H2O

H2O may + NaBH4

H2O deion + NaBH4
0.2926
0.4738
0.9059
0.3271
0.7757
1.0332
0.453

H2O deion + NaBH4 lan 2

0.6484
0.6329

H2O
H2O NaBH4 nha ko binh tia
0.1437

0.3369
0.3872
0.3371

0.2987

V NaBH4
2
4
8

Area
0.2383
0.3349
0.5609

Chart Title
0.6
f(x) = 0.0541571429x + 0.1253
R = 0.9985983737

0.5
0.4
0.3
0.2
0.1
0

40

50

60

70

80

0.9852 0.988433 0.060615 6.132403

0.9295
1.0506
1.2353 1.198233 0.079106 6.601878
1.252
1.1074
1.3639
1.3818 0.055461 4.013644
1.3375
1.444
1.4542
1.5333 0.072939
4.757
1.5979
1.5478
1.6969
1.6262 1.66155

1.2
1

1.7096
1.9786
2.05294 1.969647 0.088112 4.473484
1.8774

0.8
0.6
0.4
0.2
0
35

40

40
50
60
70
80
100

0.988
1.19
1.38
1.53
1.66
1.96

0.688
0.89
1.08
1.23
1.36
1.66

Chart Title
1.2
f(x) = 0.0196x - 0.094
R = 0.9996877277

1
0.8
0.6
0.4
0.2
0
35

40

45

50

55

60

65

NaBH4

10

0.2216
0.2961
0.2724
0.41
0.568
0.3571
0.5008
0.531
0.4115
0.4058
0.4118
0.4056
0.4306
0.6359
0.6558

30

0.9693
0.9861
0.9012

50

1.382
1.5249
1.3515

0.64585

0.24585
-0.4
-0.4
0.9522
0.5522 0.044959
-0.4
-0.4
-0.4
1.419467 1.019467

4.72159

mcn
mHg
msau
C
0.4229 401.233
40.663
0.116
1.145
9.823
0.1042
12.142
10.755

10 ppm
100 ppb
1 ppb
NaBH4

9.867
116.5
1.129

0.4874
0.405

Blank
NaBH4 HNO3

Area
TB
Sd
RSD
0.6503 0.65805 0.01096 1.665551
0.6658

mHg

30
30
30
50
50
50
70
70
100
100
100

35.11248
35.11248
35.11248
58.5208
58.5208
58.5208
81.92912
81.92912
117.0416
117.0416
117.0416

31.11
31.11
31.11
51.85
51.85
51.85

103.7
103.7
103.7

0.7936
0.7253
0.7596
1.478
1.6157
1.5256
2.0855
1.9553
2.16
2.5247
2.6284
3.8056
3.9635
4.0151

0.03415 4.496394
0.7595
0.069935 4.541894
1.539767
0.103605 5.012514
2.066933
0.073327 2.845936
2.57655
0.109152 2.778777
3.928067

4
3.5
3

f(x) = 0.0291654102x - 0.2448545662

R = 0.9754564368

2.5
2
1.5
1
0.5
0
30

40

50

60

70

80

90

100 110 12

0.5
0
30

40

50

60

70

80

90

100 110 12

VHNO3
mHNO3
m
dHNO3
25.00
25.9073 25.9183
1.037
25.9246
25.9229

Area - Blank

f(x)
4 = 0.0334768687x - 0.2293918803
R = 0.9894244638
3.5

0.13555
0.06725
0.10155
0.81995
0.95765
0.86755
1.42745
1.29725
1.50195
1.86665
1.97035
3.14755
3.30545
3.35705

#DIV/0!

0.00189

#DIV/0!
3
2.5

0.026356
0.030783
0.027887
0.02753
0.025019
0.028967
#DIV/0!
#DIV/0!
0.030352
0.031875
0.032373

#DIV/0!
2
1.5
1
0.5
0
20

54102x - 0.2448545662
4368
Column H
Linear (Column H)

70

80

90

100 110 120 130

30

40

50

60

70

80

70

80

90

100 110 120 130

CHg

dHg
1000

60

70

80

1.054

90

100

110

0 mcn
mHg
msau
C
10 ppm
0.4229 401.2334 40.6629 9.867309
100 ppb
0.1044 1.030147 10.9075 94.44392
1 ppb
0.1173 11.07827 10.5885 1.046255

VHNO3
25
0
0

f(x)
3.5 = 0.0249614354x - 0
R = 0.9872705957
3

blank

54.23424
54.23424
54.23424
75.92793
75.92793
75.92793
108.4685
108.4685
108.4685
130.1622
130.1622
130.1622

151.8559

0.4848
0.6322
0.6108
1.1313
1.1101
1.1179
1.9214
1.8425
1.7052
2.4613
2.3551
2.3857
3.0958
3.3805
3.2165
3.7548
3.6689
3.7081
4.4291
4.8762

2.5

0.575933

0.555367
0.534167
0.541967
1.345467
1.266567
1.129267
1.885367
1.779167
1.809767
2.519867
2.804567
2.640567
3.178867
3.092967
3.132167
3.853167
4.300267

#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
0.024808
1.2471
0.023354
0.020822
0.024831 1.824767
0.023432
0.023835
0.023231
2.655
0.025856
0.024344
0.024422 3.134667
0.023762
0.024064
#DIV/0! 4.076717
#DIV/0!

#DIV/0!

#DIV/0!

1.5
1
0.5
0
50

60

70

mHNO3
m
dHNO3
25.9073 25.91827 1.036731
25.9246
0
0
25.9229
0
0

f(x)
3.5 = 0.0249614354x - 0.086016092
R = 0.9872705957
3
2.5
2
1.5
1
0.5
0
50

60

70

80

90

100

110

120

130

140

3.5
3

f(x) = 0.0249614354x - 0.086016092

R = 0.9987821384

2.5
2
1.5
1
0.5
0
50

60

70

80

90

100

110

120

130

140

0 mcn
mHg
msau
C
10 ppm
0.4229 401.2334 40.6629 9.867309
100 ppb
0.1106 1.091324 11.4715 95.13354
1 ppb
0.0997 9.484814 10.4043 0.911624

blank

50
50
50
60
60
60
80
80
80
100
100
100
120
120
120

47.25545
47.25545
47.25545
56.70654
56.70654
56.70654
75.60872
75.60872
75.60872
94.5109
94.5109
94.5109
113.4131
113.4131
113.4131

0.5149
0.6536
0.5088
0.402
0.6306
0.4851
1.3597
1.8425
1.7052
2.4613
2.3551
2.3857
3.0958
3.3805
3.2165
3.7548
3.6689
3.7081
4.4291
4.8762

0.5591

0.8006
1.2834
1.1461
1.9022
1.796
1.8266
2.5367
2.8214
2.6574
3.1957
3.1098
3.149
3.87
4.3171

0.016942
1.0767
0.027159
0.024253
0.033545
1.8416
0.031672
0.032211
0.03355 2.671833
0.037316
0.035147
0.033813
3.1515
0.032904
0.033319
0.034123 4.09355
0.038065

VHNO3

mHNO3
m
dHNO3
25 25.9073 25.91827 1.036731
0 25.9246
0
0
0 25.9229
0
0

5
4.5
4

f(x) = 0.0425835355x - 0.7329392765

R = 0.9548076657

3.5
3
2.5
2
1.5
1
0.5
0
40

50

60

70

80

90

100

110

120

4.5
4

f(x) = 0.042571112x - 0.7321791667

R = 0.977806714

3.5
3
2.5
2
1.5
1
0.5
0
40

50

60

70

80

90

100

110

120

110

120

0 mcn
mHg
msau
C
10 ppm
0.4229 401.2334 40.6629 9.867309
100 ppb
0.1086 1.07159 10.1617 105.4538
1 ppb
0.1229 12.96027 12.2777 1.055594

2.5
2

blank

50
50
50
70
70
70
100
100
100
120
120
120
200
200
200
300
300
300
500
500
500
700
700
700
1000
1000
1000

54.71835
54.71835
54.71835
76.60569
76.60569
76.60569
109.4367
109.4367
109.4367
131.324
131.324
131.324

0
0
0
0
0
0
0.9871
1.0066
1.0273
1.2643
1.2209
1.2858
1.4977
1.524
1.4349
1.8227
1.983
1.8722

f(x) = 0.071
R = 0.9486

1.5
1

0.9871
1.0066
1.0273
1.2643
1.2209
1.2858
1.4977
1.524
1.4349
1.8227
1.983
1.8722

0.01804
0.018396
0.018774
0.016504
0.015937
0.016785
0.013686
0.013926
0.013112
0.013879

1.007

0.5

1.257

1.51085

50

60

VHNO3

mHNO3
m
dHNO3
25 25.9073 25.91827 1.036731
0 25.9246
0
0
0 25.9229
0
0

2.5
2
f(x) = 0.0716351966 x^0.6584638135
R = 0.9486408455

1.5
1
0.5
0
50

60

70

80

90

100

110

120

130

140

0 mcn
mHg
msau
C
10 ppm
0.4229 401.2334 40.6629 9.867309
100 ppb
0.1086 1.07159 10.1617 105.4538
1 ppb
0.1229 12.96027 12.2777 1.055594

blank

50
50
50
70
70
70
100
100
100
120
120
120
200
200
200
300
300
300
500
500
500
700
700
700
1000
1000
1000

54.71835
54.71835
54.71835
76.60569
76.60569
76.60569
109.4367
109.4367
109.4367
131.324
131.324
131.324

0
0
0
0
0
0
0.9871
1.0066
1.0273
1.2643
1.2209
1.2858
1.4977
1.524
1.4349
1.8227
1.983
1.8722

0.9871
1.0066
1.0273
1.2643
1.2209
1.2858
1.4977
1.524
1.4349
1.8227
1.983
1.8722

0.01804
0.018396
0.018774
0.016504
0.015937
0.016785
0.013686
0.013926
0.013112
0.013879

1.007

1.257

1.51085

VHNO3

mHNO3
m
dHNO3
25 25.9073 25.91827 1.036731
0 25.9246
0
0
0 25.9229
0
0

0V H2O cat
0.4195
0.4818
0.3504

100
200
300
400
500
700

0.1652
0.3038
0.4168
0.5884
0.7134
0.9105

8.3139
15.3009
27.561
34.6709
41.7317
57.6083

1
0.9

f(x) = 0.0012675429x + 0.0515842857

R = 0.9923771246

0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0

100

200

300

400

500

70
60
f(x) = 0.0827918571x + 0.5074357143
R = 0.9937231447

50
40
30
20
10
0
0

100

200

300

400

500

5429x + 0.0515842857
246

300

400

500

600

700

800

571x + 0.5074357143
47

300

400

500

600

700

800

0
0
0
50
50
50
100
100
200
200
400

0.0517
0.049
0.0545
0.0746 0.080567
0.0782
0.0889
0.1376
0.1465
0.1554
0.246 0.25735
0.2687
0.5154

0.3
0.25

f(x) = 0.0011685476x + 0.0251416667

R = 0.998023482

0.2
0.15
0.1
0.05
0
40

60

80

100

120

140

0.6
0.5

f(x) = 0.0011588488x + 0.0352112654

R = 0.9883017363

0.4
0.3
0.2
0.1
0
0

50

100

150

200

250

5476x + 0.0251416667
82

100

120

140

160

180

200

220

0.0352112654

150

200

250

300

350

400

450

0 mcn
mHg
msau
C
10 ppm
0.4229 401.2334 40.6629 9.867309
100 ppb
0.1086 1.07159 10.1617 105.4538
1 ppb
0.1229 12.96027 12.2777 1.055594

2.5
2

blank

50
50
50
70
70
70
100
100
100
120
120
120
200
200
200
300
300
300
500
500
500
700
700
700
1000
1000
1000

54.71835
54.71835
54.71835
76.60569
76.60569
76.60569
109.4367
109.4367
109.4367
131.324
131.324
131.324

0
0
0
0
0
0
0.9871
1.0066
1.0273
1.2643
1.2209
1.2858
1.4977
1.524
1.4349
1.8227
1.983
1.8722

f(x) = 0.071
R = 0.9486

1.5
1

0.9871
1.0066
1.0273
1.2643
1.2209
1.2858
1.4977
1.524
1.4349
1.8227
1.983
1.8722

0.01804
0.018396
0.018774
0.016504
0.015937
0.016785
0.013686
0.013926
0.013112
0.013879

1.007

0.5

1.257

1.51085

50

60

VHNO3

mHNO3
m
dHNO3
25 25.9073 25.91827 1.036731
0 25.9246
0
0
0 25.9229
0
0

2.5
2
f(x) = 0.0716351966 x^0.6584638135
R = 0.9486408455

1.5
1
0.5
0
50

blank

60

70

80

90

100

0.0461
0.0552
0.0522 10.12067
0.0553
0.0921
0.0715 0.083333 12.76426
0.0864

110

120

130

140

10

20

35

50

0
0
0

88.08315
88.08315
88.08315
176.1663
176.1663
176.1663
176.1663
308.291
308.291
308.291
440.4158
440.4158
440.4158

65

80

100

704.6652
704.6652
704.6652
880.8315
880.8315
880.8315
1056.998
1056.998

0.0269
0.0465
0.0483
0.0313
0.035
0.0364
0.0359
0.0292
0.0368
0.0366
0.0304 0.035755 18.66877

1000
10
100
10

0.0607
0.054
0.0516
0.1244
0.1052
0.1227
0.093
0.2249
0.2307
0.1974
0.3054
0.3323
0.3364
0.4942
0.4327
0.5109
0.54
0.5697
0.5676
0.7117
0.6982
0.7258
0.877
0.9126

0.024945
0.018245
0.015845
0.088645
0.069445
0.086945
0.057245
0.189145
0.194945
0.161645
0.269645
0.296545
0.300645
0.458445
0.396945
0.475145
0.504245
0.533945
0.531845
0.675945
0.662445
0.690045
0.841245
0.876845

