open Ensure that the nitrogen blanket and vent valves are energised and working normally, * — PCV-141033 B + PCV-141034 The pressure in T-4101 is regulated by the above pressure control valves. The normal operating pressure in tank is 1.015 bara (atmospheric pressure). This pressure can be monitored using PG-141032 which is readable from the platform. Connect the road tanker to the quick release coupling connection. Start up pump P-4102 according to Vendor instructions: ‘* Ensure that the discharge valve on line O-41008- 3"(C1A)-N is opened, the pipe work and pump casing are fully primed. * — Start P-4102 using HS-141045. Check the system for leaks and observe for excessive noise a and vibration, * Monitor the level in the tank using LI-141034 * Monitor the pressure in the tank using PG- 141032. Tank pressure during filling/emptying operation is regulated by PCV-141033 and PCV- 141034. * Continue until the road tanker inventory has been transferred to T-4101 ‘* Stop the pump if necessary using HS-141045. Uncontrolled if Pri Page 30 of 52LNG Plant Project d Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 157883-011-CG-MA-0001 Revision C1 Step Desc! Checked Initial fill of the Hot Oil System. The capacity of T-4101 is not sufficient to fil the hot oil system, so for the first start- up, the T-4101 and V-4101 will have to be filled in batches until the total hot oil system is filled. Ensure that all manual valves and spectacle blinds around V- 4101, P-4101A/B, H-4101A/B and in the hot oil distribution are in their normal working positions as per P&lD 157883-041-PR-PI- 0170/171/172/174 with the following exceptions: * 3" manual gate valve on P-4102 discharge line, 4 0-41008: Open * 3" manuat globe valve P-4102 discharge line O- 41008 to V-4101: Closed * 3" manual gate valve on P-4102 recycle line, O- 41038: Open Set the hot oil circulation valve to manual mode with an output of 5 | 0% (i.e. closed) © Fv-t4t014 Start the hot oil transfer pump P-4102 using HS-141045, * Ensure that the pump is operating satisfactorily via the restriction orifice RO-141090 on the pump minimum recycle line 0-41038-3"(C1A)-N. * Slowly open the 3° globe valve on P-4102 discharge line 0-41008-3"(C1A)-N. This valve will control the flow of hot oll to the hot oil expansion drum V-4101. (Once the flow to V-4101 is establish via the 3” manual globe valve: Monitor the level in the tank T-4101 using L- 141031. * Monitor the pressure in the tank using PG- 141032. Tank pressure during filling/emptying operation is regulated by PCV-141033 and PCV- 141034. ° Monitor the level in the expansion drum V-4101 using LI-141001 (locally) or LI-141002 via DCS. * Stop the pump if necessary using HS-141045. * Close 3" manual globe valve on line 0-41008- 3"(C1A)-N to prevent overfilling of V-4101 Uncontrolled if Printed Page 31 of 52LNG Plant Project Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 157883-011-CG-MA-0001 Revision C1 Step Description Checked As the drum fills, it will begin to drain to the hot oil circulation pumps, P-4101A/B and to the majority of the system from downstream of the heaters. * Ensure that the 12” discharge valve downstream of P-4101 on line O-41015-12"(C3A)-N (or line O- 41080-12"(C3A)-N depending on selected duty pump) is partially closed to provide system resistance. . Ensure that the suction valves are opened and the pipe work and pump casing are fully primed. * Ensure that pump minimum flow control vaive FV-141046 is energised and set in manual mode to 30% open. Complete the commissioning of the Hot Oil Recirculation Pumps P-4101 . Start P-4101 using HS-141001 (or HS-141002 depending on selected duty pump). . Allow hot oil to circulate and check that P-4101 operates satisfactorily. * Set the pump minimum flow control valve FV- 141046 to automatic. 10 It may be necessary to stop P-4101 as the hot oil system fills up and re-fill the expansion drum (repeating steps 1 to 8 as necessary) as more oil becomes available from the hot oil storage © Monitor the level in V-4101 using LI-141002 . If liquid level in V-4101 reaches its low level, stop P-4101 using HS-141001 (or HS-141002 depending on selected duty pump) to prevent the pump running dry Starting the Hot Oil Heaters, H-4101AV/B Uncontrolled if Printed Page 32 of 52LNG Plant Project ) Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 157883-011-CG-MA-0001 Revision C1 5.2.2 5.2.3 Step Description Checked Once the hot oil system is filled and the liquid level in V-4101 has. stabilised, * Fully open the discharge valve downstream of P- 4101 on line 0-41015-12"(C3A)-N (or line O- 41060-12"(C3A)-N depending on selected duty W pump) . Allow hot oil to circulate and check that P-4101 operates satisfactorily. © Set the hot oll circulation valve FV-141011 to automatic to allow hot oil to circulate. Start the Hot Oil Heaters in line with the Vendor's procedure to begin heating the oil to operating temperature. * Atstart-up there will be a significant reduced duty required of the hot oil system so the use of all burners is not required once the hot oil operating temperature is reached. Refer to the following Vendor documents: 12 * Technical Operating and Maintenance Manual Table of Contents, Doc mo. 134157883-PO- 45301-NO1-02 . Technical Operating and Maintenance Manual, Doc no, 134157883-PO-45301-NO2-02 * H-41014/B_ Control Philosophy and Block gram, Doc no. 134157883-PO-45301-EC2- 001 Start-up After Controffed Shutdown After a controlled shutdown, if the hot oil has remained inventoried, * Start a hot oil circulation pump P-4101 (see section 5.2.1 - step 8 onwards) . Then start the Hot Oil Heaters in line with the Vendor's procedure (see section 5.2.1 — step 11 to 12) to begin heating the oil to operating temperature. If after a control shutdown and the hot oil system inventory is deficient and a Partialtotal start-up fill is required, then follow the steps 1 to 12 outlined in Section 5.2.4 Controlled Shutdown Step Description Checked Shutdown of the Hot Oil System is achieved as follows: Uncontrolled if Pi Page 33 of 52LNG Plant Project d Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 157883-011-CG-MA-0001 Revision C1 Step Description Checked Shut down the Hot Oil Heaters H-4101A/B as per the Vendor's procedure. Refer to the following Vendor documents: * Technical Operating and Maintenance Manual Table of Contents, Doc no. 134157883-PO- 1 45301-NO1-02 * Technical Operating and Maintenance Manual, Doc no. 134157883-PO-45301-NO2-02 + H-4101A/B_ Control Philosophy and Block Diagram, Doc no. 134157883-PO-45301-EC2- 001 ‘Stop the Hot Oil Circulation pumps. 