Download as doc, pdf, or txt
Download as doc, pdf, or txt
You are on page 1of 28

Set 1

HONG KONG DIPLOMA OF SECONDARY EDUCATION EXAMINATION

CHEMISTRY PAPER 1
(MOCK EXAMINATION)
Time allowed: 2 hours 30 minutes
This paper must be answered in English.

GENERAL INSTRUCTIONS
1. There are TWO sections, A and B, in this Paper. Section A carries 36 marks and Section B
carries 84 marks. You are advised to finish Section A in about 45 minutes and Section B in about
105 minutes.
2. Section A consists of multiple-choice questions in this question book, while Section B contains
conventional questions printed separately in Question-Answer Book B.
3. Answers to Section A should be marked on the Multiple-choice Answer Sheet while answers to
Section B should be written in the spaces provided in Question-Answer Book B. The Answer
Sheet for Section A and the Question-Answer Book for Section B must be handed in
separately at the end of the examination.

SECTION A (MULTIPLE-CHOICE QUESTIONS)

INSTRUCTIONS FOR SECTION A


1. Read the instructions on the Answer Sheet carefully. Write your name, class and class number in
the space provided.
2. When told to open this book, you should check that all the questions are there. Look for the
words END OF SECTION A after the last question.
3. All questions carry equal marks.
4. ANSWER ALL QUESTIONS. You should use an HB pencil to mark all the answers on the
Answer Sheet, so that wrong marks can be completely erased with a clean rubber.
5. You should mark only ONE answer for each question. If you mark more than one answer, you
will receive NO MARKS for that question.
6. No marks will be deducted for wrong answers.

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
1

This section consists of two parts. There are 24 questions in PART I and 12 questions
in PART II.
Choose the best answer for each question.
Candidates may refer to the Periodic Table printed on the back of this Question Book.
PART I
1.

Which of the following reactions involve oxygen gas?


(1) Pop sound test of hydrogen
(2) Burning of petrol in car engine
(3) Corrosion of sodium metal

2.

A.

(1) and (2) only

B.

(1) and (3) only

C.

(2) and (3) only

D.

(1), (2) and (3)

Non-metal elements X and Y are in the same group of the Periodic Table. Element X
has a greater atomic number. Which of the following statements are correct?
(1) Atomic size of X is smaller than that of Y.
(2) X is less reactive than Y.
(3) X and Y have different physical properties.

3.

A.

(1) and (2) only

B.

(1) and (3) only

C.

(2) and (3) only

D.

(1), (2) and (3)

The table below shows the number of neutrons and the number of electrons in five
given atoms/ions:

Atom/ion
X
Y
Z2+
Q2
R+

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

Number of
neutrons
electrons
8
8
8
6
12
10
9
10
12
10

CHEMISTRY
2

Which of the following atoms is an isotope of X?

4.

5.

A.

B.

C.

D.

X, Y, and Z are three metals. X can be extracted from its oxide by carbon reduction and
Y can be extracted by direct heating of its oxide. Z cannot be extracted by such
methods. Which of the following statements is correct?
A.

Z is the least reactive one.

B.

Y is more reactive than X.

C.

Y should be discovered before Z.

D.

X is probably calcium.

Given three metals, X, Y and Z. The table below lists the results of their reactions with
different substances.
X

slow reaction

steady reaction

vigorous reaction

no reaction

steady reaction

no reaction

no reaction

Reaction with dilute


explosive reaction
hydrochloric acid
Reaction with
steam
Reaction with cold
water

Arrange the reactivity of X, Y, and Z in descending order.

6.

A.

X, Z, Y

B.

Y, Z, X

C.

X, Y, Z

D.

Z, Y, X

Which of the following substances contains the same number of ions as 2.340 g of
sodium chloride does?
(Relative atomic masses: Na = 23.0, Cl = 35.5, K = 39.1, Zn = 65.4, Ca = 40.1, S = 32.1,
O = 16.0, Mg = 24.3, Br = 79.9)
A.

2.984 g of potassium chloride

B.

3.125 g of zinc chloride

C.

3.598 g of calcium sulphate

D.

5.529 g of magnesium bromide

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
3

7.