0.019679 8.508029

1.012
1.0347
1.0696
1.0711
1.0092
1.0262
1.0784

0.976245 1.003012 2.793172

0.998945
1.033845
1.035345 0.999745 3.088438
0.973445
0.990445
1.042645

0.07557

10

1.2
1

0.181912

f(x) = 0.0008426924x
R = 0.9944259023

0.8

0.288945 0.000656

0.6
0.4

0.479267

8.59298

0.523345

0.2
0
0

200

400

0.676145

0.859045

120

140
150
150
150
160
160

1233.164
1233.164
1233.164
1321.247
1321.247
1321.247
1409.33
1409.33

1.2
1
0.8

f(x) = 0.000872
R = 0.9985032

1.2

160

1409.33

f(x) = 0.000872
R = 0.9985032

0.8
0.6
0.4
0.2
0
0

200

0.4068
0.4068
0.3967
0.4905
0.5201

385.9583
3.793495
46.25512
49.04646

40.3611
40.3611 9.56263
40.2271 94.30198
5.4456 8.494036
5.8811 8.339675

0.3021 28.48863

3.819 7.459709

f(x) = 0.0008426924x - 0.0688153241

R = 0.9944259023

200

400

88.08315
176.1663
308.291
440.4158
704.6652
880.8315
1056.998
1233.164

600

800

0.019679
0.07557
0.181912
0.288945
0.523345
0.676145
0.859045
1.003012

1.2
1
0.8

f(x) = 0.0008720945x - 0.0794598776

R = 0.9985032669

1000

1200

1400

1.2
1

f(x) = 0.0008720945x - 0.0794598776

R = 0.9985032669

0.8
0.6
0.4
0.2
0
0

200

400

600

800

1000

1200

1400

blank
15
0.0531
14
0.0638
13
0.0633
12
0.0547
11
0.0601
10
0.0627
9
0.0255
8
0.0000
7
0.0000
4
0

tb
0.0632
0.0704
0.0571
0.0551
0.0513
0.0493
0.0144
0.0000
0.0000
0.0000

0.0636
0.0657
0.0566
0.0599
0.0621
0.0564
0.0194
0.0000
0.0000
0.0000

sd
0.0600
0.0666
0.0590
0.0566
0.0578
0.0561
0.0198
0.0000
0.0000
0.0000

0.0060
0.0034
0.0037
0.0029
0.0057
0.0067
0.0056
0.0000
0.0000
0.0000
4.3027

95%
0.014781
0.00844
0.009272
0.007188
0.014273
0.016654
0.01381
0
0
0

0.0700
0.0600
0.0500
0.0400
Tn hiu (vol)
0.0300
0.0200
0.0100
0.0000
2

8 lu lng10
Vch trn
k

8 lu lng10
h trn
k

0.499
0.5992

12

14

16

0.0284
0.0391
0.0296

15
15
15
15
14
14
14
13
13
13
12
12
12
11
11
11
10
10
10
9
9
9
8
8
8
7
7
7

0.4082
0.3698
0.378
0.4087
0.3818
0.3941
0.3945
0.3516
0.3696
0.4088
0.3637
0.3847
0.3319
0.3428
0.3364
0.3379
0.3404
0.341
0.3532
0.0901
0.0832
0.0858
0.0215
0.0226
0.021
0.0147
0.015
0.014

0.391175

0.390133

0.376667

0.3601

0.339033

0.344867

0.086367

15
15
15
15
14
14
14
13
13
13
12
12
12
11
11
11
10
10
10
9
9
9
8
8
8
7
7
7

521.7391
521.7391
521.7391
500
500
500
444.4444
444.4444
444.4444
387.0968
387.0968
387.0968
324.3243
324.3243
324.3243
285.7143
285.7143
285.7143
244.898
244.898
244.898
176.4706
176.4706
176.4706
141.1765
141.1765
141.1765

0.3936
0.3999
0.4082
0.3818
0.3941
0.3945
0.3516
0.3696
0.363
0.3637
0.3558
0.3687
0.3428
0.3364
0.3379
0.3404
0.341
0.3532
0.0901
0.0832
0.0858
0.0215
0.0226
0.021
0.0147
0.015
0.014

109.0909
76.92308
69.76744

15
14
13
12

2.3 521.7391
2.4
500
2.7 444.4444
3.1 387.0968

20
18
16
14
12

20

11
10
9
8
7
6
5
4
3
2
1

3.7
4.2
4.9
6.8
8.5
11
15.6
17.2

324.3243
285.7143
244.898
176.4706
141.1765
109.0909
76.92308
69.76744

18
16
14
12
10
8
6
4
2
0
2

0.069
0.271

0.45
0.4
0.35
0.3
0.25
0.2
0.15
0.1
0.05
0
100

150

16.66667
58.33333

20
18
16
14
12

200

250

300

350

400

450

500

550

20
18
16
14
12
10
8
6
4
2
0
2

10

12

14

16

15
15
15
14
14
14
13
13
13
12
12
12
11
11
11
10
10
10
9
9
9
7
7
7

Lu lng (mL/pht)
522
500
444
387
324
286
245
141

0.4336
0.4462
0.4595
0.4726
0.4984
0.4934
0.4435
0.4597
0.4307
0.4133
0.4437
0.4515
0.4225
0.4294
0.4464
0.3233
0.3728
0.336
0.0728
0.0788
0.0823
0.0194
0.02
0.0224

Vch
15
14
13
12
11
10
9
7

0.4881333333 2.80304405
0.4314
0.4446333333 3.26857645

0.4746
0.4487

0.44636

4.9203894

0.4427

0.3623
0.3478

Chiu cao (Vol)

0.446
0.447
0.443
0.426
0.444
0.408
0.069
0.021

0.34844 5.69067572

SD (n=3)
0.013
0.017
0.017
0.017
0.015
0.005
0.008
0.002

RSD
2.9
3.8
3.8
4.1
3.5
1.2
12.3
7.7

Kho st lu lng kh bo v
0.500
0.450
0.400
0.350
0.300

0.500
0.450
0.400
0.350
0.300
Chiu cao peak (Vol)

0.250
0.200
0.150
0.100
0.050
0.000
100

150

200

250

300

350

Lu lng kh bo v (mL/pht)

40

0.4336
0.4462
0.4595
0.4608
0.4513
0.4282
0.4401
0.4613
0.4283
0.4249
0.4444
0.4098
0.4585
0.4276
0.445
0.4025
0.412
0.4081
0.0625
0.0654
0.0784
0.0194
0.02
0.0224

kh bo v

10
100
10

0.446433 2.901122

0.446767 3.752772

0.4068 385.9583
0.3967 3.793495
0.5003 47.17928

40.3611
40.2271
5.2925

0.6
0.5

0.443233

3.77265

0.426367 4.068462

0.4
0.3
0.2

0.4437 3.491315

0.407533 1.171753

0.1
0
6

10

11

12

13

10

11

12

14

15

0.068767 12.31379

0.0206 7.706072

0.5
0.45
0.4
0.35
0.3
0.25
0.2
0.15
0.1
0.05
0
6

13

14

00

350

h bo v (mL/pht)

400

450

500

550

9.56263
94.30198
8.914366

Column B

12

13

14

15

16

Column F

11

12

13

14

15

16

10
100
10

0.4068 385.9583
0.3967 3.793495
0.723 68.18033
0.0505

100
100
100
200
200
200
300
300
300
400
400
400
500
500
500

0.0373

0.3943
0.4023
0.3917
0.612
0.5996
0.6089
1.007
1.0314
0.9811
1.0971 8.079082
0.9499
0.9645
1.055
1.0577
1.0513

40.3611 9.56263
40.2271 94.30198
7.7399 8.808942
0.0404 0.042733

1.0731
1.0856
0.9265

1.0458
0.9533

0.01

100
100
100
200
200
200
250
250
250
300
300
300
400
400
400
500
500
500

0.3943
0.4023
0.3917
0.612
0.5996
0.6089
0.7473
0.7708
0.7418
0.8754
0.9043
0.8804
0.9533
0.9499
0.9645
1.055
1.0577
1.0513

0.005524

0.3961

0.006453 0.606833

0.015403

0.7533

0.015446

0.8867

0.007639

0.9559

0.003213 1.054667

1.2

Lu lng (mL/pht)
100
200
250
300
400
500

Chiu cao (Vol) SD (n=3) RSD

0.396
0.006
0.607
0.006
0.753
0.015
0.887
0.015
0.956
0.008
1.055
0.003

1.2

1.4
1.1
2.0
1.7
0.8
0.3

1
0.8

Chiu cao (Vol)

0.6
0.4
0.2

0.1187
0.1402
0.1

0.120

50

1.2
1
0.8

0.7473
0.7708
0.7418
0.8754
0.9043
0.8804

0.6
0.4
0.2
0
50

100

150

200

250

300

350

400

250

300

350

400

450

500

450

1.2
1
0.8
0.6
0.4
0.2
0
50

100

150

200

Kho st lu lng kh mang

1.2

550

500

hiu cao (Vol)

Kho st lu lng kh mang

1.2
1
0.8
0.6
0.4
0.2
0
50

100

150

200

250

300

350

Lu lng kh mang (mL/pht)

400

450

500

550

50

400

50

500

450

550

500

550

500

550

mcn
10 ppm
100 ppb
10 ppb

0
0
0
10
10
10
20
20
20
30
30
30
40
40
40
50
50
50
70
70
70
100
100

0
0
0
100.5123
100.5123
100.5123
201.0247
201.0247
201.0247
301.537
301.537
301.537
402.0493
402.0493
402.0493
502.5617
502.5617
502.5617
703.5864
703.5864
703.5864
1005.123
1005.123

mHg
msau
C
0.1051 99.71537 10.3066 9.674904
0.4001 3870.929 39.0983 99.00505
0.5008 49.58173
4.9329 10.05123

0.1558 0.1278333333
0.123
0.1047
0.2685
0.1486
0.2976
0.2632
0.4406 0.3076333333
0.4656
0.4002
0.6009 0.4730666667

0.7962 0.6542166667
0.7679
0.9394
0.9088
0.9329
0.9508
0.9554
0.9617
0.9558
0.9555

0.7992

1
0.9

f(x) = 0.0016108686x + 0.11

R = 0.9953316039

0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0

100

200

dHg=1.054

0.9
0.8

f(x) = 0.0164778333x - 0.0177916667

R = 0.9990960864

0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
5

10

15

20

25

30

35

40

0.0016108686x + 0.1198916216
0.9953316039

100

200

300

400

500

600

45

50

55

10 ppm
100 ppb
1 ppb

0.0522
0.0462
0.0643
0.1099
0.1181
0.1081
0.2268
0.2206
0.2066
0.292
0.3127
0.2904
0.3997
0.4017
0.4063
0.5089
0.5064
0.495
0.7217

56.63324
50.12367
69.76087
119.2336
128.13
117.2807
246.0617
239.3351
224.1461
316.799
339.257
315.0631
433.6457
435.8156
440.8062
552.1199
549.4075
537.0394
782.9925

50
100
200
300
400
500

0.061408
0.118024
0.268446
0.371694
0.494352
0.603088

0.0976
0.1088
0.1008
0.1896
0.1558
0.1777
0.244
0.2739
0.2214
0.4197
0.4376
0.402
0.498
0.4889
0.5211
0.6568
0.6436
0.6258
0.7747
0.7663
0.7428
0.7792
0.7739

mcn
mHg
msau
C
0.1051 99.71537 10.3066 9.674904
0.4001 3870.929 39.0983 99.00505
0.1161 11.49449 10.5947 1.084928
0.1024

0.0872
0.0534
0.0753
0.1416
0.1715
0.119
0.3173
0.3352
0.2996
0.3956
0.3865
0.4187
0.5544
0.5412
0.5234
0.6723
0.6639
0.6404
0.6768
0.6715

0.00154
0.001065
0.001079
0.001188
0.001338
0.001015
0.00129
0.001401
0.001337
0.001249
0.001139
0.001329
0.001278
0.001242
0.001187
0.001218
0.001208
0.001192
0.000864

0.001228 0.061408

0.00118 0.118024

0.001342 0.268446

0.001239 0.371694

0.001236 0.494352

0.001206 0.603088

0.7
0.6

f(x) = 0.0012106966x + 0.0067387513

R = 0.9972791658

0.5
0.4
0.3
0.2
0.1
0
0

100

200

300

400

0.1
0
0

100

200

300

400

0.8
0.7
f(x) = 0.0012098129x + 0.0078317132
R = 0.9910412433

0.6
0.5
0.4
0.3
0.2
0.1
0
0

100

200

300

6x + 0.0067387513

300

400

500

600

400

500

600

300

400

500

600

10 ppm
100 ppb
1 ppb

mcn
mHg
msau
C
0.1051 99.715370019 10.3066 9.674904
0.4001 3870.92926325 39.0983 99.00505
0.1065 10.5440381432 10.2098 1.032737

0.0933
0.1187
0.1353
0.1275
mcan
mHg
cao
cao - blank
0.0467 48.22882
0.2604
0.1417 0.002938
0.0402 41.51603
0.2156
0.0969 0.002334
0.0669 69.0901
0.2171
0.0984 0.001424
0.1091 112.6716
0.482
0.3633 0.003224
0.1048 108.2308
0.383
0.2643 0.002442
0.1058 109.2636
0.3301
0.2114 0.001935
0.2486 256.7384
0.6753
0.5566 0.002168
0.2007 207.2703
0.6507
0.532 0.002567
0.1911 197.356
0.4209
0.3022 0.001531
0.3183 328.7202
0.585
0.4663 0.001419 0.120845
0.299 308.7884
0.6173
0.4986 0.001615
0.3147 325.0023
0.7065
0.5878 0.001809
0.4062 419.4978
0.9211
0.8024 0.001913
0.4107 424.1451
0.9005
0.7818 0.001843
0.4134 426.9335
0.8287
0.71 0.001663
0.4969 513.167
0.9981
0.8794 0.001714
0.505 521.5322
1.0497
0.931 0.001785
0.5164 533.3054
0.9266
0.8079 0.001515
0.5603 578.6425
1.0953
0.9766 0.001688
0.6122 632.2416
1.1667
1.048 0.001658
0.6114 631.4154
1.1606
1.0419 0.00165
0.7613 786.2227
1.1683
1.0496 0.001335

10 ppm
100 ppb
5 ppb

mcn
mHg
msau
C
0.1051 99.71537002 10.3066 9.674904
0.4001 3870.929263 39.0983 99.00505
0.518 51.28461745 10.0647 5.095494