2 * Stop P-4101 using HS-141001 (or HS-141002 depending on selected duty pump). * Allow the hot oil system to cool. 5.3 Acid Gas Removal . 5.3.1 Initial Start Up - Acid Gas Removal Step Description Checked this can be done in V-1106 using the Demin Water Make-up. amine to its required concentration. The initial charge (110 tonnes) of a 40 weight % aqueous solution aMDEA must be loaded into the system. The AGR Solvent Sump Drum, V-1106 can be filled via the 2” fill connection. The AGR Solvent Sump Pump, P-1104 wil! transfer the pure solvent to Solvent Tank, T-1101. ff the supplied aMDEA is pure solvent and requires diluting, The Solvent Tank T-1101 can also be filed directly using the 2” connection located at grade on line SV-11284-2"(C1B)-N. The Demineralised water make-up connection via line DM-65012-2"(S1C)-N via Nozzle G also provides the facility to dilute the Initial Fill of Solvent Tank via V-1106. Ensure that all other manual valves and spectacle blinds around V-1106 are in their normal working position, including instrumentation isolation valves as per P&ID 157883-011-PR-PI- 0036 Using the 2" fill connection installed on the AGR Solvent Sump Drum, V-1106 (line SV-11330-2"(C1B)-N) begin to load the 2 | aMDEA into V-1106, (The aMDEA may be delivered in drums or IBCs.) Carefully measure the level on LI-111072 along with the number of drums/containers loaded and the volume. Uncontrolled if Printed Page 34 of 52LNG Plant Project Operating Manual - Acid Gas Removal & Hot Oil PERU LNG 157883-011-CG-MA-0001 Revision C1 Step Description Checked Ensure that all manual valves and spectacle blinds around T- 1101 (on P&ID 157883-011-PR-PI-0033) are in the following positions: * 6" manual ball valve on line SV-11237-6"(C3A)-N, 3 ‘on (nozzle A): Closed * 3" manual ball valve on Nozzle C on tine SV- 11223-3"(S1C)-N: Closed * 3" manual ball valve on Nozzle D on drain line SV-11252-3"(C1B)-N: Closed Ensure that the minimum liquid level (0.3m) in the over-flow seal 4. |i established on the tank over-tiow line SV-11249-10"(C1B)-N (Nozzle G). Ensure that the nitrogen blanket and vent valves to T-1101 are energised and working normally: + PV-111056A 5 + PV-111056B . The pressure in T-1101 is regulated by the above pressure control valves. The normal operating pressure in tank is 1.005 bara (atmospheric pressure). This pressure can be monitored using PIC-111056 from the DCS. When there is sufficient fevel in V-1106, transfer the amine to the Solvent Tank T-1101 using P-1104, * Start P-1104 using HS-111072, * Ensure that the manual valves in the recirculation loop (SV-11244-3"(S1B)-N) are opened and that 6 the pipe work and pump casing are fully primed, All other discharge valves should be closed. * Check the system for leaks and observe for excessive noise and vibration. Monitor operating parameters (discharge pressure, motor current etc). Divert the pure amine through the AGR Solvent Sump Filter, S- 1104, to the Solvent Tank, T-1101. 7 © Monitor the level in T-1101 using LI-111056. Continue to unload fresh solvent into V-1106 and transfer it | across, batch wise, to T-1101 until the whole inventory has been loaded. Both T-1101 and V-1106 are designed to hold approximately 25% of the plant aMDEA inventory Initial Fill of Amine to AGRU Uncontrolled if Printed Page 35 of 52LNG Plant Project Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 157883-011-CG-MA-0001 Revision C1 Step Description Checked Lining C-110 Up Unit 1100 and filling of the AGR Regenerator, C-1102 and AGR Absorber, 1. Ensure that all other manual vaives and spectacle blinds are in their normal working position, including instrumentation isolation valves etc as pes P&ID 157883-011-PR-PI-0028/29/30/32. 10 All control valves should be in manual mode with an output of 0% [Hold 1] (i. closed) with the exception of the following: © FV-110050 - Slip stream to filters S-1101/2/3 © FV-111096 - P-1101A/B minimum recycle valve These valves are opened to allow the system to be amine filled Prior to start up. " Start the AGR Solution Make-up pump P-1106 according to Vendor instructions: . Ensure that the suction valves are opened and that the pipe work and pump casing are fully primed. + With the solvent make-up line to C-1102 closed start the pump using HS-111080 and run the pump through the minimum flow line back to the tank, T-1101. * Check the system for leaks and observe for excessive noise and vibration, Monitor operating parameters (discharge pressure, motor current etc). + Stop the pump if necessary using HS-111080. Page 36 of 52LNG Plant Project Operating Manual - Acid Gas Remo 157883-011-CG-MA-0001 Revision C1 4 1 & Hot Oil == PERU LNG Step Description Checked 12 With the AGR Solution Make-up Pump, P-1106, running, open ‘the 2" ball valve in line SV-11221-2"(S1C)-N and fill the AGR Regenerator to approximately normal working level, including the following: + _ E+11034/B: AGR Lean/Rich Solvent Cooler + P-1101A/B: AGR Lean Solvent Booster Pumps + $-1101: AGR Lean Solvent Filter * $-1102: AGR Solvent Carbon Filter * — $-1103: AGR Solvent After filter * P-1103A/B: AGR Lean Solvent Charge Pumps * _ E+1104: AGR Regeneration Reboiler shells Once the AGR Regenerator is filled to normal working level: * Monitor the level of the AGR Regenerator column, C-1102 using LI-111029. * Monitor the level of the AGR Regeneration Reboilers, E-1104A/B, using LG-111034/5. * When complete close off the valve and shutdown the pump. ‘Amine circulation through the AGR unit. 13 Ensure that all other manual valves and spectacle blinds are in their normal working position, including instrumentation isolation valves etc. 14 The following control valves should be in manual mode with an output of 0% (.e. closed): * FV-111050 - flow control valve to S-1101, S- 1102 and S-1103 filters. © FV-111068 — flow control valve to AGR Absorber, C-1101 © LV-111006 - AGR Absorber, C-1197, level control vaive * _LV-111002 - Treated Gas Wash Drum, V-1105, level control valve © PV-111014 — HP Flash Vessel, C-1103, pressure control valve + LV-411013 - HP Flash Vessel, C-1103, level control valve. Uncontrolled if Printed Page 37 of 52LNG Plant Project Operating Manual - Acid Gas Removal & Hot Oi! = PERU LNG 157883-011-CG-MA-0001 Revision C1 Step Description Checked The following control valves should be in manual mode set to 30% open: ae © FV-111096 - P-1101A/B minimum recycle valve . FV-111095 — P-1103A/B minimum recycle valve Start the AGR Lean Solvent Booster pumps P-1101 and AGR Lean Solvent Charge pumps P-1103 (P&ID 157883-011-PR-PI- 0028/32/34/35) . Ensure that the suction and discharge valves are ‘opened and that the pipe work and pump casing are fully primed. © Start P-1101 using HS-111018 (or HS-111019 - depending on selected duty pump). 