TUTORIAL 4: MATTER

NAME:
PRA-U BAWAH SAINS

Q1
The volume of a gas at 298K and 100kPa pressure is 76.0 cm3. Calculate the volume it would occupy at
265 kPa at the same temperature.
[2 marks]

Q2
A sample of helium occupie a volume of 358cm3 at 100kPa and 300K. At what pressure would the volume
be reduced to 250 cm3 at the same temperature
[2 marks]

Q3
50 cm3 of a sample of chlorine gas is heated from 25oC to 200oC, calculate the final volume of the gas if
the pressure remains constant.
[2 marks]

Q4
A sample of gas at 30oC was heated.At what temperature would the volume of the gas be doubled,
assuming no change in pressure
[2 marks]

Q5
At 60oC and 1.50 x 105 Pa, a sample of gas occupies a volume of 400cm3. What is the volume occupied by
the gas at s.t.p?
[2 marks]

0.01 mol of a sample of gas occupies 250.0cm3 at 27oC. If the temperature is raised to 35oC, calculate
[6

Q6
marks]

a) The volume occupied if the pressure remains unchanged.

b) The pressure of the gas if the volume is fixed
c) The volume occupied by the gas at s.t.p (273 K, 101 kPa)

Q7
5.0 dm3 of the helium gas at 4.0 x 105 Pa and 3.0 dm3 of oxygen gas at 5.0 x 105 Pa is injected into a 2.0
dm3 container. Determine
[4 marks]
a) The partial pressures of helium gas and oxygen gas in the container
b) The final pressure in the container

Q8
Density of solid carbon dioxide is 1.50 gdm-3. What is the volume of gas produced by 2.5 dm3 of solid
carbon dioxide at s.t.p.?
[3 marks]
( 1 mol of gas occupies 22.4 dm3 at s.t.p: Relative atomic mass: C, 12; O, 16)

Q9

Explain
a)
b)
c)
d)

[8 marks]

Ideal Gas
Two factors that cause a real gas to deviate from ideal behaviour
Two conditions where a real gas deviates most from ideal behaviour
Two conditions where a real gas approaches an ideal gas

Q10

State the allotropes of carbon and its uses

[6 marks]

Q11

Draw the phase diagrams of i) carbon dioxide, ii) water

[ 6 marks]

Q12

State and explain the effect of a non-volatile solute on the vapour pressure of a solvent
[ 6 marks]

Q13

Draw the graph depression of freezing point

[ 3 marks]