An element forms a compound X2Cl3 which contains 25% by mass of chlorine. What is
the relative atomic mass of the element X?
(Relative atomic mass: Cl = 35.5)

8.

A.

39.9

B.

79.9

C.

106.5

D.

159.8

Car exhaust pipes made of iron rust rapidly. Which of the following are correct
reasons?
(1) The temperature of car exhaust pipes is high.
(2) Car exhaust contains water vapour.
(3) Car exhaust contains acidic gases.

9.

A.

(1) and (2) only

B.

(1) and (3) only

C.

(2) and (3) only

D.

(1), (2) and (3)

Two solutions were mixed in a beaker. The mass of the beaker and contents was then
noted at various times. The mass of the beaker and contents is plotted against time as
below.
Mass of the beaker and contents

Time
What could the two solutions be?
A.

Sodium chloride solution and iron(II) sulphate solution

B.

Potassium hydroxide solution and aluminium nitrate solution

C.

Potassium carbonate solution and dilute hydrochloric acid

D.

Dilute nitric acid and magnesium sulphate solution

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
4

10. Which of the following statements about all alkalis is/ are INCORRECT?
(1) They must contain metal ions.
(2) They produce hydroxide ions when dissolved in water.
(3) Their aqueous solutions turn red litmus blue.
A.

(1) only

B.

(2) only

C.

(1) and (3) only

D.

(2) and (3) only

11. The table below shows the observations of the chemical tests of three ionic
compounds.
Adding barium chloride
Adding dilute
solution acidified by
hydrochloric acid
dilute HNO3

Compound

Flame test

QT

White precipitate

No observable change

Brick-red

XZ

Colourless solution

Colourless gas
bubbles

Golden yellow

X2T

White precipitate

No observable change

Golden yellow

Which of the following combinations of ions involved is most likely to be correct?


X

A.

Potassium ion

Sodium ion

Carbonate ion

Sulphate ion

B.

Sodium ion

Calcium ion

Sulphate ion

Hydrogencarbonate ion

C.

Calcium ion

Sodium ion

Sulphate ion

Hydrogencarbonate ion

D.

Sodium ion

Calcium ion

Sulphate ion

Carbonate ion

12. After the addition of marble chips to an excess of dilute hydrochloric acid in a conical
flask, each of the following was measured and plotted against time on a graph.

Time(min)
HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)
Aristo Educational Press Ltd. 2011

CHEMISTRY
5

If the reaction was complete in 2.5 minutes, which of the following, when plotted
against time, would give a graph like the one shown above?
A.

Total mass of the conical flask and its contents

B.

Volume of carbon dioxide produced

C.

pH of the solution

D.

Temperature of the solution

13. Which of the following statements about the reaction of propane with bromine in an
organic solvent are correct?
(1) The reaction does not occur in darkness.
(2) The reaction is a substitution reaction.
(3) The colour of the reaction mixture fades.
A.

(1) and (2) only

B.

(1) and (3) only

C.

(2) and (3) only

D.

(1), (2) and (3)

14. Which of the following is the correct set of numbers which fits into the equation
aC4H8 + bO2 cCO2 + dH2O?
a

A.

10

B.

C.

D.

15. Consider the following compounds:

Compound X

Compound Y

Which of the following statements about the above two compounds is correct?
A.

Both compounds have the same boiling point.

B.

Both compounds can turn pH paper to red.

C.

Both compounds have the same molecular formula.

D.

Both compounds have the same odour.

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
6

16. Consider the simple chemical cell shown below.

silver electrode

iron electrode

electrolyte
Which of the following solutions should be used as an electrolyte in order to produce
the largest ammeter reading?
A.

0.3 M sulphuric acid

B.

0.5 M sulphuric acid

C.

0.3 M ethanoic acid

D.

0.5 M ethanoic acid

17. Which of the following statements concerning the reaction between chlorine gas and
dilute sodium hydroxide solution is/are correct?
Cl2(g) + 2NaOH(aq) NaCl(aq) + NaOCl(aq) + H2O(l)
(1) NaOH(aq) is an oxidizing agent in the reaction.
(2) Cl2(g) is an oxidizing agent in the reaction.
(3) Cl2(g) is a reducing agent in the reaction.
A.

