\

A dilision of "VID\ --r.Ri'HI .{CADEMY PVT. LTD." JEE & NEET

(b) Pressure correction or effect of molecular attrsction forces - A molecule in r: :::idle
in of ;.:::;::* is atlracted unifomrly on a-r s-jes

le:;:luring

molecules. Therefore ll::e is

no ris::::i1: ai:rracd\.e fOrCe On the molecu.e.
Bu: ''..::,':: --::e :nolecuie approaches the u a.- of
con:e-:::: i'.::ore collision,it lvould experienc.atira;:ii: :-orce;rom the bulk ofthe molecules
beiii:-. Due io:hl=se attractive forces speeri
durilg col;isio:: ri:I bereducedas momentum
rrill r; ie:<ser- i-rrc: epplied onthewall be will

rniiile of

b1

cL::.a^t.Iter

rnolecule
be Iess L)lpre-<s'Jre.;-i1l be lesser.
collision

.'. P,,j".r= P

-+ correction term o no. of molecules attracting the curl.iiir:g molccule

correction term cx densit-r' of molecules (n/v)

lcorrection tenn,}'
{

-+ no. of collision a densitv ofmolecules (n/r,)

it'):

net correction term u (n 1v)(n

an: / v

-a-

is aconstant

ofpropodionality

'a' is dependent on forces of attraction. Stronger the tbrce of attraction gteater will be 'a'

j.P:P+
I
f,'t
f

... Vander waal's equation is (P

,1tt'

)(V-nb)

Verification of vander lvaal's equation

Vandu wall equation for I mole

(r*-1.],"
- b\=- r\1
Rr
- r't,Jt'-u)
['

nRT.

z:l

_____+

Variation of ZwithP forvanderrvaal equation

at any temperature
At lorv pressure : At lo\ir pressure V will be high. Hence b can be neglected in comparison to
v. But a/v2 can't be neglected as pressrire is also low. Thus equation rvould be

t.

,/^\

lp"*l.r=nr
\ r-J
I

Forz<l

rl

+pL,+9=RT
t'

PL'uu
RT I,'RT

lR7'

I Vreal<Videal'

' n*aT gas

il eeiily compressible in comparison i.rr an icleai gas.
At high pressure : V will be low so b can't be neglected in comparison to V. But a/V2 can be

Regd.

to a much higher value of P. Then vander q'aal

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