16 * Allow amine to pressurise P-1103 using the head of the AGR Lean Solvent Booster pump P-1101, * Check that P-1101 operates satisfactorily and ‘once the pump flow is established, set control| + valve FV-111096 to automatic. * Start P-1103 using HS-111063 (or HS-111064 ~ | depending on the selected duty pump). Allow amine flow to circulate and check that P- 1103 operates satisfactorily. Set control valve FV-111095 to automatic. Circulate the amine through to the AGR Absorber, C-1 101. * Once flow through pumps P-1101 and P-1103 are established, set the control valve FV-111050 to automatic. * Set FV-111088 to automatic with a set point of | Om%hr. Slowly increase the set point to establish 7 flow through FV-111068. * Amine should now circulate to the absorber. Ensure that the amine circulation rate is low prior to LV-111006 is in operation. © Set the C-1101 level control valve LV-111006 to automatic. This will allow the amine to circulate to the HP Flash Vessel, V-1105. Uncontrolled if Printed Page 38 of 52LNG Plant Project d Operating Manual - Acid Gas Removal & Hot Oil PERU LNG 157883-011-CG-MA-0001 Revision C1 Step Description Checked Circulate amine through the HP Flash Vessel, C-1103. + Monitor the level in G-1103 using LIC-111013. Manually adjust the set point of LV-111013 to 18 ensure that the working level is maintained. . Monitor the pressure in C-1103 using PI-111015. Manually adjust the set point of PV-111014 if the pressure in the HP Flash Vessel rises too quickly. Maintaining a steady amine flow through the solvent loop. * Slowly increase set point of FV-111068 to 19 incrementally increase amine circulation until normal operating set point is reached. Tune controllers as necessary. Warming up the AGR Unit. The Hot Oil unit should be commissioned and ready to start prior to warming up the AGR unit (See Section 5.1.2 for start-up of the Hot Oil system). Increase the temperature in C-1102 by incrementally increasing the opening of control valves FV-111034 and FV-111035. . Monitor the temperature in C-1102 overheads using TI-111028. 20 ‘* Monitor the temperature exiting E-1102 using T- 111045. * Set LV-111045 to manual mode and output to 0% [Hold 1] (i. closed) Start the AGR Regenerator Overhead Condenser E-1 102. at * — Start E-1102 motors using HS-111044 and HS- 111084. Uncontrolled if Printed Page 39 of 52LNG Plant Project Operating Manual - Acid Gas Removal & Hot Oil PERU LNG 157883-011-CG-MA-0001 Revision C1 Step Description Checked Fill the AGR Regenerator Reflux drum, V-1104 and when there is sufficient level in the drum complete the commissioning of the AGR Regenerator Reflux pump P-1102 using the recirculation line. * Ensure that the suction and discharge valves are opened and that the pipe work and pump casing are fully primed. . Start P-1102 using hand switch HS-111046 (or HS-111047 — depending on the selected duty pump). * Check the system for leaks and observe for excessive noise and vibration. Monitor operating parameters (discharge pressure, motor current etc). 22 When steady operation of P-1102 has been established, divert the reflux through LV-111046. 23 a * Set the control valve LV-111045 to automatic to allow reflux to circulate back to C-1102. Increase the temperature in C-1102 by incrementally increasing the opening of control valves FV-111034 and FV-111035. * Monitor the temperature in C-1102 overheads using TIC-111029. * Monitor the temperature exiting E-1102 using TI- 111045. 24 The normal operating temperature in C-1102 overheads is 28 | 114°C, Set TIC-111029 to automatic mode to allow cofumn temperature to reach its normal operating target. Starting up the AGR Water Make-up System. Ensure that Demin. Water system is available and the suction pipe work to P-1105 is primed and ready. * Check that LV-111002 is closed and the set point adjusted to ensure the valve is fully closed. 26 Uncontrolled if Printed Page 40 of 52LNG Plant Project 0 Operating Manual - Acid Gas Removal & Hot Oil © PERU LNG 157883-011-CG-MA-0001 Revision C1 5.3.2 5.3.3 Step Description Checked Start the AGR Water Make-up pump P-1105A/B. * Ensure that the suction and discharge valves are opened and that the pipe work and pump casing are fully primed. * Start P-1105 using hand switch HS-111001 (or a7 HS-111002 - depending on the selected duty Pump). * Check the system for leaks and observe for excessive noise and vibration. Monitor operating Parameters (discharge pressure, motor current ete). Fill the Treated Gas Wash Drum V-1105 to approximately normal working levels * Monitor the level of the Treated Gas Wash Drum V-1105 using LIC-111002. 