0.118
0.0921
0.1447 0.118267
mHg
Cao
Cao-blank
RSD

10 50.9549
0.2233
0.1050 49.4803
10 50.9549
0.2822
0.1639
10 50.9549
0.1666
0.0483
10 50.9549
0.1974
0.0791
20 101.9099
0.3013
0.1830 44.3819
20 101.9099
0.3504
0.2321
20 101.9099
0.2753
0.1570
20 101.9099
0.2771
0.1588
40 203.8198
0.5142
0.3959 20.0789
40 203.8198
0.4682
0.3499
40 203.8198
0.6298
0.5115
40 203.8198
0.4533
0.3350
50 254.7747
0.5359
0.4176
8.5788
50 254.7747
0.6078
0.4895
50 254.7747
0.5887
0.4704
50 254.7747
0.6311
0.5128
60 305.7296
0.6462
0.5279
8.1034
60 305.7296
0.6793
0.5610
60 305.7296
0.6770
0.5587
60 305.7296
0.7550
0.6367
80 407.6395
0.8828
0.7645
4.5305
80 407.6395
0.8634
0.7451
80 407.6395
0.8438
0.7255
80 407.6395
0.8053
0.6870
100 509.5494
0.9671
0.8488
2.4261
100 509.5494
0.9749
0.8566
100 509.5494
0.9789
0.8606
100 509.5494
0.9338
0.8155

nht TB
0.0021
0.0991
0.0032
0.0009
0.0016
0.0018 0.182758
0.0023
0.0015
0.0016
0.0019 0.398108
0.0017

1.0000
0.9000
0.8000
0.7000
0.6000
0.5000
0.4000
0.3000

0.0016
0.0016
0.0019
0.0018
0.0020
0.0017
0.0018
0.0018
0.0021
0.0019
0.0018
0.0018
0.0017
0.0017
0.0017
0.0017
0.0016

20.36021

0.2000

0.472608

0.1000
0.0000
0.0000

0.571108

0.754213

0.845408

1.0000
0.9000
0.8000
0.7000

f(x) = 0.0016690343x + 0.0340026995

R = 0.965768757

0.6000
0.5000
0.4000
0.3000
0.2000
0.1000
0.0000
0.0000

100.0000

200.0000

300.0000

400.0000

500.0000

600.0000

0.8000
0.7000

f(x) = 0.001850381x + 0.0044112833

R = 0.9986174371

0.6000
0.5000
0.4000
0.3000
0.2000
0.1000
0.0000
0.0000

100.0000

200.0000

300.0000

400.0000

500.0000

10 ppm
100 ppb
5 ppb

Blank

0.123

mHg
10
10
10
10
20
20
20
20
40
40
40
40
50
50
50
50
60
60
60
60
80
80
80
80
100
100
100
100

mcn
mHg
msau
C
0.1051 99.71537 10.3066 9.674904
0.4001 3870.929 39.0983 99.00505
0.4944 48.9481 10.9806 4.457689

0.1152

0.123

Cao
Cao-blank RSD

45
0.2031
0.0801
7.8324
45
0.2129
0.0899
45
0.2103
0.0873
45
0.1987
0.0757
89
0.2634
0.1404
8.7058
89
0.2583
0.1353
89
0.2856
0.1626
89
0.2609
0.1379
178
0.5068
0.3838 14.3375
178
0.4510
0.3280
178
0.3933
0.2703
178
0.4407
0.3177
223
0.5053
0.3823
6.7259
223
0.5164
0.3934
223
0.5681
0.4451
223
0.5297
0.4067
267
0.5964
0.4734
7.9004
267
0.5894
0.4664
267
0.6306
0.5076
267
0.6758
0.5528
357
0.7931
0.6701
7.3850
357
0.7293
0.6063
357
0.6833
0.5603
357
0.7296
0.6066
446
0.8872
0.7642
3.0120
446
0.8700
0.7470
446
0.9198
0.7968
446
0.8720
0.7490

nhy
TB
0.0018 8.718882
0.0020
0.0018
0.0020
0.0017
0.0016
0.0015
0.0018
0.0015
0.0022
0.0018
0.0015
0.0018
0.0017
0.0018
0.0020
0.0018
0.0018
0.0017
0.0019
0.0021
0.0019
0.0017
0.0016
0.0017
0.0017
0.0017
0.0018
0.0017

0.083

0.144

0.325

0.407

0.500

0.611

0.764

40.35088

0.9000
0.8000
f(x)
+ 0.0111929577+ 0.0020521504x - 0.0172646465
f(x) =
= 0.0017173195x
- 6.91703298087636E-007x^2
R
=
0.9799975473
R = 0.9824296761

0.7000
0.6000
0.5000
0.4000
0.3000
0.2000
0.1000
0.0000
0

50

100

150

200

250

300

350

400

450

500

0.900
0.800
f(x) = 0.0017173195x + 0.0111929577
R = 0.9948512269

0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
0

50

100

150

200

250

300

350

400

450

500

500

10 ppm
100 ppb
10 ppb
Blank

0.0676

V
10
10
10
10
20
20
20
20
40
40
40
40
60
60
60
60
80
80
80
80
100
100
100
100

mHg
0.0996
0.0996
0.0996
0.0996
0.1991
0.1991
0.1991
0.1991
0.3983
0.3983
0.3983
0.3983
0.5974
0.5974
0.5974
0.5974
0.7965
0.7965
0.7965
0.7965
0.9957
0.9957
0.9957
0.9957

mcn
mHg
msau
C
0.1051 99.71537 10.3066
0.4001 3870.929 39.0983
1.0244 101.4208 10.1861
0.0623

0.0619 0.063933

Cao
Cao-blank RSD
0.1569
0.0930
5.2
0.1733
0.1094
0.1646
0.1007
0.1762
0.1123
0.2581
0.1942
4.5
0.2632
0.1993
0.2857
0.2218
0.2735
0.2096
0.4917
0.4278
3.4
0.5067
0.4428
0.4826
0.4187
0.4674
0.4035
0.6609
0.5970
3.7
0.6617
0.5978
0.6522
0.5883
0.7066
0.6427
0.9103
0.8464
2.3
0.8613
0.7974
0.8953
0.8314
0.8970
0.8331
1.0603
0.9964
1.7
1.1010
1.0371
1.0944
1.0305
1.0946
1.0307

44.57689 0.044577 0.099568 0.092967

44.57689 0.044577 0.099568 0.109367

9.675
99.01
9.957

0.0801
0.0899

nhy
0.93
1.10
1.01
1.13
0.98
1.00
1.11
1.05
1.07
1.11
1.05
1.01
1.00
1.00
0.98
1.08
1.06
1.00
1.04
1.05
1.00
1.04
1.03
1.04

44.57689
44.57689
89.15378
89.15378
89.15378
89.15378
178.3076
178.3076
178.3076
178.3076
222.8844
222.8844
222.8844
222.8844
267.4613
267.4613
267.4613
267.4613
356.6151
356.6151
356.6151
356.6151
445.7689
445.7689
445.7689
445.7689

0.044577
0.044577
0.089154
0.089154
0.089154
0.089154
0.178308
0.178308
0.178308
0.178308
0.222884
0.222884
0.222884
0.222884
0.267461
0.267461
0.267461
0.267461
0.356615
0.356615
0.356615
0.356615
0.445769
0.445769
0.445769
0.445769

0.099568
0.099568
0.199136
0.199136
0.199136
0.199136
0.398271
0.398271
0.398271
0.398271
0.597407
0.597407
0.597407
0.597407
0.796543
0.796543
0.796543
0.796543
0.995678
0.995678
0.995678
0.995678

0.100667
0.112267
0.194167
0.199267
0.221767
0.209567
0.427767
0.442767
0.418667
0.403467
0.596967
0.597767
0.588267
0.642667
0.846367
0.797367
0.831367
0.833067
0.996367
1.037067
1.030467
1.030667

0.0873
0.0757
0.1404
0.1353
0.1626
0.1379
0.3838
0.328
0.2703
0.3177
0.3823
0.3934
0.4451
0.4067
0.4734
0.4664
0.5076
0.5528
0.6701
0.6063
0.5603
0.6066
0.7642
0.747
0.7968
0.749

TB
0.1038

1.2
1.0
0.8

0.2062

f(x) = 1.0264133591x + 0.0036908447

R = 0.9973697785

0.6
0.4

0.4232

0.2
0.0
0.0

0.2

0.4

0.6

0.8

1.0

1.2

0.6064
1.2

0.8270

1.0
0.8

1.0236

f(x) = 1.0264133591x + 0.0036908447

R = 0.9995770205

0.6
0.4
0.2
0.0
0.0

0.2

0.4

0.6

0.8

ng chun Hg
1.2
1

f(x) = 1.0264133591x + 0.0036908447

1.0

1.2

ng chun Hg
1.2
1

f(x) = 1.0264133591x + 0.0036908447

R = 0.9973697785

0.8

Chiu cao (Vol)

f(x) = 1.7173194625x + 0.0111929577

R = 0.9799975473

0.6

100 mL/pht
Linear (100 mL/pht)
300 mL/pht
Linear (300 mL/pht)

0.4
0.2
0
0

0.2

0.4

0.6

0.8

Khi lng Hg (ng)

1.2

1.0

1.2

1.2

mL/pht

ar (100 mL/pht)

mL/pht

ar (300 mL/pht)

10 ppm
100 ppb
10 ppb
Blank

0.0459

V
10
10
10
10
20
20
20
20
40
40
40
40
60
60
60
60
80
80
80
80
100
100
100
100

mHg
0.0955
0.0955
0.0955
0.0955
0.1910
0.1910
0.1910
0.1910
0.3821
0.3821
0.3821
0.3821
0.5731
0.5731
0.5731
0.5731
0.7642
0.7642
0.7642
0.7642
0.9552
0.9552
0.9552
0.9552

mcn
mHg
msau
C
0.1051 99.71537 10.3066
0.4001 3870.929 39.0983
0.5141 50.8985
5.3283
0.0426

0.0329 0.040467

Cao
Cao-blank RSD
0.1433
0.1028
2.7
0.1441
0.1036
0.1358
0.0953
0.1404
0.0999
0.2340
0.1935
4.2
0.2372
0.1967
0.2381
0.1976
0.2563
0.2158
0.4657
0.4252
3.8
0.4519
0.4114
0.4303
0.3898
0.4322
0.3917
0.6912
0.6507
4.9
0.6707
0.6302
0.7197
0.6792
0.6412
0.6007
0.8688
0.8283
2.1
0.8960
0.8555
0.8557
0.8152
0.8894
0.8489
1.0410
1.0005
2.5
1.1045
1.0640
1.0801
1.0396
1.0906
1.0501

44.57689 0.044577 0.099568 0.092967

44.57689 0.044577 0.099568 0.109367

9.675
99.01
9.552

0.0801
0.0899

nhy
1.08
1.08
1.00
1.05
1.01
1.03
1.03
1.13
1.11
1.08
1.02
1.03
1.14
1.10
1.19
1.05
1.08
1.12
1.07
1.11
1.05
1.11
1.09
1.10

4.231909

44.57689
44.57689
89.15378
89.15378
89.15378
89.15378
178.3076
178.3076
178.3076
178.3076
222.8844
222.8844
222.8844
222.8844
267.4613
267.4613
267.4613
267.4613
356.6151
356.6151
356.6151
356.6151
445.7689
445.7689
445.7689
445.7689

0.044577
0.044577
0.089154
0.089154
0.089154
0.089154
0.178308
0.178308
0.178308
0.178308
0.222884
0.222884
0.222884
0.222884
0.267461
0.267461
0.267461
0.267461
0.356615
0.356615
0.356615
0.356615
0.445769
0.445769
0.445769
0.445769

0.099568
0.099568
0.199136
0.199136
0.199136
0.199136
0.398271
0.398271
0.398271
0.398271
0.597407
0.597407
0.597407
0.597407
0.796543
0.796543
0.796543
0.796543
0.995678
0.995678
0.995678
0.995678

0.100667
0.112267
0.194167
0.199267
0.221767
0.209567
0.427767
0.442767
0.418667
0.403467
0.596967
0.597767
0.588267
0.642667
0.846367
0.797367
0.831367
0.833067
0.996367
1.037067
1.030467
1.030667

0.0873
0.0757
0.1404
0.1353
0.1626
0.1379
0.3838
0.328
0.2703
0.3177
0.3823
0.3934
0.4451
0.4067
0.4734
0.4664
0.5076
0.5528
0.6701
0.6063
0.5603
0.6066
0.7642
0.747
0.7968
0.749

1.2

f(x)
f(x) =
= 1.1010189939x
1.0264133591x
R
=
R = 0.9965356002
0.9973697785

0.8

f(x) = 1.7173194625x + 0
R = 0.9799975473
0.6

0.4

0.2

0
0

0.2

0.4

TB
0.1004

1.2
1.0

f(x) = 1.1010189939x - 0.0064440639

R = 0.9965356002

0.8

0.2009

0.6
0.4

0.4046

0.2
0.0
0.0

0.2

0.4

0.6

0.8

1.0

1.2

0.6402
1.2

0.8370

1.0

f(x) = 1.1010189939x - 0.0064440639

R = 0.999406821

0.8

1.0386

0.6
0.4
0.2
0.0
0.0

0.2

0.4

0.6

0.8

1.0

1.2

f(x)
f(x) =
= 1.1010189939x
1.0264133591x -+0.0064440639
0.0036908447
R
=
0.9965356002
R = 0.9973697785

f(x) = 1.7173194625x + 0.0111929577

R = 0.9799975473

0.2

0.4

0.6

0.8

1.2

1.0

1.2

1.2

0.925

0.616667

8.166667

5.714286
11.375
2.5
7.333333
5.333333

125

mcn
mHg
msau
C
0.1051 99.71537 10.3066 9.674904
0.4001 3870.929 39.0983 99.00505
0.5139 50.8787
4.946 10.28684

10 ppm
100 ppb
10 ppb
0.0705

0.0766

0.0735 0.073533

0.5143
0.5143
0.5143

0.5919
0.6125
0.5707

0.5184
0.5390
0.4972

0.3
0.3
0.3
1
1

0.5881
0.6023
0.5898
0.6145
0.6125

0.5934

0.0471

0.5463

0.6135

0.0887

0.5248

QC
50
50
50

2
2
2
4
4
4
6

1.01 1.007436
1.05
0.97

0.8

0.6444 0.640267
0.6408
0.6356
0.6862
0.6798
0.6734

0.1101 0.530167

0.7392
0.686

0.1696

0.7126

0.7

f(x) = 0.0207077
R = 0.98882043

0.6

0.138

0.5418

0.5
0.4

0.543

0.3
0.2
0.1
0
0

0.0705
0.0766
0.0735
0.004665 0.005069 0.004864

0.8
0.7

f(x) = 0.0207077192x + 0.5928308002

R = 0.9888204327

0.6
0.5
0.4
0.3
0.2
0.1
0
0

10 ppm
100 ppb
10 ppb
0.0935
50
50
50

0.470
0.470
0.470
Blank
0.3
0.0586
0.3
0.0512
0.3
0.0457
1
0.0491
1
0.0444
1
0.046
2
0.0739
2
0.091
2
0.0838
4
0.083
4
0.0947
4
0.08
6
0.1022
6
0.1257
6
0.135
7
0.119
7
0.1258
7
0.102