(1) only

B.

(2) only

C.

(1) and (3) only

D.

(2) and (3) only

18. Which of the following statements concerning the hydrogen-oxygen fuel cells is/are
correct?
(1) They consist of three compartments separated from one another by two porous
nickel electrodes.
(2) The porous nickel electrodes can be replaced by graphite rods.
(3) Hydrogen is fed into the cathode compartment and oxygen is fed into the anode
compartment.
A.

(1) only

B.

(2) only

C.

(1) and (3) only

D.

(2) and (3) only

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
7

19. Which of the following statements concerning the electrolysis of concentrated sodium
bromide solution using graphite electrodes are correct?
(1) The main product at the anode is O2(g).
(2) H+(aq) ions are preferentially discharged at the cathode to form H2(g).
(3) The solution becomes sodium hydroxide solution after electrolysis.
A.

(1) and (2) only

B.

(1) and (3) only

C.

(2) and (3) only

D.

(1), (2) and (3)

20. The reaction between zinc and dilute hydrochloric acid is carried out in two different
conditions respectively. One reaction is carried out in a stoppered flask, which is
regarded as a closed system. The other is carried out in a flask without a stopper, which
is regarded as an open system. Which of the following statements concerning the two
reactions are correct?
(1) The pressure increases in the closed system.
(2) The change in internal energy of the reaction in the open system is smaller than
that in the closed system.
(3) The heat change of the reaction in the open system is smaller than that in the
closed system.
A.

(1) and (2) only

B.

(1) and (3) only

C.

(2) and (3) only

D.

(1), (2) and (3)

21. Given that:


H c [C2H2(g)] = x kJ mol1
H c [H2(g)] = y kJ mol1
H c [C2H6(g)] = z kJ mol1
Calculate the standard enthalpy change of the following reaction:
C2H2(g) + 2H2(g) C2H6(g)
A.

x + 2y z

B.

x+yz

C.

2xy z

D.

z x 2y

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
8

22. Which of the following concerning the enthalpy change cycle shown below are
correct?
C2H4(g) + H2(g)
+ 3O2(g)

C2H6(g)

+O2(g)

+O2(g)
H 3

H 2

H 1

2CO2(g) + 3H2O(l)
(1) H = H 1 + H 2 H 3
(2) H 1 = H c [C2H4(g)]
(3) H = H c [C2H4(g)] + H c [H2(g)] H c [C2H6(g)]
A.

(1) and (2) only

B.

(1) and (3) only

C.

(2) and (3) only

D.

(1), (2) and (3)

Directions:

Each question below (Questions 23 to 24) consists of two separate statements.


Decide whether each of the two statements is true or false; if both are true,
then decide whether or not the second statement is a correct explanation of
the first statement. Then select one option from A to D according to the
following table:

A. Both statements are true and the 2nd statement is a correct explanation of the 1st
statement.
B. Both statements are true and the 2nd statement is NOT a correct explanation of the 1st
statement.
C. The 1st statement is false but the 2nd statement is true.
D. Both statements are false.
1st statement

2nd statement

23. Ammonium chloride is not an


electrolyte.

Ammonium chloride is made up of nonmetals only.

24. Polyethene can be softened by


heating and hardened by cooling.

Polyethene is an addition polymer.

END OF PART I

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
9

Part II
25. Which of the following exist in liquefied HF?
(1) Hydrogen bond
(2) Dispersion forces
(3) Covalent bond
A.

(1) and (2) only

B.

(1) and (3) only

C.

(2) and (3) only

D.

(1), (2) and (3)

26. Some marble chips are mixed with excess dilute hydrochloric acid in a stoppered
conical flask. The flask is placed on an electronic balance to determine its mass. The
mass of the reaction mixture is measured at regular time intervals. Which of the
following graphs represents the rate of the reaction?
A.

B.

Reading of
the balance

Reading of
the balance

Time

Time
C.

D.

