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Moles Andas Equations Worksheets 2 1-2-11 1 Ans
Moles Andas Equations Worksheets 2 1-2-11 1 Ans
Moles Andas Equations Worksheets 2 1-2-11 1 Ans
2.1
Worksheet
(2
(2
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(3) Calculate the mass, in grams, of each of the following amounts. [Relative atomic
masses are given in brackets]
(a) 0.5 mol of oxygen atoms [O = 16]
(1 mark)
(b) 10 mol of sodium atoms [Na = 23]
(1 mark)
(c) 0.01 mol of hydrogen atoms [H = 1]
(1 mark)
(d) 0.25 mol of zinc atoms [Zn = 65.4]
(1 mark)
(4) Calculate the molar masses, in g mol1, of each of the following substances.
(a) Br2 [Br = 80]
(b) CO2 [C = 12, O = 16]
(c) HNO3 [H = 1, N = 14, O = 16]
(d) CuSO4 . 5H2O [Cu = 64, S = 32, O = 16, H = 1]
(1
(1
(1
(1
(5) Calculate the number of moles present in each of the following samples.
(a) 128 g of oxygen, O2 [O = 16]
(b) 25.25 g of potassium nitrate, KNO3 [K = 39, N = 14, O = 16]
(c) 414 g of ethanol, C2H5OH [C = 12, H = 1, O = 16]
(1 mark)
(1 mark)
(1 mark)
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(1 mark)
(1 mark)
(1 mark)
Total: 30 marks
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Worksheet
2.2
Empirical formulae
(1) Calculate the empirical formulae of the following compounds from the
information given:
(a) 1.12 g of iron combines with oxygen to form 1.60 g of an oxide of iron.
[Fe = 56, O = 16]
(b) 23.8 g of tin combines with chlorine to form 38.0 g of a chloride of tin.
[Sn = 119, Cl = 35.5]
(c) 5.8 g of aluminium combines with 22.9 g of chlorine. [Al = 27, Cl = 35.5]
(d) A compound was found to contain 43.4% sodium, 11.3% carbon and
45.3% oxygen by mass. [Na = 23, C = 12, O = 16]
(e) A compound contains 82.75% by mass of carbon and 17.25% by mass of
hydrogen. [C = 12, H = 1]
(2) Deduce the molecular formula of the compound determined in Question 1(e)
above, given that its molar mass is 58 g mol1.
(3) Calculate the empirical formula of the following compounds from the
percentages by mass given:
(a) C = 66.67%, H = 11.11%, O = 22.22% [C = 12, H = 1, O = 16]
(b) C = 40.4%, H = 7.9%, N = 15.7%, O = 36.0% [C = 12, H = 1,
N = 14, O = 16]
(c) 85.25% BaCl2, 14.75% water of crystallisation [Ba = 137, Cl = 35.5,
H = 1, O = 16]
(d) Be = 12.9%, C = 17.3%, O = 69.8% [Be = 9, C = 12, O = 16]
(4) Deduce the molecular formula of each compound given the empirical formula
and the molar mass of the compound in g mol1:
(a) C2H2O (molar mass = 42 g mol1)
(b) CH2O (molar mass = 120 g mol1)
(c) NaO (molar mass = 78 g mol1)
(d) CHO (molar mass = 174 g mol1)
(2 marks)
(2 marks)
(2 marks)
(2 marks)
(2 marks)
(2 marks)
(2 marks)
(2 marks)
(2 marks)
(2 marks)
(1
(1
(1
(1
mark)
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(5) Calculate the percentage by mass of each of the stated elements in the following
compounds:
(2 marks)
(a) Silicon in SiCl4 [Si = 28, Cl = 35.5]
(2 marks)
(b) Nitrogen in NH4NO3 [N = 14, H = 1, O = 16]
(2 marks)
(c) Sulfur in CuSO4.5H2O [Cu = 64, S = 32, O =16, H =1]
Total: 30 marks
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Worksheet
2.3
(5 marks)
(5 marks)
(4) Write names for the substances represented by the formula in each case.