0.3
0.3
0.3
1
1
1
2
2
2
4
4
4
6
6

0.0586
0.0512
0.0457
0.0491
0.0444
0.046
0.0739
0.091
0.0838
0.083
0.0947
0.08
0.1022
0.1257

mcn
mHg
msau
C
0.1051 99.71537 10.3066 9.674904
0.4001 3870.929 39.0983 99.00505
0.4937 48.87879
5.2011 9.39778
0.0796

0.0769 0.083333

0.6056 0.522267 1.111468

0.5982 0.514867 1.09572
0.6224 0.539067 1.147221
Hg
0.051833
0.5477 0.550067
12.48864
0.5413 1.84685
0.5612
0.0465
0.5415 0.549767
5.13884
0.56 1.710816
0.5478
0.0829
0.5612
0.5643
10.3564
0.5536 2.222352
0.5781
0.0859
0.5841
0.5677
9.042187
0.5546 2.646523
0.5644
0.120967
0.6051 0.598967
13.97454
0.5781 3.101276
0.6137
0.1156
0.5746 0.576167
10.60456
0.5638 2.294442
0.5901

0.0935
0.083621
1.118136

0.16

0.498233

0.14
0.12

0.503267

0.1
0.08

0.4814

0.06
0.04

0.4818

0.02
0
0

0.478

0.460567

0.5477 0.051833 0.006473 0.550067

0.5413
0.5612
0.5415
0.0465 0.00239 0.549767
0.56
0.5478
0.5612
0.0829 0.008585
0.5643
0.5536
0.5781
0.5841
0.0859 0.007767
0.5677
0.5546
0.5644
0.6051 0.120967 0.016905 0.598967
0.5781

0.010159

0.009405

0.012541

0.015024

0.018576

6
7
7
7

0.135
0.119
0.1258
0.102

0.6137
0.5746
0.5638
0.5901

0.1156 0.012259 0.576167

0.3 0.051833 0.006473 0.550067

1
0.0465 0.00239 0.549767
2
0.0829 0.008585
0.5643
4
0.0859 0.007767
0.5677
6 0.120967 0.016905 0.598967
7
0.1156 0.012259 0.576167

0.01322

0.010159
0.009405
0.012541
0.015024
0.018576
0.01322

Kho st nh hng ca H
0.7

0.6

0.5

0.4
Chiu cao (Vol)
0.3

0.2

0.1

0
0

4
C% HNO3

4
C% HNO3

0.0796
0.0769
0.07119 0.068775

0.16
0.14
0.12
0.1
0.08
0.06
0.04
0.02
0
0

0.51
0.5
0.49
0.48
0.47
0.46
0.45
0.44
0.43
0

h hng ca HNO3

Blank HNO3
500 pg Hg

4
C% HNO3

4
C% HNO3

10 ppm
100 ppb
10 ppb
blank

0.1207
50 0.477035
50 0.477035
50 0.477035

m
HCl

H2O2

HNO3

mcn
mHg
msau
C
0.1051 99.71537 10.3066 9.674904
0.4001 3870.929 39.0983 99.00505
0.516 51.08661
5.3546 9.540695
0.1313
0.6084
0.6478
0.6231

cao
1.0103
1.0169
0.986
4.9817
4.9334
4.9516
1.0636
1.036
1.0148
5.0582
5.0014
5.0474
0.9766
0.98
1.014
5.041
5.1144
5.0591

H2SO4

4.952
5.0301
5.182

0.1203
0.1241 nhy tb
0.4843 1.01523 1.053033
0.5237 1.097824
0.499 1.046045

cao-blank mHg ng
0.0424
0.0531
0.045
0.0785
0.09
0.0724
0.0598
0.0496
0.0461
0.1003
0.1014
0.0989
0.0409
0.039
0.0387
0.1039
0.1075
0.0961
0.0547
0.0496
0.05
0.0713
0.0744
0.0726

0.025
0.036
0.019
0.006
-0.004
-0.008
0.047
0.048
0.045
-0.013
-0.015
-0.015
0.050
0.054
0.042
0.001
-0.004
-0.004
0.018
0.021
0.019

0.024
0.035
0.018
0.006
-0.004
-0.007
0.044
0.045
0.043
-0.012
-0.014
-0.014
0.048
0.051
0.040
0.001
-0.004
-0.003
0.017
0.020
0.018

CHg ng/g CHg

0.005
0.007
0.004
0.005
-0.004
-0.007
0.009
0.009
0.009
-0.012
-0.014
-0.014
0.009
0.010
0.008
#DIV/0!
#DIV/0!
#DIV/0!
0.003
0.004
0.003

0.185
0.273
0.140
0.219
-0.149
-0.283
0.333
0.345
0.324
-0.497
-0.568
-0.561
0.371
0.392
0.312

0.1338340924
0.1549192863
0.1373227997

0.048

0.200 0.169182

0.333681 0.307966

0.35864 0.273938

0.142025 0.082602

0.0672

0.0458 0.053667

blank

blank 1

blank 2

m1

mcn
mHg
msau
C
10 ppm
0.1051 99.71537 10.3066 9.674904
100 ppb
0.4001 3870.929 39.0983 99.00505
10 ppb
0.5309 52.56178
5.3717 9.784944
0.052535 0.06214 0.065397
0.0629
0.0744
0.0783
0.0719
nhy tb
50 0.489247
0.6676
0.5957
1.22
1.197
50 0.489247
0.6898
0.6115
1.25
50 0.489247
0.6284
0.5501
1.12

m cn
cao
mHg
CHg
mHg vial
0.196
0.4593 0.383612 1.957203 75.77428 72.81189
0.208
0.4588 0.383194 1.84228 71.32496
0.2188
0.4827 0.403156 1.842576 71.33644
0.2346
0.4831 0.40349 1.719905 66.11315 62.54679
0.2755
0.5195 0.433891 1.574923 60.54005
0.2191
0.4162 0.347614 1.586555 60.98718
0.2149
0.6992 0.583979 2.717443 105.3466 104.2018 36.52247
0.2012
0.6456 0.539211 2.679977 103.8941
0.2131
0.6803 0.568193 2.666321 103.3647

378.4712

mcn
10 ppm
100 ppb
10 ppb
blank

0.1033
50
50
50

m mu
blank 1

blank 2

blank 3

m1

m2

m3

0.1067
0.1067
0.1067
0.0915
0.0915
0.0915
0.1069
0.1069
0.1069

mHg
msau
C
0.1051 99.71537
10.3066 9.6749044
0.4001 3870.9293
39.0983 99.005053
0.514109 50.899389
5.5152 9.2289289

0.0989
0.4614464461
0.4614464461
0.4614464461

m nh mc
38.3851
38.3851
38.3851
39.1489
39.1489
39.1489
38.2425
38.2425
38.2425
38.7394
38.7394
38.7394
38.4343
38.4343
38.4343
38.4205
38.4205
38.4205

0.1409
0.6088
0.6016
0.6428

m cn
0.199
0.2177
0.2204
0.2164
0.2238
0.235
0.21
0.2374
0.2155
0.2027
0.2152
0.2091
0.2048
0.2143
0.2058
0.4013
0.4006
0.3993

0.1144
0.4944
0.4872
0.5284

cao
0.5119
0.6171
0.6094
0.1908
0.1484
0.1221
0.1046
0.1529
0.2009
0.2034
0.2197
0.2267
0.2467
0.2127
0.2044
0.1761
0.1624
0.1526

1.07
1.06
1.15

mHg
0.4693
0.5657
0.5586
0.1749
0.1360
0.1119
0.0959
0.1402
0.1842
0.1865
0.2014
0.2078
0.2262
0.1950
0.1874
0.1614
0.1489
0.1399

nhy tb
1.091

CHg
2.358
2.599
2.535
0.808
0.608
0.476
0.457
0.590
0.855
0.920
0.936
0.994
1.104
0.910
0.910
0.402
0.372
0.350

 nhy tb

mHg vial
90.52
99.75
97.29
31.64
23.80
18.65
17.46
22.58
32.68
35.64
36.26
38.50
42.44
34.97
34.99
15.46
14.28
13.46

TB
95.85

RSD
4.99

24.70

26.50

24.24

31.95

36.80

4.10

37.47

11.49

14.40

6.97

mcn
10 ppm
100 ppb
10 ppb
blank

0.0864
50
50
50
10
10
m mu

blank 1

blank 2

blank 3

m1

m2

m3

0.1067
0.1067
0.1067
0.0915
0.0915
0.0915
0.1069
0.1069
0.1069

mHg
msau
C
0.1051 99.71537
10.3066 9.6749044
0.4001 3870.9293
39.0983 99.005053
0.5477 54.225068
5.7094 9.4975072

0.1065
0.4748753592
0.4748753592
0.4748753592
0.0949750718
0.0949750718
m nh mc
38.3851
38.3851
38.3851
39.1489
39.1489
39.1489
38.2425
38.2425
38.2425
38.7394
38.7394
38.7394
38.4343
38.4343
38.4343
38.4205
38.4205
38.4205

0.0743
0.542
0.5345
0.6428
0.1241
0.131
m cn
0.199
0.2177
0.2204
0.2164
0.2238
0.235
0.21
0.2374
0.2155
0.2027
0.2152
0.2091
0.2048
0.2143
0.2058
0.4013
0.4006
0.3993

0.0891
0.4529
0.4454
0.5537
0.0350
0.0419
cao
0.5119
0.6171
0.6094
0.1908
0.1484
0.1221
0.1046
0.1529
0.2009
0.2034
0.2197
0.2267
0.2467
0.2127
0.2044
0.1761
0.1624
0.1526

0.95
0.94
1.17
0.37
0.44
mHg
0.5022
0.6054
0.5979
0.1872
0.1456
0.1198
0.1026
0.1500
0.1971
0.1996
0.2155
0.2224
0.2420
0.2087
0.2005
0.1728
0.1593
0.1497

nhy tb
1.019

CHg
2.524
2.781
2.713
0.865
0.651
0.510
0.489
0.632
0.915
0.984
1.002
1.064
1.182
0.974
0.974
0.431
0.398
0.375

 nhy tb

mHg vial
96.87
106.75
104.13
33.86
25.47
19.96
18.69
24.16
34.98
38.14
38.80
41.21
45.42
37.43
37.45
16.54
15.28
14.41

TB
102.58

RSD
4.99

26.43

26.50

25.94

31.95

39.38

4.10

40.10

11.49

15.41

6.97

mcn
10 ppm
100 ppb
10 ppb
0.061207
blank
0.061
QC
50
QC
50
QC
50
K2Cr2O7
10
10
50
50
100
100

mHg
msau
C
0.1051 99.71537
10.3066 9.6749044
0.4001 3870.9293
39.0983 99.005053
0.4976 49.264914
5.7456 8.5743725
0.0572940397 0.0433468
0.0571
0.0432
0.0538
nhy tb
0.4287
0.4912
0.4374
1.02
0.997
0.4287
0.4701
0.4163
0.97
0.4287
0.4818
0.4280
1.00
0.0373
0.0344
0.0324
0.043
0.0333
0.0327

 nhy tb

mcn
10 ppm
100 ppb
10 ppb
blank
QC
QC
QC

0.0781
100
100
100

mHg
msau
C
0.1051 99.71537
10.3066 9.6749044
0.4001 3870.9293
39.0983 99.005053
0.4976 49.264914
10.8676 4.5331917
0.0672
0.4533
0.4533
0.4533

m cn

m Hg

m cn
0.8324
0.8324
0.8324
1.983
1.983
1.983
3.1967
3.1967
3.1967

m Hg

0.073
0.5579
0.5367

CHg vial

blank 1

blank 2

TC1

TC2

TC3

3.773
3.773
3.773
8.989
8.989
8.989
14.49
14.49
14.49

CHg vial
0.0978
0.0978
0.0978
0.2329
0.2329
0.2329
0.375
0.375
0.375

0.0728
0.4851
0.4639

1.07
1.02

m cn
1.963
1.9517
1.933
1.98
1.982
m cn
2.0135
2.0666

mHg

mHg
0.2343
0.2405

1.9088
1.9821
1.9895
1.951
1.9474
2.0053

0.4800
0.4985
0.5003
0.7687
0.7673
0.7901

nhy tb
1.047

Cao
0.0406
0.0395
0.030
0.0434
0.037
Cao

0.485
0.509
0.516
0.770
0.781
0.800

 nhy tb

mHg
C
Ctb
0.0388
0.0198
0.0186
0.0377
0.0193
0.0290
0.0150
0.0415
0.0209
0.0355
0.0179
nhy

1.01
1.02
1.03
1.00
1.02
1.01

mcn
10 ppm
100 ppb
10 ppb
blank
QC
QC
QC

mHg
0.1051
0.3167
0.5035

99.715370019
3.0640422336
51.4756314439

50
50
50
50
50
50
50
50
50

0.4448
0.4448
0.4448
0.4448
0.4448
0.4448
0.4448
0.4448
0.4448

1
1
1
3
3
3
10
10
10

1
3
10

0.070
0.210
0.700

0.0070
0.0210
0.0700

Kho st s mo
0.70
0.60
0.50
0.40
Tn hiu (Vol)

0.30
0.20
0.10
0.00
0

50

100

150

S mol Sn

0.10
0.00
0

50

100

150

S mol Sn
Blank Sn2+

Blank Sn2+ & 500

msau

C
10.3066
29.9704
5.786

9.674904432
102.2356135927
8.8965833813

0.5398
0.5584
0.5742
0.5525

0.5575

0.0172189818

0.58

0.0284368306

0.5719
0.6085
0.6359
0.6053
0.6475

0.6296

S mol Sn2+ (mol)

31
93
310

0.0218012232

Tn hiu Sn2+ (Vol)

SD ( n=3)
0.10
0.11
0.18

0.013
0.012
0.027

Kho st s mol Sn2+

50

100

150

200

S mol Sn2+ ( mol)

250

300

350

50

100

150

200

250

S mol Sn2+ ( mol)

Blank Sn2+

Blank Sn2+ & 500 pg Hg

500 pg Hg

300

350

0.4593

0.4639

0.4515

0.1090
0.1020
0.0835
0.1067
0.1069
0.1276
0.1600
0.2093
0.1648

Tn hiu Sn2+ & 500 pg Hg (Vol)

SD (n=3)
0.5575
0.017
0.5776
0.028
0.6296
0.022

300

350

0.0982 0.013175

0.1137333333 0.012009

0.1780

0.027184

Tn hiu 500 pg Hg (Vol)

0.46
0.46
0.45

SD (n=3)
0.022
0.031
0.035

300

350

0.000470076666666668
0.000952876666666668
0.001214256666666670

200
300
500
700
900

0.5
1.5
3
6
9
10.5

100
150
250
350
450

3.8
5.7
9.5
13.3
17.1

CM HNO3
0.07
0.22
0.44
0.88
1.32
1.54

0.76
1.14
1.9
2.66
3.42

Tn hiu Blank
0.0518
0.0465
0.0829
0.0859
0.1210
0.1156

SD (n=3)
0.0065
0.0024
0.0086
0.0078
0.017
0.012

nh hng ca n
0.7000
0.6000
0.5000
0.4000
Tn hiu (Vol)

0.3000
0.2000
0.1000
0.0000
0.00

0.20

0.40

0.60

0.