Reading of
the balance

Time

Reading of
the balance

Time

27. 20 cm3 of ethane (C2H6) are burned with 95 cm3 of oxygen to give carbon dioxide and
water as the only products. What is volume of oxygen unreacted?
(All volumes are measured at r.t.p.)
2C2H6(g) + 7O2(g) 4CO2(g) + 6H2O(l)
A.

20 cm3

B.

25 cm3

C.

55 cm3

D.

75 cm3

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
10

28. Consider the following equilibrium:


SO2Cl2(g)

SO2(g) + Cl2(g)

In an experiment, 13.5 g of SO2Cl2(g) was introduced into a 4 dm3 container and


allowed to reach equilibrium with SO2(g) and Cl2(g). At equilibrium, 0.069 mol of
Cl2(g) was found in the reaction mixture. What is the equilibrium constant of the
reaction?
(Relative atomic masses: S = 32.1, O = 16.0, Cl = 35.5)
A.

0.0384 mol dm3

B.

0.0768 mol dm3

C.

2.23 mol dm3

D.

3.34 mol dm3

29. Consider the following equilibrium system:


N2(g) + 3H2(g)

2NH3(g)

H = ve

Which of the following changes will occur if the temperature of the system increases at
constant pressure?
(1) The equilibrium position will shift to the left.
(2) The value of Kc will increase.
(3) The yield of NH3(g) will decrease.
A.

(1) and (2) only

B.

(1) and (3) only

C.

(2) and (3) only

D.

(1), (2) and (3)

30. Which of the following compounds has/have a pair of geometrical isomers?


(1) CH3CH=CH2
(2) CH3OCCH=CHCOCH3
(3) CH2BrCH=CHCH2Cl
A.

(1) only

B.

(2) only

C.

(1) and (3) only

D.

(2) and (3) only

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
11

31. Which of the following statements concerning the compound below are correct?

(1) It has no reaction towards acidified potassium dichromate solution.


(2) It can react with lithium aluminium hydride in dry ether, followed by dilute
hydrochloric acid to give

.
(3) It is optically inactive.
A.

(1) and (2) only

B.

(1) and (3) only

C.

(2) and (3) only

D.

(1), (2) and (3)

32. Which of the following products are formed when peanut oil is boiled with sodium
hydroxide solution?
(1) Propane-1,2,3-triol
(2) Soapy detergents
(3) Ester
A.

(1) and (2) only

B.

(1) and (3) only

C.

(2) and (3) only

D.

(1), (2) and (3)

33. Which of the following comparisons about aluminium oxide and silicon dioxide is
INCORRECT?
Al2O3

SiO2

A.

White solid at 25C

White solid at 25C

B.

Giant ionic structure

Giant covalent structure

C.

Reacts slowly with water

Do not react with water

D.

Amphoteric oxide

Acidic oxide

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
12

34. Which of the following statements concerning the reaction between KMnO4 and NaCl
in alkaline solution is correct?
A.

A brown precipitate is formed.

B.

KMnO4 acts as a catalyst.

C.

A brown gas is produced.

D.

The solution turns pale pink.

Directions:

Each question below (Questions 35 to 36) consists of two separate


statements. Decide whether each of the two statements is true or false; if both
are true, then decide whether or not the second statement is a correct
explanation of the first statement. Then select one option from A to D
according to the following table:

A. Both statements are true and the 2nd statement is a correct explanation of the 1st
statement.
B. Both statements are true and the 2nd statement is NOT a correct explanation of the 1st
statement.
C. The 1st statement is false but the 2nd statement is true.
D. Both statements are false.
1st statement

2nd statement

35. All hydrocarbons containing OH


groups are soluble in water.

Methane and ethane are insoluble in water


but methanol and ethanol are soluble in
water.

36. Although a catalyst will not be used


up in a reaction, it is regarded as a
reactant.

A reaction is always speeded up when a


catalyst is used in a reaction.

END OF PART II
END OF SECTION A

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
13

Set 1

Name

HONG KONG DIPLOMA OF SECONDARY EDUCATION


EXAMINATION

CHEMISTRY PAPER 1

Class
Class no.

(MOCK EXAMINATION)

SECTION B : Question-Answer Book B


This paper must be answered in English.