(a) NH3
(b) SO2
(c) H2
(d) CH4
(e) Na2CO3
(f) Ca(OH)2
(g) Cu(NO3)2
(h) CuCl
(i) C4H10
(j) KAt
(10 marks)
(10 marks)
Total: 30 marks
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Worksheet
2.4
(1
(1
(1
(1
(1
(1
(1
(1
(1
(1
(2) Convert the following word equations into balanced symbol equations,
including state symbols:
(a) solid zinc + copper(II) sulfate solution zinc sulfate solution + solid copper
(1
(b) solid calcium hydroxide + solid ammonium chloride solid calcium chloride
+ steam + ammonia gas (1
(c) silicon tetrachloride + water solid silicon dioxide + hydrogen chloride gas
(1
(d) gaseous octane + oxygen carbon dioxide + steam
(1
(e) sodium + water sodium hydroxide solution + hydrogen gas
(1
(3) 1.133 g of solid silver nitrate were heated. Solid silver metal (0.720 g) and
gaseous nitrogen dioxide (0.307 g) were given off in addition to oxygen gas.
From the data given, write a balanced equation for the reaction.
[Ag = 108, N = 14, O = 16]
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(3 marks)
(4) Write ionic equations derived from each of the following full chemical equations:
(2 marks)
(a) AgNO3(aq) + NaCl(aq) AgCl(s) + NaNO3(aq)
(2 marks)
(b) Zn(s) + H2SO4(aq) ZnSO4(aq) + H2(g)
(2 marks)
(c) HCl(aq) + NaOH(aq) NaCl(aq) + H2O(l)
(2 marks)
(d) CuO(s) + H2SO4(aq) CuSO4(aq) + H2O(l)
(2 marks)
(e) Pb(NO3)2(aq) + 2NaCl(aq) PbCl2(s) + 2NaNO3(aq)
(2 marks)
(f) CaCO3(s) + 2HCl(aq) CaCl2(aq) + H2O(l) + CO2(g)
Total: 30 marks
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Worksheet
2.5
Reacting masses
(1) Calculate the mass of magnesium chloride, MgCl2, that would be obtained when
48 g of magnesium metal is reacted completely with chlorine. [Mg = 24, Cl = 35.5]
Mg(s) + Cl2(g) MgCl2(s)
(2 marks)
(2) Calculate the mass of calcium carbonate, CaCO3, that must be decomposed in
order to produce 14 tonnes of calcium oxide, CaO. [Ca = 14, C = 12, O =16]
CaCO3(s) CaO(s) + CO2(g)
(2 marks)
(2 marks)
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Worksheet
2.5
Continued
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Worksheet
2.6
Gas volumes
(1) The expression volume of one mole of gas =
The densities of some gases, measured at room temperature and pressure, are given in the
table below
Name of gas
Formula
Argon
Ar
1.66
Chlorine
Cl2
2.99
Fluorine
F2
1.58
Helium
He
0.17
Hydrogen
H2
0.08
Neon
Ne
0.84
Nitrogen
N2
1.17
Oxygen
O2
1.33
Carbon dioxide
CO2
1.81
Hydrogen sulfide
H 2S
1.41
32
1.33
= 24.1 dm3 ]
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2.6
Worksheet
Continued
Gas
Formula
Argon
Ar
Helium
He
Neon
Ne
Hydrogen
H2
Oxygen
O2
Nitrogen
N2
Chlorine
Cl2
Fluorine
F2
Carbon dioxide
CO2
Hydrogen sulfide
H 2S
32
24.1
(9 marks)
Note: To a good approximation, the above experimental data show that the volume occupied
by one mole of any gas at room temperature and pressure is approximately 24 dm3.
[In the following questions, assume that the molar volume of a gas at room temperature and
pressure is 24 dm3 mol1 (24 000 cm3 mol1). ]
(2) Calculate the number of moles of gas contained in the following volumes (all measurements
at room temperature and pressure).
(a) 48 dm3 of oxygen gas, O2
(1 mark)
(1 mark)
(b) 3 dm3 of ammonia gas, NH3
3
(1 mark)
(c) 96 cm of neon gas, Ne
(1 mark)
(d) 240 000 cm3 of chlorine gas, Cl2
(3) Calculate the volume of the following amounts of gases at rtp.
(a) 3.0 mol of nitrogen, N2
(b) 0.20 mol of neon, Ne
(c) 0.50 mol of carbon dioxide, CO2
(1 mark)
(1 mark)
(1 mark)
(1
(1
(1
(1
(5) Calculate the mass of the following volumes of gases (measured at rtp).