Nng
Blank HNO3

Blank HNO3 +

0.0000
0.00

0.20

0.40

0.60

0.

Nng
Blank HNO3

Blank HNO3 +

STT

Chiu cao (Vol)

STT
1
0.0835
2
0.1313
3
0.0989
4
0.0864
0.018 Mean
0.053 LOD
0.18 LOQ

SD
3SD
10SD

Tn hiu Blank + 500 pg Hg

0.5501
0.5498
0.5643
0.5677
0.5990
0.5762

SD (n=3)
0.010
0.0094
0.013
0.015
0.019
0.013

5
6
7
8

Tn hiu 500 pg Hg
0.4982
0.5033
0.4814
0.4818
0.4780
0.4606

nh hng ca nng HNO3

0.40

0.60

0.80

1.00

1.20

Nng HNO3 ( mol/L)

Blank HNO3

Blank HNO3 + 500 pg Hg

500 pg Hg

1.40

1.60

1.80

0.40

0.60

0.80

1.00

1.20

Nng HNO3 ( mol/L)

Blank HNO3

Blank HNO3 + 500 pg Hg

500 pg Hg

1.40

1.60

1.80

Chiu cao (Vol) STT

Chiu cao (Vol)
0.1020
9
0.1207
0.1203
10
0.1033
0.1409
11
0.1090
0.1065
0.1093
0.16
0.33
S/N= Mean/SD=6 ( LOD c chp nhn)

SD (n=3)
0.012
0.010
0.015
0.017
0.025
0.018
0.0001451067
9.4173333333E-005
0.00023098
0.00028606
0.0006308167
0.0003250433

1.80

0.012046
0.009704
0.015198
0.016913
0.025116
0.018029

1.80

50

50000

7000

175

12.06301 0.452363 0.150788

0.15
0.3
0.6
1
1.5

2.25
4.5
9
15
22.5

0.5625
1.125
2.25
3.75
5.625

Cho HCl vo vial 40, gn y, rt 33 mL cho vo bnh teflon c vch. Cho nc n vch 100 => dc 10
Pha HNO3 1%: cho 10.3 g HNO3 1% vo bnh teflon c vch ri nh mc ln 500 mL, th QC xong th

33.1675

CM HCl

V HCl 4M
0.1
0.5
0.3
1
0.5
2
0.8
3
1.3
5

1.5
3
6
9
15
34.5

c n vch 100 => dc 100 mL HCl 4M

500 mL, th QC xong th chuyn qua bnh teflon ko vch

mcn
mHg
msau
C
10 ppm
0.1051 99.71537 10.3066 9.674904
100 ppb
0.3167 3.064042 29.9704 102.2356
10 ppb
0.5456 55.77975
6.3529 8.780203
0.1227
0.1309
0.1165 0.123367
55 0.482911
0.4892 0.365833 0.757558
55 0.482911
0.5134 0.390033 0.807671

50
50
50

mcn

mHg

10 ppm
100 ppb
10 ppb

msau
C
0.1207
120.7 11.2264 10.75144
0.1144 1.229965 10.4854 117.3026
0.5243 61.50177
6.1891 9.937111

mHg
Cao
0.496856
0.496856
0.496856

cao-blank nhy
0.4858 0.362433 0.729454
0.4853 0.361933 0.728448
0.4832 0.359833 0.724221

mcn
mHg
msau
C
10 ppm
0.1207
120.7 11.2264 10.75144
100 ppb
0.1144 1.229965 10.4854 117.3026
10 ppb
0.5111 59.95338
5.6056 10.69527
0.534763
blank
Hg
0.133333
0.0376 0.040733 0.009018
0.5983 0.573167 0.024664
0.133333
0.0337
0.549
0.133333
0.0509
0.5722
0.266667
0.058 0.063567 0.005928
0.5509 0.566567 0.01753
0.266667
0.0698
0.5855
0.266667
0.0629
0.5633
0.533333
0.0835 0.082767 0.007826
0.6262 0.630433 0.01023
0.533333
0.0746
0.6421
0.533333
0.0902
0.623
0.8
0.1284 0.122567 0.006117
0.6331
0.6324 0.01876
0.8
0.1162
0.6133
0.8
0.1231
0.6508
1.333333
0.1338 0.131767 0.006205
0.52
0.5128 0.00908
1.333333
0.1367
0.5158
1.333333
0.1248
0.5026

CM HCl
Tn hiu bl SD
0.13 0.04073
0.27 0.06357
0.53 0.08277
0.80 0.12257
1.33 0.13177

(n=3) Tn hiu bl SD (n=3) Tn hiu 5 SD (n=3)

0.0090
0.5732
0.025
0.5324
0.026
0.0059
0.5666
0.018
0.5030
0.019
0.0078
0.6304
0.010
0.5477
0.013
0.0061
0.6324
0.019
0.5098
0.020
0.0062
0.5295
0.009
0.3978
0.011

nh hng ca nng
0.7000
0.6000
0.5000
0.4000
Tn hiu (Vol)

0.3000
0.2000
0.1000

0.4000
Tn hiu (Vol)

0.3000
0.2000
0.1000
0.0000
0.00

0.20

0.40

0.60

Nng HCl (mo

Blank HCl

Blank HCl + 550 pg Hg

0.532433

0.503

0.547667

0.509833

0.381033

0.00069
0.000342
0.000166
0.000389
0.000121

ng ca nng HCl

0.40

0.60

0.80

Nng HCl (mol/L)

Blank HCl + 550 pg Hg

550 pg Hg

1.00

1.20

1.40

QC

mcn
mHg
msau
C
10 ppm
0.1207
120.7 11.2264 10.75144
100 ppb
0.1144 1.229965 10.4854 117.3026
10 ppb
0.4622 54.21728
6.2853 8.626045
0.1193
0.0707
0.0574 0.082467
50 0.431302
0.4 0.317533 0.73622
50 0.431302
0.4034 0.320933 0.744103
50 0.431302

m cn
blank 1

m vial
38.252

blank 2

38.3473

blank 5

blank 6

c 1

0.103

38.0978

c 2

0.0971

38.1684

m cn
mHg
1.0795
1.1047

0.740162

Cao
mHg
0.3694
0.4991
0.3745
0.5060

1.4866
0.9992
1.1875
1.877
1.2244

0.0629
0.0788
0.0493
0.391
0.2691

0.0850
0.1065
0.0666
0.5283
0.3636

0.9762
1.5279
1.6061
1.3723
1.1585

0.0525
0.0711
0.0797
0.5177
0.4627

0.07093
0.0961
0.1077
0.6994
0.6251

1.3602

mHg vial Ctb

0.4623 17.68487
0.4580 17.52004
0.0572
0.1065
0.0561
0.2814
0.2969
0.07266
0.0629
0.0670
0.5097
0.5396

mcn
mHg
msau
C
10 ppm
0.1071
107.1 10.9337 9.795403
100 ppb
0.1279 1.252832 11.8142 106.0446
10 ppb
0.5378 57.03078
6.403 8.906885
0.0386
0.0378
0.0373
0.0379
50 0.445344
0.3987
0.3608 0.81016
50 0.445344
0.3772
0.3393 0.761883
50 0.445344

blank
V

mcn
mHg
msau
C
10 ppm
0.1104
110.4 10.8169 10.20625
100 ppb
0.1154 1.177801 10.8743 108.3105
10 ppb
1.009 109.2853 11.2163 9.74344
0.0451
0.0568
0.053 0.051633
mHg
Cao
Cao - blank
10 0.097434
0.1384 0.086767
10 0.097434
0.134 0.082367
10 0.097434
0.1311 0.079467
10 0.097434
0.1274 0.075767
30 0.292303
0.2891 0.237467
30 0.292303
0.2741 0.222467
30 0.292303
0.2826 0.230967
30 0.292303
0.3112 0.259567
50 0.487172
0.4805 0.428867
50 0.487172
0.4784 0.426767
50 0.487172
0.5103 0.458667
50 0.487172
0.5212 0.469567
60 0.584606
0.5818 0.530167
60 0.584606
0.5798 0.528167
60 0.584606
0.6157 0.564067
60 0.584606
0.6283 0.576667
70 0.682041
0.6768 0.625167
70 0.682041
0.7092 0.657567
70 0.682041
0.7257 0.674067
70 0.682041
0.7226 0.670967
100 0.974344
1.0018 0.950167
100 0.974344
0.9852 0.933567
100 0.974344
0.9915 0.939867
100 0.974344
0.992 0.940367

1.2

0.8

0.6
Tn hiu (Vol)

Nhy
0.081092

0.237617

0.445967

0.549767

0.656942

0.940992

RSD
0.89
0.85
0.82
0.78
0.81
0.76
0.79
0.89
0.88
0.88
0.94
0.96
0.91
0.90
0.96
0.99
0.92
0.96
0.99
0.98
0.98
0.96
0.96
0.97

3.5

5.5

4.3

4.0

3.2

0.7

ng chun Hg
f(x) = 1.0264133591x + 0.0036908447
R = 0.9995770205
f(x) = 0.9982218859x - 0.0333302928
R = 0.9981390023

f(x) = 1.0264133591x + 0.0036908447

R = 0.9995770205
f(x) = 0.9982218859x - 0.0333302928
R = 0.9981390023

0.8

0.6
Tn hiu (Vol)

0.4

0.2

0
0

0.2

0.4
NaBH4

0.6

0.8

mHg (ng)
Linear (NaBH4)
SnCl2

Linear (SnCl2)

6.0

5.0

0.097434
0.292303
0.487172
0.584606
0.682041
0.974344

3.5
5.5
4.3
4.0
3.2
0.7

0.099568
0.199136
0.398271
0.597407
0.796543
0.995678

5.2
4.5
3.4
3.7
2.3
1.7

4.0

RSD (%)

3.0

2.0

1.0

0.0
0

0.2

0.4

m
NaBH4

mHg
Cao
Cao-blank
0.099568
0.1569 0.092967
0.099568
0.1733 0.109367
0.099568
0.1646 0.100667
0.099568
0.1762 0.112267
0.199136
0.2581 0.194167
0.199136
0.2632 0.199267
0.199136
0.2857 0.221767
0.199136
0.2735 0.209567
0.398271
0.4917 0.427767
0.398271
0.5067 0.442767
0.398271
0.4826 0.418667
0.398271
0.4674 0.403467
0.597407
0.6609 0.596967
0.597407
0.6617 0.597767
0.597407
0.6522 0.588267
0.597407
0.7066 0.642667
0.796543
0.9103 0.846367
0.796543
0.8613 0.797367
0.796543
0.8953 0.831367
0.796543
0.897 0.833067
0.995678
1.0603 0.996367
0.995678
1.101 1.037067
0.995678
1.0944 1.030467
0.995678
1.0946 1.030667

RSD
0.103817

5.2

0.206192

4.5

0.423167

3.4

0.606417

3.7

0.827042

2.3

1.023642

1.7

2.156863

0.8

1.2

Linear (SnCl2)

0.2

0.4

0.6
mHg (ng)

NaBH4

SnCl2

0.8

1.2

blank
0.5

1.5

10.5

0.0363
0.0329
0.0332
0.0574
0.0565
0.0519
0.0833
0.0764
0.0761
0.1139
0.1194
0.1112
0.1684
0.1572
0.16
0.1804
0.1747
0.177

mcn
mHg
msau
C
10 ppm
0.1104
110.4 10.8169 10.20625
100 ppb
0.1154 1.177801 10.8743 108.3105
10 ppb
0.5312 57.53456
7.0374 8.175543
0.0451
0.0568
0.053 0.051633
0.034133 0.001882

0.055267

0.00295

0.0786 0.004073

0.114833 0.004179

0.161867 0.005829

0.177367 0.002868

0.5809
0.5604
0.5596
0.5843
0.6052
0.5826
0.6212
0.6228
0.6023
0.6512
0.6732
0.6736
0.7369
0.7437
0.7351
0.7356
0.7343
0.7331

0.566967 0.012073

0.5907 0.012586

0.615433 0.011402

0.666 0.012819

0.738567 0.004536

0.734333

0.00125

CM HNOTn
hiu BlankSD
Tn
(n=3)
hiu Blank + 500SD
pg(n=3)
Hg
Tn hiu 500 pg SD
Hg (n=3)
3
0.07
0.0341
0.0019
0.5670
0.012
0.5328
0.012
0.2
0.0553
0.0030
0.5907
0.013
0.5354
0.013
0.4
0.0786
0.0041
0.6154
0.011
0.5368
0.012
0.8
0.1148
0.0042
0.6660
0.013
0.5512
0.013
1.3
0.1619
0.0058
0.7386
0.005
0.5767
0.007
1.5
0.1774
0.0029
0.7343
0.001
0.5570
0.003

0.034133 0.001882 0.566967 0.012073

0.055267 0.00295
0.5907 0.012586
0.0786 0.004073 0.615433 0.011402
0.114833 0.004179
0.666 0.012819

0.161867 0.005829 0.738567 0.004536

0.177367 0.002868 0.734333 0.00125

nh hng ca HNO3 vi ch
0.8000
0.7000
0.6000
0.5000

Tn hiu (Vol)

0.4000
0.3000
0.2000
0.1000
0.0000
0

0.2

0.4

0.6

0.8

Nng HNO3
Blank HNO3

Blank HNO3 + 500 pg H

0.0001493067
0.0001671133
0.0001465933
0.0001817833
0.0000545467
0.0000097867

a HNO3 vi cht kh NaBH4

0.4

0.6

0.8

Nng HNO3 (mol/L)