INSTRUCTIONS

Question
No.

(1) Write your name, class and class number in the


space provided on this page.

Marks

1
2

(2) Refer to the general instructions on the cover of


the Question Book for Section A.
(3) This section consists of TWO parts, Part I and
Part II. Part I carries 56 marks and Part II carries
28 marks. The marks to each question are
indicated in brackets at the end of the question.

3
4
5
6
7
8

(4) Answer ALL questions in each part. Write your


answers in the spaces provided in this QuestionAnswer Book. Do not write in the margins.
Answers written in the margins will not be marked.
(5) Supplementary answer sheets will be provided on
request. Write your name, class and class number,
fill in the question number. Tie them loosely but
securely with a string INSIDE this QuestionAnswer Book.

9
10
11
12
Total

(6) A Periodic Table is printed on the back of this


Question-Answer Book. Atomic numbers and
relative atomic masses of elements can be
obtained from the Periodic Table.

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
14

PART I
Answer ALL questions. Write your answers in the spaces provided.
1.

John dropped a piece of chalk into dilute hydrochloric acid. He found that gas bubbles
appeared immediately.
(a) What is the chemical name for chalk?

(b) Write a word equation for the reaction occurred.

(c) What is the gas formed? Suggest a test for the gas.

(d) A piece of chalk can be turned into a metal, a student claimed. Comment on his
statement.

(6 marks)

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
15

Consider the set-up as shown below.

Answers written in the margins will not be marked.

carbon rod

carbon rod
Answers written in the margins will not be marked.

2.

dilute hydrochloric acid


dilute hydrochloric acid

a gel containing copper(II)


ions and dichromate ions
(a) Explain why dilute hydrochloric acid is added to each side of the tube.

(b) Which colour slowly migrates towards the cathode? Which type of ions is
responsible for this colour migration?

(c) Which colour slowly migrates towards the anode? Which type of ions is
responsible for this colour migration?

(d) State the hazardous nature of dilute hydrochloric acid.

(e) If the carbon rods are replaced by wooden rods, what would happen?

(7 marks)

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
16

In an experiment to determine the concentration of ammonia solution, 25.0 cm 3 of the


ammonia solution was transferred into a conical flask and titrated against 0.1 M
sulphuric acid. A few drops of indicator were added. The titration results are listed in
the table below:
1
2
3
4
Final reading (cm3)
15.90
16.70
18.40
18.50
Initial reading (cm3)
0.00
1.50
3.10
3.40
(a) Which indicator is suitable for this titration?

(b) What will be the colour change of the indicator at the end point?

(c) (i)

Calculate the reasonable average volume of sulphuric acid used.

(ii) Calculate the molarity of the ammonia solution.

(d) Name the salt formed and suggest ONE common use of the salt.

(8 marks)

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
17

Answers written in the margins will not be marked.

Answers written in the margins will not be marked.

3.

5.8 g of a dry gaseous compound X (containing carbon and hydrogen only) were
completely burnt in excess dry oxygen. The products were passed through a suitable
drying apparatus containing anhydrous calcium chloride, and it was found that 9.0 g of
water had been formed.
(a) Calculate the mass of hydrogen in 9.0 g of water.

(b) Calculate the mass of carbon in 5.8 g of X.

(c) Find the empirical formula of X.

(5 marks)

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
18

Answers written in the margins will not be marked.

Answers written in the margins will not be marked.

4.

Consider the following organic molecules:

(a) Give the IUPAC name of C.

(b) Which of the above organic molecules can undergo addition polymerization?

(c) For those molecule(s) which can undergo addition polymerization, write the
equation for each reaction.

(d) Name the polymer made from C and give a daily use of the polymer.

(7 marks)

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
19

Answers written in the margins will not be marked.

Answers written in the margins will not be marked.

5.

Consider the simple chemical cell shown below.


digital multimeter
(as voltmeter)
flow of electrons

metal Y
electrode

metal X
electrode

sulphate solution
of metal X

Answers written in the margins will not be marked.

Answers written in the margins will not be marked.

6.

salt
bridge

nitrate solution
of metal Y

(a) Which metal is more reactive, X or Y? Explain.