(a) 48 dm3 of helium, He [He = 4]
(b) 0.12 dm3 of oxygen, O2 [O = 16]
(c) 0.72 dm3 of ammonia, NH3 [N = 14, H = 1]
(1 mark)
(1 mark)
(1 mark)
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(1 mark)
(1 mark)
Total: 25 marks
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Worksheet
2.7
(2 marks)
(2) Calculate the volume of carbon dioxide gas, CO2 (measured at room temperature
and pressure) which would be formed when 90.0 g of glucose, C6H12O6, completely
ferments according to the equation:
C6H12O6(aq) 2C2H5OH(aq) + 2CO2(g)
[C = 12, H = 1, O = 16]
(2 marks)
(1 mark)
(2 marks)
(5) Chlorine reacts with sodium iodide as shown in the equation below:
Cl2(g) + 2KI(aq) 2KCl(aq) + I2(s)
Calculate the volume of chlorine gas, measured at room temperature and pressure,
required to produce 25.4 g of solid iodine (I = 127).
(2 marks)
(6) A car engine burns the compound octane, C8H18
2C8H18(g) + 25O2(g) 16CO2(g) + 18H2O(l)
Calculate:
(a) the volume of oxygen required to completely burn 2 dm3 of octane vapour (1 mark)
(b) the volume of carbon dioxide gas you would expect to be formed
(1 mark)
[Assume that all gas volumes are measured at the same temperature and pressure.]
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Worksheet
2.7
Continued
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Worksheet
2.8
Amounts in solution
(1) What is meant by the term standard solution?
(2 marks)
(2) 0.100 mol of sodium hydroxide was placed in each of the four volumetric flasks
shown below and diluted to the volumes shown. Calculate the concentration
(4 marks)
of the solution formed in each case, in mol dm3.
V = 2000 cm3
V = 500 cm3
V = 250 cm3
V = 100 cm3
(3) Calculate the concentration (in mol dm3) of the following solutions:
(a) 0.001 mol KOH in 20 cm3 of solution
(b) 0.006 mol H2SO4 in 0.075 dm3 of solution
(c) 0.012 mol CuSO4 in 0.20 dm3 of solution
(d) 0.40 mol of AgNO3 in 1250 cm3 of solution
(4) Calculate the concentration (in mol dm3) of the following solutions:
(a) 4.9 g of H2SO4 in 100 cm3 of solution [H = 1, S = 32, O =16]
(b) 3.31 g of Pb(NO3)2 in 2.5 dm3 of solution [Pb = 207, N = 14, O = 16]
(c) 0.106 g of Na2CO3 in 25.0 cm3 of solution [Na = 23, C = 12, O = 16]
(d) 125 g of CuSO4.5H2O in 5.0 dm3 of solution
[Cu = 64, S = 32, O = 16, H = 1]
(5) Calculate the mass of:
(a) calcium chloride, CaCl2, required to make 100 cm3 of a solution,
concentration 2.0 mol dm3. [Ca = 40, Cl = 35.5]
(b) pure sulfuric acid, H2SO4, required to make 0.500 dm3 of a solution,
concentration 5.0 mol dm3. [H = 1, S = 32, O = 16]
(c) sodium chloride, NaCl, required to make 200 cm3 of a solution,
concentration 0.50 mol dm3. [Na = 23, Cl = 35.5]
(1
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(1 mark)
(1 mark)
(1 mark)
(1 mark)
(2 marks)
(2 marks)
(2 marks)
(6) Calculate the number of moles of solute present in each of the following solutions:
(a) 250 cm3 of 0.200 mol dm3 KMnO4
(1 mark)
3
3
(1 mark)
(b) 200 cm of 0.117 mol dm NaOH
3
3
(1 mark)
(c) 2.00 dm of 0.100 mol dm NaCl
(1 mark)
(d) 0.100 dm3 of 2.00 mol dm3 H2SO4
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2.8
Worksheet
Continued
(7) Express the following molar concentrations (mol dm3) in units of g dm3:
(a) 0.200 mol dm3 KMnO4 [K = 39, Mn = 55, O = 16]
(b) 0.117 mol dm3 NaOH [Na = 23, O = 16, H = 1]
(c) 0.100 mol dm3 NaCl [Na = 23, Cl = 35.5]
(d) 0.500 mol dm3 Al2(SO4)3 [Al = 27, S = 32, O = 16]
(1
(1
(1
(1
(8) A sample of battery acid contains 1176 g of sulfuric acid, H2SO4, in 3.0 dm3 of
liquid. Calculate the concentration of the sulfuric acid in:
(a) g dm3
(b) mol dm3
[Assume H = 1, S = 32, O = 16]
mark)
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(1 mark)
(1 mark)
Total: 30 marks
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Worksheet
2.9
(2 marks)
(3 marks)
Name of chemical
Formula
Hydrochloric acid
Sulfuric acid
Nitric acid
(2 marks)
(3 marks)
Name of chemical
Formula
Sodium hydroxide
Potassium hydroxide
Ammonia
(2 marks)
(1 mark)
(1 mark)
(1 mark)
(7) The molar mass of anhydrous sodium carbonate, Na2CO3, is 106 g mol1 and
that of water, H2O is 18 g mol1. 0.572 g of hydrated sodium carbonate,
Na2CO3.xH2O, was heated to constant mass. The residue weighed 0.212 g.
