IV.

DATA
Table 1. List of Weight of Sodium Chloride Solution
Molarity (M), Weight of Empty
Weight of
Weight of
M
Pycnometer
Pycnometer + Pycnometer
(We), 0.0005g
Water (Wo),
+ Solution
0.0005g
(W),
0.0005g
Trial 1
0.1875
18.0121
44.3913
44.7654
0.375
18.0121
44.3913
45.0717
0.75
18.0121
44.3913
45.5991
3
18.0121
44.3913
47.3622
Trial 2
0.1875
20.1782
45.2379
45.5971
0.375
20.1782
45.2379
45.8745
0.75
20.1782
45.2379
46.3665
3
20.1782
45.2379
48.0155
Trial 3
0.1875
31.1210
55.8446
56.2091
0.375
31.1210
55.8446
56.4800
0.75
31.1210
55.8446
56.9554
3
31.1210
55.8446
58.5805

Weight of
Solution
(W-We), g

26.7533
27.0596
27.5870
29.3501
25.4189
25.6963
26.1883
27.8373
25.0881
25.3590
25.8344
27.4695

V.
CALCULATIONS
Table 2. Summary of Calculated Apparent Molal Volume Sodium Chloride Solution
Trial 1
Molarity
(M), M
0.1857

Density of
Solution (d),
g/cm3

Molality of
solution (m),
mol/g

Square root of
Molality,

Apparent
Molal Volume,

1000

1.0112

0.1875

0.4330

-17.0121

75.65232

0.375

1.0228

0.3747

0.6121

-10.1582

68.83938

0.75

1.0427

0.7509

0.8665

-2.4248

60.97833

1.1093

3.2120

1.7922
Trial 2

21.0823

35.06264

0.1875

1.011335

0.1874295

0.432931313

-17.8235

76.47552

0.375

1.022372

0.37483

0.612233629

-9.11894

67.77295

0.75

1.041947

0.7514203

0.866845036

-1.42531

59.9351

1.107556

3.2181739

1.793926958

21.67685

34.44168

0.1875

1.01174342

0.187353107

0.432843051

-20.00603538

78.69097

0.375

1.02266817

0.374719178

0.612143102

-9.910418237

68.58507

0.75

1.04183992

0.751501182

0.866891678

-1.281685636

59.78531

1.10737634

3.218793146

1.794099536

21.73680682

34.37917

Trial 3

Table 3. Summary of the Graphical Results of Apparent Molal Volume , Versus Square root of
Molality, m .
Slope,

y-intercept, o

Trial 1
27.36864417

Trial 2
27.8149729

Trial 3
29.05599647

-27.47029183

-27.4429

-29.285549

Table 4. List of Calculated Values of Partial Molal Volume of Water and NaCl at Different
Molality
Molality
(mj)

0
0.5
1
1.5
2

Trial 1
Partial molal
Partial
Volume of
molal
solvent
Volume of
water (V1)
solvent
water (V2)
18.069
-27.4703
17.98036202
10.74976
17.81829395
22.97808
17.60842357
32.3612
17.3598962
40.27153

Trial 2
Partial molal
Partial
Volume of
molal
solvent
Volume of
water (V1)
solvent
water (V2)
18.069
-27.4429
17.98233706
10.91316
17.8238802
22.869
17.61868618
32.04304
17.37569651
39.77711

Trial 3
Partial molal Partial molal
Volume of
Volume of
solvent
solvent water
water (V1)
(V2)
18.069
18.00279488
17.88174365
17.72498812
17.53935906

-29.28554944
10.48437644
19.6179
26.62629912
32.53465289