28 © When V-1108 is filled to the normal working level, | « slowly increase the set point of LV-111002 to allow forward flow of water to the HP Flash Vessel C-1103. © Check that P-1105 operates satisfactorily and set the control valve LV-111002 to automatic. The vapour traffic in the column should now be established and the AGRU should now be ready to accept acid gas from the Inlet Gas Facilities. It should be noted that the pressure in the AGR Absorber will decay quickly without the introduction of feed gas to the AGRU. Start-Up Atter Controlled Shutdown Start-up of the AGR unit after a controlled shutdown is similar to a cold start, Liquid levels in the AGR Absorber, HP Flash Vessel and AGR Regenerator should be just below normal as the level controllers would have been closed in a controlled manner. + To-start the plant after a controlled shutdown, refer to Section 5.3.1 from steps 8 onwards. Start-up After AGR Absorber (C-1101) Trip The AGR Absorber trip |-1110 will close the AGR Absorber leve! contro! vaive LV- 111006 and the upstream shut off valve XV-111005, + To prevent potential water hammer onto LV-111006 upon rapid re-opening of XV-111005, open the 3" bypass across LV-111006 (SP-1095) and equalise the pressure across LV-111006. © Tostart the plant after C-11101 trip, refer to Section 5.3.1 from step 8 onwards. Uncontrolled if Printed Page 41 of 52LNG Plant Project Operating Manual - Acid Gas Removal & Hot Oil 157883-011-CG-MA-0001 Revision C1 4 PERU LNG 5.3.4 Controlled Shutdown Step Description Checked ‘The AGRU can be shutdown on a routine basis by following the general sequence. Stop the forward flow of gas through the unit by dropping the production through the MCHE to zero, * Set the LNG Master Rate Controller to manual mode and slowly decrease the set point of the LNG Master Rate Controller, FIC-114505, to zero to close FV-114001A/B, * The pressure through the gas trai automatically close. upstream of the MCHE will rise and the Inlet Gas Plant Pressure control valves, PV-110014A/B, will Stop the hot oil circulation to the AGR Regenerator Reboilers. + Set the hot oil circulation flow controller FIC- 111034 and FIC-111035 to manual and slowly decrease the set points to zero to close FV- 111034 and FV-111035. * Stop the AGR Lean Solvent Charge pump P- 1103 using HS-111063 (or HS-11 1064 depending on selected duty pump). * Stop the AGR Lean Solvent Booster pump P- 1101 using HS-111018 (or HS-111019 depending on selected duty pump). ‘Stop the AGR Regenerator overhead pumps * Set the AGR Regenerator Reflux Drum ievel controfier LIC-111046 to manual and slowly decrease the set points to zero to close LV- 111045. * Stop the AGR Regenerator Reflux pump P-1102 using HS-111046 (or HS-111047 depending on selected duty pump). Uncontrolled if Printed Page 42 of 52Operating Manual - Acid Gas Removal & Hot Oil LNG Plant Project 157883-011-CG-MA-0001 Revision C1 ¢ PERU LNG Step Description Checked Close all the liquid outlet valves on all pressurised vessels with fiquid compartments, Set the level controller LIC-111002 to manual mode and slowly decrease the set point to zero to close LV-111002. Set the level controller LIC-111006 to manual mode and slowly decrease the set point to zero to close LV-111006. Close XV-111005 using HS-111005. Set the level controller LIC-111013 to manual mode and slowly decrease the set point to zero to close LV-111013. ‘Amine is held in-situ within all vessels via closure of the vessel liquid outlet SDV's (AGR Absorber / HP Flash Drum / AGR Regenerator / AGR Regenerator Reflux Drum / AGR Regenerator Reboilers).. Uncontrolled if Printed Page 43 of 52LNG Plant Project d Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 157883-011-CG-MA-0001 Revision C1 6. SAFETY AND HEALTH CONSIDERATIONS 64 General 6.1.1 Permit To Work System 6.1.1.1 Purpose During plant operation it is necessary to take all practicable steps to protect personal safety, assets, property and the environment, and to conserve material resources. This will be achieved through the Permit to Work System. Essential features of the Permit to Work System are: ‘Aclear definition as to who may authorise particular work and who is responsible for specifying the necessary precautions. Instruction and continuous training in both the issue and receiving of work permits. Monitoring to ensure that permit procedures are being followed and that the system functions correctly. All work will be assessed and granted written permission to proceed by the issue of a work permit. The Work Permit will: Specify the conditions and impose limitations under which potentially hazardous work may be carried out. Control entry into contined spaces that might contain, or might have contained, a hazardous atmosphere or material. Ensure that the safe conditions established at the time of issuing the work permit remain so throughout the operation. 6.1.1.2 Function The functions of a Permit to Work System are as follows: To ensure the appropriate authorisation and control by Permit Authorities for all work other than routine activities. To inform those carrying out the work of the potential hazards of the work and the precautions and safety equipment required. To ensure that the work site is prepared and safe before work commences. To ensure that work starts and continues to be carried out, in a safe manner and that safety in the surrounding areas is not jeopardised, To enable a number of unrelated jobs to be carried out, possibly in close proximity, safely and with the full knowledge of the person(s) in charge. To provide a written record to show that the method of work and any precautions needed have been specified and checked by competent persons. To provide checks that the work site is returned to its original state. To provide a system of formally handing over responsibility for the work site at the commencement and completion of the work. Provide an opportunity to obtain a second opinion, where necessary, to minimise errors of judgement or the taking of short cuts which may increase risks. Uncontrolled if Printed Page 44 of 52LNG Plant Project ¢ Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 157883-011-CG-MA-0001 Revision C1 6.1.2 6.1.3 6.1.4 Operator Training All hydrocarbons and chemicals can be dangerous if not properly handled therefore the operators should be thoroughly acquainted with the hazardous properties of all materials in use and should be properly trained in the correct procedures for handling these materials, Because of the hazardous nature of the some of the materials being used and stored in the Plant it is necessary to carry out regular inspections of all items of equipment, piping and valves. Any leaks must be reported immediately and remedial actions, which may include a unit shutdown, initiated as soon as possible. ‘The operators should familiarise themselves with the location and use of fire fighting equipment i.e. hydrants, hose reels, monitors, deluge