(a) Calculate the number of moles of water that were driven off.
(1
(b) Calculate the number of moles of anhydrous sodium carbonate in the residue. (1
(c) Deduce the formula of hydrated sodium carbonate.
(1
(d) Why was the hydrated sodium carbonate heated to constant mass?
(1
(8) A hydrated salt has the empirical formula FeN3H12O15. Deduce the formula of
the salt, showing the moles of water of crystallisation after the dot.
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(1 mark)
(9) 5.50 g of a hydrated sample of iron(III) oxide, Fe2O3.xH2O, was heated until all
the water was driven off. 4.71 g of anhydrous solid was left. Deduce the formula
of the hydrated compound. [Fe = 56, O = 16, H = 1]
(2 marks)
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Worksheet
2.9
Continued
(10) Write both (i) the full equation and then (ii) the ionic equation for each of the
following reactions:
(a)magnesium + hydrochloric acid magnesium chloride + hydrogen
(2 marks)
[Assume the solid magnesium oxide and solid magnesium carbonate are
insoluble when writing the ionic equations for parts (b) and (c).]
(b) magnesium oxide + hydrochloric acid magnesium chloride + water
(2 marks)
(c)magnesium carbonate + hydrochloric acid magnesium chloride +
water + carbon dioxide
(2 marks)
(11) Ethanoic acid, CH3COOH, is the acid present in vinegar. Write the equation for
the reaction between aqueous sodium carbonate solution and dilute ethanoic acid.
Include all state symbols.
(1 mark)
(12) Aqueous ammonia reacts with dilute ethanoic acid to form a solution of ammonium
ethanoate. Write the equation for this reaction, including all state symbols.
(1 mark)
Total: 30 marks
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Worksheet
2.10
(2 marks)
(2 marks)
(3) In a titration, 12.0 cm3 of an aqueous solution of sulfuric acid exactly neutralised
20.0 cm3 of a solution of sodium hydroxide, concentration 0.150 mol dm3.
H2SO4(aq) + 2NaOH(aq) Na2SO4(aq) + 2H2O(l)
Calculate the concentration of the aqueous sulfuric acid, in mol dm3.
(2 marks)
(4) In a titration, 25.0 cm3 of dilute nitric acid exactly neutralised 15.0 cm3 of a
dilute solution of ammonia, concentration 0.0200 mol dm3.
HNO3(aq) + NH3(aq) NH4NO3(aq)
Calculate the concentration of the nitric acid, in mol dm3.
(1 mark)
(5) In a titration, 20.0 cm3 of dilute hydrochloric acid, concentration 0.100 mol dm3,
reacted with 25.0 cm3 of sodium carbonate solution.
Na2CO3(aq) + 2HCl(aq) 2NaCl(aq) + H2O(l) + CO2(g)
Calculate the concentration of the sodium carbonate solution:
(a) in mol dm3
(b) in g dm3
[Na = 23, C = 12, O = 16]
(2 marks)
(1 mark)
(1 mark)
(1 mark)
(1 mark)
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Worksheet
2.10
Continued
(7) A carbonate of metal M has the formula M2CO3. The equation for the reaction
of M2CO3 with dilute hydrochloric acid is:
M2CO3(s) + 2HCl(aq) 2MCl(aq) + CO2(g) + H2O(l)
0.188 g of M2CO3 was found to exactly neutralise 23.6 cm3 of dilute hydrochloric
acid, concentration 0.150 mol dm3.
(a) Calculate the moles of hydrochloric acid that reacted with 0.188 g
of M2CO3.