(b) Which is the positive pole, metal X or Y?

(c) (i) How can a salt bridge be prepared?

(ii) State the main functions of the salt bridge.

(5 marks)

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
20

In an experiment, 20.0 cm3 of 1.0 M HCl solution at 25C was added to 10.0 cm3 of 1.0
M Na2CO3 solution at 25C in an expanded polystyrene cup with stirring. The highest
temperature recorded after mixing was 40.0C.
(a) Write the equation for the reaction between HCl(aq) and Na2CO3(aq).

(b) State TWO observations during the experiment.

(c) Calculate the enthalpy change of the reaction.


(Assume that the specific heat capacity and the density of the reaction mixture are
4.2 J g1 K1 and 1.0 g cm3 respectively.)

(d) The theoretical value of the enthalpy change of the reaction is greater than the
calculated value. Give TWO reasons for the difference.

(9 marks)

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
21

Answers written in the margins will not be marked.

Answers written in the margins will not be marked.

7.

Briefly describe some chemical methods of extracting metals from their ores,
illustrating with an example in each case. State the relationship between the position of
a metal in the reactivity series and its extraction method.
(9 marks)

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
22

Answers written in the margins will not be marked.

Answers written in the margins will not be marked.

8.

Answers written in the margins will not be marked.

Answers written in the margins will not be marked.

END OF PART I

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
23

PART II

9.

A certain amount of solid ammonium hydrogensulphide is placed in a sealed flask


already containing 0.60 mol dm3 of ammonia gas at room temperature. It dissociates
as follows:
NH4HS(s)

H2S(g) + NH3(g)

At equilibrium, the concentration of ammonia gas is found to be 0.87 mol dm3.


(a) Write the expression for the equilibrium constant, Kc, for the above dissociation at
room temperature.

(b) Calculate the equilibrium constant for the above dissociation at room temperature
and state its unit.

(c) If the volume of the flask used was doubled, calculate the equilibrium
concentration of ammonia gas.

(10 marks)

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
24

Answers written in the margins will not be marked.

Answers written in the margins will not be marked.

Answer ALL questions. Write your answers in the spaces provided.

(a) Draw the synthetic route with the corresponding intermediates, reagents and
conditions required for each step.

(b) Ethanol obtained is further heated with propanoic acid to form an ester.
(i) State the reagent and condition required for the esterification.

(ii) Identify the ester formed.

(c) The percentage yields for step 1, step 2 and step 3 are 70%, 67% and 42%
respectively. What is the overall percentage yield?

(7 marks)

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
25

Answers written in the margins will not be marked.

Answers written in the margins will not be marked.

10. Ethene can be converted to ethanol in a two-step synthesis.

(4 marks)

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
26

Answers written in the margins will not be marked.

Answers written in the margins will not be marked.

11. An industrial chemist who works for a firm which manufactures ethyne (C 2H2)
discovers a very cheap way of producing ethyne. Unfortunately, the ethyne is
contaminated with ethene. Unless the mixture contains at least 50% by volume of
ethyne, it is useless. In order to determine the relative proportions of the two gases in
the mixture, he exploded 10.0 cm3 of the mixture with 30.0 cm3 of oxygen. After
absorbing the residual CO2 with KOH, the unreacted O2 occupied 2.0 cm3. Calculate
the composition of the mixture by volume.

(a) (i)

Sulphur dioxide and sulphur trioxide are oxides of sulphur. Draw their
structures.

(ii) Write a balanced equation for the conversion of sulphur dioxide to sulphur
trioxide. Give the name of the catalyst used.

(iii) State the colour of SO2.

(b) (i)

Draw the structure of dichlorine oxide.

(ii) State the colour of dichlorine oxide.

(7 marks)
END OF PART II
END OF SECTION B

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

CHEMISTRY
27

Answers written in the margins will not be marked.

Answers written in the margins will not be marked.

12. Answer the following questions:

HKDSE CHEMISTRY Mock Exam Paper 1 (Set 1)


Aristo Educational Press Ltd. 2011

28

CHEMISTRY

Answers written in the margins will not be marked.

Answers written in the margins will not be marked.

You might also like