skids, extinguishers, and safety equipment i.e. safety showers, eye baths, breathing apparatus and all other safety equipment installed on the units. In addition the operators should be thoroughly familiar with basic first aid measures and should be able to take appropriate action in case of an incident. Periodic practice drills, and more specifically fire fighting drills should be carried out in order to instruct operators in the hazards involved and the proper emergency actions required to ensure that the maximum protection for both personnel and equipment is achieved, Fire Hazards The first action to be performed on discovery of a fire, (regardless of size), is to raise the alarm and evacuate personnel from the hazard area immediately. In this way adequate support in the form of trained fire fighting personnel and mobile fire fighting equipment will be rapidly mobilised to assist in dealing with the fire. Then, should the incident escalate, personne! and equipment are already on the scene and prepared. Before attempting to tackle a plant fire of any magnitude the operators must be aware of the nature of the fire. It is essential that they are familiar with the capabilities and limitations of any particular piece of fire fighting equipment (e.g. water must not be used on an electrical fire; burning liquid spills should be tackled with foam, not water, etc). Operating personnel shall not endanger themselves while attempting to deal with a fire. White small scale fires can be tackled with hand held extinguishers or steam lances, major fires should be dealt with from a distance using deluge systems, firewater monitors and fire hoses. The operators should familiarise themselves with the location and the details of operation of all fre fighting and safety equipment. It is the responsibility of the Safety Officer to periodically check the fire fighting and safety equipment to ensure that all systems are in full working order. Any items which are noted as being faulty, non-functional or missing should be immediately reported to the Safety Officer. Personnel Protection Equipment Safety showers and eye wash stations are located within buildings, in process areas and utility areas, wherever there is a hazard of chemical spillage or splashes. They are self-contained and supplied with potable water. Piping is insulated where necessary to prevent high water temperatures due to solar radiation. Uncontrolled if Printed Page 45 of 52LNG Plant Project ) Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 157883-011-CG-MA-0001 Revision C1 615 6.2 6.2.1 6.2.2 The need for, number and location of safety showers are determined by good design practice with the shower or eye wash stations located as close as practical to identified hazard focations. Upon activation of an eyewash station or safety shower an alarm shall be generated at ‘the control room. Operators and maintenance crews attending pipe fittings, valves, etc. on LNG duty shall wear gloves, face shields and suitable clothing to protect them from frost bite and cold splashes of LNG and liquid nitrogen. These personnel protection devices shall protected against the cold liquid temperatures for at least 10 minutes. Hot and Cold Surfaces and Steam Leaks Particular attention should be taken to PPE regarding personal injury resulting from hot and cold services and steam leaks. Despite personnel protection i.e. insulation, cages etc there is always a potential for direct contact between hot/cold surfaces and the skin which can result in skin buns. The appropriate clothing including gloves, overalls with long sleeves etc must always be worn on site. More serious is the possibilty of coming into contact with an unexpected steam leak, hence safety goggles should also be worn. It is important to note that superheated steam leaks can not be seen and therefore particular care should be exercised when in the vicinity of superheated steam lines. On no account should a superheated steam leak repair be carried out on a pressurized system. The system should instead be first shutdown and depressurized. * Material Safety Information for aMDEA. This section contains information about the physical and hazardous properties of aMDEA,. Included is information on the toxic nature of the substance, physiological effects of exposure and first aid procedures to affect recovery from methanol poisoning. ‘The procedures outlined in the following pages are offered as a quide only. Adherence to the information detailed_on the current Material Safety Data Sheet (MSDS) accompanying the delivery of the chemical to site is mandatory. Avoid liquid, mist or vapour contact, Skin contact or inhalation may cause sensitization of the skin. Physical Properties Normal Physical State: Liquid Colour: Colourless to slightly yellow Boiling Point: > 100°C 7 <-10°C 4-12 Other characteristics of gaseous aMDEA are as follows: * Strong exothermic reaction with acids. Chemical and Hazardous Properties Primary routes of entry: Skin contact, eye contact and ingestion General Acute Exposure: Risk of serious damage to eyes. May cause sensitization by inhalation and skin contact. Inhalation Uncontrolled if Printed Page 46 of 52LNG Plant Project d Operating Manual - Acid Gas Removat & Hot Oi! = PERU LNG 157883-011-CG-MA-0001 Revision C1 6.2.3 6.2.4 May cause sensitization by inhalation and skin contact. ‘Skin May cause sensitization by inhalation and skin contact Eye Risk of serious damage to eyes. Protection of Operating Personnel Respiratory protection requirements: Wear a NIOSH certified (or equivalent) organic vapour respirator. For emergency or on routine, high exposure situations, use a NiOSH-certified full face piece pressure demand self-contained breathing apparatus (SCBA) or full face piece pressure demand supplied air respirator (SAR) with escape provisions. Skin Protection Requirements Equipment should prevent repeated or prolonged skin contact with the product. This May include rubber boots, resistant gloves and other impervious and resistant clothing. Eye Protection Requirements Use chemical (indirectly vented) goggles when there is a potential for contact with aMDEA, including the vapour. A full face shield may be worn over goggles