Blank HNO3 + 500 pg Hg

500 pg Hg

1.2

1.4

1.6

10 ppm
100 ppb
10 ppb
0.5

0.0865
0.0659
0.0665
0.0754
0.0652
0.0678
0.0746
0.0768
0.0761
0.1035
0.0953
0.0935
0.2147
0.2181
0.2122

0.13
0.27
0.53
0.80
1.33

mcn
mHg
msau
C
0.1104
110.4 10.8169 10.20625
0.1154 1.177801 10.8743 108.3105
0.5109 55.33586
6.0629 9.126962
0.072967 0.011724

0.069467

0.0053

0.075833 0.001124

0.097433

0.00533

0.215 0.002961

0.0730
0.0695
0.0758
0.0974
0.2150

0.012
0.005
0.001
0.005
0.003

0.5886
0.5766 0.014216 0.503633
0.5803
0.5609
0.6186 0.599767 0.022058
0.5303
0.6052
0.5755
0.6015
0.612 0.009995 0.536167
0.6214
0.6131
0.6343
0.6264 0.007202 0.528967
0.6247
0.6202
0.8407 0.890633 0.060562 0.675633
0.8732
0.958

0.5766
0.5998
0.6120
0.6264
0.8906

0.014
0.022
0.010
0.007
0.061

0.5036
0.5303
0.5362
0.5290
0.6756

0.018
0.023
0.010
0.009
0.061

0.8000
0.7000
0.6000

0.8000
0.7000
0.6000
0.5000
Tn hiu (Vol)

0.4000
0.3000
0.2000
0.1000
0.0000
0.00

0.658
0.1162

0.00034
0.000515
0.000101
8.03E-005
0.003677

0.5418

NaBH4
SnCl2
CM HCl Tn hiu HgSD (n=3) Tn hiu HgSD (n=3)
0.13
0.026
0.5036
0.018 0.5324
0.27
0.019
0.5303
0.023 0.503
0.53
0.013
0.5362
0.010 0.5477
0.8
0.02
0.5290
0.009 0.5098
1.33
0.011
0.6756
0.061 0.3978
Tn hiu blank HCl(Vol)
Tn
SD hiu
(n=3)blank HCl + 550
SD (n=3)
pg Hg
0.04073
0.009
0.5732
0.025
0.06357
0.0059
0.5666
0.018
0.08277
0.0078
0.6304
0.01
0.12257
0.0061
0.6324
0.019
0.13177
0.0062
0.5295
0.009

nh hng ca acid HCl

0.8000
0.7000
0.6000

nh hng ca acid HCl

0.8000
0.7000
0.6000
0.5000
(Vol)

0.4000
0.3000
0.2000
0.1000
0.0000
0.00

0.20

0.40

0.60

0.80

Nng HCl (mol/L)

NaBH4

SnCl2

1.00

1.20

SD (n=3)

1.00

1.20

1.40

mcn
mHg
msau
C
10 ppm
0.1104
110.4 10.8169 10.20625133
100 ppb
0.1154 1.177801403 10.8743 108.310549
10 ppb
0.5086 55.08674524
5.7902 9.51378972
0.0478
0.0398
0.0376 0.041733
50 0.475689
0.4987 0.96064067 0.975917
50 0.475689
0.5112 0.986918316
50 0.475689
0.508 0.980191239
Thi gian
Blank
1.3 umol 5s
0.0321
0.041
0.035
2.6 umol 10s
0.0328
0.033
0.036
3.9 umol 15s
0.0408
0.03
0.032

1s 10^-5 g

2.6434E-007

5 1.3217E-006
10 2.6434E-006
15 3.9651E-006

mol NaBH4

pH 1
pH 7

H
SD
H
SD

1.3 mol
39
1
24
1

pH 1
pH 7

H
SD
H
SD

62
4
73
5

MeHg

274.4988 13.77053

0.2351

TB
0.036033

0.033933

0.034267

mHg
Tin hieu TB
TB-blank mHg
50 0.55007
0.2434 0.243833 0.207367 0.211599
50 0.55007
0.2363
0.200267 0.204354
50 0.55007
0.2518
0.215767 0.22017
0.55007
0.209 0.196567 0.172967 0.176497
0.55007
0.2088
0.172767 0.176293
0.55007
0.1719
0.135867 0.138639
0.55007
0.1974 0.202367 0.161367 0.16466
0.55007
0.2015
0.165467 0.168844
0.55007
0.2082
0.172167 0.17568

4 ppb

M MeHgCl
M Hg

4000 pg/mL
319.5635

251.08
200.59

44

Hiu sut thu hi MeHgCl ch

100
90
80
70

2.6 mol 3.9 mol

30
31
4
1
37
38
2
2

60
Hiu sut thu hi MeHgCl (%)

50
40
30
20
10
0

Hiu sut thu hi MeHgCl (%)

50
40
30
20
10
0
1.3 mol

2.6 m

S mol NaB
pH=1

pH=7

pH=1 + T=750 C

pH=7 + T=7

38.4676 38.54798 1.43935

37.15051
40.02584
32.08622 29.77977 3.962799
32.04912
25.20398
29.93436 30.8557 1.011358
30.69493
31.93782

22000 ppb
220 ppb

hi MeHgCl chun

3 mol

2.6 mol
S mol NaBH4

T=750 C

pH=7 + T=750 C

3.9 mol

mcn
mHg
msau
C
10 ppm
0.1104
110.4 10.8169 10.20625
100 ppb
0.1154 1.177801 10.8743 108.3105
10 ppb
0.4962 53.74369
4.8597 11.05906
0.0596
0.0486
0.0446 0.050933
0.552953
0.552953
0.552953

MeHg

0.5873 0.536367 0.970004

0.6 0.549067 0.992972

0.57485
0.57485
0.57485

M MeHgCl
M Hg

251.08
200.59

274.4988 14.39088

0.1828

5s

15s

30s

blank H2O
Hg
0.1 0.105767
0.2429 0.139932 24.34234 23.5258 1.278432
0.0961
0.23 0.126769 22.05248
0.1212
0.242 0.139014 24.18259
0.1377 0.105767
0.3216 0.220238 38.31227 36.60819 1.557227
0.14
0.3044 0.202687 35.25912
0.134
0.31 0.208401 36.25317
0.142 0.105767
0.31 0.208401 36.25317 38.02826 1.775086
0.121
0.32 0.218605 38.02826
0.13
0.33 0.22881 39.80334

0.5441 0.447279 77.80793 72.93828

0.5192 0.421871 73.38797
0.4867 0.388707 67.61894

5.10936

mcn
mHg
msau
C
10 ppm
0.1104
110.4 10.8169 10.20625
100 ppb
0.1154 1.177801 10.8743 108.3105
10 ppb
0.648 70.18524
7.4194 9.459692
0.038
0.0298
0.028 0.031933
0.472985
0.3543 0.322367 0.681559
0.472985
0.3059 0.273967 0.57923
0.472985
0.2887 0.256767 0.542865
0.601218

10 ppm
100 ppb
10 ppb
0.407636

mcn
mHg
msau
C
0.1104
110.4 10.8169 10.20625
0.1298 1.324771 11.7012 113.2167
0.7088 80.24801
9.8431 8.152717

0.3093 0.680428

MeHg

0.538286
0.538286
0.538286
0.0974 0.538286
0.0788 0.538286
0.538286

274.4988 13.47553 M MeHgCl

M Hg

251.08
200.59

0.2392 0.344745 64.0449 62.07762 3.623626

0.24 0.346075 64.2921
0.2193 0.311645 57.89585
0.3374
0.3495
0.3091

pH=1
pH=7
62.07762 72.93828
3.623626 5.10936

0
0
0

NaBH4

CM HNOTn
hiu BlankSD
Tn
(n=3)
hiu Blank + 500 pg Hg
3

0.07
0.2
0.4
0.8
1.3
1.5

0.0341

0.0019

0.567

0.0553

0.003

0.5907

0.0786

0.0041

0.6154

0.1148

0.0042

0.666

0.1619

0.0058

0.7386

0.1774

0.0029

0.7343

NaBH4
CM HNO
Tn
SD (n=3)
Tn hiu Hg (Vol)
3 hiu Hg (Vol)
0.07
0.5328
0.012
0.4982
0.2
0.5354
0.013
0.5033
0.4
0.5368
0.012
0.4814
0.8
0.5512
0.013
0.4818
1.3
0.5767
0.007
0.478
1.5
0.557
0.003
0.4606

Tn hiu BlankSD
Tn
(n=3)
hiu Blank + 500 pg Hg
0.0518
0.0065
0.5501
0.0465
0.0024
0.5498
0.0829
0.0086
0.5643
0.0859
0.0078
0.5677

SnCl2

0.121
0.1156

0.017
0.012

0.599
0.5762

NaBH4
CM HNO
Tn
SD (n=3)
3 hiu Hg (Vol)
0.07
0.5328
0.012
0.2
0.5354
0.013
0.4
0.5368
0.012
0.8
0.5512
0.013
1.3
0.5767
0.007
1.5
0.557
0.003

SD (n=3)
0.012
0.013
0.011
0.013
0.005
0.001
SnCl2
SD (n=3)
0.012
0.01
0.015
0.017
0.025
0.018

SD (n=3)
0.01
0.0094
0.013
0.015

0.019
0.013

SnCl2
Tn hiu Hg (Vol)
0.4982
0.5033
0.4814
0.4818
0.478
0.4606

SD (n=3)
0.012
0.01
0.015
0.017
0.025
0.018

CV - AFS (2015)
0.0063
0.0039

So snh LOD ca cc h CV ca phng th nghim

0.035
0.03
0.025
0.02
LOQD( ng/mL)

0.015

0.025
0.02
LOQD( ng/mL)

0.015
0.009

0.01
0.0063
0.005

0.0039

0
CV - AFS (2015)

CV- Amalgam -AAS (1999)

H phn tch Hg
SnCl2

NaBH4

CV

nh hng ca acid HNO3

0.7
0.6
0.5
0.4
Tn hiu (Vol)

0.3
0.2
0.1
0
0

0.2

0.4

0.6

0.8

Nng HNO3 (mol/L)

NaBH4

SnCl2

0.0451

0.0568

0.053

0.038

0.0298

0.028

0.0596

0.0486

0.0446

0.0478

0.0398

0.0376

1.2

STT
1
2
3
4
SD
3SD
10SD

Chiu cao (Vol) STT Chiu cao (Vol)

0.0451
5
0.0568
0.038
6
0.0298
0.0596
7
0.0486
8
0.0478
0.0398
0.010 Mean
0.0432455
0.030 LOD
0.1085717
0.100 LOQ
0.1793486

CV- Amalgam -AAS (19CV- Amalgam -AAS (2010)

0.009
0.0312

ng th nghim B26 qua cc nm

0.0312

0.009

Amalgam -AAS (1999)

phn tch Hg

BH4

CV- Amalgam -AAS (2010)

HNO3

mol/L)

1.2

1.4

1.6

STT Chiu cao (Vol)

9
0.028
10
0.0446
11
0.0376

S/N= Mean/SD=4 ( LOD c chp nhn)

mcn
mHg
msau
C
10 ppm
0.1104
110.4 10.8169 10.20625
100 ppb
0.1298 1.324771 11.7012 113.2167
10 ppb
0.5157 58.38586
6.2498 9.342037
0.03
0.0512
0.0537 0.044967
0.467102
0.4244 0.812314 0.738811
0.467102
0.3787 0.714477
0.467102
0.3671 0.689643
m vial
m cn o m Hg
C vial
Ctb
m Hg tng
1 38.1072
2.1966
0.1230
0.0961
0.1054
3.663
38.1072
2.1075
0.1440
0.1137
4.332
38.1072
2.4096
0.1562
0.1063
4.050
2 38.7031
2.51
0.1277
0.0867
0.1267
3.354
38.7031
2.045
0.2509
0.1879
7.273
38.7031
2.3786
0.1525
0.1056
4.085
3 38.7037
2.3891
0.1651
0.1122
0.0996
4.344
38.7037
2.7432
0.1283
0.0796
3.080
38.7037
2.0961
0.1326
0.1069
4.139
4 38.4037
2.1442
0.1629
0.1237
0.1284
4.749
38.4037
2.7553
0.2017
0.1153
4.428
38.4037
2.0977
0.1938
0.1463
5.620
5 38.6013
2.1393
0.1154
0.0939
0.0875
3.624
38.6013
2.8531
0.1262
0.0755
2.915
38.6013
2.3873
0.1310
0.0930
3.589
6 38.7117
2.1018
0.1511
0.1186
0.1165
4.590
38.7117
1.9351
0.1558
0.1321
5.112
38.7117
2.5054
0.1501
0.0989
3.829
7 38.6524
2.085
0.2747
0.1998
0.1953
7.721
38.6524
2.428
0.3461
0.2113
8.169
38.6524
2.788
0.3269
0.1747
6.754

mcn
mHg
msau
C
10 ppm
0.1104
110.4 10.8169 10.20625
100 ppb
0.1298 1.324771 11.7012 113.2167
10 ppb
0.4944 55.97434
5.6044 9.987571
0.1433
0.1353
0.1294
0.136
0.499379
0.5531 0.835238 0.834771
0.499379
0.5655 0.860069
0.499379
0.54 0.809006
m vial
m cn o cao
C vial
Ctb
m Hg tng
1
1.891
0.0418
0.0474
0.0609
1.8602
0.0761
0.0703
2.1643
0.0846
0.0651
2
0.2437
0.000
0.2509
0.5522
3
1.7442
0.1707
0.1399
0.1594
1.7315
0.1981
0.1599
1.8066
0.2359
0.1783
4
2.0005
0.0478
0.0484
0.0483
2.1455
0.0608
0.0524
2.2486
0.0497
0.0441
5
1.8148
0.0574
0.0597
0.0591
1.8808
0.0649
0.0624
1.9758
0.0583
0.0554
6
2.0417
0.0738
0.0627
0.0633
2.1066
0.0794
0.0639
7

2.1443
2.0985

0.1459
0.1221

0.0999
0.0885

0.0942

MeHg

274.4988
31.86931

M MeHgCl
M Hg

251.08
200.59

mcn
mHg
msau
C
10 ppm
0.1104
110.4 10.8169 10.20625
100 ppb
0.1298 1.324771 11.7012 113.2167
10 ppb
0.4938 55.90641
5.1857 10.78088
0.0715
0.0949
0.0747 0.080367
0.539044
0.5249 0.82467 0.802965
0.539044
0.5079 0.793132
0.539044
0.5068 0.791092
m vial
m cn o cao
C vial
Ctb
m Hg tng
1 38.4063
0.0686
38.4063
0.1097
38.4063
0.0832
2 38.7778
0.1092
#DIV/0!
#DIV/0!
38.7778
0.1062
38.7778
3 38.2488
0.1227
38.2488
0.1200
38.2488
4 38.3162
0.1932
38.3162
0.1777
38.3162
5 38.1105
0.2213
38.1105
38.1105
6 38.6675
2.2821
1.0016
0.5466 21.1353
38.6675
38.6675
7 38.3934
38.3934
38.3934

