FT-IR Spectroscopy of Polymer Solution and Polymer-Nanoparticle Suspension

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P olymer 5000 ppm

P olymer 5000ppm + NP 8000 ppm

Transmittance (%)

90

60
1640.6

3452.2
1106.8

30

1626.7
3424.8

4000

3500

3000

2500

2000

1500

1000

Wave Number (cm-1)

FT-IR spectroscopy of Polymer solution and Polymer-Nanoparticle


suspension

Rheological Studies
Polymer 5000ppm
polymer 5000,np2000
5000ppm.np5000ppm
polymer 5000,np8000
polymer 5000,np10000

Shear Stress (Pa)

100

10

10

100

Shear Rate (1/s)

Effect of nano particle concentration on Shear Stress at polymer


concentration of 5000 PPM

Viscosity (PAs)

Polymer 5000ppm
polymer 5000,np2000
5000ppm.np5000ppm
polymer 5000,np8000
polymer 5000,np10000

0.1

0.01
10

100

Shear Rate (1/s)

Effect of nano particle concentration on Viscosity at polymer concentration


of 5000 PPM

Viscosity (Pas)

0.1

0.01

1E-3

20

40

60

80

100

Shear Rate (1/s)

Effect of nano particle concentration on Viscosity at polymer concentration


of 2500 PPM

Shear Stress (Pa)

10

0.1
20

40

60

80

100

Shear Rate (1/s)

Effect of nano particle concentration on Viscosity at polymer concentration


of 2500 PPM

30 C
60 C
90 C

Viscosity

0.1

0.01

1E-3
10

100

Shear Rate

Effect of temperature on viscosity of 5000PPM polymer and 5000 PPM

30 C
60 C
90 C

Shear Stress

0.1

0.01

10

100

Shear Rate

nano particle
Effect of temperature on Shear Stress of 5000PPM polymer and 5000 PPM
nano particle sample
P-5000,N-5000,S-150000
P-5000,N-5000,S-5000
P-5000,N-5000,S-250000

Shear Stress

0.1

10

Shear Rate

Effect of salt concentration on Shear Stress of 5000 PPM polymer and


5000 PPM nano particle sample

Viscosity

P-5000,N-5000,S-150000
P-5000,N-5000,S-5000
P-5000,N-5000,S-250000

0.01

1E-3
10

20

30

40

50

60

70 80 90

Shear Rate

Effect of salt concentration on viscosity of 5000 PPM polymer and 5000


PPM nano particle sample

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