for additional protection, but not as a substitute for goggles, if splashing hazard exists. Other Protective Equipment A safety shower and eyewash fountain should be provided in the amine handling area Proper fire extinguishing equipment must be kept nearby. If possible, provide local exhaust ventilation to control vapours/mists. First Aid General advice: Remove any contaminated clothing. First Aid for Eyes Immediately flush eyes with copious amounts of tepid water for at least 15 minutes. The patient should be seen in a health care facility and a referral to an ophthalmologist considered. First Aid for Skin Wash affected areas with water while removing contaminated clo persist, seek medical attention. First Aid for Inhalation Remove the affected individual into fresh air and keep the person calm. Assist in breathing if necessary. Seek medical attention if irritation persists. First Aid for Ingestion Rinse mouth and then drink plenty of water. Do not induce vomiting. Never induce vomiting or giving anything by mouth if the victim is unconscious or having convulsions. Seek immediate mecicat attention. 1g. If symptoms, Uncontrolled if Printed Page 47 of 52LNG Plant Project d Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG. 157883-011-CG-MA-0001 Revision C1 63 6.3.1 6.3.2 Material Safety Information for Hot Oil This section contains information about the physical and hazardous properties of the hat oil, Therminol-S5. Included is information on the toxic nature of the substance, Physiological effects of exposure and first aid procedures to affect recovery from methanol poisoning. ‘The procedures outlined in the following pages are offered as a quide only. Adherence to_the information _detailed_on the current Material Safety Data Sheet (MSDS) accompanying the delivery of the chemical to site is mandatory. Avoid liquid, mist or vapour contact. Skin contact or inhalation may cause moderate irritation of the skin. Physical Properties * Normal Physical State: Liquid * Colour: Colourless to slightly yellow * Boiling Range: 340 - 390°C @ 1013 hPa. * Auto-ignition temperature: 343°C * Kinematic viscosity: 13 - 34.1 mm’/s @ 38°C Chemical and Hazardous Properties Primary routes of entry: Skin contact, eye contact ‘skin Moderately i No more than slightly toxic if absorbed. Repeated contact may cause a drying, solvent like action on the skin. Eye Moderately irritating to eyes. \gestion and inhalation, tating to skin, Inhalation Elevated processing temperatures may cause release of vapours which are irritating it inhaled. Significant adverse health effects are not expected to develop under normal conditions of exposure. No more than slightly toxic if inhaled. Ingestion No more than slightly toxic if ingested. Significant adverse health effects are not expected to develop if only small amounts (less than a mouthful) if swallowed. Signs and symptoms of overexposure Headache Dizziness/incoordination Nausea/vomiting Loss of consciousness Vertigo Uncontrolled if Printed Page 48 of 52LNG Plant Project } Operating Manual - Acid Gas Removal & Hot Oil = PERU LNG 157883-011-CG-MA-0001 Revision C1 6.3.3 6.3.4 Confusion Anxiety Laboured breathing Drowsiness Protection of Operating Personnel Respiratory protection requitements: Wear a NIOSH certified (or equivalent) organic vapour respirator. For emergency or non routine, high exposure situations, use a NIOSH-certified full face piece pressure demand self-contained breathing apparatus (SCBA) or full face piece pressure demand supplied air respirator (SAR) with escape provisions. Skin Protection Requirements Equipment should prevent repeated or prolonged skin contact with the product. This may include rubber boots, resistant gloves and other impervious and resistant clothing Eye Protection Requirements Use chemical (indirectly vented) goggles when there is a potential for contact with hot oil. A full face shield may be wom over goggles for additional protection, but not as a substitute for goggles, if splashing hazard exists. Other Protective Equipment A safety shower and eyewash fountain should be provided in the amine handling area. Proper fire extinguishing equipment must be kept nearby. It possible, provide local exhaust ventilation to control vapours/mists. First Aid First Aid for Eyes Immediately flush eyes with copious amounts of tepid water for at least 15 minutes. If easy to do, remove any contact lenses, Remove material from skin and clothing Get medica! attention if irritation persists. First Aid for Skin Wash affected areas with water while removing contaminated clothing. If symptoms persist, seek medical attention. Wash heavily contaminated clothing betore re-use. First Aid for Inhalation Remove the affected individual into fresh air and keep the person calm. If breathing is difficult, give oxygen. Assist in breathing if necessary. Seek medical attention if invitation persists. First Aid for Ingestion Immediate first aid is not likely to be required. A physician or Poison Control Centre can be contacted for advice. Wash heavily contaminated clothing before re-use. Uncontrolled if Printed Page 49 of 52LNG Plant Project Operating Manual - Acid Gas Removal & Hot Oil © PERU LNG 187883-011-CG-MA-0001 Revision C1 APPENDIX 1 - PFD & UFD Drawings included: © 157883-011-PA-PF-0001 Acid Gas Removal * 187883-041-PR-UF-0001 Hot Oil System Uncontrolled if Printed Page 50 of 52sania Sue nLte® west AGE DRAW sue co) hc ABSOREER 1108 aga sousent ‘Sve Daa P-n03K/e GR LE3N SO,¥ENT ‘CHABGe PUMPS e-n034/8 = 07 rao; (1196 esnosaye NOTES. set102 P10, Tena panna sem | & Ree crmenana runs sy sau lcas105a/0 Sea it ES SEA we ce compo soot ve ou rss | Mee Wen RrReERINT FLOW FRESE Ome gee | @rvom FZ onewe | Ome 2 ype @© BE @ mmo @® smear (3 means @ concen mse nats om ei © Fr/eared wrvone rx crm] vw [sos] ue ‘b+ p7/07/07| aro Fon cescn | ww | sw [o05] Po es parr27d sino rox comer [| |e] ro pasar rusk 9 ora Revoon| ew [osm [5 fovaivea|rcmssue ror oon pve oe [pe + [ovsa2| sue For abo xl a2 [> 2 [i762 [roe eum woven prs oz vm 2 PERU LNG PERU ING S.RLL LNG PLANT PROJECT Gh PROCESS FLOW DIAGRAM ‘ACID GAS REMOVAL Fae Oe come ne cay et ala Se [eon coin it waist [fname we o|8 157883-011~PR-PF-00012 n 2 L fo ei L Gee Loo . ene ee