MeHg

327.104
24.56467

M MeHgCl
M Hg

251.08
200.59

mcn
mHg
10 ppm
0.1197
100 ppb
0.1191
10 ppb
0.5117
0.0344
0.0422
0.422196
0.397 0.358733
0.422196
0.4026 0.364333
0.422196
0.4006 0.362333
m vial
m
38.7535
38.7535
38.7535
2 39.1331
39.1331
39.1331
3 38.1319
38.1319
38.1319
4 38.5674
38.5674
38.5674
5 38.4185
38.4185
38.4185
6 38.6811
38.6811
38.6811
7 39.0626
39.0626
1

msau
C
119.7 11.2762 10.61528
1.2642796332 12.0377 105.0267
53.7421507691
6.3646 8.443916
0.0382 0.038267
0.849684704 0.856948
0.8629486912
0.8582115529

cn o cao
1.828
2.507
2.2183
2.077
1.8885
2.0371
2.6826
2.6327
2.7638
2.586
2.6334
1.9314
2.1103
3.2533
1.9613
2.374
2.2084
2.6637
2.1502
2.467

0.0496
0.1139
0.0536
0.4708
0.3949
0.4537
1.0354
1.0434
1.2281
1.2321
1.2482
1.0692
0.41
0.6245
0.4119
0.0806
0.0456
0.0986
0.1531
0.1551

C vial
m Hg tng
0.0527
2.04
0.0684
2.65
0.0456
1.77
0.2831
11.08
0.2644
10.35
0.2788
10.91
0.4648
17.72
0.4771
18.19
0.5325
20.30
0.5709
22.02
0.5677
21.90
0.6659
25.68
0.2450
9.41
0.2358
9.06
0.2647
10.17
0.0558
2.16
0.0415
1.61
0.0577
2.23
0.1010
3.95
0.0890
3.48

0.052729 0.055554
0.068377
0.045556
0.05584 0.051675
0.041533
0.057652
Blank (ng/mL)
0.09424

TB

0.09231

0.1054
0.1267
0.0996
0.1284
0.0875
0.1165
0.1953
0.05555
0.05167
0.06091
0.04827
0.05913
0.06329

SD

0.040946

MeHg

327.104
24.56467

mHg tng tb

m Hg l thuyt

Hiu sut

2.153

10.778

25

32

18.740

30

54

23.199

31

66

9.547

27

25

1.999

3.710
blank tb
2.621

LOD

0.22

S/N

M MeHgCl
M Hg

251.08
200.59

mcn
mHg
msau
C
10 ppm
0.1197
119.7 11.2762 10.61528
100 ppb
0.1422 1.509493 12.8672 117.3132
10 ppb
0.4961 58.19908
7.3282 7.941798
0.0319
0.032
0.033
0.0323
0.39709
0.3005
0.2682 0.675414 0.708656
0.39709
0.3024
0.2701 0.680199
0.39709
0.3382
0.3059 0.770355
0.5

0.0413
0.0412
0.027
0.0356
0.0339

0.0545
0.052

0.0601
0.0623

3.5

0.0666
0.0661

0.467
0.4511
0.4635
0.4458
0.4499
0.4426
0.4575
0.4624
0.4609
0.457
0.4486
0.4524
0.439
0.4665
0.4345

mcn
mHg
msau
C
10 ppm
0.1197
119.7 11.2762 10.61528
100 ppb
0.1168 1.239864 10.8904 113.8493
10 ppb
0.5113 58.21115
6.4023 9.092225
0.0404
0.0414
0.0407 0.040833
0.454611
0.4976 0.456767 1.004741 1.009801
0.454611
0.5022 0.461367 1.01486
0.454611
m vial
m
38.352
38.352
38.352
2 38.4924
38.4924
38.4924
3 39.3359
39.3359
39.3359
4 38.0591
38.0591
38.0591
5 38.4261
38.4261
38.4261
6 39.1693
39.1693
39.1693
7 38.1441
38.1441
38.1441
8 38.1441
38.1441
38.1441
1

cn o cao
C vial
m Hg tng
2.0795
0.0395
0.0188
0.72
2.16
0.1197
0.0549
2.10
2.1911
0.0687
0.0310
1.19
2.0905
0.2319
0.1099
4.23
1.752
0.1963
0.1110
4.27
2.6686
0.2444
0.0907
3.49
1.9485
0.0661
0.0336
1.32
2.2292
0.067
0.0298
1.17
2.1916
0.1013
0.0458
1.80
2.46
0.2561
0.1031
3.92
2.4953
0.3117
0.1237
4.71
2.1266
0.2262
0.1053
4.01
1.8463
0.2281
0.1223
4.70
2.683
0.3143
0.1160
4.46

RSD
53

11

23

10

1.812
1.5579

0.308
0.3169

0.1683
0.2014

6.59
7.89

13

2.3448
2.0556
2.6889
2.6416
1.7672

0.3112
0.5858
0.4217
0.425
0.2285

0.1314
0.2822
0.1553
0.1593
0.1280

5.01

12

5.92
6.08
4.88

15

0.0404
0.040007902

mHg TB

0.4545
0.0414
###

0.0407
###

m Hg l t Hiu sut

4.21

23

18

4.58

22

21

7.24

23

31

5.47

22

25

5.48

23

24

2.0415
2.6618
1.6082
2.8263
0.2977
0.1004
0.6246
0.015
17.54687 -39.80415 98.79625 -62.21863

0.9573
0.1025
0.147015

mcn
mHg
msau
C
10 ppm
0.1197
119.7 11.2762 10.61528
100 ppb
0.1243 1.319479 10.5319 125.284
10 ppb
0.55 68.90623
5.7996 11.8812
0.0704
0.0641
0.06725
0.59406
0.7665 0.69925 1.177069 1.155859
0.59406
0.7413 0.67405 1.134649
0.59406
m vial

m cn o cao

10
10
10
20
20
20
40
40
40
65
65
65
80
80
80

cuong toan
0.118812
0.237624
0.475248
0.772278
0.950496

0.118812
0.118812
0.118812
0.237624
0.237624
0.237624
0.475248
0.475248
0.475248
0.772278
0.772278
0.772278
0.950496
0.950496
0.950496

0.14
0.26
0.51
0.84
1.04

0.098
0.1058
0.0849
0.2311
0.2211
0.2571
0.3482
0.3691
0.3493
0.6055
0.6078
0.593
0.9424
0.9362
0.9227
1.1442
1.1528
1.1167

C vial

m Hg tng

RSD

0.0962
0.1349
0.1249
0.1609
0.2520
0.2729
0.2531
0.5093
0.5116
0.4968
0.8462
0.8400
0.8265
1.0480
1.0566
1.0205

0.14

13

0.26

0.51

0.84

1.04

HNO3 0.5%
0.097434 0.081092
0.292303 0.237617
0.487172 0.445967
0.584606 0.549767
0.682041 0.656942

mHg TB

0.974344 0.940992

ng chun Hg trong hai

1.20
1.00

f(x) = 1.0849577292x + 0.0026173851

R=
=0.9982218859x
0.9994825249 - 0.0333302928
f(x)
R = 0.9981390023

0.80

Tn hiu Hg (Vol)

0.60
0.40
0.20
0.00
0

0.2

0.4

0.6
ng Hg

Nc cng toan pha long

Linear (Nc cng toan pha long)

0.4545

m Hg l t Hiu sut

0.097434
0.097434
0.097434
0.097434
0.292303
0.292303
0.292303
0.292303
0.487172
0.487172
0.487172
0.487172
0.584606
0.584606
0.584606
0.584606
0.682041
0.682041
0.682041
0.682041
0.974344
0.974344
0.974344
0.974344

0.081092

0.237617
2.0415
2.6618
1.6082
2.8263
0.9573
0.2977
0.1004
0.6246
0.015
0.1025
0.445967 -127.3595 -207.9641 -43.51798 -234.1571 -65.12406

0.549767

0.656942

0.940992

Hg trong hai nn acid

292x + 0.0026173851
49
9x - 0.0333302928

0.4

0.6

0.8

1.2

ng Hg

c cng toan pha long)

HNO3 0.5%

Linear (HNO3 0.5%)

mcn
mHg
msau
C
10 ppm
0.1197
119.7 11.2762 10.61528
100 ppb
0.1243 1.319479
10.319 127.8689
10 ppb
0.4876 62.34887
5.7637 10.81751
0.0609
0.0622
0.0607 0.061267
0.540875
0.6553 0.594033 1.098281 1.108358
0.540875
0.6662 0.604933 1.118434
0.540875
m vial
1

tc

m cn o cao
C vial
m Hg tng
0.0594
0.0861
0.0744
0.1694
0.0908
0.1235
1.2892
0.4021
0.2814
0.32
1.1795
0.4485
0.3431
1.3468
0.4847
0.3247
0.5494
0.732
0.9699
0.5665
0.6239
0.6787
0.7885
0.6243
0.9714
1.0622
1.0079
0.9094
182.72
1.0735

RSD

mHg TB

54 83333.33

0.4545

m Hg l t Hiu sut

2.0415
2.6618
1.6082
2.8263
0.9573
0.2977
0.1004
0.6246
0.015
0.1025
49.65943 16.74776 104.1897 2.502155 17.09806

mcn
10 ppm
100 ppb
10 ppb
0.0419
0.327659
0.3539
0.327659
0.3684
0.327659
0.3802

mHg
0.1176
0.0994
0.5221
0.036
0.3136
0.3281
0.3399

m vial
m cn o
38.1149
38.1149
38.1149

msau

117.6
0.988728463
44.083273318
0.043
0.9570919041
1.0013451969
1.0373582213
cao

C vial

2.5615
1.9012
2.5454

0.0372
0.0579
0.0585

2.1094
2.4721
1.8494
2.2003
2.39
1.9956
1.9304
1.883

0.2038
0.2331
0.2287
0.1736
0.211
0.2632
0.1745
0.1657

1.7392
2.2038

0.2022
0.2272

1.9771
2.2452
1.8951

0.5446
0.5803
0.6125

38.0026
38.0026
38.0026
38.1086
38.1086
38.1086
38.3944
38.3944
38.3944
37.966
37.966
37.966

tc

11.8227
11.71
6.727
0.0403
0.9985984408

0.0145
0.0305
0.0230
#DIV/0!
#DIV/0!
#DIV/0!
0.0968
0.0944
0.1238
0.0790
0.0884
0.1321
0.0905
0.0881
#DIV/0!
0.1164
0.1032

mHg o (ng) AFS

Blank
1
2
3
4

RSD (n=3)
0.86
3.13
2.94
2.56
3.31

mHg l thuyt
35
16
28
2
8

17.22
16.50
18.21
19.01

C
9.946966
84.43454
6.553185

0.4545
0.043
0.0431

0.0419
0.0419588078

0.036
0.0360505269

RSD
35

mHg TB
0.86

3.68
3.59
4.71
3.01
3.37
5.03
3.48
3.38

16

3.13

17

18

28

2.94

16

18

2.56

18

14

4.42
3.92

3.31

19

17

m Hg tng
0.55
1.16
0.88

0.55
0.58
0.61

Hiu sut
18
18
14
17

0.34
0.35
0.42

mHg o (ng) MVU

Hiu sut MVU

21

125

27

140

m Hg l t Hiu sut

107
109
131

0.444392

Hiu sut
0.036269 1.382394

0.601168

21

125

0.738431

27

140

mcn
10 ppm
100 ppb
10 ppb
0.0362
0.390367
0.3828
0.390367
0.3704
0.390367

mHg
0.1079
0.1346
0.5334
0.0356
0.3488333333
0.3364333333

m vial
m cn o
38.1243
38.1243
38.1243

107.9
1.2204795079
57.7555976034
0.0301
0.8936032432
0.8618382737

cao

38.1853
38.1853
38.1853
38.658
38.658
38.658
38
38.3944
38.3944
38.3046
38.3046
38.3046
38.555
38.555
38.555
38.46
38.46
38.46

0.0397
0.0339
0.0301
0.1398

2.2573
1.824
1.8786
2.3288
2.5529
1.7439
1.9304
1.883

0.4464
0.3758
0.4185
0.3079
0.357
0.2632
0.1745
0.1657

0.4616
0.9433
0.946
0.7112
0.9338
1.1845
0.6025
0.5264

0.309
0.5255
0.502
0.6611
0.8621
1.0846
0.5351
0.4974

mHg o (ng) AFS

Blank
1
2
3
4

RSD (n=3)
0.86
3.13
2.94
2.56
3.31

11.8997
11.2717
7.3976
0.0339666667
0.88

C vial

2.2051
2.9552
2.3089

msau

0.0205
0.0131
0.0149
#DIV/0!
#DIV/0!
#DIV/0!
0.2253
0.2347
0.2538
0.1506
0.1593
0.1720
0.1030
0.1003
#DIV/0!
0.7627
0.6347
0.6046
1.0591
1.0518
1.0432
1.0119
1.0765

mHg l thuyt
35
16
28
2
8

17.22
16.50
18.21
19.01

C
9.067455
108.2782
7.807343

m Hg tng
0.78
0.50
0.57

8.60
8.96
9.69
5.82
6.16
6.65
3.91
3.85

0.0362
0.0412431854

0.0356
0.0405595967

RSD
24

mHg TB
0.62

8.47

12

71

5.59

13

43

3.27

23

14

23.12

24.31
23.16
40.83
40.55
40.22
38.92
41.40

Hiu sut
18
18
14
17

0.4545
0.0301
###

m Hg l t Hiu sut

C c

39.92

11

138

39.54

11

147

mHg o (ng) MVU

Hiu sut MVU

21

125

27

140

0.569885

Hiu sut

229.1335
mHg c
24.58602

23.32579

mcn
10 ppm
100 ppb
10 ppb
0.0219
0.576794
0.577
0.576794
0.5877
0.576794

mHg
0.1272
0.2116
0.5003
0.0271
0.5529666667
0.5636666667

m vial
m cn o
38.5213
38.5213
38.5213
2 38.2617
38.2617
38.2617
3 38.7585
38.7585
38.7585
4 38.5453
38.5453
38.5453
5 38.8566
38.8566
38.8566
6 39.1228
39.1228
39.1228
7 39.3239
39.3239
39.3239
9
1