(b) Calculate the number of moles of M2CO3 that reacted with the
hydrochloric acid.
(c) Calculate the molar mass of the metal carbonate, M2CO3.
(d) Calculate the molar mass of the metal, M, and hence deduce its identity.
(1 mark)
(1 mark)
(1 mark)
(2 marks)
(8) Lead(II) nitrate, Pb(NO3)2, may be produced by the reaction shown in the
equation below.
PbO(s) + 2HNO3(aq) Pb(NO3)2(aq) + H2O(l)
3
175 cm of dilute nitric acid, concentration 1.50 mol dm3, reacted with excess
lead(II) oxide, PbO.
Calculate the maximum mass of lead(II) nitrate which could have been obtained
in this reaction. [Pb = 207, N = 14, O = 16]
(2 marks)
(9) 1.575 g of hydrated ethanedioic acid, H2C2O4.xH2O, was dissolved in 250 cm3
distilled water.
In a titration, 25.0 cm3 of this acid solution was neutralised by exactly 25.0 cm3 of dilute
sodium hydroxide, concentration 0.100 mol dm3.
COOH
COONa
+ 2H2O
+ 2NaOH
COOH
COONa
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Worksheet
2.10
Continued
(10) A student carried out an experiment to find the percentage by mass of calcium
carbonate, CaCO3, in a 1.00 g sample of limestone.
The student found that 50.0 cm3 of dilute hydrochloric acid, concentration
0.100 mol dm3, reacted with the calcium carbonate in the sample.
CaCO3(s) + 2HCl(aq) CaCl2(aq) + CO2(g) + H2O(l)
Calculate the percentage purity of the limestone. [Ca = 40, C = 12, O = 16] (2 marks)
(11) An experiment was carried out to find the percentage purity of a sample of
magnesium carbonate.
An impure sample of magnesium carbonate was added to 30.0 cm3 of a
0.100 mol dm3 solution of dilute hydrochloric acid.
The magnesium carbonate reacted with the hydrochloric acid as shown in the
equation:
MgCO3(s) + 2HCl(aq) MgCl2(aq) + CO2(g) + H2O(l)
(a) Calculate the moles of hydrochloric acid in 30.0 cm3 of 0.100 mol dm3
hydrochloric acid.
(b) Calculate the moles of hydrochloric acid that reacted with the magnesium
carbonate.
(c) Calculate the moles of magnesium carbonate, MgCO3, which reacted with
the dilute hydrochloric acid.
(d) Calculate the mass of magnesium carbonate in the sample.
[Mg = 24, C= 12, O = 16]
(e) If the weighed sample of the impure magnesium carbonate had a mass
of 0.124 g, calculate the percentage purity of the solid.
Total:
(1 mark)
(1 mark)
(1 mark)
(1 mark)
(1 mark)
35 marks
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Worksheet
2.11
Yield calculations
(1) 2-chloro-2-methylpropane may be prepared from 2-methylpropan-2-ol by a reaction with
concentrated hydrochloric acid.
(CH3)3COH + HCl (CH3)3CCl + H2O
2-methylpropan-2ol 2-chloro-2-methylpropane
In a preparation, 5.8 g of 2-chloro-2-methylpropane was obtained from 7.9 g of
2-methylpropan-2-ol. Calculate the percentage yield of 2-chloro-2-methylpropane
in this reaction. [Molar masses/g mol1: (CH3)3COH = 74, (CH3)3CCl = 92.5] (2 marks)
(2) In an organic chemistry experiment, 49.2 g of nitrobenzene (C6H5NO2) were
obtained from 39.0 g of benzene (C6H6). The equation for the reaction is:
C6H6(l) + HNO3(l) C6H5NO2(l) + H2O(l)
Calculate the percentage yield of the reaction.
[Relative atomic masses: C = 12, H = 1, N = 14, O = 16]
(2 marks)
(2 marks)
(2 marks)
(2 marks)
(2 marks)
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Worksheet
2.11
Continued
(7) Calculate the atom economy for the production of propan-2-ol by the hydration
of propene, CH3CH=CH2.
CH3CH=CH2 + H2O CH3CH(OH)CH3
[Relative atomic masses: C = 12, H = 1, O = 16]
(1 mark)
(8) Explain one advantage to industry and one advantage to the environment of
a process with a very high atom economy.
(2 marks)
Total: 15 marks
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