y-aio1 eaa101/8 seat oa E1001 nares ot at ot Hor OL wor ot or ou wor ot et cas 08 seomNEsa ON HP FUL Ga Waa vet OF ara om or ou 10 108) stokace Tame ast Bove vrai Gru RUAN PUP uPsTRLA FATEH ene vor ou reac muBoue venice sate : © FRE ib ba ay ab eos anc 4. a SDN wet on | ee Se. eer © rove @ sa @ Fah. @ smo HOLOS: + pee, dina. @ [evse| wero ot encrar) e [su[2s] 1 favover owas rem orson | [rae os] ot [sree vox cawenr | [ef] re 3 [a7v78 rae Wo wi svc [5 7 vier e=ssu rom aoc [ve] ar | re 7 3 fever si ro vo [ve [a PERU LNG rr 4 . PERU We SAL ; NG PLANT PROJECT H | ] . Ga | oTiury Flow oases gaan Hor oie “yard | att ‘iRecT FIRED 4 aa SCALE fan): _ i ae + a ca Toowent @ 78 é fe cae se cones wee 3 es aoe eh [Bier conmerie H _ _ _ —_ — 17885-041-PRour 0001 oiOperating Manu: 157883-011- LNG Plant Project G-MA-0001 Revision C1 - Acid Gas Removal & Hot Oil = PERU LNG APPENDIX 2 - P&IDS Drawings included: © 157883-010-PR-PI-0021 © 157883-011-PR-PI-0025 © 157883-011-PR-PI-0026 © 157883-011-PR-PI-0027 157883-011-PR-PI-0028 © 157883-011-PR-PI-0029 © 157883-011-PR-PI-0030 © 157883-011-PR-PI-0031 157883-011-PR-PI-0032 157883-011-PR-PI-0033, 157883-011-PR-PI-0034 © 187883-011-PR-PI-0035 * — 157883-011-PR-PI-0036 © 157883-011-PR-PI-0037 157883-041-PR-PI-0170 157883-041-PR-PI-0171 157883-041-PR-PI-0172 157883-041-PR-PI-0173 187883-041-PR-PI-0174 Inlet Gas Receivin: and Flash Drum Acid Gas Removal: Wash Acid Gas Removal Acid Gas Removal Acid Gas Removal: Booster Pumps Acid Gas Removal: Acid Gas Removal: Reboilers Acid Gas Removal: Drum Acid Gas Removal: Acid Gas Removal: Acid Gas Removal: Pumps, Acid Gas Removal: Acid Gas Removal: Acid Gas Removal: Collection inlet Gas Heater, Filter Inlet Gas Exchange and Acid Gas Absorber HP Flash Vessel Lean/Rich Coolers and Solvent Regenerator Solvent Regenerator Regenerator Reflux Lean Solvent Filtration Solvent Tank Lean Solvent Charge Lean Solvent Cooler Solvent Drain Drum Solvent Drainage Hot Oil System: Expansion Tank and Pumps Hot Oil System: Hot Oil Heater (A) Hot Oil System: Hot Oil Heater (B) Hot Oil System: Storage Hot Oil System: Distribution Uncontrolled if Printed Page 51 of 52PERU ING S.RL LNG PLANT PROJECT __& PR fag MST a cto revien ape 157483~010-PR-PI-0021 1LNG PLANT PROJECT Ca "NCIPING_ AND, WSTRUMENTATION a)acRaM Ui og la ks meavat iwteT "GAS HEAT EXCHANGE AND “WASHNOTES CONT. ee 2, - Tie aa se sneer? 2 51 FRG lume vo awa ene ap | -LNEREONT oF AME 0 & 50 u vn ssa Siete Sokgac uae ho Se 9: gigs om RABE OER. ESSA ‘W.mtveastt S50. Fok Bok DRDENCEANE aon, GN me a ran cr 2B aoe Si aoe et.” HOLDS orf weooo + forovse| ees ron covsrmucren] ww | sv [as] Fo ‘bt [ozan/07| wwrnoven rom cesex | ww [2] 405] re | [a |snvo%ves ase ax vrowes: PERU one PERU ING S.RL ING PLANT PROJECT GD PIPING AND INSTRUMENTATION DIAGRAM UNIT T100'= ACID GAS. REMOVAL ACID GAS ABSORaER Sen 187883~011-PR-PI-0026 7een pores ne FAS vise. ear Sis Se on {ts Nave Sac eR Oke oF EL WA 4 vente semi ned Gig soe ry een ae Same [poner Oe oa st 0 nom 3 fo voce To rea mE) ror J rent te aeee TL | +, cores, 4 a oa ae eee oe _e . et BEBE cemctas Ge) + [27 en tr || | Svomfeemnes tw | — ve omen rae |w Po wk iy |G £ " ee ee D ye ‘of — Ec ; Out's ©) ‘ an Same eee Me cm - ‘DATE DESCRTION Jorn cur |aee| prs sates | @ ral wee ° J i oS S 2 i ' oe wer nme EERE | PERU LNG i op! oS . Hl cere PewU 6 SRL e we Punt prolker a eealis ae @x = a PNG. AND INSTRUMENTATION Duca 4 as. 1te38-stc18)-6 po main FRO — L : 187883-015-PR-PI-0027 7petites > PERU LNG PERU LNG S.A. ANG PLANT PROJECT PING, AND INSTRUMENTATION o1AcRAM 7H jrsttog.s ac ean) "act Boo eA ans BOSE Pours 157883-011-PR-PI~0028wy = dens.) eens hn seimnggig-| wee pr 70 Fo =. Ch ote ee-stera-W [Arun fg 6 24 aneeeaee is [OULU fog ioe oS eta T NOTES gt ages oe ven mace Heme 1 gees ror roe een Pesan GRE ASR en ROC he scan BB et cra Bi ERE ret We ETON TA BENG eH. wa een HOLS * HSGEESPEE lowell Fred ex nan pan, soruae simvems pple | eclememanenlatals : wfiealarermae teehee vmavys OX} = : ecann seaman cg [roe ss | le Sc be] sue «2 sre an rox me | 0 fs] rr een sn [fu ts oor a ae TEES [a [arvana mrs svosiaan— Z5tC)-W $ ahgt— [rev] ome ‘bescmenon [ota] crm | are [ra svn 10yere—t nore 13816 r. ser 2 TRE DORR © © 7 PERU LNG stodgy | al, e— sn meer PERU LNG S.RL. UNG PLANT PROJECT _ & PIPING, AND INSTRUMENTATION, QuagpaM ir ‘eID cas REMOVAL Sopfesr AEENERATOR eae Oh 157883-011-PR-PI-0029L os ef sv ya sete a os (Came setae. wteain hore suse oeinas- 2618-4 srime-r1e1)-4 £=11044/B Siena ee Steen GP Rome sie 71 NOTES eRe S me Teer muy gm we mn «ona or men ee >.uer, cane eee ew ce rnaeeem pean mma Benes ash Si ei, HoLos (Seenpeeenenennnee) iO ors Sm te rm resets [umn ams] Be] [oR a [eye wena ror corn] we [SH ‘x fvsa% we we ne forever wrro rok een | a a[3lalaty @ [iyo sco ror acer Gr favors mace # a ev 1 fos) a wre 2 PERU LNG PERU ING SRL LNG PLANT PROJECT _ @& PNG. AND, STRUMENTATION DaGRAM NWoo'=v ACI GAS REMOVAL SOLVENT REGENERATOR REBOILERS Sea DOCWENT O: 148 157883-011-PR-PI~0030 1£=1102 2-1102/8 va1104 = = sc mcraaren ‘x one oR 1 NN fon ser [owe oe] | cr gag es os ws EE BO nee Se Te Sarees Srna 8 (te ime ye sie ase Sie aan 0 He ENC ct A Pm cme says iat aa ome Sargent ee 2 & mG oS eae LL eet eres NE ners See a - en ae evar PANTIE -N. HOLDS wer art WO he nat OO 4 af “ west — wit ea van 4 ee. _sg nm um eee es. 9 LONE SSREREEAS lore fensl oe se rere 2 1 eee ¥ ipa See wofe cs ila on war [a elev a See ee ae eg? 1 fi ose x roe os Se tate eens tee Pana ING PLANT PROJECT _ & PPI AMO INSTRUMENTATION pingRAM Unit “og' = ACID Recenter Reridx ‘DRUM. SAE Oh woe EF ) riesi-s{eay- 8 “DRAM Wo, ve | 157885~011-PR-P!