1
2
3
4

127.2
2.2801453708
56.0816444122
0.0231
0.9586906654
0.9772414945

cao
2.1587
2.9614
2.1853
0.8657
1.2484
0.5473
1.3391
1.499
1.2697
1.1047
1.0951
0.9622
0.5585
1.044
0.6701
0.7176
0.5696
0.9656
0.7829
1.1099
0.7066

mHg o (ng) AFS

Blank

msau

C vial
0.0741
0.0878
0.0719
0.6784
0.9782
0.5743
0.7771
0.8535
0.745
0.8944
0.8802
0.8188
0.5703
0.9932
0.673
0.7125
0.5809
0.9252
0.8188
1.1058
0.7275

RSD (n=3)
0.86
3.13
2.94
2.56
3.31

11.8043
20.341
4.8615
0.0240333333
0.97

0.0355
0.0306
0.0340
0.8096
0.8095
0.5995
0.5882
0.6062
0.8364
0.8304
0.8791
1.0549
0.9828
1.0376
1.0258
1.0536
0.9899
1.0805
1.0293
1.0637

mHg l thuyt
35
16
28
2
8

17.22
16.50
18.21
19.01

C
10.77573
112.096
11.53587
0.0219
0.0226247597

0.0271
0.0279968488

0.0231
0.0238644726

39
m Hg tng
1.37
1.18
1.31
30.98
30.97
23.24
22.80
23.49
32.24
32.01
33.89
40.99
38.19
40.32
40.13
41.22
38.73
42.49
40.48
41.83

Hiu sut
18
18
14
17

RSD
7

mHg TB
1.29

31.0

21.89

31.43

38.55

m C
0.1024

38.74

m C
0.1069

40.31

m C
0.1132

mHg o (ng) MVU

Hiu sut MVU

21

125

27

140

0.4545

0.589979

C c

Hiu sut

TB
309

RSD
267

206

287

mHg c
27.38

75

mHg c
28.58

68

mHg c
30.27

60

20

mcn
10 ppm
100 ppb
10 ppb
0.0203
0.504381
0.4976
0.504381
0.4977
0.504381
0.504381
m vial
m cn o
1 38.8245
38.8245
38.8245
2 38.2352
38.2352
38.2352
3 38.4434
38.4434
38.4434
4 38.3352
38.3352

mHg
0.1075
0.1026
0.51
0.0168
0.4800666667
0.4801666667

msau

107.5
1.0440647482
50.8385706795
0.0155
0.9517938635
0.9519921263

cao
1.8455
2.0052
2.6436
1.6174
1.1699
1.0703
1.5114
1.3337
1.876
1.25
1.1746

10.564
10.4738
5.0397
0.0175333333
0.95

C vial
0.0601
0.0691
0.1084
0.7663
0.5655
0.5323
0.8023
0.7633
1.1131
0.8244
0.7912

0.0342
0.0362
0.0431
0.4977
0.5078
0.5225
0.5577
0.6012
0.6233
0.6929
0.7076

mHg o (ng) AFS

Blank
1
2
3
4

RSD (n=3)
0.86
3.13
2.94
2.56
3.31

mHg l thuyt
35
16
28
2
8

17.22
16.50
18.21
19.01

C
10.17607
99.68347
10.08762

10 ppm
100 ppb
10 ppb

m Hg tng
1.33
1.41
1.67
19.03
19.42
19.98
21.44
23.11
23.96
26.56
27.13

RSD

Hiu sut

mHg o (ng) MVU

Hiu sut MVU

21

125

27

140

18
18
14
17

mcn
0.2138
0.2239
0.5256

mHg TB
1.47

19.5

m C
0.1

22.84

m C
0.1044

25.8834991109
m C
0.1119

mHg
msau
C
202.8463 20.8441 9.731593
2.178904 21.9016 99.48605
52.28987
5.7526 9.08978

0.52465

C c

Hiu sut

TB
180

205

218

RSD
#DIV/0!
#DIV/0!

mcn
10 ppm
100 ppb
10 ppb
0.0256
0.529448
0.4341
0.529448
0.4289
0.529448
0.4988
0.529448
m vial
m cn o
1

mHg
0.1135
0.1251
0.5295
0.0365
0.40305
0.39785
0.46775

C vial
0.2261
0.2014
0.2312
0.7585
0.8863
0.6271
1.0968
0.9321
1.0133
0.6479
0.7261

0.5587
0.8947
0.9823
0.8786
1.053

0.5162
0.759
0.8342
0.9564
1.1516

0.5812
0.9787
0.4802

0.5674
0.9592
1.0006
1.3165789474
0.694340091

RSD (n=3)
0.86
3.13
2.94
2.56
3.31

10.3843
11.2097
6.0995
0.03105
0.76

0.7612639032
0.7514423617

cao

mHg o (ng) AFS

1
2
3
4

113.5
1.3673381932
64.5874174436

2.3531
1.6643
2.0097
0.9524
1.0604
0.7115
0.9772
0.7976
0.8808
1.0981
1.255

Blank

msau

0.1270
0.1600
0.1521
1.0530
1.1051
1.1653
1.4840
1.5451
1.5210
0.7801
0.7649
#DIV/0!
1.2216
1.1216
1.1228
1.4392
1.4459
1.2907
1.2958

mHg l thuyt
35
16
28
2
8

17.22
16.50
18.21
19.01

C
10.92996
121.9781
10.58897

m Hg tng

10 ppm
100 ppb
10 ppb

RSD

mcn
0.2138
0.2239
0.5256

mHg TB

m C
0.1024
m C
0.1069
m C
0.1132

Hiu sut
18
18
14
17

mHg o (ng) MVU

Hiu sut MVU

21

125

27

140

mHg
msau
C
202.8463 20.8441 9.731593
2.178904 21.9016 99.48605
52.28987
5.7526 9.08978

0.64199

C c

Hiu sut

TB
0

mHg c
0.00

mHg c
0.00

mHg c
0.00

RSD
0
#DIV/0!

mcn
10 ppm
100 ppb
10 ppb
0.0419
0.522396
0.466
0.522396
0.4649
0.522396
0.5078
0.522396
0.5101
m vial
m cn o
1 39.6025
39.6025
39.6025
3 38.9552
38.9552
38.9552
4 38.1089
38.1089
38.1089
5 38.3885
38.3885
38.3885
6 38.4878
38.4878
38.4878
7 38.2028
38.2028
38.2028
8 38.1293
38.1293
38.1293
QC

mHg
0.204
0.2177
0.5208
0.0358
0.4284666667
0.4273666667
0.4702666667
0.4725666667

204
19.846
2.2377708354
21.4163
54.4179457279
5.2085
0.0349
0.0375333333
0.8201958393
0.85
0.8180901552
0.9002118329
0.9046146268
cao
C vial
2.0848
0.0853
0.0484
2.4334
0.1028
0.0499
2.2841
0.0967
0.0500
1.5142
0.4722
0.3685
1.3715
0.4291
0.3697
1.3794
0.3987
0.3416
0.5137
0.7156
1.6463
0.6529
0.9011
1.6311
0.7511
0.9519
1.4977
0.8189
0.776
1.1199
1.2305
1.1171
1.0729
0.8233
0.7237
1.0388
1.1319
1.0423
1.0883
0.9162
0.84
1.0835
0.8474
0.7858
1.0959
1.0049
0.6995
0.8226
0.889
0.6359
0.8453
1.165
0.8157
0.8275
1.152
0.8525
0.8746
0.8754
0.608
0.8208
1.5128
1.0448
0.8162

mHg o (ng) AFS

Blank
1
2
3
4

msau

RSD (n=3)
0.86
3.13
2.94
2.56
3.31

mHg l thuyt
35
16
28
2
8

17.22
16.50
18.21
19.01

C
10.27915
104.4891
10.44791

10 ppm
100 ppb
10 ppb

mcn
0.2138
0.2239
0.5256

m Hg tng
1.91
1.98
1.98
14.36
14.40
13.31
62.74
62.16
57.08
42.99
41.19
39.88
41.88
41.70
42.18
31.43
32.29
31.61
33.35
31.30
31.12

RSD
2

mHg TB
1.96

14.0

60.66

41.35

m C
0.0927

41.92

m C
0.0976

31.78

m C
0.1265

31.92

m C
0.1232

Hiu sut

mHg o (ng) MVU

Hiu sut MVU

21

125

27

140

18
18
14
17

mHg
msau
C
202.8463 20.8441 9.731593
2.178904 21.9016 99.48605
52.28987
5.7526 9.08978

0.549943

C c

Hiu sut

TB

RSD

111.4

mHg c
22.20

141

mHg c
23.37

137

C c
235.73
Ctb
C c
243.21

239.47

Ngy
3-Jun
10-Jun
15-Jun
19-Jun

Mu 1

Mu 2
229
250
180
236

Mu 3
240
206
205
243

TB
250
240
218
250

RSD
240
232
201
243
Trung bnh cc ngy RSD
229
205.43 0.69

4.4
10
9.6
2.9
8.4

Hiu sut thu hi

75

68

60

141

137

130

mcn
10 ppm
100 ppb
10 ppb
0.0508
0.525947
0.5272
0.525947
0.5505
0.525947
0.5252
0.525947
0.5829
m vial
m cn o
1 39.3651
39.3651
39.3651
3 38.2193
38.2193

mHg

msau

0.1114
0.1157
0.5101
0.0558
0.4747666667
0.4980666667
0.4727666667
0.5304666667

111.4
10.3663
1.243353945
10.4287
60.8162903662
5.7816
0.0507
0.0524333333
0.902689376
0.92
0.9469904273
0.8988867106
1.0085936059
cao
C vial
1.6491
0.235
0.1555
2.1343
0.2862
0.1464
2.0738
0.2727
0.1435
0.9324
0.7266
0.8506
0.8126
0.6358
0.8540
0.8129

1.2594
1.3549

1.6910

38.4487
38.4487

1.0073
1.0193

0.5384
0.5364

0.5834
0.5744

6 38.8517
38.8517
38.8517
7 38.6392
38.6392
38.6392
8 38.7757
38.7757

0.7261
1.0145
1.0995
0.5822
0.6791
0.6582
0.9254
0.6559

0.6554
0.8766
0.9556
0.5586
0.6152
0.6134
0.9057
0.6445

0.9852
0.9431
0.9486
1.0472
0.9888
1.0172
1.0682
1.0725

0.9127
0.5159
0.7493
0.5511

0.9187
0.7645
0.9768
0.8896

1.0987
1.6174
1.4229
1.7619

mHg o (ng) AFS

Blank
1
2
3
4

RSD (n=3)
0.86
3.13
2.94
2.56
3.31

mHg l thuyt
35
16
28
2
8

17.22
16.50
18.21
19.01

C
10.74636
119.2243
10.51894

m Hg tng
6.12
5.76
5.65
32.51
32.64

10 ppm
100 ppb
10 ppb

mcn
0.2148
0.2161
0.5256

RSD
4

mHg TB
5.84

32.6

#DIV/0!

#DIV/0!

22.43
22.08

22.26

38.28
36.64
36.86
40.46
38.21
39.30
41.42
41.59

37.26

39.32

m C
0.1088

41.50

m C
0.1086

mHg o (ng) MVU

Hiu sut MVU

21

125

27

140

Hiu sut
18
18
14
17

mHg

msau
C
214.8 20.4593 10.49889
2.268811 20.1732 112.4666
59.11243
5.7526 10.27578

0.627496

C c

Hiu sut

TB
254

RSD
234

150

299

mHg c
25.49

80

mHg c
25.44

94

33

mcn
10 ppm
100 ppb
10 ppb
0.0485
0.535675
0.5608
0.535675
0.5712
0.535675
0.6956
0.535675
0.6687
m vial
m cn o
1 39.5435
39.5435
39.5435
3 39.9601
39.9601
39.9601
4 38.8516
38.8516
38.8516
5 38.7814
38.7814
38.7814
6
39.036
39.036
39.036
7 38.7853
38.7853
38.7853
8
39.233
39.233
39.233
9 39.8287
39.8287
39.8287

mHg
0.1173
0.1172
0.555
0.0417
0.5157
0.5261
0.6505
0.6236

1
2
3
4

117.3
1.2534930795
62.2400947544

10.9674
11.1775
5.8095
0.0451
0.97

0.9627103435
0.9821250954

cao

C vial

1.8225
2.3547
1.9805
1.1339
0.9008
1.0707
1.375
0.5158

0.0731
0.0789
0.0755
0.8646
0.7256
0.8387

0.598
0.6815

0.6303
0.6943

0.0412
0.0345
0.0392
0.7841
0.8284
0.8055
0.0000
1.2313
#DIV/0!
1.0839
1.0477

1.0254
1.0988
0.7759
0.9725
1.2185
0.916
0.8113
0.9375
1.1527
1.0817
1.0481

0.9262
1.0226
0.7855
0.7388
0.8584
0.6969
0.695
0.7647
0.9066
0.822
0.8222

0.9289
0.9570
1.0411
0.7812
0.7245
0.7824
0.8809
0.8388
0.8088
0.7815
0.8067

mHg o (ng) AFS

Blank

msau

0.6176

RSD (n=3)
0.86
3.13
2.94
2.56
3.31

mHg l thuyt
35
16
28
2
8

17.22
16.50
18.21
19.01

C
10.69533
112.1443
10.7135

m Hg tng
1.63
1.36
1.55
31.33
33.10
32.19
0.00
47.84
#DIV/0!
42.04
40.63
36.26
37.36
40.64
30.30
28.10
30.35
34.56
32.91
31.73
31.12
32.13

Hiu sut
18
18
14
17

10 ppm
100 ppb
10 ppb

mcn
0.2148
0.2161
0.5256

RSD
9

mHg TB
1.51

32.2

m C
0.1084

#DIV/0!

#DIV/0!

m C
0.1088

41.33

m C
0.1548

38.09

m C
0.1240

29.58

m C
0.0969

33.07

m C
0.1028

31.63

m C
0.1063

mHg o (ng) MVU

Hiu sut MVU

21

125

27

140

mHg

msau
C
214.8 20.4593 10.49889
2.268811 20.1732 112.4666
59.11243
5.7526 10.27578

0.590233

C c

Hiu sut

TB
283

278

257

295

mHg c
289.65
mHg c
306.94
283

RSD

-2537