Subject: Chemistry( Date of submission: 01-04-2015)
1. Write the IUPAC name for the following compounds: i. CH3CH=C(Cl)CH2CH(CH3)2 ii. p-Cl C6H4CH2CH(CH3)2 2. Which of the following would undergo SN2 reaction faster: i. CH3CH2CH2Cl or CH3CH2CH2Br ii. CH2=CH-Br or CH2=CH-CH2Br 3. Write the major product from the elimination of the following halides: CH(Br)CH3
4. An optically active compound A with molecular formula C4H9Br when treated
with aqueous KOH solution, the rate of reaction is found to be dependent on concentration of compound and KOH both. Write the structure of A and explain the mechanism involved and the stereochemical aspect of the reaction. 5. How will you carry out the following conversions: i. Propene to 1-nitropropane ii. Benzene to biphenyl iii. Isopropyl alcohol to iodoform iv. Aniline to iodobenzene v. 2-Bromopropane to 1-Bromopropane 6. Which has higher dipole moment and why : CHCl3 or CH2Cl2?