-0081 7a L S$-1101 68 LEN SLVENT FLIER syrmaateey2 S=1102 5-105 408 SOUT casey ree SENT AERP ‘Ss. FSIO-N sense-26e-4 arose Las) ave NOTES SSO FoR eaten rune 5 ae Da ea Hox PONT To -190 2: ge es 510/23 10 cn Ens 18, 06 rumen wm TREE use M/ONET RANE SAH TBE 30K HOLDS era fons WE | 1 onze esa roe comm) irra ae wm os frre one FoR oe 2 |ivaz) ws Fon noe elelslels | € & lalala rt 1 favo mace 2 A VB 1 [reves ast rs a PERU LNG PERU ING S.L. ING PLANT PROJECT _ _ @ PIPING. AND INSTRUMENTATION DIAGRAM ‘UNIT "1100. = ACID GAS) REMOVAL [LEAN SOLVENT FILTRATION Geae recor 15)a ° 1 «4 oT aa fl ‘ L ey ! ' : ‘ es P=1106 Teo) pee 5 10 a soupon poor || ‘Cam oe SE ioe menescnmen || ea, SERIES 2 Mt (uc) ae, cure sen on watt -oo2r-rtemen 1 ae mt we es nae em ceo # RD 1 SUP sg ee ee severe sate Sto me HOLS: EAS wy REBUT REUSE BY as severe win sss TS foo rae von ni Z| een2" (stew 2 [iss] ead ree war [sees] ase 2 nw von 1 fire rase 8 vans ote sysas gO few] one | eesemmnox [awsome am] 2 PERU LNG PERU LNG S.RL. (nig PLANT PROJECT svasiern e sera Te a foes : PIPING AND INSTRUMENTATION BAM von apt 764 Ti NaN ae AE serena! (%) 9, Bouvet ve ND od 157883-011-PR-PI-0038Conair NOTES siass-ris9-2 signe Bf were ren iS). i Setters Eom cm a ones ster-4 —I oevat-sictis a rea —d om an oe aoa Soares, | {YR wea or Pou o coms is 6 5 eS 70H Hm ED © [hoor uaooy sree ce aed sn ge ee a arose 2 or ra at 0s 4 Hows 08 BY KBR SUSTOUENT RONSON cea ee Toe ea Tw [es weno ro consmiin vn | [as] 6 om [svar fre win rows jum} Ls] po 05 forsvnrmov vox ween |u| Eos] 2 [vies sano son acer | a |ves| ru [ro «raven mac we mon [foe > [vos ase ins Jae] ome | eesonwnon [amon 2 PERU LNG PERU ING S.RL. LNG PLANT PROJECT GD Pipi, AND INSTRUMENTATION DIAGRAM UNIT To0"=" ACID ‘GAs 8 LEAN ‘SOLVENT CHARGE PUMS sae Oh 157883~011-PR-PI-0054 7 é :: an " : . i ‘ £=1101 ]seeEENSS EOD rcs OUEESEEE sc Ea saves ie eee AS SEO 05 con a Moe fc He CONNOR To MAA, MEE EG5 ok ta sure res oe HOLDS (ozone ox exsmcen | | 05 alalala 3 foxes |noroc Fm ven | wu S| share] eae For waor | SENS eens ¢ suum mL ee | comme —poloalela ' penu’ ine 5 PERU LNG S.RAL. of. LNG PLANT PROJECT seed Ssenam-2e0 4 We PIPING AND INSTRUMENTATION DIAGRAM UNIT 1 a = ACID GAS. REMOW ae LEAN SoLVenr Cooter ernest Sour Oh 187885-011~PR-PI-0085 crya et 7 . a . 7 ‘ 7 ' 7 ‘ i * i ' 4 U=1107 S$-1104 nores aon, son sata rae "Seema a RUB Bie Tel rego rn-wt-n Sa ce ron ae risen SEE ae eae wr | eure rene cman oer nee ** (hen Yor cawon St Une ae ‘oy sence 4 1S serwmrteins sens (ra. tore 15.16 S| [RIM + Townes exces vw | 20 ee 1 [ora ra ro ose [ ws resets fra amar [so FEE ecreesoteI a a [svienr ac wees fou ae zlalalal er [tere pase > wa. weve | ou fv 1 [rave] pase oes 2 PERU LNG A PERU ING S.R.L. LNG PLANT PROJECT ec) PIPING AND INSTRUMENTATION DIAGRAM UNIT “ito9'= ACID “GAS REMOVAL ‘Sovenr’ bra RUM ™ cecr0-2108)-4 ® ok a S an Ree A 8 aT oT Fa 157883-011-PR-PI-C0S6 4NOTES «anaes Smo i 1 1 1 \ \ \ I L I 1 tl sen - CCEET EERE EEE EP EE EEE EP SSP EE EEE EEE EEE EEE al fel [al eee sor snout ee ON: AOR LEAN SOLVENT REVERSE FLOW PROTECTIONTAP TE SORT aE PONE P| BE ee aaa ‘CAUSE ales] SR wares [ocnang] ‘escAION Tan [ROS BEA EESSeSe SSC 9S 0s 80) Ialelelalelalelelal=telelslsielslelelal=| SSCSOG880)ES Sa aoa aaa ea Freon rosase grate Pha ‘Sis = eaPeGuanons system ITERLOCK See mesa aurosrancey Pu ontow Row ne] es] SCH [vores] sone] Teena [ET eletelealelelelelataTE ANG FEET WTAE FREE REE EREEEEEEREE EER EE EE IRPTION, H08 AE HOT OL HEATER TIP CAUSE DescaPnON RSTO RETR TTS TT nn (2 | || /a | |e a BE oo Sea eefease ae Breer war Se EE He ee EEE EEE EEE EEE EERE ERE aS Sarat ae —— (eno CAUSE =[alefeletelet eS Se ERS RESSEBIslelslalalelal tseleial EEERIwrenvock no, sccm Panaconus teu Ave ronmonga CAUSE EGE ele eee Seale ele ee elstelsle ele Sa EEE EE EEE EEE EEE EEE ERcause OLHEATER ave ats & fe aa efa fais letstatelelalsletateletebalolels Foon SOW I ACTIONVENDOR DOCUMENT COVER SHEET PERU LNG LNG Plant Terminal Vendor Name: Purchase Order Title: Equipment / Tag Number: Boustead International Heaters Limited Fired Heaters H-4101A & H-4101B, Vendor's Document No.: 578-434-183-BA Vendor's issue Rex 2 Pires] Reiaed- Cin commenta_| ee WoW; Ze Tale, '3_|30/0/40/8|~ Revised. Client Comments ‘SF og/osios_| ~~ GLP 08/08/08 2[ 20/02/08 | Revised-BIH comments. EK — RUC. 28/02/08 1_[12n2v07 First Issue, EX GLP 25/07/08 Rev | Date (eoue 3 Checked cored Document Numi Purchase Order Number 134157883-P0-45301 Document Title: SIGNATURE: | TypeCode __Sea.ne - EC2 - 004 H-4101A&B Cause and Effect Charts VENDOR DOCUMENT REVIEW ‘Purchasers review of Vendors decurnents does not aleve Vendor of the responsibly for correctness under the Purchase Order. Permission to proceed does not constitute acceptance of design, detall and calculatona, test methods or materials ‘daveloped of selacted by the Vendor and does not rliove the Vendor from full complance withthe Purchase Ordar or any ‘other obligations, nor detract from any ofthe Purchasar's rights. DaTe:] 26 Jon 08 CODE - CODEA - CODER - CODE 1 IMPORTANT Final (Accepted). Work may proceed, ‘Qualied Release. Revise and re-submt, but work may proceed subject tothe incorporation of Purchaser comments Rejected. Fuly incorporate comments and resubmit documents as required. Work may not proceed. ‘Accapted for information only. |Should the Vendor consider thet any comments made by the Purchaser change the Scope of Supply, the Vendor shell ledvise the price and delivery implications of euch changes within flve working days of receipt. The Vendor must not incorporate such changes without prior approval of the Purchaser of the revised price andior delivery period. PECTIVE CLAIMS WILL NOT BE CONSIDERED. ‘The documont consists ofthis frontsheet plus 3 pages.mae ENVIRO\izietics fe 090 seomeraa rev Fat: 908-621-7099 CAUSE AND EFFECT Bumer Management System, H-4101A8 8 Doc Ne. S78-434-1838A [Gient —[Boustead iterational heater ob Nox [3506 [Equip Nox _[H-4t0707 8 [Date: [une 15,2008, [Rev tio __[3re rn Ee -- SOOO TEES fair é noea ae es Magnet Sa Gh) Cause ar tet me : PETRIEIE LIE] lel blithe t delta > leeldslae/galee del Ese] a |e a5 | ae | a2 | 45 | 321 as | fal asl & i — | 83 | 83| 83 | 85) 88) 85) 88) 82) F aa ona 5D ton xfxtxlx|xlxlslefale ene ES 11044 eladefxlxfxlxlelel x rn ct ips Pre Ltn Pte xpd] x : ft on Po 024 xpxlaele : Fn ont Penn PTA cfedads : pre esr Pre i, C284 eran pce arp Hi, TANTaAAAD xfxfxle pete sa To, 7-464 ey eee ahh eae ala ee eae xfafx|x Jose Header tock Va Fou, XV:1410240 x{xfx | « x eee eee efelalx : ee eee eae elalx| x : rn one ck Ve Fat 0th : ee een eee Rea ee |Fuel Header Bleed Valve Fault, XV-1410228 | x x x x x x et acer Beck ane Fi 024 meade an en i eve aut pA ; ee F psrecrane Ft serene : esr rane ue 1 cfefxtalefefelalals tae xl efe[s : Nolet: Heoter ome out occurs when any 3 consecutive bumers have fare out. Flare outs any plovbumner witheul tome dalecton